Risk and exposure assessment for subsurface environment is very important for both aspects of health and environmental protection as well as making decision of remedial goal for engineering activities. Exposure due to hazardous chemicals in the subsurface environment is essential to assess risk lev121 to individual person, especially from soil and groundwater environmental media. In this paper, the status of soil and groundwater contamination is presented to discuss on the problem for environmental risk assessment. The methodologies of fate and exposure models are also discussed by conducting the case studies of exposure assessment for heavy metals, organic compounds, and dioxin compounds. In addition, the structure of exposure models and available data for model calculation are examined to make clear more realistic exposure scenarios and the application to the practical environmental issues. Three kinds of advanced remediation techniques for soil and groundwater contamination are described in this paper, The most practical method for VOCs is the bio-remediation technique in which biological process due to consortium of microorganisms can be applied. For more effective remediation of soil contaminated by heavy metals we have adopted the soil flushing technique and clean-up system using electro-kinetic method. We have also developed the advanced techniques of geo-melting method for soil contaminated by DXNs and PCB compounds. These techniques are planed to introduce and to apply for a lot of contaminated sites in Japan.

We consider influences of the aperture variation and the ambient groundwater flow on the migration of DNAPL within a fracture network. In context of a modified invasion percolation (MIP) growth algorithm, we formulate a mechanistic model that includes capillary and gravity forces as well as viscous forces within the DNAPL and the ambient groundwater. The MIP model is verified against laboratory experiments, which is conducted using a two-dimensional random fracture network model. The results show that the aperture variation and ambient groundwater flow can be significant factors controlling DNAPL migration path within fracture networks.

We carried out rock pneumatic fracturing test which to increase groundwater yield by injection of highly pressured air in artificially under the surface every four borehole. The result of test performing shows that effect of increasing groundwater was not found in three testhole around igneous and metamorphic formation area, but we can realized that about 15 percent increased wateryield appeared in number P-5 test hole at sedimmentary rock formation.

Three kinds of experiments were conducted to test existing methods and develop an effective methodology for the remediation of DNAPL trapped in vertical dead-end fractures. A water-flushing method failed to remove TCE from vertical dead-end fractures where no fluid flow occurs. A water-flushing experiment implies that existing remediation methods, utilizing water-based remedial fluid such as surfactant-enhanced method, have difficulty in removing DNAPL trapped from the vertical downward dead-end fractures, because of no water flow through dead-end fractures, capillary, and gravity forces. Fluid denser than TCE was injected into the fracture network, but did not displace TCE from the vertical dead-end fractures. Base(B on the analysis of the experiments, the increase in the density of the dense fluid and the addition of surfactant to the dense fluid were suggested, and this composite dense fluid with surfactant effectively removed TCE from the vertical dead-end fractures.

제주도 동부지역에 위치한 심부관측정(해수면 하 60m 이상 착정) 11개소를 대상으로 2001 년 11월부터 2002년 10월까지 1년간 담.염수 경계면의 분포와 변화에 대하여 조사를 실시하였다. 담.염수 경계면의 두께는 대체로 해안에서 내륙 쪽으로 향함에 따라 두터워지는 경향을 나타냈고, 해안에서 6~6.kmm 이상 지역에는 담.염수 경계면을 갖는 기저지하수체가 발달하지 않는 것으로 조사되었다. 또한, 담.염수 경계면은 조석의 영향에 의해 1일 동안 최대 8.1m, 최소 0.14m의 변화를 나타냈으며, 계절에 따라서는 최대 33.2m, 최소 2m의 수축 및 확장을 일으키는 것으로 조사되었다. 조석과 계절에 따른 담.염수 경계면의 수축과 확장의 폭은 조사대상 관측정의 위치, 지하지질, 강우량 등의 여러 가지 요인에 의해 좌우되고 있는 것으로 해석되었다.

동위원소희석법에 의한 열이온화 질량분석법 (ID-TIMS)을 이용하여 지하수내 희토류원소의 함량을 측정하였다. 희토류원소의 분리에는 철공침법과 양이온교환수지에 의한 컬름분리법을 이용하였다. 경희토류(La-Eu)와 Gd, Dy, Er의 경우 수-수십 ppt의 수준에서 1%이내의 오차범위를 측정되어졌으며, 중희토류 중 Yb와 Lu은 정확도가 다소 떨어진 10% 전후에서 측정되었다. 지하수내 함량을 운석으로 규격화한 결과, 경희토류가 부화되었고 중희토류는 결핍되었으며 Eu의 이상은 거의 존재하지 않는다. 특히 경희토류에서는 M-type의 테트라드효과, 중희토류에서는 W-type의 테트라드효과가 관찰되었다. 이는 희토류원소의 수화수와 밀접한 관련이 있는 것으로 사료된다.

This study applied a hydrogeological field survey and isotope investigation to identify source locations and delineate pathways of groundwater contamination by nitrogen compounds. The infiltration and recharge processes were analyzed with groundwater-level fluctuation data and oxygen-hydrogen stable isotope data. The groundwater flow pattern was investigated through groundwater flow modeling and spatial and temporal variation of oxygen isotope data. Based on the flow analysis and nitrogen isotope data, source types of nitrate contamination in groundwater are identified. Groundwater recharge largely occurs in spring and summer due to precipitation or irrigation water in rice fields. Based on oxygen isotope data and cross-correlation between precipitation and groundwater level changes, groundwater recharge was found to be mainly caused by irrigation in spring and by precipitation at other times. The groundwater flow velocity calculated by a time series of spatial correlations, 231 m/yr, is in good accordance with the linear velocity estimated from hydrogeologic data. Nitrate contamination sources are natural and fertilized soils as non-point sources, and septic and animal wastes as point sources. Seasonal loading and spatial distribution of nitrate sources are estimated by using oxygen and nitrogen isotopic data.

제주도 동부지역에 설치한 심부관측정과 지하수 개발공에 대한 시추코아 지질검층, EC 및 수온검층, 지하수위 관측, 수질조사 등의 자료를 기초로 이 지역의 지하지질 분포와 지하수 부존특성에 대해 해석을 실시하였다. 제주도 동부 해발 200m 이하지역은 평균 해수면 하 90~120m 깊이까지 투수성이 좋은 용암류 누층으로 이뤄져 있으며, 일부지역에서는 서귀포층 상부에 유리쇄 설성 각력암층(hyaloclastite breccia)이 두껍게 분포하고 있어 담수지하수의 확산과 해수의 유입이 잘 일어날 수 있는 지질상태를 이루고 있다. 특히 서귀포층은 G-H비에 의한 담.염수 경계면 분포 깊이보다 깊은 위치에 존재하고 있어 제주도 서부지역에서처럼 담수지하수를 저류 해주는 역할을 기대하기 어려운 것으로 판단된다. 제주도 동부지역 지하수체는 수직적으로 담수지하수, 저염지하수, 염수지하수로 구분할 수 있으며, Ghyben-Herzberg 원리가 적용되는 담수렌즈(기저지하수) 두께는 일반적인 G-H비 보다 훨씬 얇은 평균 1:20의 비율을 나타냈다. 담수렌즈는 대체로 해안으로부터 내륙쪽 8km 지역까지 광범위하게 발달하고 있으며, 담수렌즈 포장량은 822백만톤(공극율 5%)에서 1,970백만톤(공극율 12%)의 범위로 추정되었다.

SF$_{6}$ (Sulfur Hexafluoride) is a gaseous compound whose use is being greatly increased recently. The compound has a negligible background concentration from natural sources and is stable in most of groundwater environments. Therefore, SF$_{6}$ has potential for a dating tool for young groundwater. It has many advantages over chlorofluorocarbons (CFCs) for groundwater investigation that sampling procedure is much simpler than CFCs and its growth is continued up to at least near future in the atmosphere. However, solubility of SF$^{6}$ is so low that excess air causes large uncertainties in recharge date of groundwater. To compensate the limitation, $N_2$/Ar method can be employed to estimate excess air content. A groundwater study is currently carrying out in Jeju Island using SF$_{6}$ as an environmental tracer, Well waters and spring waters were sampled for SF$_{6}$ and $N_2$/Ar. To establish SF$_{6}$ input history in the study area, air sampling is being conducted in the area near the center of the island on a monthly and weekly basis. Based on the present data, the level of SF$_{6}$ concentration in the atmosphere of the Island is corresponding to the trend of the Northern Hemisphere.

일반세균, 질산성질소, 탁도로 오염된 지하수 관정의 2개공에 대해 수질개선을 시행하였다. 그 결과 2개공 모두 음용수 기준에 적합한 수질개선 효과를 가질 수 있음으로 하여 수질오염 발생의 주요 요인 중의 하나가 지하수 지표하부 오염방지 시설인 그라우팅이 부실함으로써 기인함을 규명할 수 있었다. 따라서, 본 연구를 통해 수질이 오염된 지하수 관정의 수질개선이 가능하다는 확인은 물론 또한, 지하수 관정내 지표수의 유입을 방지하기 위해서 지하수 상부오염방지 시설의 설치가 적극적으로 추진되어야 할 것이다. 지하수 오염을 예방하기 위해서는 지하수 개발 단계에서부터 지하수 지표하부 오염방지 시설이 연암 암반층까지 견실하게 적용되어져야 한다는 것을 확인할 수 있었다.

강원도 춘천시 신북읍 유포리 연구지역의 지하수의 NO$_3$-N 2차원 공간 분포를 정의하기 위하여 지구통계학적 해석 방법인 sequential Gaussian simulation(SGS)을 이용하였다. 원자료의 공간적 clustering을 제거하기 위하여 cell declustering을 수행한 후 normal score 변환을 거친 후 variogram 분석과 모델링을 수행하였다. Exponential, gaussian, spherical variogram model에 대한 각각의 nugget, range, sill을 정의하여 SGS에 이용하였다. SGS에 의해 도출된 결과들은 모두 동일한 결과를 나타낸다. 또한 관측 자료의 분포와 주 오염원의 분포와 상응하는 모델링 결과를 나타내는 것으로 보아 SGS를 이용한 농촌지역 지하수내 NO$_3$-N의 공간적 오염 분포 영상화가 매우 유용하게 활용될 수 있을 것으로 판단된다.

GIS의 공간분석 기법을 이용하여 지하수가 집중적으로 개발.이용되고 있는 지역을 지하수 보전구역으로 설정하기 위한 연구를 제주도를 대상으로 실시하였다. 제주도 전역을 250 $\times$ 250m 간격으로 그리드를 작성한 후 각 그리드 격자점을 중심으로 반경 500m 내의 지하수 관정밀도, 지하수 이용량 및 개발량을 GIS 공간분석 기법을 활용해 분석하였다. 그 후 지하수 관정 밀도, 지하수 개발량, 이용량을 전체 자료 분포를 고려해 일정 구간으로 구분하고, 그 각각에 대해 계급값을 부여한 후, 3개 인자에 대한 계급값을 이용하여 중첩분석한 결과, 반경 500m 내의 지하수 관정밀도 평균 4공 이상, 지하수 개발량 평균 1,352m$^3$/일 이상, 지하수 이용량 평균 1,138m$^3$/일 이상 되는 지역을 지하수 보전구역으로 지정해 관리하는 것이 타당하다는 결론을 얻었다.

Sampling of waters from each stage of treatment system, SAPS (Successive Alkalinity Producing System), and spring water near the Hanchang coal mine of Kangwon. Province were carried out periodically and analyzed to evaluate the source and possible path of groundwater contamination by acid mine drainage(AMD). Chemical and sulfur isotope compositions showed that spring water was affected by seepage from mine tailings, and seepage of stonewall, a part of treatment system, was affected by both seepage from mine tailings and mine adit drainage. Through the treatment system no appreciable decrease of sulfur content was identified. And almost similar sulfur isotope compositions of water from each stage of the treatment system may suggest incomplete or very poor sulfate reduction by sulfate reducing bacteria.

Since 1995, MOCT(Ministry of Construction and Transportation) and KOWACO(Korea Water Resources Corporation) have established the National Groundwater Monitoring Network in South Korea and also MOE(Ministry of Environment) has operated Groundwater Quality Monitoring network. Until 2001, 202 monitoring stations by MOCT and 780 monitoring wells by MOE have been constructed, measured groundwater level and analyzed water samples. Groundwater quality analysis has been conducted two times a year during last 6 years for all monitoring wells. The quality data has about 15 components including pH, COD, Count of Coliform group, and etc.. Trend analysis has been peformed for 6 components(Coliform, pH, COD, NO$_3$-N, Cl and EC) of water quality which are analyzed more than 7 times for total monitoring wells. Two test methods have been used ; Sen's test and Mann-Kendall test. These trend tests have been done at the 0.05 significance level. By the result of Sen's test, Count of Coliform group has either upward or downward trends at 4.3 percent of the monitoring points. pH does at 5.6 percent, COD does at 8.6 percent, Nitrate-Nitrogen does at 13.2 percent, Chloride does at 13.4 percent, and. EC does at 11.6 percent of the monitoring points. The exact causes of the groundwater quality trends are difficult to specify. Notable downward trends in nitrate at many monitoring points may be the result of reduction on some contamination sources. Potential causes include diminished agricultural areas, improvements in sewage treatment and a decrease in atmospheric deposition. Increase in chloride at many monitoring points may be the result of increased non-point source pollution such as road salting and runoff from sprawling paved developments and suburbs.

Lineament density maps can be used for the quantitative evaluation of relationship between lineaments and groundwater occurrence. There are several kinds of lineament density maps including lineament length density, lineament cross-points density, and lineament counts density maps. This paper reports the usefulness of the representative elementary area (REA) concept for lineament analysis. This concept refers to the area size of the unit circle to calculate the lineament density factors distributed within the circle: length, counts and cross-points counts. The circle is a unit circle that calculates the sum of the lineament length, lineament counts and the number of cross-points within it. The REA is needed to obtain the best representative lineament density map prior to the analysis of relation between lineaments and groundwater well yield or other groundwater characteristics. A basic lineament map for the Yongsangang-Seomjingang watershed of Korea, drawn from aerial black-and-white photographs of 1/20, 000 scale was used for demonstrating the concept. From this study, the conclusions were as follows: (1) the REA concept can be efficiently applied to the lineament density analysis and mapping, (2) for whole Yongsangang-Seomjingang watershed which has 6, 502 lineaments with an average lineament length of 3.3 km, the lower limits of each REA used for drawing the three density maps were about 1.77 $\textrm{km}^2$ (r=750 m) for lineament length density, 7.07 $\textrm{km}^2$ (r=1, 500 m) for lineament counts density, and 4.91 $\textrm{km}^2$ (r=1, 250 m) for lineament cross-points density, respectively, (3) the lineament densities are inversely proportional to the size of REA, and the REA can be calculated with this inversely linear regression model, (4) if the average lineament density values for the whole study area are known, the most accurate density maps can be drawn using the REAs obtained from each linear regression model, and (5) but critical attention should be paid to draw lineament counts density and lineament cross-points density maps because.

This study was conducted to evaluate in-situ bioremediation ability of Bioil-D, microbial material for oil degradation, at a gas station that had been treated by SVE system. TPH concentrations and total contaminated soil volume were rapidly decreased after Bioil-D treatment. The performance of Bioil-D was also estimated based on the observation of microbial population at the soil samples and $CO_2$ concentration produced at the extraction wells. The field study showed a successful work of Bioil-D.

Reduction of nitrate by zero valent iron (Fe$^{0}$ ) has been previously studied, but the proper treatment for the by-product of ammonium has not been reported. However, in terms of nitrogen contamination, ammonium may be regarded as another form of nitrogen contaminants since it can be oxidized to nitrate again under aerobic conditions. This study is focused on simultaneous removal of nitrate and its by-product of ammonium, with the ZanF (Zeolite anchored Fe), a product derived from zeolite modified by Fe(II) chloride followed by reduction with sodium borohydride. Batch experiments were performed without buffer at two different pH condition with ZanF, iron filing, Fe(II)-sorbed zeolite, and pure zeolite to estimate the nitrate reduction and the ammonium production. At higher pH, removal rate of nitrate was reduced in both ZanF and iron filings. ZnF removed 60 % of nitrate at initial pH of 3.3 with no production of ammonium, while iron filing showed equivalent production of ammonium to the reduced amount of nitrate. In terms of nitrogen contamination, ZanF removed about 60 % and 40 % at initial pH of 3.3 and 6, respectively, while iron filing presented negligible removal against total nitrogen including nitrate and ammonium.

A new monitoring system has been developed for in-situ and realtime measurement of ozone transport in unsaturated porous media using a fiber optic sensor. The calibration of the fiber optic transflection dip probe (FOTDP) system was successfully carried out at various ozone concentrations using a column with length of 30 cm and diameter of 5 cm packed with glass beads, which don't react with gaseous ozone. The breakthrough curves (BTCs) of ozone was obtained by converting the normalized intensity into ozone concentration. The FOTDP system reflected the ideal transport phenomena of gas phase ozone at various flow rates. The FOTDP system worked well for in-situ monitoring of gas phase ozone at various water saturations and in presence of SOM. However, the FOTDP system did not measure the ozone concentration at more than 70% water saturation.

Pollutants from industry, mining, agriculture, and other sources have contaminated sediments in many surface water bodies. Sediment contamination poses a severe threat to human health and environment because many toxic contaminants that are barely detectable in the water body can accumulate in sediment at much higher levels, the purpose of this study was to make convenient sampling method and optimal treatment of sediment for water quality improvement in reservoir or stream based on an evaluation of degree of contamination. Results for analysis of S-reservoir sediments were observed that copper concentration of almost areas were higher than the regulation of soil pollution (50 mg/1) for the riverbed. S-stream sediments were observed that copper, arsenic and TPH concentration of almost areas were exceeded soil pollution concerning levels for factorial areas. We used Remscreen(version. 1.0) program which is contaminated soil recovery program to select optimal treatment method of contaminant sediments. The result was shown in the order of Thermal Calcination > Excavation, Retrieval and Off-site Disposal(comparative less then contaminant) > Low Temperature Thermal Desorption + Solidification/Stabilization.

Immobilization behavior of methyl tert-butyl ether (MTBE) by various cyclodextrins(CDs) was studied to investigate the feasibility of MTBE removal using cyclodexrins. Even though MTBE has relatively low hydrophobicity and higher polarity compared to other organics, it was effectively immobilized by CDs. The immobilization isotherms was shown as a type of Freundlich isotherms, and the immobilization capacity of -CDs was the largest among natural COs. The initial apparent association constant for MTBE-CD complex follows the order : gamma = beta > methyl-beta > hydroxypropyl beta > alpha. These differences of the constants are related to the size of MTBE and CDs. The size of beta-CD and gamma-CD is large to encapsulate MTBE molecule into the cavity, which that of alpha-CB is too small to encapsulate MTBE.

Laboratory scale experiments on in-situ ozonation were carried out to delineate the effects of liquid phases, such as soil water and nonaqeous phase liquid (NAPL) on the transport of gaseous ozone in unsaturated soil. Soil water enhanced the transport of ozone due to water film effect, which prevent direct reaction between soil particles and gaseous ozone, and increased water content reduced the breakthrough time of ozone because of increased average linear velocity of ozone and decreased air-water interface area. Diesel fuel as NAPL also played a similar role with water film, so the breakthrough time of ozone in diesel-contaminated soil was significantly reduced compared with uncontaminated soil. However, ozone breakthrough time was retarded with increased diesel concentration, because of high reactivity of diesel fuel with ozone. In multiphase liquid system of unsaturated soil, the ozone transport was mainly Influenced by nonwetting fluid, diesel fuel in this study.

It is well known that the membrane separation process combined with surfactant micelle (micellar-enhanced ultrafiltration) or polyelectrolyte (polyelectrolyte-enhanced ultrafiltration) can remove heavy metals effectively. However, the environmental hazard of surfactant or polyelectrolyte remained in effluent is a serious disadvantage of these methods. In this study, humic substances (HS) were used as complexing agents for metal removal instead of synthetic chemicals. The HS are a sort of natural organic matters which are biodegradable and abundant in natural environment. And the functional groups such as carboxyl groups and phenols in HS can bind with the cationic radionuclides and form complexes. Therefore separation process using them will be more environmental-friendly. The effects of concentration of HS and pH on the removal of cobalt were investigated. The ultrafiltration process was applied to the separation of the cobalt - HS complexes from the aqueous stream. At the concentration of > 3 g/L of HS and pH of 6, over 95 % of cobalt was removed by regenerated cellulose membrane of molecular weight cut-off (MWCO) 3,000. As the concentration of HS increased, the removal of cobalt also was improved because of increase in biding sites (functional groups). The cobalt removal increased from 72.5 % to 97.5 % when pH increased from 4 to 8 at the concentration of 3 g/L HS because of increase in HS solubility and cobalt hydroxide precipitation. In the presence of NaCl, the removal efficiency of cobalt decreased.

폐광된 광산에 방치된 폐광석에 함유되어 있는 황화광물이 분해되어 다른 광물에 흡착되거나, 산화환경에 안정한 형태의 2차 광물로 침전 혹은 공침 되는가에 대한 연구는 광산복 원을 결정하는데 직접적인 지구화학적 자료로 활용될 수 있다. 따라서 이번 연구에서는 청양광산에 방치된 폐광석을 대상으로 XRD, SEM/EDS연구를 이용하여 산화작용으로 인한 황화광물 주변에 침전된 2차 광물에 대한 광물학적 연구를 수행하였다. 광물학적 연구 결과, 산화환경에서 황화광물의 산화작용으로 인하여 용출된 중금속 이온과 철과 망간 이온들은 침전(Fe, Mn, Pb), 공침 (Fe, Mn, As, Pb) 및 흡착(As, Cu, Pb, Zn) 등의 화학반응을 통하여 다시 고정화됨으로서, 현장에서 자연적으로 정화되고 있는 것이 확인되었다.

This study presents a mathematical model for simulating the fate and transport of a reactive organic contaminant degraded through cometabolism in dual-porosity soils during the in situ bioaugmentations. To investigate the effect of dual-porosity on transport and biodegradation of organic hydrocarbons, a bimodal approach was incorporated into the model. Modified Monod kinetics and a microcolony concept [Molz et at., 1986〕 were employed to represent the effects of biodegrading microbes on the transport and biodegradation of an organic contaminant. The effect of permeability reduction due to biomass accumulation on the flow field were examined in the simulation of a hypothetical field-scale in situ bioaugmentation. Simulation results indicate that the presence of the immobile region can decrease the bioavailablity of biodegradable contaminants and that the placement of microbes and nutrients injection wells should be considered for an effective in situ bioaugmentation scheme.

청양 및 서보광산에서 채취한 광미 및 오염된 토양에 대한 산성비를 고려한 용출실험 결과, 아연, 카드뮴 및 망간 pH 6.2-5.8, 철 pH 5.2-3.2, 코발트 pH 4.4-3.2, 구리 pH 3.2-3.0, 납과비소 pH3.0-3.5의 용출조건에서 최초로 각 원소의 용출이 발생하였다. 반응용액의 최종 pH5.0-1.5사이에서 용출되는 중금속은 이온교환형태 및 탄산염광물형태와 수반된 것이 용해된 것이다. 반응용액의 최종 pH1.5이하에서 용출되는 중금속은 철과 밀접하게 수반된 것으로 해석되었다. 청양광산과 서보광산의 광미가 pH2.0이하로 유지되는 경우가 발생한다면, 청양광산은 비소(최대 6,006$\mu\textrm{g}$/g), 아연(최대 2,503$\mu\textrm{g}$/g) 및 납(최대 29,638$\mu\textrm{g}$/g), 서보광산은 납(최대 2,258$\mu\textrm{g}$/g)과 111소(최대 874$\mu\textrm{g}$/g)의 오염확산이 크게 우려되며, 이 결과는 광미에 대한 환경복원이 필요한 것을 지시한다. 서보광산의 오염된 토양은 pH3.0까지의 산성비와 반응하는 경우에는 중금속의 오염확산이 거의 우려되지 않으며, pH3.0이하의 강산 용액과 반응한다면 아연의 오염확산이 우려된다.

The batch experiments showed that 0.515mM 4-chlorophenol and its oxidation intermediates could be totally decomposed within 60 minutes by 1g/L steelers' dust and 0.485mM hydrogen peroxide at pH 2.7. The rate constants in the simplified kinetic model proposed in this study were estimated by fitting to the experimental data obtained in $H_2O$$_2$/steelers' dust system. Using the estimated kinetic rate constants, the simulation of 4-chlorophenol, ferrous iron, hydrogen peroxide, and hydroxyl radical concentration was performed. The predicted concentrations of 4-chlorophenol and hydrogen peroxide corresponded to the actual concentrations.

Objectives of this research were to fractionate heavy metals in soil samples in the upper Okdong River basin and to assess the potential pollution index of each metal fraction. Soil samples were collected from cultivated land soils and analyzed for physical and chemical properties. pH of cultivated soils ranged from 5.2 to 7.6. Contents of total kelhaldal nitrogen and loss on ignition were in the ranges of 0.6∼2.5%, and 1.9∼12.9%, respectively. Heavy metals in the cultivated land soils were higher in the abandoned closed coal mine near field soils than those in the paddy soils. Total concentrations of metals in the cultivated land soils were in the orders of Zn > Pb > Ni > Cu > Cd, exceed the corrective action level of the Soil Environment Conservation Law and higher than the naturals were abundance levels reported from uncontaminated cultivated land soils. Mobile fractions of metals were relatively small compared to the total concentrations. Soil Pollution Assesment Index(SPAI) values of each fraction of metals were leveled from Non polluted to Moderately polluted based on total concentrations. SPAI values of mobil fractions were lower than those of immobile fractions. Results on metal fractions and SPAI values of the cultivated land soils indicate that field soils samples were contaminated with heavy metals and had potential to cause a detrimental effects on plants. A prompt countermeasure to prevent field soils in the abandoned closed coal mine near fields are urgently needed.

유럽의 여러나라들의 경우 토양내 중금속의 허용치는 그 사용 목적에 따라 다르게 책정되고 있으며 1999년에 제정된 독일의 새로운 토양보전법에서도 토양의 사용목적별로 중금속 허용치를 달리 정하고 있다. 여기서 중금속 농도를 측정하기 위한 방법으로는 DIN(독일 공업규격)에서 정하고 있는 증류수추출법과 왕수추출법이 채택되고 있다. 그러나 이 2가지 방법들은 토양의 중금속분석에서 가장 큰 factor로 작용하는 것이 pH인데 반하여 pH가 7인 증류수와 pH가 0인 왕수를 사용함으로써 실제환경에 적용하기에는 많은 무리수를 내포하고 있으며 차츰 적당치 못한 것으로 판명되고 있다. 실질적인 중금속의 유해성 여부는 토양에서의 그 중금속의 용해도와 유동성으로 결정되는데 강한 산성비가 내린다고 가정하였을 때 비의 pH가 약 4 정도이고 이 경우 식물 뿌리 부분의 pH는 5 정도가 되므로 pH를 기준으로 할 때 잠재적으로 유동가능한 중금속을 분석하는 데에는 pH 4.5 에서 EDTA 추출이 가장 적당하고 또한 이를 토대로 토양내 중금속 허용치를 정하는 것이 합리적이라고 하겠다. 그러나 EDTA는 pH 4에서 부분적으로 Proton과 결합되어 Metal Chelate로의 능력을 잃게 되고 또한 식물 뿌리의 중금속 흡착을 Simulation할 수 없어 불리한 점이 있다. 또한 EDTA는 분해기간이 길고 인체에 해롭다는 것이 알려지고 있어 점점 사용이 어려워지고 있다. 본 연구에서는 토양에 함유된 유동가능한 중금속농도분석을 보다 적절히 하기 위한 방법으로 EDTA와 같이 Carboxyl기가 결합된 고분자 자성체를 이용해 토양의 중금속을 분석하는 것을 제안하였고 분석을 위한 중금속 추출 시 토양시료와 증류수 그리고 고분자 자성체만을 사용하여 근본적으로 토양에서 유동 가능성이 있는 중금속만을 추출하였다. 분석실험은 토양의 Cd2+ 와 Pb2+를 대상으로 행하여졌으며, 여러 토양에서 추출 분석한 결과를 EDTA분석결과와 비교하였다. 실험결과, 중금속은 매우 신속하게 고분자 자성체와 결합하였고, 그 후 자성체를 외부 자장으로 모은 후 산으로 용해시키고, 결합된 중금속은 Graphite furnace AAS로 분석함으로써 빠르고 효율적으로 분석실험을 수행할 수 있음을 알 수 있었다. 한편, 실험에서 나타난 수치들을 비교 검토한 결과 토양 분석시 sandy soil에서는 자성체를 이용한 분석이 EDTA에 의한 방법보다 더 높은 추출도를 보인 반면, silt 함량이 많은 토양의 경우에서 EDTA분석에서 더 높은 중금속 추출도를 보였다.

Based on the transient finite difference solution of Richards' equation, an infiltration model is developed to analyze temporal variation of precipitation recharge in the region of monsoon climates. Simulation results obtained by using time series data of 20-year daily precipitation and pan evaporation indicate that a linear relationship between the annual precipitation and the annual recharge holds for the soils under the monsoon climates with varying degrees of the correlation coefficient depending on the soil types. A sensitivity analysis reveals that the water table depth has little effects on the recharge for the sandy soil, whereas, for the loamy and silty soils, rise of the water table at shallow depths causes increase of evaporation by approximately 100㎜/yr and a corresponding decrease in recharge. A series of simulations for two-layered soils illustrate that the amount of recharge is dominantly determined by the soil properties of the upper layer, although the temporal variation of recharge is affected by both layers.

연속주입추적자시험이 실시된 현장사이트의 규모는 4.5m$\times$4.5m$\times$6.0m 정도이다. 시험 사이트내에서 실시된 추적자시험은 주입공(Pl)에서 Rhodamine WT 50ppm 용액을 1.8$\ell$/min의 주입율로 6일 동안 연속적으로 주입함과 동시에 관측공(P2, P3, Il, I2, I3)에서 일정한 시간간격으로 지하수를 채수하여 추적자농도를 산출하였다. 시험결과, 지하수면 하부를 포함하는 관측공(P2, P3)의 최대추적자농도는 초기주입농도의 10% 정도이며, 지하수면 상부에 위치한 지하수공(Il, I2, I3)들에서의 최대추적자농도는 초기농도의 75% 정도로서 추적자의 농도차이가 상대적으로 매우 크게 나타났다. 본 연구에서는 자유면대수층내에서 포화대를 포함한 관측공과 비포화대만을 포함한 관측공에서의 수리분산특성에 대해 비교.분석한 결과, 오염물이 연속적으로 토양에 유입되는 경우 비포화대 구간에서는 이류기작에 의한 농도희석이 거의 없으므로 오염물농도가 매우 클 것으로 판단된다.

우리나라 서남해 도서지역의 암반대수층을 통한 해수침투 실태 파악과 합리적인 지하수 이용관리 계획을 수립하기 위하여 농림부와 농업기반공사가 운영중인 해수침투 관측망에 대한 대략적인 소개와 일부 지역의 운영 사례를 제시하였다. 강화도 숭뇌지역 운영사례에서는 2002년 1월 1일부터 11월 30일까지의 수위, 전기전도도, 수온 등 세 항목의 지하수 장기관측 결과와 전기전도도 검층, 변형된 단극배열 전기비저항 탐사 및 지하수 시료들의 이온분석 결과를 바탕으로 관측정의 해수유입 실태를 파악하였으며, 소유역에 대한 개략적인 해수침투 유형파악이 가능함을 확인하였다.

Fuel oxygenates, such as Methyl tertiary Butyl Ether (MTBE) is additive in gasoline used to reduce air pollution. Gasoline components and fuel additives can leak form underground storage tanks. MTBE is far more water soluble than gasoline hydrocarbons like BTEX then it travels at essentially the same velocity as groundwater. MTBE in drinking water causes taste and odor problems. Therefore, the purpose of the this study is to examine the ability of ground rubber to sorb MTBE form water. The study consisted of running both batch and column tests to determine the sorption capacity and the flow through utilization efficiency of ground rubber. The result of Column test indicate that ground tire rubber has on the 36% utilization rate. Finally, it is clear that ground rubber present an attractive and relatively inexpensive sorption medium for a MTBE. The Author thought that to determine the economic costs of ground rubber utilization, the cost to sorb a given mass of contaminant by ground rubber will have to be compared to currently accepted sorption media.

Recently, the pollution of soil and groundwater becomes a serious social problem, and geophysical exploration methods have been introduced as a remedial investigation method of subsurface. Digital technologies such as personal computer have revolutionized our ability to acquire large volumes of data in a short term, and to produce more reliable results for subsurface image. Also, color graphics easily visualizes the survey results in a more understandable manner, and it is widely used for not only characterizing the contaminated subsurface but also monitoring contaminant and remedial process. In this paper, electrical resistivity survey were carried out In order to understand characteristics of waste landfills, and the applicability of geophysical prospecting to site assessment of waste landfill was also tested. According to the result, electrical resistivity survey were effective in estimating distribution of the leachate plume.

The preliminary data from the application of the ultrasound to the degradation of TCE were shown. The first order degradation coefficients were are 0.0134 s$^{-1}$ and 0.0151s $^{-1}$ with saturating gas of air and argon, respectively. The pH of the solution went down to 3 and stabilized in each case.

Sing]e-well-push-pull tests were developed for use in assessing the feasibility of in-situ aerobic cometabolism of chlorinated aliphatic hydrocarbons (CAHs). The series includes Transport tests, Biostimulation tests, and Activity tests. Transport tests are conducted to evaluate the mobility of solutes used in subsequent tests. These included bromide or chloride (conservative tracers), propane (growth substrate), ethylene, propylene (CAH surrogates), dissolved oxygen (electron acceptor) and nitrate (a minor nutrient). Tests were conducted at an experimental well field of Oregon State University. At this site, extraction phase breakthrough curves for all solutes were similar, indicating apparent conservative transport of the dissolved gases and nitrate prior to biostimulation. Biostimulation tests were conducted to stimulate propane-utilizing activity of indigenous microorganisms and consisted of sequential injections of site groundwater containing dissolved propane and oxygen. Biostimulation was detected by the increase in rates of propane and oxygen utilization after each injection. Activity tests were conducted to quantify rates of substrate utilization and to confirm that CAH-transforming activity had been stimulated. In particular, the transformation of injected CAH surrogates ethylene and propylene to the cometabolic byproducts ethylene oxide and propylene oxide provided evidence that activity of the monooxygenase enzyme system, responsible for aerobic cometabolic transformations of CAHs had been stimulated. Estimated zero-order transformation rates decreased in the order propane > ethylene > propylene. The series of push-pu3l tests developed and field tested in this study should prove useful for conducting rapid, low-cost feasibility assessments for in situ aerobic cometabolism of CAHs.

As a part of our research project for in-situ bioremediation of nitrate contaminated. groundwater, screening studies to determine an effective electron donor (EO) and/or carbon source (CS) such as acetate, ethanol, formate, fumarate, lactate, and propionate were conducted. To evaluate the feasibility for the biological degradation of nitrate, soil microcosm studies using nitrate-contaminated soil and groundwater were performed. The nitrate removal percentage in the order from the highest to the lowest was: formate, fumarate, and ethanol > lactate > propionate. Essentially no nitrate consumption was observed In acetate-fed microcosms. The order of nitrate removal rate from the highest to lowest was fumarate, formate, lactate, ethanol, and propionate. These results suggest that fumarate and formate are promising EDs/CSs for in-situ bioremediation of nitrate - contaminated oxygenated groundwater.

A gas chromatography/mass spectrometric assay method was developed for the simultaneous determination of ethylene glycol monomethyl ether (EGME) and diethylene glycol monomethyl ether (DEGME) in spilled aviation fuels. Ethylene glycol monobutyl ether (EGBE) and ethylene glycol monoethyl ether (EGEE) were used as internal standard and surrogate, respectively. The sample preparation consists of back-extraction with 7 mL of methylene chloride after extraction of 50 mL of fuel with 2 mL of water. The extract was concentrated to dryness and dissolved with 100L of methanol and analyzed by CC-MS (SIM). The peaks had good chromatographic properties by using semi-polar column and the extraction of these compounds from fuel also gave high recoveries of 75 and 85 % with small variations for EGME and DEGME, respectively. Method detection limits were 1.3 ng/mL for EGME and 1.0 ng/mL for DEGME in spilled fuel. The method may be useful for fuel-type differentiation between kerosene and JP-8, which may originate from the storage tank.

Solubilization isotherms of 1-chlorobenzene (MCB) and 1, 2-dichlorobenzene (DCB) were investigated in ionic surfactant solutions such as sodium dodecyl sulfate (SDS), cetylpyridinium chloride (CPC), and dedecyltrimethylammonium chloride (DMAC). The solubilization extent of DCB was much higher than that of MCB because of the main driving force of solubilization Is hydrophobic interactions between chlorobenzenes and hydrophobic interior of ionic micelles and DCB is more hydrophobic than MCB. CPC showed highest solubilization capacity because of longest hydrophobic tails. Simultaneous solubilization of MCB and DCB decreased slightly the extent solubilization of both MCB and DCB because the solubilization locus in the micelles is same.

In this research analyzed the daily precipitation depths of 4 climatic stations in south eastern part of Korea. It aimed to present some indices for regionalization of the area. The items are frequency distributions of precipitation quantity and days and the longest days less than class limit set up by arithmetic differences. The regression analysis between class value and frequency show very good correlation coefficients better than 0.99 which are cubic equation for the precipitation, exponential equation for the precipitation days, and first degree equation for the longest day less than class limit.

본 연구는 운동장, 주차장, 도로측면, 보도, 기타 주거시설 등의 우수 차집시설에 사용되는 콘크리트 구조물의 침투능 확보를 위한 투수성 차집구조물 개발에 관한 것이다. 일반적인 차집시설(측구, 받이, 맨홀등)을 투수가 가능한 구조로 변경하여 우수의 침투를 발생시킴으로서 우수유출을 저감하고 지하수론 확보할 수 있다. 투수성을 확보하기 위하여 일반 차집시설의 콘크리트 구조체 벽면에 천공을 하고 천공된 측구내에 쇄석을 충진시켜 침투되는 우수의 수질도 개선할 수 있다. 본 제작방법은 별도의 침투소재를 사용하는 경우와 비교해 볼 때 경제성이 우수하며 동일시공방법과 규격으로 대체재로서 활용성이 높을 것으로 전망된다.

In the case of the remediation studies, push pull test is a more time and cost effective mettled than multi-well tracer test. It also gives Just as much or more information than the traditionally used methods. But the data analysis for the hydraulic parameters, there have been some defections such as underestimation of dispersivity, requirement for effective porosity, and calculation of recovery of center of mass to estimate linear velocity. In this research, Weibull distribution function is proposed to estimate the center of mass of breakthrough curve for Push pull test. The hydraulic parameter estimation using Weibull function showed more exact values of center of mass than those of exponential regression for field test data.

이 연구는 국내의 균열암반에 대한 지하수 유동 연구가 대수층이 등방이라는 가정하에 진행피고 있는 방법에서 벗어나 대수층이 이방성을 띤다는 가정하에 대수층의 수리적 이방성을 해석하는데 중점을 두었다. 수리시험은 30.91 $m^3$/day로 BH-1공에서 300분간 양수였으며, 각각의 관측공 BH-2, BH-3, BH-4, 및 BH-5공에서 시간에 따른 수위강하를 관측하였다. 수리시험에 의해 얻어진 시간별 수위강하 자료를 이용하여 Jacob(1950)의 직선법에 의해서 직선의 기울기(m)와 수위강하가 영이 되는 지점에서의 시간( $t_{0}$)을 계산하였다. 대수층의 수리학적 이방성 텐서 (tensor) 즉, 최대투수량계수텐서 ( $T_{ξξ}$)와 최소투수량계수텐서 ( $T_{ηη}$)를 산출하기 위해서 Stewart(1973)에 의해서 정립된 정규최소제곱(Ordinary least-square)방법을 적용하였으며, 이 방법은 관측공이 최소한 4개를 필요로 한다. 그 결과로, $T_{ξξ}$는 12.21 $m^2$/day이고 $T_{ηη}$는 10.47 $m^2$/day로 산출되었다. 최대투수량계수텐서의 방향은 Nl9.13$^{\circ}$E 이고 이방성율은 1.17로 산출되었다. BH-1공에서 수리시험시 대수층의 이방성은 등방성에 가깝게 표현되었다. 이는 연구지역 대수층이 다수의 균열에 의해서 수리적 상호연결성이 고루 분포된 것으로 판단된다.

For the purpose of finding out the distributions of groundwater uses, the effect of facilities on the parameter and the correlations among measurements, various statistical analysis were carried out with the data of groundwater quality measurements from January to December in 2002. 1. The rates of groundwater for drinking water were 10.5% in Yangcheon-Gu, 10.2% in Kangdong-Gu, and 9.9% in Eunpyung-Gu. The rates of other uses of groundwater were shown to be 58.1%(786 wells) for civil defense emergency, 22.1%(299 wells) for contamination-concerning, 9.8%(133 wells) for water quality monitoring, consisting of 90% of all groundwater. 2. The 52.6% of groundwater for drinking were demonstrated to be appropriate while 91.9% for tither uses-domestic, industrial, agricultural uses- were shown to be proper. 3. For drinking water, the average values of colar, turbidity, NH3-N, F, and Fe were 11.216 degree, 2.138 NTU, 2.458mg/l, 0.212mg/1 and 0.507mg/1 respectively. 4. In cases of drinking water wells for emergency, the results of statistical analysis showed that building year of the wells, depth and pumping rate didn't affect on whether it was proper for that use or not. It were shown that there were linear correlations between depth and NO$_3$-N(-0.171) and F￣(0.332) while the correlation coefficients were 0.381 and -0.169 between the building year of well and depth and pumping rate respectively.

본 연구는 울산지역 지하수오염 저감기술의 개발에 필요한 대수층의 공간적 분포특성을 파악하는 데 목적이 있다. 울산 공업도시의 대수층에서 공간적 분포특성을 파악하기 위하여 시추조사가 많이 필요 하지만 비용 및 시간 관계상 어려움이 있기 때문에, 지질조사 보고서나 논문 등에서 지하수자료와 시추 자료를 획득하여 지구통계기법을 이용한 울산지역 대수층의 공간적 분포를 모사하였다. 그리고 인구가 밀집되어 있는 남구와 중구를 중심으로 대수층 단면 분포를 모사하였다. 이와 같은 분석결과는 표토층 하부경계부와 풍화대 하부경계부에서 유사한 분포심도로 나타났으며, 지하수 수위는 표토층 하부경계와 암반층 상부경계부인 풍화대에 분포하는 것으로 나타났다.

밀양지역 지하수의 계절별 수위변동 특성을 파악하기 위하여 500여개 공을 대상으로 총3회 측정하였다. 봄에서 늦가을까지의 시기별로 측정된 현장지하수위 자료를 이용하여 밀양시 전역의 충적층 및 암반 대수층의 지하수위 등치선도를 작성하였다. 지구통계기법을 이용하여 작성된 밀양지역의 지하수위 등치선도는 계절별로는 큰 변동이 없었으나, 충적대수층과 암반대수층에서의 지하수위 분포양상은 다르게 나타났다. 계절적인 지하수위 변동이 약한 것은 밀양지역의 지하구는 대부분이 농업용수로 이용되고 봄과 가을에는 용수 사용량이 비슷하며, 여름에는 강수량은 맑지만 농업용수의 사용량이 증가하여 함양량이 크지 않기 때문이다. 대수층유형에 따른 지하수위는 암반대수층의 피압 정도와 충적 및 암반 지하수공들의 공간적인 분포 양상에 따라서 영향을 받고 있는 것으로 나타났다.

본 연구에서는 강원도 속초시 쌍천에 위치한 쌍천지하댐이 지하수흐름에 미치는 영향을 범용 지하수 흐름해석 프로그램인 MODFLOW를 사용하여 검토하였다. 먼저 지하댐이 설치되기 전인 초기 정상류 상태를 모의하여 수두 분포를 확인하였으며, 그 후 지하댐 설치 전의 정상류 상태를 수위를 초기 수두로 하여 지하댐이 설치된 후의 대수층의 지하수위 변화를 모의하였다. 모의 결과 대수층에 지하댐을 설치하면 지하댐을 설치하기 전에 비하여 지하수위가 약 0.4m 정도 상승하는 것으로 나타났다.

본 연구는 무주군 적상산 부근에 위치하는 소유역에서 지표수와 인접한 천층 지하수의 안정동위원소 조성의 시공간적 변화를 규명하기 위해서 시행되었다. 조사는 2001년 8월과 10월, 2002년 4월 세 차례에 걸쳐 수행되었다. 각 계절에 따라 지표수와 지하수의 안정동위원소 조성이 비슷하게 나타나는 것은 이 지역 지표수와 지하수사이에는 배수와 충진이 지속적으로 생기고 있음을 암시한다. 조사지역의 안정동위원소 조성은 북쪽에 위치하는 한강의 안정동위원소 조성보다는 무거우며, 남쪽에 위치하는 섬진강의 안정동위원소 조성보다는 가벼운 위도효과를 잘 나타내고 있다. 또한 시료를 채취한 가장 높은 지점과 가장 낮은 지점의 고도차가 400m인 작은 소유 역에서도 계절의 변화와 관계없이 안정동위원소의 고도효과는 잘 나타나고 있다. 선행된 연구에서 우리나라 강우가 우량효과를 반영하는 결과를 나타내는 것과 같이 강우의 영향을 직접 받는 8월 지표수의 안정동위원소 조성은 10월과 4월보다 더 가벼운 조성을 나타내고 있다.

충북 괴산군-보은군 일대를 따라 발달된 중부 옥천대의 구룡산층과 운교리층 분포지역에서, 기반암에 따른 지하수의 수질특성의 차이를 규명하고자 하였다. 2002년 11월에 18개 지점에서 지하수 시료를 채취하였고, 이를 분석하여 기반암에 따른 지하수의 수질을 분류하였다. 구룡산층 시료와 운교리층 시료 모두 Ca-(HCO$_3$+ CO$_3$) 유형의 수질특성을 보였다. 군집분석의 결과 기반암의 종류에 따라 수질특성이 나됨을 알 수 있었다. 수질 분석결과를 국내 먹는물 수질기준와 비교 하였을때, 질산성 질소 항목만 기준치를 초과하였다. 질산성 질소의 경우, 국내 먹는물 수질기준인 10 mg/L를 초과한 시료는 한 지점이었지만, 인간 활동에 의해 오염된 것으로 여겨지는 2 mg/L이상의 시료는 전체 18개 시료 중 61%인 11개 지점으로 나타나, 이 연구지역에서 인간활동에 의한 질산성 질소의 오염이 진행되고 있음을 추정할 수 있었다.

본 연구에서는 여러가지 해석해를 이용하여 균열암반 대수층에서 얻어진 양수시험자료를 해석하였다. 균열암반 대수층의 수리적 특성을 연구해 본 결과, 1.3차원에서 2.9차원까지 다양한 분포 차원을 나타나며, 양수시험 자료중 52%에 해당하는 자료가 1차원과 2차원 사이의 분할 유동차원을 보여준다. 이에 대하여 6.3%만이 Theis 이론에 맞는 2차원의 방사상 흐름을 보여준다 2∼3차원의 대수층이 암반대수층에서 나타나기는 어려우며, 만약 2차원 이상으로 해석되는 경우는 다른 방향으로 해석하는 것도 검토해야 한다. 즉, Leaky, constant head boundary, no flow boundary 등을 고려해야 한다.

The purpose of this study is to understand characteristics of stream and spring water and subsurface geologic structure in Seogwipo area. This study area is surrounded by various smaller parasitic volcanic cinder cones, tuff cones, strangely shaped basalt and trachyte rocks, beautiful waterfalls. The geologic structure in study area is classified into the Upper layer(volcanic rocks), Middle layer(SGF), Lower layer(UF), and Basement layer. The groundwater in Seogwipo area is classified into the Upper layer groundwater, Middle layer groundwater, Lower layer groundwater and Basement layer groundwater on the basis of the hydrostratigraphy structure.

In the Republic of Korea, Ministry of Construction & Transportation and Korea Water Resources Corporation manage the national groundwater monitoring network at the 169 stations and will organize the supplementary groundwater monitoring network at the 10,000 stations by 2011 year. The method that organizes the monitoring network was developed using the Analytic Hierarchy Process with pairwise comparison. Several estimation factors for the estimating every district were selected to reflect each district conditions. Their weighting value was decided by pairwise comparison and questions to the experts about groundwater The optimal number of groundwater monitoring well was calculated through the developed method. To verify this method, groundwater was monitored in Jeonju city by way showing the example. The study area In Jeonju city needs 7 stations for the supplementary groundwater monitoring network. The results monitored in 7 stations inferred the groundwater level around the study area by Kriging. The mean of residual between inferred groundwater level value from Kriging and actual groundwater level is rather low. Furthermore, the mean and standard deviation of residual between inferred groundwater level change and actual groundwater change is much lower. The Fact that 7 monitoring stations are sufficient for observing the groundwater condition in the study area makes it possible for suggested monitoring number to be proper.

물만 주입한 1군과 물-토양을 주입한 2군, 물-ORC를 주입한 3군, 물-토양-ORC를 전부 주입한 4군의 4개군으로 조건을 차별화하여 2$0^{\circ}C$ 항온 OER시험을 실시하였다. 1군은 약4mg/L, 2군은 3mg/L, 3군은 12~13mg/L, 4군은 11~12mg/L의 DO를 나타내었다. ORC를 투여하지 않은 1군과 2군은 2$0^{\circ}C$ 용존산소 포화선인 Bmg/L에 크게 못미치는 것으로 나타났고 ORC를 투여한 3군과 4군은 포화선보다 3~4mg/L 높은 수치를 나타내었다. 토양을 주입한 2군과 4군에서는 토양 미생물의 영향을 받아 DO가 감소하나 ORC를 투입한 4군에서는 그 영향이 미미하게 나타난다. TCE 분해능 시험은 15$^{\circ}C$에서 항온으로 30일간 시험하였다. 초기 농도 5000ppb가 30일 경과 후 약 4000ppb로 약20%의 분해율을 나타내었고, 메탄을 첨가했을 때 더 잘 분해됨을 보여주었다.

연구지역에 설치된 3개 관정에서 추적자시험 방법 중 단공 주입-회수시험을 실시하였다. Push-pull 추적자시험 자료 분석 결과 종분산지수는 0.086~0.657m의 값을 가지며(Pickens and Grisak, 1981), 지하수 유동속도는 9.07$\times$$10^{-4}$6.14$\times$$10^{-3}$m/min의 값을 보인다(Hall and other, 1991). 또한 계산된 종분산지수와 지하수 유속을 이용하여 종분산계수(3.77$\times$$10^{-4}$ ~ 9.53$\times$$10^{-4}$ $m^2$/min)를 산정하였다. 추적자의 거동특성이 크고 작음을 비교할 수 있게 하는 특성변수(Characteristic property)는 분산지수이므로, 분산지수의 크고 작음에 따라서 추적자의 거동특성이 달라짐에 주의해야 한다..

지하터널과 같은 대규모 지하구조물 건설시 구조물의 안정성을 확보하고 시공성 등의 실시 설계를 위해서는 그 지역의 수리적 매개변수를 파악하는 것이 필수적이다. 부산광역시 북서부에 위치한 금정산 화강암지역의 수리상수를 산출하기 위하여 야외시험과 실내시험을 수행하였으며, 각각의 결과를 서로 비교 분석하였다. 야외에서는 6개의 시추공에서 수압시험을 수행하여 심도 구간별 수리전도도를 구하였고, 실내시험에서는 시추코아를 이용하여 절리투수시험을 실시하여 수리전도를 산출하였다. 수압시험에 의해 산정된 수리전도도는 2.28E-10 m/sec∼1.49E-06 m/sec 이며, 절리투수시험에 의해 산정된 수리전도도는 1.16E-11 m/sec∼3.26E-05 m/sec이다.

충적층 지하수 개발이 활발히 이루어짐에 따라 철, 망간이 충적층 지하수를 이용한 취수원 확보 시에 정수처리의 주요관심대상이 되고 있다. 이에 본 연구에서는 기존 충적층 지하수의 개발이 이루어졌거나 검토되었던 지역을 중심으로 철, 망간의 분포특성을 고찰하여 보았다. 연구지역은 크게 금강권역, 낙동강권역, 영산-섬진강권역, 한강권역으로 나누었고, 조사 관정이 밀집된 권역들은 더 세분된 지구로 나누어 연구를 수행하였다. 철의 경우, 563개의 시료가 망간의 경우, 483개 시료가 수집 분석되었다. 수집된 충적층 지하수 시료들의 철, 망간 농도를 살펴보면, 철의 경우는 전체 조사 관정의 약 27%, 망간의 경우는 약 39%가 음용수 수질기준(WHO)을 상회하였다. 본 연구에서는 철, 망간의 분포특성을 고찰하기 위하여 철, 망간 농도에 대한 다양한 통계 분석을 수행하였다 수집 분석된 철의 산술평균 농도는 2.7ppm이며, 망간의 산술평균 농도는 0.4ppm로 이들 산술평균 역시, 모두 음용수 수질 기준을 상회하는 것으로 나타났다 그러나 철 및 만간 농도의 중간 값은 각 각 50 및 20 ppb이며, 실제 이들 농도가 기하학적 분포를 한다고 가정할 경우, 이들의 대표 값인 기하평균은 모두 먹는 물 수질기준을 만족하는 것으로 나타났다.

국내의 12개소 저산출 우물을 대상으로, 외국의 유정들에서의 산출량 증대를 위하여 많이 사용되고있는 인공수압파쇄 방법을 적용하여 산출성 증대 효과를 검증하였다. 12개소에 대하여 수압파쇄시험 전후로 양수 시험을 실시하여 투수성 증대 등의 효과와 비양수량을 정량적으로 평가한 결과, 비양수량의 경우 전체적으로 평균 약 45%의 증가하였으며 투수량계수 또한 약 26%가 증가하였다. 이러한 결과는 인공수압파쇄 방법이 대수층내 열극의 생성 혹은 확장 및 균열내의 막힘(clog) 물질 제거를 통해 투수성을 상당히 개선시킨 것으로 평가된다. 특히, 현재까지의 시험 결과, 퇴적암류 지역에서 보다 화성암류 지역에서의 시험 결과가 양호하게 나타났다. 화성암 지역에서 개발된 홍천에서의 사례를 볼 때, 고압의 주입을 통하여 상부 및 하부의 파쇄대가 확장 연결되고, 이들 파쇄 열극에 부착된 광물학적, 생물학적 막힘 물질이 제거되면서 산출성이 증대되는 것으로 나타났다.

To delineate the internal structures of alluvial aquifer, high resolution seismic and GPR methods were adopted in Buyeo Gunsu-Ri area. The result of seismic refraction survey shows the water table of the aquifer and the result of seismic reflection reveals the basement and somewhat dominant internal structures of alluvial aquifer. The internal heterogeneity due to variations in channel behavior can be delineated using GPR survey. GPR profiles for the point bar deposits near Buyeo county reveals two different stratigraphic units the lower inclined heterogeneous strata and the upper horizontally stratified strata. According to the increase of demand for water resource using artificial recharge in alluvium, it is believed that the information acquired by high resolution geophysical methods will have an important roles for the effective and sustainable development and usage of groundwater in alluvial aquifer.

제주도 전역의 88개소에서 측정한 양수시험자료를 분석하여 투수량계수를 산출하였으며, 투수량계수계수와 비양수량의 관계식을 산출하였다. 제주도의 화산암 대수층은 대체로 투수성이 크고 대수층의 상.하부로부터 상당량의 지하수가 공급되므로 누수피압대수층이 적합한 모델로 판단된다. 투수량계수는 0.405~1038.52m$^2$/d로서 넓은 범위에 걸쳐서 분포하며 이는 제주도 화산 암의 투수성이 지역에 따라 다양하다는 것을 의미한다. 비양수량(Q/s)-투수량계수(T) 관계식은 T = 0.582(Q/s)$^{0.974}$ 로 계산되었으며, 이 관계식은 지역적으로 투수량계수 산출이 불가능할 경우에 비양수량만으로 투수량계수를 추정하는데 이용될 수 있다.

광미와 오염된 토양에 함유되어 있는 중금속 원소는 존재형태에 따라서 환경에 미치는 영향의 차이가 있다. 그러므로 중금속 원소의 존재형태를 규명하여 물리화학적 환경변화에 따른 중금속의 거동을 예측하고자 Tessier et al. (1979)의 방법을 이용하여 연속추출을 수행하였다. 청양광산과 서보광산의 광미를 비교하면, As와 Co는 두 광산 모두 잔류형태로 안정화되었다. Cd과 Zn은 서보광산의 광미가 청양광산의 광미보다 잔류형태가 더 우세하였다. Pb는 서보광산의 광미가 양이온교환형태로 존재하는 함량이 높고 청양광산의 광미도 양이온교환과 탄산염광물의 형태로 존재하는 함량이 높아 오염 확산의 우려가 있다. 서보광산의 오염된 토양의 경우, As, Co, Cd, Cu및 Zn는 대체로 안정한 형태였으나, Pb는 산화환경에서 불안정한 형태로 존재하였다.

The purpose of this study was to assess the effect of surfactant on the rate of NAPLs(non-aqueous phase liquids) solubilization. The experimental variables were surfactant type, NAPLs type and water type. The main experimental designs were consists of two phases. The solubilization rate is sensitive to surfactant type based on this test. Used aqueous surfactants were solubilized and removed 72.77 to 89.90% of toluene, PCE(tetrachloroethylene) from the contaminated water during the test, respectively. T60 has higher and stable recovery ratio than SDS in surfactant type but, the micelle of the T60 is more weaker than that of SDS based on this study's results. And the solubilization rate in used water type was almost same.(deionized water, surface water).

Surfactant-enhanced electrokinetic (EK) remediation is an emerging technology that can effectively remove hydrocarbons from low-permeability soils. In this study, the electrokinetic remediation using Calfax 16L-35 was conducted for the removal of phenanthrene from kaolinite. An anionic surfactant Calfax 16L-35 was used at concentrations of 5, 15, and 30g/L to enhance the solubility of phenanthrene. When the surfactant solution was applied to EK system, low electrical potential gradient was maintained because of its ions. Even when the surfactant concentration was high, the removal efficiency of phenanthrene was low After the operation, most of surfactants were remained in soil and there were few in effluent. This phenomena was observed because the migration of Calfax 16L-35 from cathode to anode was predominant over electroosmotic flow which moved in opposite direction. Therefore, the anionic surfactant Calfax 16L-35 is considered to be improper in surfactant - enhanced electrokinetic remediation.

Removal of phenanthrene by electrokinetic method combined with Fenton-like process was studied in a model system. The scale of reactor was 120 cm in length, 10 cm in width, and 50 cm in height. Sand was selected as a model soil. Bentonite was filled in the space between reservoir and contaminated soil to control the flow rate of water. When constant voltage of 100 V was applied to this system, current varied from 1000 mA to 290 mA for 28 days. pH of anode and cathode reservoirs became to 2 and 13, respectively. Removal efficiency of phenanthrene was more than 60 %.

The overall objective of the adsorption study of arsenic was to elucidate the ability of iron coated sand(ICS), synthesized in the laboratory, to remove arsenic from polluted waters. Batch tests were conducted to provide a relation between arsenic removal and iron content of ICSs. The ICS, developed in the laboratory by coating iron onto the surface of ordinary sand by a simple and easy process has proved as an effective medium for use in removal of arsenic from waters over a wide range of particle sizes of ICS. The composite media is inexpensive to prepare and could serve as the basis of a useful arsenic removal process in variety settings.

This study explored the feasibility of applying Electrokinetic-Fenton process(EK-Fenton process) to remediation of contaminant sorbed on the soil possessed low-permeability. The addition of 0.01 N H$_2$SO$_4$ in the anode reservoir for the $H_2O$$_2$stabilization improved the stabilization of $H_2O$$_2$and the treatment effect of phenanthrene across the entire soil specimen. The use of $H_2O$$_2$and dilute acid as anode purging solution is a promising method treating of HOCs in low-permeability subsurface environments.

The feasibility of treating 2-chlorophenol (2CP) contaminated soils with ozone venting was investigated in this research. Adding ozone to the existing air-venting process provides an alternative to achieve a complete in-situ treatment by oxidizing the contaminant in the process. A column study with artificial soil was used to simulate the venting process. Ozone concentrations at 2.4, 7.6 and 19.4 mg/L, and flow rates at 100 and 150 mL/min were used. The reaction times were 10, 20, 50, and 60 minutes. Blank samples using air venting were also run for comparison. It is obvious that ozone-venting had a much faster removal rate than air-venting. As higher concentration of ozone is applied, the reaction rate increased significantly. As higher concentration was applied, the flux of ozone to the liquid film increased. This also increased the removal rate of 2CP and therefore the breakthrough curve came out earlier.

본 연구에서는 유류 오염 토양의 복원에 효율적인 것으로 나타난 Biopile 공법을 오염 토양에 적용하였을 경우, 토양의 생물학적 복원이 가능한지 여부를 평가하고자 하였다. 45일간 의 Biopile 실험 결과, 공기 주입 및 영양분 주입 후 TPH의 감소율이 최대 64.75 %까지 나타났다. 또한 공기만을 주입하였을 경우에도 제거율이 약 33 %를 나타내었다. TPH가 6,000 mg/kg인 인공 오염 토양을 사용하여 Biopile 공법을 적용하였을 경우에는 30일 반웅 후 43.46 %의 높은 제거율을 나타내었다. 오염 토양의 균주를 순화/분리 하였을 때 오염 토양 내에 고 활성의 유류 분해 미생물이 확인되었으며, 이들의 유전자 역시 확인되어 자체적으로 생물학적 분해능을 가지고 있는 토양으로 나타났다.

Recently, considerable researches have been focused to find out inexpensive sorbents. for removal of heavy metals in aquatic environments. In particular, various natural materials including geologic media have been attractive. In order to evaluate the applicability of the scoria taken from the Jeju island, Korea, to remove Zn(II) from aqueous solutions, the kinetic sorption experiments were performed in this study. The batch-type kinetic sorption tests were carried out under different conditions, such as different initial Zn(II) concentration, particle size of the scoria, and sorbate/sorbent ratio. The results indicated that the removal of Zn(II) by scoria increased with decreases in initial Zn(II) concentration, particle size of the scoria, and sorbate/sorbent ratio. However, the sorption capacity of the scoria decreased with increasing amount of the scoria. The sorption behavior of Zn(II) onto scoria seemed to be mainly controlled by cation exchange.

The technology removing radionuclides from soil using soil washing was studied. The main radionuclides contaminated in the soil are Cs$^{137}$ and Co$^{60}$ . It is suitable that scrubbing time is 4 hours and a mixing ratio of soil weight and washing solution volume is 1:10. more than two times continuous scrubbing method with 0.5 M oxalic acid was needed to remove Cs$^{137}$ and Co$^{60}$ from soil more than 70%. Radionuclides removal efficiencies of recycling washing solutions recycled with strong acid resins until 5 times are similar to that of 0.5 M oxalic acid.

Soils contaminated by hazardous hydrophobic organic compounds, such as polycyclic aromatic hydrocarbons (PAHs), have become a major environmental issue due to toxic and carcinogenic properties of those compounds. In this work, we investigated effects of various metabolic inducers on phenanthrene biodegradation. Biodegradation tests were peformed with two different Pseudomonads: Pseudononrdia hydrocarboxydans (Gram positive) and Pseudomonas putida (Gram negative). Intermediates of phenanthrene metabolism (1-hydroxy-2-naphthoate, salicylate, catechol, phthalate and protocatechuate) were selected as inducers. The tests indicated that 1-hydroxy-2-naphthoate was the most effective inducer and enhanced the phenanthrene degradation rate up to 5.7 times, even though all the others also had induction ability to some extent. The effective induction could be achieved even at a low concentration of 1-hydroxy-2-naphthoate. Addition of metabolic inducers would be an attractive trick for the successful bioremediation of PAH-contaminated soil.

본 조사를 통해 토양오염유발시설 중 유류 유출사고가 잦은 주유소에서의 오염현황 조사방법과 오염토양에 대한 적정한 정화기법을 제시하고자 하였다. 오염현황 조사결과, 지층구조 는 전반적으로 Clay로 구성되어 있으나 오염토양 주변은 비교적 투수도와 통기성이 우수한 Silty Sand층을 나타내고 있었다. 본 주유소의 경우 주유기 주변(상층부)과 지하유류저장탱크 주변(수직분포)에 오염이 분포되어 있고, 오염원인은 주유기의 배관 파손 및 결함에 의해 발생한 것으로 예상된다. 본 조사지역에 대한 정화기법으로는 토양증기추출기술(SVE)과 불포화대를 생물학적으로 복원할 수 있는 바이오벤팅기술을 결합시킨 Bioslurping이 효과적일 것으로 평가된다. 또한 Bioslurry injection treatment를 병행하여 효과적으로 고농도의 오염토양을 처리하는 것이 바람직할 것으로 판단된다.

Trichloroethylene, which is one of the representative DNAPL, has been found in underground water sources as a result of the manufactural use, and disposal of the chemical. In this research, in situ air sparging method was chosen to reduce the TCE concentration from the source zone. The concentration reduction in the source zone resulting from air sparging is simulated using the modified STOMP Water-Air operational mode in a two dimensional axisymmetric domain and bench scale test is conducted to analyze the performance of air sparging. The results of laboratory tests are compared with numerical simulations.

27 passive systems in 21 mines constructed by The Coal Industry Promotion Board since 1996 were investigated to evaluate the treatment efficiency of systems and find problems in each system, which will eventually lead to the improvement or suggesting the alternative method of the passive treatment system. Problems in operation include overflow, leakage, inefficiency and unusablness. The efficiency of systems which has been evaluated by metal(Fe) removal rate and/or by acidity removal rate do not reflect the poor removal rate of S $O_4$$^{2-}$. Especially high concentration of S $O_4$$^{2-}$ and high COD in the beginning of the operation would decrease the bacteria activity due to the lack of the nutrition. To solve the problem of overflow the upflow-type SAPS is being considered.

영화유기화합물의 제거에 있어서 일반적으로 이용되는 금속분말로는 아연, 주석, 니켈, 납, 철 등이 알려져 있으며, 경제성과 반응성이 좋고, 독성을 야기하지 않는다는 측면에서 영가 철이 가장 많이 연구·실용화되어 적용되고 있는 실정이다. 본 연구에서는 제철부산물들의 비표면적 측정, 화학적 구성성분 분석 및 pH의 변화를 통해 TCE, PCE 제거능력 평가 및 탈염소화반응을 확인하였으며, 제철부산물인 사상분진과 열연슬러지가 TCE 및 PCE의 제거효율적인 측면이나 산업폐기물의 재활용적인 측면에서 순수철보다 우수하다는 것을 확인하였다.

Bioremediation is often used for in situ remediation of petroleum-contaminated site. We studied the microbial degradation of hydrocarbon in an artificially diesel contaminated soil in laboratory microcosm. In control soil, about 30% of the initial TPH was diminished and the degradation of diesel oil was significantly enhanced by the addition of bioremediation agent (70% of TPH reduction).

In this paper, we have examined the MTBE cometabolic degradation by pure culture, which is isolated gasoline contaminated aquifer. Propane was more effectively utilized as a growth substrate to oxidize MTBE. Specific substrate degradation rate was Increased with increasing initial propane amount. Respiking propane was enhanced and continued MTBE degradation and TBA observation was supported MTBE degradation. The mass balance of MTBE and TBA indicated that MTBE was oxidized to TBA as well as further oxidation of TBA.

Leaking underground storage tanks are a major source of groundwater contamination by petroleum hydrocarbons. Bioremediation of aromatic hydrocarbons in groundwater and sediments is often limited by dissolved oxygen. Aerobic bioremediation has been highly effective in the remediation of many fuel releases, but Many aromatic hydrocarbons degrade very slowly under anaerobic conditions. Nitrate is a good alternative electron acceptor to oxygen and denitrifying bacteria are commonly found in the subsurface and in association with contaminated aquifer materials. Because nitrate is less expensive and more soluble than oxygen. it may be more economical to restore fuel-contaminated aquifers using nitrate rather than oxygen. This study show that biodegradation of BTEX and MTBE is enhanced by the nitrate-amended microcosms under aerobic/anaerobic conditons. Although aromatic hydrocarbons degrade very slowly under anaerobic conditions. Biodegradaton was observed for all of the test compounds.

This study investigates the fractional composition and the leaching characteristics of heavy metals in polluted soils due to mining activities. The fractionated composition of heavy metals is classified into five fractions, adsorbed, carbonate, reducible, organic and residual fraction. The status of humic substances in mine wastes of most sites are polyhumic except tailing from Sangdong mine. According to the sequential extraction procedures (SEPs), leaching probabilities of Cd in coal wastes and tailing are relatively low due to high percentage of residual fraction. 46.4% of Ni in tailings from Sangdong mine is probably leached under oxidized environment, and 39.4% of Cu in these tailings is readily extracted under strongly oxidized environment by organic fraction. According to leaching condition of pH 3.0 and pH 5.6, the amount of heavy metals leached out of coal wastes and tailing increases to 1/2 hours. At pH 3.0 and pH 5.6, concentration of Ni in tailing increases up three times of the initial value. Heavy metals released from coal wastes and tailing were not influenced significantly by leaching time.

해안방조제에서 해수가 강물에 유출되는 현상은 생태계의 변화를 초래하고 강물을 농업에 이용할 수 없게 한다. 이런 현상을 방지하기 위하여 해수의 유출수량을 예측할 필요가 있다. 해수와 강물 사이의 지하수 흐름은 염도에 따른 밀도의 차이를 고려하여 연구되어야 한다. 또한, 담수와 염수의 혼합에 따른 물질의 이송 및 분산도 고려하여야 한다. 본 연구에서는 염도에 의한 밀도 차이에 따른 지하수의 흐름을 나타내는 지배방정식을 이용하여, 해안방조제에서의 해수가 강물로 유출되는 현상을 수치모사하였다. 수치모사 결과, 밀도 차이를 고려하지 않았을 때 발견할 수 없었던 지하수의 흐름이 생겼고, 밀도 차이로 인하여 해수의 유출 수량이 증가하였다. 따라서, 해안방조제의 해수의 유출수량 연구에서는 반드시 밀도 차이를 고려하여야 한다.

폐광석에 함유되어 있는 총중금속함량을 측정하기 위한 전함량분석과 중금속을 다량 함유한 폐광석이 산성환경에 노출되어 있을 경우 중금속의 지화학적 거동을 파악하기 위해 산도를 변화시키면서 용출실험을 실시하였다. 전함량분석과 용출실험을 종합한 결과, 중금속 및 미량원소의 용출거동 특성을 크게 As-Co-Fe 형태와 Cu-Mn-Cd-Zn형태와 Pb로 구분할 수 있었다. As-Co-Fe의 용출특성은 약산성의 환경에서는 용출이 미약하나, 최종 pH 1.5이하의 강산성환경에서는 용출량이 급격하게 증가하며, Cu-Mn-Cd-Zn형태에서는 최초로 용해되는 pH가 5.0-3.0으로 As-Co-Fe 보다 다소 높았다. Pb는 다른 형태에 비해 상당히 적게 용출되었다 최종 용출된 함량과 관계없이 초기 용출이 발생하는 pH값을 기준으로 한 각 원소의 상대적인 이동성은 Mn =Zn>Cd=Cu>>Fe=Co>As>Pb 순서이며, 산성비는 Zn, Mn 및 Cu를 쉽게 용출시켜 이동도를 증가시킬 것으로 판단된다.

Coalfields in Korea have been grouped into thirteen based on mainly geographycal and geological structure, ten out of which have been developed. To classify the phisico-chemical characteristics of mine drainage from each coalfield and, if possible, to clarify the intrinsic reasons of them. Sampling of waters from 59 mines in eight coalfields has been carried out. Higher pH of drainage water from the mines of the Cungchung coalfield belong to the Beading system, Mesozoic era than those belong to the Pyungan system, Proterozoic era is due to the low content of sulfides of neighboring strata. The drainage from coal beds overlying limestone bed mostly show high pH. Waters from the Gangrung and Samchuck coalfields coal beds are located within black shale formation which contains a lot of sulfides showed mostly very high metal and S $O_{4}$$^{2-}$ concentrations.

Soil contains the several kinds of metal oxides. Magnetite in soil may contribute the generation of secondary waste during the decontamination of soil by citric acid. Dissolution of magnetite powders by citric acid was investigated in the pH range between 2.0 and 5.0. The dissolution behaviour of magnetite was well described by the equation, A[1 - $e^{-B(x-c)}$]. The parameters of the equation were optimized by the iteration method, and the physical meaning of each parameter was explained. Concentration of each of the dissociated chemical species of citric acid was calculated using the ionization constants. The dissolution reaction was explained by the concentration of the dissociated chemical species of citric acid.d.

In this study, humic and fulvic acids in soils at the vicinity of domestic atomic power plants(NPPs), located in Yungkwang(YK), Uljin(UJ), Kori(KR), Koseong(KS), Wolseong(WS) area, and in volcanic ash soils of the Cheju island(Mt. Hanla(HL), Manjanggul(MJ)) were isolated, and characterized using chemical(elemental analysis, proton exchange capacity, molecular size distribution) and spectroscopic(UV/Vis., IR, FL, $^{13}$ C NMR spectra) methods. The results were compared with one another and compiled for their DB establishments. The humic substances distribution (humic acid, fulvic acid, Humin) in the soils were also determined by IHSS standard method. Main purpose of this study was to provide a basic data needed to evaluate the effect of humic substances on the migrational behaviour of radioactive elements in contaminated surface soil.

경북 고령군 다산면의 충적층 강변여과 취수에 따른 수위변화 모델링을 시도하였다. 단순화된 2가지 모델을 기본으로 하여 1일 평균 1만 5천톤의 상수도 공급 시, 일정수두 유지를 위한 연간 취수 계획 및 적정 취수량을 검토하였다. 한편, 질량 균형(mass balance)을 통하여 모델 검증 및 시기별 하천수와 지하수의 유입 비율을 예비적으로 산정하였으며, 투수계수와 함양량 변화에 따른 지하수위의 민감도를 검토하였다. 하천수 유입 비율은 시기별로 65∼85% 범위를 갖는 것으로 나타났으며, 지하수위는 함양량 변화에는 둔감한 반면, 투수계수에 대해서는 상대적으로 민감한 것으로 평가되었다.

The soild phase microextraction(SPME)fiber which contains 100${\mu}{\textrm}{m}$ polydimethyl siloxane of a stationary phase was used for the analysis of volatile organic compounds contained in aqueous solution. volatile organic compounds, which were spiked in blank water and extracted by the headspace SPME techique, were analyzed by gas chromatography/flame ionization detector(GC/FID). The optimu condition of SPME fiber is determined that the analytes were extracted for 40min from extracts by using PDAfS100${\mu}{\textrm}{m}$ fiber. This new method could have wide application for the analysis of VOCs in aqueous solution.

본 연구는 호소내 오염된 퇴적물 처리를 위한 전처리 장치로 Hydrocyclone의 이용가능 성을 평가하는 실험이다. 외국의 선행 연구자인 Rietema의 표준 규격을 참고하여 제작된 Hydrocyclone을 이용하여 기흥저수지 퇴적물로 실험을 실시하였다. 실험결과 입자에 따른 오염 도 평가에서는 입자가 작을수록 포함된 오염물의 농도가 높은 것으로 나타났다. 또한 퇴적물을 이용한 장치특성 및 운전조건 변화에 따른 실험에서 공급속도가 빠르고, 공급시료의 농도가 낮으며, 장치의 크기가 작을수록 입자별 분리효율이 높았다.

The last few decades have seen drastic growth in the use of brominated flame retardants(BFRs). There is the problems of polybrominated dibenzo-p-dioxins(PBDDS) and polybrominated dibenzofurans(PBDFs) generation as by-products in combustion process of BFRs. PBDDs/PBDFs are highlighted the new pollutants of environmental contamination, recently. In this study, the 10 kinds of PBDDs/PBDFs standards were used to perform the experiments of recoveries. The analysis of PBDDs/PBDFs in soil environmental samples. was carried out. In silica gel column cleanup, PBDDs/PBDFs eluted until 80mL of n-hexane, and the recovery was obtained 73∼105%. In multi-layer silica gel column cleanup, the recovery was obtained 56∼125% with various elution solvents. In alumina clean process, the standard mixture(PBDES, PBDDs/PBDFs) eluted the first fraction of 2% dichloromethane with n-hexane in the range of 0∼100mL, PBDEs compounds eluted in the second fraction of 50% dichloromethane with n-hexane. In activated carbon column cleanup, the PBBEs eluted to the first fraction(n-hexane) and second fraction(toluene), but PBDDs/PBDFs only eluted to the second fraction. The analytical methods of PBDDs/PBDFs for soil was established based on the experimental results of the environmental samples.

Surfactant enhanced in-situ soil flushing was peformed to remediate the soil and groundwater at an oil contaminated site, and the effluent solution was treated by the chemical treatment process including DAF(Dissolved Air Flotation). A section from the contaminated site(4.5m$\times$4.5m$\times$6.0m) was selected for the research, which was composed of heterogeneous sandy and silt-sandy soils with average Hydraulic conductivity of 2.0$\times$10$^{-4}$ cm/sec. Two percent of sorbitan monooleate(POE 20) and 0.07% of iso-prophyl alcohol were mixed for the surfactant solution and 3 pore volumes of surfactant solution were injected to remove oil from the contaminant section. Four injection wells and two extraction wells were built in the section to flush surfactant solution. Water samples taken from extraction wells and the storage tank were analyzed by GC(gas-chromatography) for TPH concentration with different time. Five pore volumes of solution were extracted while TPH concentration in soil and groundwater at the section were below the Waste Water Discharge Limit(WWDL). Total 18.5kg of oil (TPH) was removed from the section. The concentration of heavy metals in the effluent solution also increased with the increase of TPH concentration, suggesting that the surfactant enhanced in-situ flushing be available to remove not only oil but heavy metals from contaminated sites. Results suggest that in-situ soil flushing and chemical treatment process including DAF could be a successful process to remediate contaminated sites distributed in Korea.

Many pumping station of Maehang-ri of Hwasung city are established for irrigation water supply, and brine permeation phenomenon is happening thereby. Proposed optimum pumping fluid amount conclusion model that use tidal efficiency and Ghyben-Hertzberg theory so that brine does not permeate in pumping station hereupon and applied this in study area.

This research introduces some preliminary results of bank filtering intake method adopted ill Backam area, Yongin city. This bank infiltration had been supplied to water resources of 750 m$^3$/day to Backam-myun, in 2002. It is believed that the bank infilteration method can afford to supply backam-myun people, Youngin city. The analysis of pumping data along the river shows the water supply pattern. Monitoring data of 1-6 pumping stations on the decline of water table along river sides and basic data on hydrogeologic properties are used to analyze the spatial disturbance range of groundwater systems due to the river pumping system.

Nitrogen pollution in urban and rural groundwater is a common problem and poses a major threat to drinking water supplies based on groundwater. In this work, the kinetics of nitrification-denitrification coupled reactions are modeled and new reaction modules for the RT3D code describing the fate and transport of nitrogen species, dissolved oxygen, dissolved organic carbon, and biomass are developed and tested. The proposed nitrogen transformations and transport model showed very good match with the results of other public codes.

The fate and the behavior of polycyclic aromatic hydrocarbons (PAHs) and heavy metals in the environment are mainly controlled by their interactions with various components of soils and sediments. Due to their large surface area and abundance in many soils, smectites may greatly influence the fate and transport of the contaminants in the environment. In our experiment, PAH sorption by hexadecyltrimethylammonium (HDTMA)-modified smectite linearly increased in proportion to the amount of HDTMA added on the clay. However, trimethylammonium (TMA)-modified smectite did not show superiority in its sorption of PAH compared with the HDTMA-smectite or dodecyltrimethylammonium (DTMA)-smectite. Meanwhile, the smectites modified with the same cationic surfactants adsorbed Cd$^{2+}$ (heavy metal) significantly from water at low surfactant loading level, but the Cd$^{2+}$ adsorption linearly decreased as the loading of surfactant increased. The result shows that the sorption tendency of organoclays for organic or inorganic contaminants was significantly influenced by the amount and size of the surfactants added on the clay. It means that the stabilization and configuration of cationic surfactant formed on the clay interlayer according to the loading amount of each surfactant of different sizes may be an important factor in effectively sorbing environmental pollutants.nts.

남해 동부 연안 지역 지하수의 해수 침투 영향을 광역적으로 파악하기 위하여, 202개소의 지하수 시료를 채취하고 수리지구화학적 연구를 수행하였다. 전체 시료 중 14.4%가 500 $\mu\textrm{m}$/cm을 초과하는 높은 EC값을 나타내어 해수 영향을 시사해 주었다. 해수 영향 판단의 또 다른 파라메터로 사용되는 CI/HCO$_3$ 몰비는 전체 시료의 23.3%가 1.3 이상의 값을 나타내었다. 한편, 대표적으로 해수침투 영향 및 인위적 오염의 영향을 각각 반영하는 것으로 알려진 Cl과 NO$_3$의 농도에 관한 누적도수분포도를 작성하여 배경수질군과 오염영향군을 구분짓는 배경치(background concentration)를 구한 결과, 각각 Cl = 22.3 mg/1 및 NO$_3$= 23.1 mg/l로 나타났다. 이 두 파라메터의 농도 분포를 기준으로 하여 채취된 지하수 시료를 크게 4개의 그룹으로 나눌 수 있었다. 그 결과, 자연적 또는 인위적 기원의 오염이 배제된 그룹 1은 전체 시료의 31%, 자연적 오염(해수 영향)을 반영하는 그룹 2는 전체의 24%, 인위적 오염의 영향을 반영하는 그룹 3은 전체의 9%, 해수 영향 및 인위적 오염을 동시에 반영하는 그룹4는 전체의 36%로 나타났다. 또한 그룹2와 그룹4는 대부분 Na-Cl유형으로 진화하는 Ca-Cl유형을 나타내었다. 따라서, 여러 지구화학 방법에 의한 해수 영향 판단 결과는 서로 잘 일치하고 있음을 알 수 있다. 결국, 지구화학적 파라메터를 종합적으로 활용함으로써, 연안 지역 해수침투의 효과적인 파악은 물론 예측 및 방지, 복구에 효과적으로 사용될 수 있을 것으로 판단된다.으로 토양에서 유동 가능성이 있는 중금속만을 추출하였다. 분석실험은 토양의 Cd2+ 와 Pb2+를 대상으로 행하여졌으며, 여러 토양에서 추출 분석한 결과를 EDTA분석결과와 비교하였다. 실험결과, 중금속은 매우 신속하게 고분자 자성체와 결합하였고, 그 후 자성체를 외부 자장으로 모은 후 산으로 용해시키고, 결합된 중금속은 Graphite furnace AAS로 분석함으로써 빠르고 효율적으로 분석실험을 수행할 수 있음을 알 수 있었다. 한편, 실험에서 나타난 수치들을 비교 검토한 결과 토양 분석시 sandy soil에서는 자성체를 이용한 분석이 EDTA에 의한 방법보다 더 높은 추출도를 보인 반면, silt 함량이 많은 토양의 경우에서 EDTA분석에서 더 높은 중금속 추출도를 보였다.s 중에서 490nm와 555nm의 복합밴드를 포함하는 OC2 알고리즘(ocean color chlorophyll 2 algorithm)을 사용하는 것이 OC2 series 및 OC4 알고리즘보다 좋은 추정 값을 도출할 수 있을 것으로 기대된다.환경에서는 5일에서 7월에 주로 이 충체의 유충이 발육되고 전파되는 것으로 추측되었다.러 가지 방법들을 적극 적용하여 금후 검토해볼 필요가 있을 것이다.잡은 전혀 삭과가 형성되지 않았다. 이 결과는 종간 교잡종을 자방친으로 하고 그 자방친의 화분친을 사용할 때만 교잡이 이루어지고 있음을 나타내고 있다. 따라서 여교잡을 통한 종간잡종 품종육성 활용방안을 금후 적극 확대 검토해야 할 것이다하였다.함을 보이고 있다.X> , ZnCl$_{3}$$^{-}$같은 이온과 MgCl$^{+}$, MgCl$_{2}$같은 이온종을 형성하기 때문인것 같다. 한편 어

이 연구는 제주도 한림 지역에서 지하수의 수질과 오염의 특성을 규명하고자 시행되었다. 2002년 8월과 11월에 걸쳐 34개 지점에서 지하수 시료를 채취하였고, 이를 분석하여 지하수의 수질을 유형별로 분류하였다. 연구지역은 주로 (Na,Mg)-HCO$_3$ 유형이 나타나며, 일부 지점에서는 Mg-(HCO$_3$+Cl), (Ca,Mg)-HCO$_3$ 유형 등이 나타난다. 이는 지하수의 유동 경로를 따라 서로 다른 수리지화학적 반응이 일어나며, 지표 오염물질의 유입 등이 지하수의 수질에 영향을 미치고 있음을 지시한다. 질산성 질소의 경우, 국내 먹는물 수질기준치 10 mg/L를 초과한 시료는 전체 시료의 8월 조사에서 약 32%, 11월 조사에서 약 27% 이었고, 공간적 분포 특성은 비교적 낮은 고도 150m 이하의 저지대에서 채취한 시료에서 주로 나타났다. 인위적인 오염물질의 유입 가능성이 있는 지점은 전체 시료의 79.4% 이었다.

The feasibility of PENTANOX 4X for the simultaneous removal of nitrate and phosphate was investigated using micellar-enhanced ultrafiltration. Because PENTANOX 4X has cationic property at low pH, anionic contaminants can be bound to PENTANOX 4X micelle by electrostatic interaction. At pH 3, 90% of nitrate and 72% of phosphate were removed by 27 mM of PENTANOX 4X, which were equivalent to 20 mM of CPC. PENTANOX 4X of > 80 % was rejected by ultrafiltration membrane and did not make any counter-ion such as chloride for CPC which might cause second-pollution.

Nonpoint source pollution of groundwater and subsurface water from irrigated agriculture is a major concern in many areas. In this study we aimed to investigate the effect of the water applied by irrigation in agricultural area on the transport of nitrogen and phosphorus originated from fertilizers applied to the surface of soil in agricultural activities. We first conducted investigation on the resdual concentrations of soil N and P in a selected agricultural area. And simulating the target area by column studies in the laboratory leaching extent of various components from the composite and urea fertilizers applied on the soil surface during irrigation was studied. Infiltration of water enhanced the leaching of nitrogen and phosphorus in both the rice paddy field soil and the patch soil. The downward N and P transport with infiltrating water was more pronounced in the patch soil column and the increased residual concentrations of N and P in the lower sections in the patch soil column was found with time.

We investigated the leaching of elements from anthracite ashes by interactions with seawater. The results show that consumption rates of dissolved oxygen are 7.5 times greater in the seawater system than in the fresh water system and indicate that the differences in DO consumption rate may plat a role in regulating the element leaching from the coal ashes. It is revealed that seawater's pH buffering capacity is the most important factor that makes the leaching of elements and their chemical behaviors in the seawater system different from those in the fresh water environments. In overall, element leaching from the weathered ash is smaller than that from the fresh ash. However, the leaching of Si, Fe, Al, Mn, phosphate, and some other elements were independent of weathering. They were dependant only on the pH of the solutions.

충청북도 증평에 위치한 문화마을 인근의 19개 지하수 관측정에서 시료를 채취하여 질산성질소 농도와 $\delta$$^{15}$ N 값, 암모니아성질소 농도와 $\delta$$^{15}$ N 값을 정량하였다. 그 결과 질산성질소에 의한 심각한 오염은 관찰되지 않으며, 질산성질소내 $\delta$$^{15}$ N이 +9.4~+36.8%0의 범위를 갖는 것으로 보아 계분이나 생활하수 혹은 두 가지 이상의 오염원이 동시에 작용함을 나타낸다. 연구지역의 $^{15}$ N 부화지수($\varepsilon$)은 -6.697%0로 탈질에 의한 범위를 만족한다. 암모늄의 질산화가 주요한 반응기작일 경우에 나타나는 암모늄 농도 감소에 따른 $^{15}$ N의 부화는 관찰할 수 없다.

전기분해에 의한 부상현상을 이용하여 유류로 오염된 토양 세정 후 발생되는 유출수 중 유분 등을 분리하기 위한 적정 운전조건을 찾고자 하였다. 전기분해 반응조(200 $\times$ 10 $\times$15cm)에 혼합 계면활성제 (POE5 : POE14, 1:1) 1% 용액에 디젤을 1,000mg/L 농도로 용해시켜 실험하였다. 양극에는 티나늄 코팅전극, 음극으로는 스테인레스 스틸전극을 이용하였다. 반응시간은 62분( 반응: 60분, 부상시간: 2분) 이었으며 전압은 6V였다. 전해질 첨가에 의한 영향을 알아보기 위하여 실험한 결과, 전해질을 첨가하였을 경우 첨가하지 않았을 때보다 40% 정도의 효율이 증가하였다. 적정 전해질, 주입농도 및 반응시간을 알아보기 위하여 1N NaCl과 NaOH의 농도를 변화시켜 가면서 실험하였다. NaCl의 경우 더 좋은 효율을 나타내었다. 전해질의 농도는 0.2 - 1.0% 의 농도 범위에서 NaCl와 NaOH 모두 농도에 따라 순차적으로 효율이 증가하였다. 두 전해질 모두 0.4 - 1.0% 농도 범위에서 평형에 도달하는 시간은 20분으로 나타났다.