Recently, we have recognized that ‘Soil Environmental Prevention Act’could not provide perfect solutions on many complicated problems which are now emerging and/or can be solved by adopting comprehensive policies. In this study, some suggestions were made to solve a few tangled problems such as conducting the Land Partnership Plan(LPP) project, investigating soil and ground water contamination of the industrial area, building a integrated information system for soil and ground water, establishing detailed guidelines for remediation and verification, and re-constructing the legal and institutional framework for integrated management of soil and ground water. These suggestions may help policy makers to build conceptual frameworks for solving these problems.

The aim of this study was to analyse the cost-benefit-ratio of a soil remediation project. The target of the study was the 'Altablagerung Osnabrueck-Wueste' the largest inhabited former landfill site in Germany. The determination of benefit resulting from the soil remediation was quantified with the help of willingness-to-pay(WTP) analysis (contingent valuation method, CVM). 400 households participated in the survey. The average WTP was 6.5 Euro per household per month or 78 Euro per house-hold per year. The projected benefit generated by the remediation (consumer value) for the population in the landfill area was determined to be 0.7 million Euro per year. Factors which influence the will-ingness to pay were evaluated. The most important factors were age, garden use and the prevailing concern about personal health. A computation of the cost-benefit relationship was made on the basis of three different scenarios, which differed in terms of the projected benefits. Finally the economical efficiency of the project was determined. With a projection of 18 years and upwards the remediation of the soil is economically worthwhile.

The capillary number is used to represent the mobilization potential of organic phase trapped within porous media. The capillary number has been defined by three different forms, according to types of flow velocity and viscosity used in the definition of capillary number. This study evaluated the suitability of the capillary number definitions for representing TCE mobilization by constructing capillary number-TCE saturation relationships. The results implied that the capillary number should be correctly employed, according to interest of scale and fluid flow behavior. This study suggests that the pore-scale capillary number may be used only for investigating the organic-phase mobilization at the pore scale because it is defined by the pore-velocity and the dynamic viscosity. The Newtonian-fluid capillary number using Darcy velocity and the dynamic viscosity may be suitable to quantify flood systems representing Newtonian fluid behavior. For viscous-force modified flood systems such as surfactant-foam floods, the apparent capillary number definition employing macroscopic properties (permeability and potential gradient) may be used to appropriately represent the desaturation of organic-phases from porous media.

Gaseous partitioning tracer test has been used for determining the volume and spatial distribution of residual non-aqueous phase liquid (NAPL) in the unsaturated soils. In this study, an experimental method for measuring the content of gas-exposed NAPL as well as that of total NAPL in a sand during air sparging was developed. Two different gaseous phase NAPL-partitioning tracers were used; n-pentane, with very low water solubility, was used as the tracer that partitions into NAPL that is only in contact with the mobile gas, and chloroform, with fairly good water solubility, was selected for detecting total NAPL content in the sand. Helium and difluromethanewere used as the non- reactive tracer and water-partitioning tracers, respectively. Using n-decane as a model NAPL (NAPL saturation of 0.018), 25.6% of total NAPL was detected by n-pentane at the water saturation of 0.68. Oniy 9.1% of total NAPL was detected by n-pentane at the water saturation of 0.84. This result implies that the quantity of gas-exposed NAPL increased about three times when the water saturation decreased from 0.84 to 0.68. At the water saturation of 0.68, more than 90% of total NAPL was detected by chloroform while 65.8% of total NAPL was detected by chloroform at the water saturation of 0.84. Considering that the removal rate of NAPL during air sparging for NAPL-contaminated aquifer is expected to be greatly dependent upon the spatial arrangement of NAPL phase with respect to the mobile gas, this new approach may provide useful information for investigating the mass transfer process during air-driven remedial processes fer NAPL-contaminated subsurface environment.

Two biokinetic models (\circled1 Mrichaelis-Menten kinetics with competitive inhibition \circled2 with both competitive inhibition and Haldane inhibition) for reductive dechlorination were developed and compared with results from batch kinetic tests conducted over a wide range of PCE and TCE concentrations with two different dechlorinating cultures. At PCE concentrations lower than 300 $\mu$M, both model simulated the experimental results well. However, The kinetic model that incorporated both competitive and Haldane inhibitions much better simulated experimental data for PCE concentrations greater than 300-400 $\mu$M, and TCE concentrations at half its solubility limit (4000 $\mu$M). The PM culture showed Haldane inhibition constants of 900, 6000, 7000 $\mu$M for TCE, c-DCE and VC, indicating very weak Haldane inhibition for c-DCE and VC, while the EV culture had lower Haldane inhibition constants for TCE, c-DCE, and VC of 900, 750, and 750 $\mu$M, respectively. The BM culture had better transformation abilities than the individual cultures over a wide range of PCE and TCE concentrations. Modeling results indicated that a combination of competitive and Haldane inhibition kinetics is required to simulate dechlorination over a broad range of concentrations up to the solubility limits of PCE and TCE.

In Korea, over three hundreds of the coal mines were closed or abandoned due to the depression of the mining industry since the late 1980s. Many of them locate in the steep mountain valleys and the coal mine wastes had been disposed without a proper treatment From these mines, enormous amounts of coal mine overburdens have been abandoned in the slopes and the ample amounts of acid mine drainage (AMD) from either portal or overburdens have been discharging directly to the streams, causing the detrimental effects on soil and water qualities. Objectives of this research were to reclaim the coal mine overburdens using the lime waste cake from the soda ash production by stabilizing the overburden slopes, introducing the vegetation alleviate the environmental problems caused by the closed coal mines. The percentages of the grass distribution ratio (%) and the surface coverage ($\textrm{cm}^2$) in each treatment plot were determined during June to August after seed spraying grasses such as orchard grass (Dactylis glomerata L), Kentucky Bluegrass (Poa pratensis L.) and Eulalia (Miscanthus sinensis Anderss) at the end of May. The grasses covered only 15.5 % of the coal overburden plot at the early stage but the coverage was increased with time to 33% in August. Growth of such grasses was enhanced with the combined treatments of lime waste and topsoil resulting in the increased surface coverage by the grasses. The Increment of the surface coverage from June to August was higher with lime waste treatments. The distribution percentages and surface coverage were highest when the lime wastes were treated at 25 % of the lime requirement. This might be related with the high salt contents in the hire wastes. Results demonstrated that the amounts of lime wastes at 25% of the lime requirement were sufficient for neutralizing the acidic coal overburden and introducing the re-vegetation. Either layering between the coal waste and topsoil or mixing with coal overburdens could be adopted as the lime waste treatment method. The combined treatment of lime wastes and topsoil was recommended for re-vegetation in the coal overburden slopes. The lime wastes from the soda ash production might have a potential to be recycled for the reclamation of the abandoned coal mines to alleviate the environmental problems associated with coal mine waste.

Objectives of this research were to reclaim the coal mine overburdens using the lime waste cake from the soda ash production by stabilizing the overburden slopes, introducing neutralizing the AMD from runoff and leachate in an attempt find the sink to dispose the lime wastes and alleviate the environmental problems caused by the closed coal mines. The pH changes of the runoff and leachate collected in the tanks at the end of the experimental plots, averaged over measurements from April to August, indicated that the runoff pH of the coal overburden was 4.3 but increased significantly to the ranges of 6.7 to 7.1 with treatments of tile calcites and lime wastes. This might be related with the decreases in Fe concentrations in the runoff and leachate from the coal overburdens. The Fe concentrations in tile runoff seemed to increase with the amounts of precipitation. Results demonstrated that the amounts of lime wastes at 25% of the lime requirement were sufficient for neutralizing the acidic coal overburden. Either layering between the coal waste and topsoil or mixing with coal overburdens could be adopted as the lime waste treatment method. The lime wastes from the soda ash production might have a potential to be recycled for the reclamation of the abandoned coal mines to alleviate the environmental problems associated with coal mine waste.

Hydraulic conductivity tests were conducted on a geosynthetic clay liner (GCL) for more than 2.5 yr using inorganic salt solutions to evaluate how the long-term hydraulic conductivity is affected by cation concentration and valence. Only small changes (i.e., $\leq$ 2X) in hydraulic conductivity (K) occurred during the test duration when the permeant solution was deionized (DI) water or 100 mM KCl and NaCl solutions. For weak CaCl$_2$ solutions ($\leq$ 20 mM), the hydraulic conductivities initially (< 0.2 yr) were comparable to the hydraulic conductivity obtained with DI water, but gradually increased by a factor of 2 to 13 over a period of nearly 2 yr. In contrast, the GCL permeated with strong CaCl$_2$ solutions ($\geq$ 50 mM) reached equilibrium nearly immediately, with a hydraulic conductivity approximately 2 orders of magnitude higher than the hydraulic conductivity to DI water.

A field pilot study on remediation of diesel-contaminated soil by hot air injection/extraction process constructing soil piling system was conducted to evaluate the effects of hot air on the removal of diesel and each constituent. After the heating process of 2 months, the equilibrium temperature of soil reached to 10$0^{\circ}C$ and soil TPH concentration was reduced to about 72% against the initial concentration. Additional extraction process of 2 months induced the continuous extraction of residual diesel and the increment of microbial activity, which made soil TPH concentration reduced to 95%. In addition biological removal of non volatile constituents in diesel was verified indirectly and the removal pattern of each DRO(diesel range organic) as soil temperature was explained.

Effects of surfactants and natural organic matter (NOM) on the sorption and reduction of tetrachloroethylene (PCE) and chromate with iron were examined in this study. PCE and chromate reduction by iron depended on the ionic type of the surfactants in this study. The apparent reaction rate constants of PCE with Triton X-100 and hexadecyltrimethyl ammonium (HDTMA) at one half and two times of the critical micelle concentration (CMC) were relatively higher than without surfactants because of the enhanced PCE partitioning and surface concentration. In the presence of sodium dodecyl benzene sulfonate (SDDBS) at 2000 mg/L and NOM at 50 mg/L, the apparent reaction rate constants of PCE increased, but TCE production decreased. The enhanced removal rate of PCE was not due to the dechlorination, and the sorption was dominant iron with SDDBS and NOM. The apparent reaction rate constants of chromate by iron with Triton X-100 and NOM were 1.4-3.1 times lower than without surfactants while that with HDTMA was two times higher than without HDTMA, When the sorbed HDTMA molecules form admicelles, negatively-charged chromate has an affinity for the positively-charged HDTMA head group.

The potential of electrokinetic (EK) technology has been successfully demonstrated for the remediation of heavy metal contaminated fine-grained soils through laboratory scale and field application studies. Arsenic contamination in soil is a serious problem affecting both site use and groundwater quality. The EK technology was evaluated for the removal of arsenic from two soil samples: kaolinite clay artificially contaminated with arsenic and arsenic-bearing tailing soil taken from the Myungbong (MB) mining area. The effect of cathodic electrolyte on the process was investigated using three different types of electrolyte: deionized water (DIW), potassium phosphate (KH$_2$PO$_4$) and sodium hydroxide (NaOH). The result of experiments on the kaolinite clay shows that the potassium phosphate was most effective in extracting arsenic, probably resulting from anion exchange of arsenic species by phosphate. On the contrary, the sodium hydroxide seemed to be most efficient in removing arsenic from the tailing soil, and it is explained by the fact that sodium hydroxide increased the soil pH and accelerated ionic migration of arsenic species through increase in desorption and dissolution of arsenic species into pore water.

This research was carried out to evaluate role of supplementary reagents, such as phosphate and SDS, to remove hydrophobic organic contaminant from soils during the EK-Fenton process. The $H_2O$$_2$ stability improved due to the role as stabilizer of phosphate and SDS during the EK-Fenton process. Furthermore, although pH in region near cathode was 8.2 after test, $H_2O$$_2$ stability improved due to transportation of SDS in the region near cathode. Therefore, in tests using phosphate and SDS as supplementary reagent, the efficiency of phenanthrene treatment improved through the EK-Fenton process using longer reaction time.

제주도 서부지역에 위치한 2개 관측정을 대상으로 대수층별 대수성시험을 실시하구 지하수 산출능력을 평가하였다. 연구대상 관측정은 대수층이 수직적으로 서로 연결되어 있지 않을 뿐만 아니라, 대체로 해수면 하 10～20m 사이 구간에 제1대수층이 발달하고 있으며, 지하수 산출능력은 절리 또는 용암류 경계의 대수층(용수2호공)보다는 유리쇄설성 각력암층(무릉1호공)에서가 상대적으로 양호한 것으로 평가되었다. 서귀포층을 포함한 제2대수층은 수위하가 l0m 이상 발생하는 것으로 미루어 보아 제1대수층보다는 지하수 산출능력이 떨어지는 것으로 판단된다. 그러나, 제1대수층은 지표로부터 얕은 깊이에 위치하고 있어 질산성질소 농도가 전반적으로 높고, 양수에 의한 영향권이 취수정 주변 l00m까지 발생하고 있어 서부지역에서 제1대수층 개발은 세심한 주의가 요구되고 있다.

The influence of a single fracture intersection on density-driven immiscible flow is compared between wetting (water into air) and nonwetting (Trichloroethylene into water) flows. At low supply rates, the intersection acted as a hysteretic gate to pulsed flow of the wetting phase, but had minimal influence on nonwetting phase flow. For both cases, increasing the supply rate led to the formation of continuous fluid tendrils that crossed the intersection without interruption. The wetting experiment returned to pulsed flow as the supply rate was decreased, while the nonwetting experiment maintained a continuous flow structure. Results suggest a fundamental difference between wetting and nonwetting phase flows in fracture network.

국내 대부분의 경작지를 차지하고 있는 논농사 지역에서의 질산성 질소의 자연저감을 고찰하기 위하여, 세 유형의 수조 환경을 조성하고 mesocosm 실험 연구를 수행하였다. 두개의 mesocosm에는 논토양을, 그리고 비교를 위하여 다른 하나에는 밭토양(황토)을 사용하였으며, 하나의 논토양 mesocosm과 밭토양(황토) mesocosm에는 벼를 재배하였다. 인위적으로 질산성 질소 성분을 용해한 지하수를 주입수로 사용하였으며, mesocosm을 통과한 물 시료를 41일 동안 12시간 또는 24시간 간격으로 채취하고 화학분석을 실시하였다. 실험 결과, 논토양에서는 실험 시작과 동시에 급격한 환원환경이 형성되었으며, 그 결과 탈질반응에 의해 질산성 질소의 농도가 현저히 저감되었다. 분석 자료의 해석 결과, 논토양 mesocosm에서는 유기물이, 밭토양 mesocosm에서는 철이온(Fe2+)이 질산성 질소의 탈질 반응에 중요한 역할을 수행하는 것으로 판단된다.

Multivariate Newton Raphson method is developed to perform the particle tracking in the three dimensional area using four objective functions. In this method, three variables are solved to compute target point and actual and real tracking time. The simulated pathlines in various types of three dimensional elements are well matched with exact pathline.

To investigate the evidence for the influence of sea water on Pohang geothermal groundwater, the chemical data for geothermal groundwaters from which are pumped during 48 hours and other hot groundwaters, another groundwater on the well for the purpose of agriculture, were considered. And to predict possible the secondary mineral which are easily to make the clogging, geochemical modeling was carried out using EQ3NR equilibrium solubility code. The results are that 1.4%～3.3%(bulk composition) of sea water were mixed with geothermal groundwater. From the well logging data, when the level of groundwater is drow down, the conductivity is increased in the geothermal groundwater, the existence of transition zone are recognized in the well. The predicted possible secondary minerals are Antigorite [Mg48Si24O85(OH)62], Chrysolite [Mg3Si2O5(OH)4] , Cristobalite, Dolomite, Talc, Tremolite. The recommended cooling temperature of best condition to minimize the production of secondary minerals is same as temperature of geothermal water pumped from the well.

지반오염을 조사하기 위해서는 시추작업을 통하여 시료를 채취하는 방법이 일반적이지만, 실시간으로 원위치에서 다양한 오염물질들의 오염도 변화를 체계적으로 모니터링하는 것은 대단히 어렵다. 본 연구에서는 Frequency Domain Reflectometry(FDR) 장비를 고안하여 지반의 유류오염을 파악하기 위한 유전율 측정법의 실험적 접근을 시도하였다. 구체적으로 포화 및 불포화 매질에 대한 오염도의 측정 및 오염도와 체적함수비의 관계를 측정하여 유전율 반응으로부터 매질의 물성치를 파악할 수 있는 것을 확인하였다.

균열 암반 대수층에 대한 지하수 인공 함양 주입 가능성을 예비적으로 평가하기 위한 시험을 수행하였다. 지하수 인공 함양 주입 시험이 수행된 지역은 경기도 포천군 이동면이며, 이 지역의 지질은 중립내지 조립질 화강암에 해당된다. 시험 정호에 대한 시추공 내부 촬영 결과, 화강암 내에 부분적으로 절리들이 발달되어 있었으며, 대체로 수직적인 절리 발달이 우세하였다. 2개소에서 인공 함양 주입 시험이 100kgf/$\textrm{cm}^2$ 이상의 확장 팩커로 대상공의 상부를 밀폐한 후 시행되었다. 이중 MW-7호 공에서는, 주입 압력을 5 내지 7kg/$\textrm{cm}^2$으로 조절하여 시간당 약 450$\ell$의 평균 주입률로 시험을 수행하였으며, O-7a 호 공에서는 주입 압력을 4kgf/$\textrm{cm}^2$ 내외, 시간당 약 1,740$\ell$의 평균 주입률로 시험을 수행하였다. MW-7호 공의 시험은 3일간 3회에 걸쳐 각 450분, 200분, 414분 동안 시험이 수행되었으며, O-7a호 공에서는 연속적으로 24시간 동안 인공 함양 주입 시험이 수행되었다. 수행된 지하수 인공 함양 주입시험은 적어도 지하수 상류 구배 구간의 지하 수두를 시험이 수행된 이후에도 24시간 이상 유지하는 것으로 평가되었다. 실험을 통해 주입한 양과 주변 관측공의 수위 상승을 단순 검토한 결과 시험이 수행된 지역의 개략적 유효 공극률을 산정 할 수 있었으며, 그 결과, 이 지역 균열 암반의 유효 공극률은 약 3 내지 6% 인 것으로 평가되었다 국내에서 지하수 인공 함양 방식을 균열 암반 대수층에 활용하여, 지속적인 수자원 관리와 수도 공급을 할 수 있는지를 평가하기 위해서는 앞으로 보다 많은 시험수행과 연구를 통한 검증이 요구된다. 까마중, 냉이, 명아주, 둑새풀 등의 생장에 현저한 조해현상을 나타냈다. 이것으로 보아 억새가 타식물의 생장에 영향을 주는 요인물질은 억새의 뿌리에서 분필되는 것으로 생각된다. 옥수수의 뿌리에서 직접 분필하는 물질이나 옥수수뿌리의 분해물질들은 모두 당귀의 생장을 조해하는 경향이 있었다.기존에 제안된 경험식들에 의한 계산결과 보다 균질화 해석법의 결과가 훨씬 정확함을 주목하여야 한다.c의 범위로서 최대값과 최소값은 4차수(four order)의 차이를 보였다. 단열대의 분포 특성을 파악하기 위하여 지구물리검층을 실시하였고, 각 시험에 의해 획득된 결과들과의 비교를 통하여 유동성이 높은 단열들이 규명되었다. 온도검층은 유동성 단열과 일반적인 단열들을 구별하는 좋은 지시자로 나타났다. 그 결과, N70-80$^{\circ}$W.60-85$^{\circ}$NE/SW, N75-80$^{\circ}$W.25-30$^{\circ}$SW, N50-64$^{\circ}$W.60-85$^{\circ}$NE, N35-45$^{\circ}$E.65-75$^{\circ}$SE, 그리고 N65-72$^{\circ}$E.80$^{\circ}$SE/60$^{\circ}$NW의 단열들이 연구지역의 지하수 흐름을 지배하는 뚜렷한 유동성 단열로 규명되었다.eatments. It was resulted from increase of weight of single cocoon. "Manta"2.5ppm produced 22.2kg of cocoon. It is equal to 9% increase in index, as compared to that of c

In order to classify the groundwater recharge characteristics in an urban area, a time series analysis of groundwater level data was performed. For this study, the daily groundwater level data from 35 monitoring wells were collected for 3 years (Fig. 1). The use of the cross-correlation function (CCF), one of the time series analysis, showed both the close relationship between rainfall and groundwater level change and the lag time (delay time) of groundwater level fluctuation after a rainfall event. Based on the result of CCF, monitored wells were classified into two major groups. Group I wells (n=10) showed a fast response of groundwater level change to rainfall event, with a delay time of maximum correlation between rainfall and groundwater level near 1 to 7 days. On the other hand, the delay time of 17-68 days was observed from Group II wells (n=25) (Fig. 1). The fast response in Group I wells is possibly caused by the change of hydraulic pressure of bedrock aquifer due to the rainfall recharge, rather than the direct response to rainfall recharge.

The purpose of this research is to investigate the noble gas isotope and the hydrochemical characteristics of hot springs in the Chungcheong area in Korea. This study was carried. out by the financial support of Korea-Japan joint research program of KOSEF, Noble gases are very useful tracers to investigate volatile elements circulation, because of their unique isotopic compositions in various reservoirs of the Earth. Isotopic ratios of noble gases has been carried out for If hot-spring samples from Daejon and its near areas in Korea last January 2004. Helium isotope ratio gave the evidence that helium gas of different origins(air-crust mixing origin, crust-origin and mantle-origin) is supplied into hot-spring waters in Korea. We found the distinct relationship between temperature of hot springs and helium gas origin.

Urban groundwater has a unique hydrologic system because of the complex surface and subsurface infrastructures such as deep foundation of many high buildings, subway systems, and sewers and public water supply systems. It generally has been considered that increased surface impermeability reduces the amount of groundwater recharge. On the other hand, leaks from sewers and public water supply systems may generate the large amounts of recharges. All of these urban facilities also may change the groundwater quality by the recharge of a myriad of contaminants. This study was performed to determine the factors controlling the recharge of deep groundwater in an urban area, based on the hydrogeochemical characteristics. The term ‘contamination’ in this study means any kind of inflow of shallow groundwater regardless of clean or contaminated. For this study, urban groundwater samples were collected from a total of 310 preexisting wells with the depth over 100 m. Random sampling method was used to select the wells for this study. Major cations together with Si, Al, Fe, Pb, Hg and Mn were analyzed by ICP-AES, and Cl, N $O_3$, N $H_4$, F, Br, S $O_4$and P $O_4$ were analyzed by IC. There are two groups of groundwater, based on hydrochemical characteristics. The first group is distributed broadly from Ca-HC $O_3$ type to Ca-C1+N $O_3$ type; the other group is the Na+K-HC $O_3$ type. The latter group is considered to represent the baseline quality of deep groundwater in the study area. Using the major ions data for the Na+K-HC $O_3$ type water, we evaluated the extent of groundwater contamination, assuming that if subtract the baseline composition from acquired data for a specific water, the remaining concentrations may indicate the degree of contamination. The remainder of each solute for each sample was simply averaged. The results showed that both Ca and HC $O_3$ represent the typical solutes which are quite enriched in urban groundwater. In particular, the P$CO_2$ values calculated using PHREEQC (version 2.8) showed a correlation with the concentrations of maior inorganic components (Na, Mg, Ca, N $O_3$, S $O_4$, etc.). The p$CO_2$ values for the first group waters widely ranged between about 10$^{-3.0}$ atm to 10$^{-1.0}$ atm and differed from those of the background water samples belonging to the Na+K-HC $O_3$ type (<10$^{-3.5}$ atm). Considering that the p$CO_2$ of soil water (near 10$^{-1.5}$ atm), this indicates that inflow of shallow water is very significant in deep groundwaters in the study area. Furthermore, the P$CO_2$ values can be used as an effective parameter to estimate the relative recharge of shallow water and thus the contamination susceptibility. The results of our present study suggest that down to considerable depth, urban groundwater in crystalline aquifer may be considerably affected by the recharge of shallow water (and pollutants) from an adjacent area. We also suggest that for such evaluation, careful examination of systematically collected hydrochemical data is requisite as an effective tool, in addition to hydrologic and hydrogeologic interpretation.ion.ion.

The groundwater in the Pocheon area occurs from both a fractured bedrock aquifer in igneous and metamorphic rocks and an alluvial aquifer with a thickness of <50 m, and forms a major source of domestic and agricultural water supply. In this study, we performed a hydrogeochemical study in order to identify the control of geochemical processes on groundwater quality. For this study, groundwater level and physicochemical parameters (EC, Eh, pH, alkalinity) were monitored once a month from a total of 150 groundwater wells between June 2003 to August 2004. A total of 153 water samples (13 surface water, 66 alluvial groundwater, 74 bedrock groundwater) were also collected and analyzed in February 2004. Groundwater chemistry in the study area is very complex, depending on a number of major factors such as geology, degree of chemical weathering, and quality of recharge water. Hydrochemical reactions such as the leaching of surficial and near-solace soil salts, dissolution of calcite, cation exchange, and weathering of silicate minerals are proposed to explain the chemistry of natural groundwater. Alluvial groundwaters locally have very high TDS concentrations, which are characterized by their chloride(nitrate)-sulfate-bicabonate facies and low Na/Cl ratio. Their grondwater levels are highly fluctuated according to rainfall event. We suggest that high nitrate content and salinity in such alluvial groundwaters originates from the local recharge of sewage effluents and/or fertilizers. Likewise, high concentrations of nitrate were also locally observed in some bedrock groundwaters, suggesting their effect of anthropogenic contamination. This is possibly due to the bypass flow taking place through macropores. Tile degree of the weathering of silicate minerals seems to be a major control of the distribution of major cations (sodium, calcium, magnesium, potassium) in bedrock groundwaters, which show a general increase with increasing depth of wells. Thermodynamic interpretation of groundwater chemistry shows that the groundwater in the study area is in chemical equilibrium with kaolinite and Na-montmorillonite, which indicates that weathering of plagioclase to those minerals is a major control of hydrochemistry of bedrock groundwater. The interpretation of the molar ratios among major ions, as well as the mass balance calculation, also indicates the role of both dissolution/precipitation of calcite and Ca-Na cationic exchange as bedrock groundwaters evolves progressively.

본 연구는 친환경적 유기흡착제로서 휴믹물질의 활용성을 평가하기 위한 기초 연구로서 Peat moss에서 추출된 불용성 휴믹성분인 피트휴민(p-Humin)을 충진한 컬럼을 이용하여 카드뮴과 구리이온에 대한 파과곡선을 얻었고, 각 금속이온에 대한 제거능을 비교해 보았다. 카드뮴의 경우, 파과시간은 7.5 hr, 77 BV로 나타났으며, 구리의 경우, 7.3 hr, 76 BV으로 나타났다. Thomas model로부터 구한 최대 흡착량은 구리가 44.66 mg/g로 카드뮴의 41.61 mg/g보다 높게 나타났다. 0.05 N HNO$_3$를 이용한 탈질실험 결과, 각 중금속에 대한 회수율은 95% 이상으로 높았다.

A hybrid permeable reactive barriers(hybrid PRBs) composed of Fe(II) PRB, biological PRB and sorptive PRB was investigated to treat groundwater with multiple contaminations. We performed batch, column and pilot tests to determine removal rates and design parameters of each PRB media, and operated two hybrid PRB systems with pilot-scale barriers in series. The pilot test of the hybrid PRB system with the combination of Fe(II), biological media and black shale showed multiple contaminations could be removed in ground water. Nitrate could be treated below 20 mg/L and Cr(VI) was treated down to 0.05 mg/L. TCE was degraded below 0.001 mg/L in system. The hybrid PRB system with a proper combination of PRBs could remediate ground water with multiple contaminations.

Tetrachloroethylene(PCE) dechlorination was investigated in an anaerobic enrichment culture from landfill soil. Anaerobic PCE dechlorinating microorganisms could convert 150mg/L of PCE via trichloroethylene(TCE) to cir-1,2-dichloroethylene(CDCE) within 2 days at the optimum temperature of 30 to 35$^{\circ}C$. The enrichment culture could dechlorinate TCE but did not degrade other chlorinated aliphatic compounds, such as cDCE, trans-1,2-dichloroethylene, 1,1-dichloroethylene, 1,1-dichloroethane, 1,2-dichloro- ethane, and 1,1,1-trichloroethane during 5 days incubation. Several isolates from the enrichment culture did not show dechlorinating activity of PCE. Microbial analysis of the dechlorinating enrichment culture by using Polymerase chain reaction-Denaturing gradient gel electrophoresis (PCR-DGGE) method showed that at least three microorganisms were related to the anaerobic PCE dechlorination in the enrichment

The environmental tracers tritium/helium-3 (3H/3He) and chlorofluorocarbons (CFCs) were investigated in ground water from Jeju Island, Korea, a basaltic volcanic island. The apparent 3H/3He and CFC-12 ages were in relatively good agreement in samples with low concentrations of terrigenic He. Ground water mixing was evaluated by comparing 3H and CFC-12 concentrations with mixing models, which distinguished old water with negligible 3H and CFC-12, young water with piston flow, and binary mixtures of the two end members. The ground water CFC-12 age is much older in water from wells completed in confined zones of the hydro-volcanic Seoguipo formation in coastal areas than in water from the basaltic aquifer. Comparison of major element concentrations in ground water with the CFC-12 age shows that nitrate contamination processes contribute more solutes in young water than are derived from water-rock interactions in non-contaminated old water. Chemical evolution of ground water resulting from silicate weathering in basaltic rocks reaches the zeolite-smectite phase boundary. The calcite saturation state of ground water increased with the CFC-12 apparent (piston flow) age. In agricultural areas, the temporal trend of nitrate concentration in ground water was consistent with the known history of chemical fertilizer use on Jeju Island, but the response of nitrate concentration in ground water to nitrogen inputs follows an approximate 10-year delay. Based on mass balance calculations, it was estimated that about 40% of the nitrogen applied by fertilizers reached the water table and contaminated ground water resources when the fertilizer use was at the highest level.

지하수중에 존재하는 극미량의 환경방사성 동위원소를 측정하기 위한 방법을 개발하였다. 각 핵종들중 234U, 238U, 222Rn, 226Ra은 섬광액을 포함한 용매추출법을 사용하여 개별분리한 후 액체섬광계수기를 사용하여 각 핵종에서 방출되는 알파선을 검출하였다. 환경방사성 원소인 U과 Th 딸핵종의 비평형에 의한 지하수 특성 연구를 위해서 국내 지하수 중의 234U와 238U의 방사능비 측정을 대전 화강암 지역에서 채취한 지하수 시료를 ICP/MS를 사용하여 U 함량을 결정하고, 지하수에서 U을 용매추출한 후 알파전용 액체섬광계수기를 사용하여 234U와 238U의 방사능을 측정하였다.

수자원을 평가하기 위해서는 먼저 한 지점에서 측정된 강수량을 보간해야 할 필요가 있다. 이를 위하여 강수현상에 영향을 주는 지형변수를 TOVA(Topographic Variables Extraction Program)를 이용하여 고도(ELEV), 경사(SLOPE), 바다까지의 거리(SEA), 방해물(OBST), 방벽(BAR), 굴곡도(SHIELD)로 구분하고 2000.1.1부터 2002.12.31까지의 강수량 자료를 사상별로 추출하여 이들을 서로 비교 분석하였다. 결정계수로 보면 각기 강수사상마다 지형의 영향이 다르게 나타나며 ELEV와 남서방향의 SLOPE, OBST 그리고 전 방향의 SHIELD가 강수량과 관계가 깊은 것으로 나타났다. 다중회귀분석 모형은 강수량의 공간적 변동량의 96%를 설명한다.

본 논문에서는 국내의 서-남해 연안지역에서 광범위하게 발생하고 있는 해수침투의 확산방지를 위하여 해수침투보호구역이라는 개념을 소개한다. 해수침투보호구역을 설정하기 위해서는 해당 지역 해수침투대의 고분해능 염분농도분포가 필요하며 이와 같은 염분농도분포도는 물리탐사 기술로 작성이 가능하다. 전남 영광지역에서 물리탐사 기술로 작성한 해수침투대의 고분해능 염분농도 분포도는 시험시추 결과, 매우 신뢰성이 높았으며 염분농도의 공간적인 분포도에서 해수침투로 인한 지하수 개발 제한지역, 보호구역 등에 대한 설정이 가능하였다. 향후, 해수침투의 확산방지와 지속적인 지하수의 개발이 가능한 해수침투보호구역설정에 대한 후속적인 조치가 필요할 것으로 판단된다.

To investigate the in-situ REV, cross-correlations between the ablsolute value of iu/outflux in tested boreholes and fracture frequency with various window widths were calculated. The changes of vertical flow rates can be considered as iu/outflux into/out of borehole. The results of cross-correlation analysis shows that 7m can be the most appropriate width of the appliable window.

This study was conducted to calculate the permeability coefficient in a single fracture while taking the true fracture geometry into consideration. The fracture geometry was measured using the confocal laser scanning microscope (CLSM). The CLSM geometry data were used to reconstruct a fracture model for numerical analysis using a homogenization analysis (HA) method. The HA is a new type of perturbation theory developed to characterize the behavior of a micro-inhomogeneous material that involves periodic microstructures. The HA permeability was calculated based on the local geometry and local material properties (water viscosity in this case). The results show that the permeability coefficients do not follow the theoretical relationship of the cubic law.

To investigate the chemical and microbiological characteristics of groundwater and surface waters in contaminated sites, hydrochemical and microbial community analysis were executed. Different indigenous bacteria were observed at 4 contaminated sites and this is considered to decompose the contaminants of groundwater. The research results showed the close relationship between hydrochemistry and microbial characteristics and those are used for the information of natural attenuation and enhanced bioremediation.

과거 광미장으로 사용되었던 곳을 복토 후 농경지로 전환한 지역을 대상으로 채취한 벼의 중금속 체내 흡수도를 평가하고자 하였다. 오염된 논에서 채취한 벼 뿌리의 중금속 함량은 배경 뿌리시료에 비교하면, Cd 65배, Pb 24배, Zn 15배, As 8.4배, Ni 3.5배, Cu 2.3배, Mn 2.1배 및 Cr 1.6배가 더 축적되어 있었다. 줄기의 경우, 배경 줄기시료에 비교하여 Pb 10.2배, Cd 5.4배, Zn 4.2배, Wi 1.9배, Cu 1.5 배, Cr 1.3배 높은 것으로 나타났다. 논토양으로부터 뿌리로 흡수되는 중금속 함량은 매우 큰 것으로 나타났으나, 뿌리로부터 줄기로의 체내 흡수도는 급격하게 감소하는 것으로 나타났다.

본 논문은 광산산성배수(AMD)에서 철 및 알루미늄 제거 효과가 입증되고 ARD(Acid Rock Drainage)에서의 비소제거 효과가 확인된 인회석을 침전제로 사용하여 철, 알루미늄 및 비소가 아닌 다른 중긍속의 제거효율을 알아보기 위해 도금폐수를 이용하여 실내실험을 실시하였다. 실험결과, 도금폐수의 수질분석결과에 의하면 '수질환경보존법 오염물질 배출허용기준' <가>지역 방출수 기준을 초과하는 것은 pH, Zn, Fe, Cu, Cr 및 P였다. 실험 결과 인회석 40번체 통과분-100번체 잔류분을 사용하는 것이 가장 적절할 것으로 생각되며 유속은 1kg의 인회석에 11의 도금폐수를 3시간 동안 반응시키면 경제적, 시간적 측면에서 가장 적절한 것으로 사료된다. 이 경우 pH는 1.98에서 5.30으로 증가하고 Cr, Fe, Cu 및 Zn은 각각 77.10%, 99.58%, 99.39% 및 40.77% 제거되는 것으로 나타났다. 용해율은 0.3619 g/min/kg으로 계산되었다. 그러나 3시간의 반응시간으로는 크롬 및 아연을 기준치 이하로 제거하지 못하므로 인회석 반응조를 다단계로 하는 실험을 수행해 그 결과를 평가해야 할 것이다.

Little study has been published specifically addressing the dynamics of nitrate reducing bacteria (NBR) during the bioremediation of nitrate-contaminated aquifer. In our previous study we successfully quantified fumarate-enhanced microbial nitrate reduction rate in a nitrate-contaminated aquifer by using a series of single-well push-pull tests (PPTs). In this study we analyzed the suspended population during PPTs. To monitor changes in the microbial community, PCR amplification of 16S rDNA genes and denaturing gradient gel electrophoresis (DGGE) were used to study the dynamics of the bacterial community in detail. Before the stimulation of NBR, the dominant DGGE bands obtained by PCR were affiliated with V-Proteobacteria consisting of Acinetobacter spp. and Pseudomonas fluorescens. However, as NBR biostimulation proceeded, the dominant patterns of DGGE bands changed, and they were affiliated with Azoarcus denitrificans Td-3 and Flavobacterium xanthum. Azoarcus denitrificans Td-3 is known to completely reduce nitrate to nitrogen gas. The series of single-well push-pull tests in this study should prove useful for conducting rapid, low-cost feasibility assessments for in situ denitrification and provide important information about which microorganisms play a key role in bioremediation of a nitrate contaminated aquifer.

Electrokinetic bioremediation was conducted on phenanthrene-contaminated soil to study the effects of soil temperature and pH on microbial population and removal efficiency at different current densities from 0.63 to 3.13 mA cm$^{-2}$ . Microorganism used in the biodegradation of phenanthrene was Sphingomonas sp. 3Y, which was isolated from a diesel-contaminated site. The microorganism was successfully penetrated into the contaminated soil by electrokinetic phenomena and the highest microbial population was observed in the middle region of soil specimen where soil pH was near neutral. Therefore, phenanthrene removal occurred mainly at anode and middle parts of soil specimen due to a relatively high microbial population. Also, the highest removal efficiency of 68.8% was obtained at 1.88 mA cm$^{-2}$ while low degradation was detected at 3.13 mA cm$^{-2}$ . It was presumably because the soil temperature at 1.88 mAcm$^{-2}$ was close to the appropriate temperature of about 30'c while the temperature increase to above 45$^{\circ}C$ at 3.13 mA cm$^{-2}$ inhibited the microbial activity severely.

The electrokinetic bioremediation employing electrolyte circulation method was carried out for the cleanup of phenanthrene-contaminated kaolinite, and microorganism used in the biodegradation of phenanthrene was Sphingomonas sp. 3Y. The electrolyte circulation method supplied ionic nutrientsand the microorganism into soil, and inhibited the significant pH change of soil by increasing the soil buffering capacity by providing phosphate buffer compounds. When the remediation process was conducted without surfactant, the removal efficiency of phenanthrene, at the initial concentration of 200 ppm, was 69% for only 7 days. Higher microbial population and lower phenanthrene concentration were observed in the anode and middle regions of soil specimen than in the cathode region. The higher density of microorganism was because the microbial movement was in the direction of the anode part due to the negative surface charge. When Triton X-100 and APG of 20 g/1 were used to improve the bioavailability of phenanthrene strongly adsorbed onto soil surface, about 90 and 39% of phenanthrene removal were obtained. Consequently, it was confirmed that the microorganism preferred APC to phenanthrene as carbon source and so the removal efficiency with APG decreased less than that without APG.

The concentration of hydrogen peroxide in soil and effluent was measured to understand the relationship between the profile of hydrogen peroxide and the removal efficiency of phenanthrene in an Electrokinetic-Fenton process. Electrokinetic phenomena were observed in two different conditions for 1, 2, 4, and 7 days; 3.5% and 10% hydrogen peroxide. The concentration of hydrogen peroxide in soil was high near the anode and decreased towards the cathode due to the direction of electroosmosis. The hydrogen peroxide concentration in effluent increased with time, but the value was lower than the initial. The removal efficiency of phenanthrene at 10% hydrogen peroxide was higher than the case at 3.5%. The removal efficiency after 7 days was high(> 97%) in both cases.

This study applied EK method to remediate contaminated soil by heavy metal(Pb), tried to increase the efficiency of remediation using zeolite as enhanced EK remediation method to overcome the limit of traditional EK remediation method. Adsorption tests on Pb were conducted to apply the EK extraction and test conditions which contained the electrode reversal, operating time were established. After tests, lead-ions were transported into the specific position of zeolite by EK phenomena, then the immobilization of lead-ions at zeolite was developed. Based on these tests, the efficiency of remediation is different with its test conditions. In addition, the efficiency of remediation was improved dramatically by adding zeolite without electrode reversal and satisfied TCLP regulation of EPA in USA through the whole sample range. Finally, absorption and immobilization capacity of zeolite were proved its excellence and confirmed the possibility of application as enhanced EK remediation method.

In this study the field-scale tests were performed in which in-situ E/K remediation technologies were applied, and then the results were present. For traditional E/K remediation method the efficiency of remediation is not large, but the enhanced method with citric acid significantly increases the removal efficiency. Also EDTA, reported as a good enhancement agent for removal of heavy metals, is similar to that of citric acid. Therefore citric acid is preferred rather than EDTA in view of the cost on the contaminant removal per unit concentration.

To analysis the electrokinetic phenomena in the ground dependent on the way of applied electric power, such as constant current and constant voltage, the governing equations are derived considering advection, diffusion, ionmigration, and then they were formulated using by finite difference method. The developed program is verified by comparing the tested and predicted results reported in present papers. The results indicate that the slightly small electrical potential is predicted for constant current and for constant voltage pH near to the cathode was small than the test results. But the other predictions including the final suction, pH of electrolyte and cumulative flow are similar to the test results and predictions.

Effect of electron accepters on anaerobic degradation of petroleum hydrocarbons by an anaerobic sludge taken from a sludge digestion tank in a soil artificially contaminated with 10,000 mg/kg soil of diesel fuel was tested. Treatments of soil with 30 mL of the digestion sludge (2,000 mg/L of vss (volatile suspended solids)) were incubated under several anaerobic conditions including nitrate reducing, sulfate reducing, methanogenic, and mixed electron accepters conditions for 120 days. Treatments with the digested sludge showed significant degradation of diesel fuel under all anaerobic conditions compare to control treatments with an autoclaved sludge and without the sludge. The amount of TPH degradation after 120days incubation was the largest in the treatment with the sludge and mixed electron accepters (75% removal of TPH) followed in order by sulfate reducing, nitrate reducing, methanegenic condition as 67%, 53％, 43%, respectively. However, the rate of TPH degradation in the nitrate- and sulfate reducing condition within 105 days were comparable with that of the mixed electron accepters condition. Microorganisms in each electron acceptor condition were plated on solid mediums containing nitrate or sulfate as sole electron acceptor and several nitrate- and sulfate reducing bacteria showed effective degradation of diesel fuel within 30 days incubations. These results suggest that anaerobic degradation of diesel fuel in soil with digested sludge is effective for practical remediation of soil contaminated with petroleum hydrocarbons.

MTBE로 오염된 토양에서 생태독성학적 접근 방법으로 3가지 토양 효소의 활성도를 측정해 보았다. MTBE의 잠재적 위험성으로 인한 논란은 계속되고 있으나 토양 오염에 대한 지표로써 토양 효소 활성도의 사용타당성 여부에 대한 실험은 이전에 행해지지 않았다. 따라서 중금속 오염 토양에 대해 좋은 지표로 사용되고 있는 토양 미생물 효소의 활성도를 MTBE에 적용하여 실험해 보았다. 사용한 토양 효소는 Acid Phosphotase, $\beta$-Glucosidase 그리고 Arysulfatase였다. 그러나 실험 결과 MTBE로 오염된 토양의 경우 중금속으로 오염된 토양에 비해 토양 미생물 활성도의 감소가 매우 적었다. 따라서 MTBE의 오염 토양의 경우 본 연구에서 측정된 효소의 활성도는 좋은 지표로 적합하지 않다는 것을 확인했다.

The electrokinetically enhanced soil flushing had a great potential to improve the removal efficiency of polycyclic aromatic hydrocarbons (PAHs) from low permeable soils. A semi-pilot study of surfactant-enhanced electrokinetic process was investigated for the removal of phenanthrene from kaolinite. A nonionic surfactant, Tergitol 15-S-12 at 10 g/L was introduced as a flushing agent and 0.001M of sodium chloride was used as an electrolyte. When the constant voltage of 100 V was applied to the system for 25 days, only 0.66 kWh of electric power was consumed and the amount of electroosmotic flow was 6.9 L. The removal efficiency of phenanthrene was about 40 % and it can be improved by increasing the ion concentration of the flushing solution or the applied voltage.

Removal characteristics of Mn and Co was studied from the contaminated solutions via surface reaction with various calcium carbonate (calcite). Synthetic calcium carbonates which has different surface morphology as well as surface areas were prepared by a spontaneous precipitation method and used. Mn and Co removal behavior by the different solid surface demonstrate characteristic sorption behaviors depend on the type of calcite used, such as surface area or surface morphology. Calcium carbonate crystals (mostly calcite) which exhibit complicated surface morphology (c-type) shows strong sorption affinity for Mn and Co removal via sorption than on the a-type or b-type calcite crystals of less complicated surfaces. The applicability of two kinetic models, the pseudo-first-order kinetic equation and the Elovich kinetic model was examined on these sorption behavior. Elovich kinetic model was found more suitable to explain the very early stage adsorption kinetics, while the pseudo-first-order kinetic equation was successfully fitted for the adsorption kinetics after 50 hours.

The importance of a proper sample preparation and analysis technique has getting attention due to the complicity of toxic elements of interest from environmental samples depend on analytical purposes. It is critical to use proper analytical method to evaluate trace elements concentration in many environmental samples especially for making remediation decisions. Therefore, it is critical to apply a proper sampling and analytical method such as EPA publication SW-846 (Test Methods for Evaluating Solid Waste, Physical/chemical Methods). The objective of this study was to compare the USEPA Methods 3050B, modified 3050B, 305 la, and KBSI method (modified EPA 3052 Method) in term of recovery rate of metals. The NIST SRM (Montana soil) was used to compare the extraction and digestion efficiency. After sample has been collected the analysis were achieved by ICP-MS (Elan 6100, Perkin Elmer) as well as ICP-AES (Ultima 2C, JY) for trace elements and major elements.

Two extraction techniques, Ultrasonic and Microwave extraction method, were tested for the determination of arsenic in contaminated soil SRM (Montana Soil). The extraction mixture was prepared by mixing 1 M ortho-phosphoric acid and 0.1 M ascorbic acid. This extractant was known to preserve arsenic species. The appropriate extraction time was 10 min to 20 min and the recovery rate was about 80%. A coupled system, SPE-HG-ICP-AES, was used for the determination of inorganic arsenic species. The detection limit was around 2 $\mu\textrm{g}$/1 and the linearity of calibration curve was better than $R^2$=0.99.

The experiments on some organic materials used in SAPS are carried out for the better sulfate reduction efficiency and the longer lifetime. Organic materials include spent mushroom compost, sewage sludge, oak chip compost and the combination of there. Reactors with mushroom compost, sewage sludge, the mixture of mushroom compost and sewage sludge, and the mixture of mushroom compost and oak chip compost maintained pH higher than 6.0. Reactors with mushroom compost, the mixture of mushroom compost and sewage sludge, and the mixture of mushroom compost and oak chip compost maintained reduction condition. Reactors with sewage sludge, oak chip compost and the mixture of sewage and oak chip compost produced COD less than 2,000ppm. Reactors with sewage and the mixture of mushroom compost, sewage sludge, oak chip compost showed about 60% of sulfate removal ratios.

This study is to study accumulation of the heavy metals by riparian vegetation throughout analysis of the heavy metal concentration in riparian vegetation, water, and sediment near mine drainage. According to analyzing concentration of the heavy metals in riparian vegetation, water, and sediment, the heavy metal was indicated at the leaf significantly. Compared with the concentration of sediment soil, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 2.6, 2.6, 2.5, non-detect, and 1.5 times in leaf, Also those concentration have 9.6, 16.6, 2.5, 1.6, and 2.5 times in root. As the results, the author can know the sediment has a very relative to vegetation in mine drainage, because the increasing of concentration of heavy metal in sediment gives the more accumulative concentration of heavy metal in vegetation. Compared with the concentration of contaminated site and non-contaminated site. As, Cd, CN, Pb, Zn the maximum concentration in sediment soil was higher 5.7, 258.1, 10.9, 370.0, and 298.3 times respectively. In case of vegetation, the maximum concentration of the As, Cd, CN, Pb, Zn was higher 5.6, 62.3, 5.0, non-detect, and 30.6 times in leaf. Also those concentration have 8.5, 63.3, 2.6, 60.7, and 62.1 times in root. In this study, the author can surmise that there indicated a lot of adsorption with the heavy metal concentration in contaminated mine drainage.

매립지 차수층에는 다짐점토층이 사용되고 있지만 건조/수축, 동결/융해 등의 환경적인 영향에 대한 내구성을 향상시키기 위한 기능성 복합차수층에 대한 연구가 진행되고 있다. 본 연구에서는 원지반토양에 고화재를 첨가한 BLT층과 벤토나이트와 미생물 배양액을 첨가한 BLM 층으로 구성된 복합차수층의 차수기능과 BLM층에서 미생물 배양액 첨가에 따른 Bio-barrier 기능을 평가하였다. 원지반토양에 고화재와 벤토나이트를 각각 8, 10%(w/w)를 첨가하였r고, 미생물 배양액은 1%(v/w)을 첨가하였다. 실험결과 원지반토양은 SC계열의 토양으로 분류되었고, BLT, BLM 차수층의 8% 혼합비율에서도 1$\times$ $10^{-7}$cm/sec 보다 낮은 투수계수를 나타내었다. BLM 층에 첨가된 미생물 배양액에 의한 Bio-barrier 기능 실험결과 미생물 배양액 첨가에 의하여 침출수에 대한 내구성이 향상된 것을 확인할 수 있었다.

일반적으로 유기오염 물질의 경우 sequestration 또는 aging 현상에 의해 탈착저항성을 띠게 되는 것으로 알려져 있다. 그러나 중금속의 경우 흡/탈착반응은 탈착저항성이 없는 가역적 반응이라는 보고가 있는 반면 홉/탈착 반응은 비가역적이며 탈착저항성이 존재한다는 보고도 있다. 본 연구에서는 해양 연안 퇴적물에 대한 납의 흡/탈착 실험을 통하여 탈착 저항성을 화인하고 연속추출 실험을 수행함으로써 탈착 저항성 부분의 크기를 규명하고자 하였다. 그리고 각기 다른 pH(4, 6)에서 흡착 실험을 수행함으로써 pH에 따른 흡착친화도를 규명하였다. 그 결과 퇴적물에 대한 납의 흡착량은 높은 pH(6)에서 더 많았고, 각 pH 범위에서 납은 탈착저항성을 가지는 것으로 나타났으며, 연속추출결과 Organic Material bound부분에 66% 정도가 흡착되어 있음을 알 수 있었다.

본 연구에서는 인산염을 이용여 납으로 오염된 Clay 사격장과 인위적으로 오염시킨 자연토양의 중금속의 고정화 실험을 수행하였다. 인산염 고정화제로는 DAP (diammonium phosphate)를 사용하였다. DAP를 투입한 중금속 오염토양을 고정화 실험과 TCLP로 용출 하였을 때, 99% 정도 고정화되었다. 인산염 투여양이 증가할수록 고정화 효율은 증가하는 것으로 나타났으며, 최적 인투입량은 128 mmol as P/kg인 것으로 나타났다. DAP 투입양이 증가할수록 토양의 pH는 증가하는 것으로 나타났으며, 토양의 초기 pH 변화에 따라 고정화 효율은 크게 변하지 않은 것으로 나타났으나, pH가 높을수록 고정화 효율은 작은폭으로 증가하는 것으로 나타났다.

In this study, the combined electrokinetic and ultrasonic remediation technique onto simple soil flushing was studied for the enhancement of water and liquid flows and the removal of contaminants in contaminated soils. The ultrasonic technique has been used to increase liquid flow and remove pollutants in contaminated soil. The laboratory soil flushing tests combined electrokinetic and ultrasonic technique were conducted using specially designed and fabricated devices to determine the effect of these both techniques. A series of laboratory permeability experiments involving the simple, electrokinetic, ultrasonic, and electrokinetic & ultrasonic flushing test were carried out. A soil admixed with sand and kaolin was used as a test specimen, and Pb and ethylene glycol were used as contaminants. An increase in out flow, permeability and contaminant removal rate was observed in electrokinetic and ultrasonic flushing tests.

The purpose of this study is to investigate environmental characteristics and in-situ hydraulic conductivity by eco cone penetration system. The underground environments and permeability of site was investigated and analyzed by this eco cone system. The electrical resistivity, pH, ORP, temperature and hydraulic conductivity were measured by eco cone penetration system. This eco cone penetration system provides a continuous environment and permeability profiles in underground, and provides reliable results for investigation of normal and contaminated ground.

대부분의 유기물은 토양의 특성에 따라 그 흡착 및 탈착 양상이 다르며 이는 오염물질의 토양에서의 지속성 및 이동성에 영향을 미치게 된다. 본 연구에서는 대표적인 유기오염물인 PAH(Polycyclic Aromatic Hydrocarbon)에 대하여 흡착 및 탈착과 오염물질의 미생물 분해 등을 통한 제거 기작과의 연관성을 연구하고자 한다. PAH의 이론적인 미생물분해반응식은 열역학적 이론을 바탕으로 하는 반쪽반응방법을 사용하여 예측할 수 있다. 오염물과 토양의 특성에 따른 흡착 및 탈착 양상을 파악하고, 앞에서 구한 미생물 분해반응식을 이용하여 이론적 분해량을 예측하면 오염물의 생물학적 이용성과 노출량을 결정할 수 있다 이를 위하여 본 연구에서는 토양의 여러 특성을 분석한 후, PAH의 미생물 분해량 및 분해율을 측정하고자 한다. 실험을 통하여 실제 토양에서 측정된 PAH 분해량과 위의 이론적 분해량 예측 결과 사이의 관계를 토양의 특성을 이용하여 설명할 수 있으며 나아가 오염물질의 생물학적이용성에 관하여 개략적으로 일반화된 예측 모형을 얻을 수 있을 것이다. 본 연구를 통하여 토양과 유기오염물질, 미생물간의 상호 작용에 대한 이해를 높이고 보다 실질적인 유기오염물의 생물학적 이용성을 예측할 수 있는 방안을 마련할 수 있을 것이다.

The use of colloidal gas aphron (CGA), as an external oxygen carrier, provides a promising alternative to promote aerobic bioremediation of BTEX in the subsurface environment. CGA is a stable bubble supported by three surfactant layers and can supply oxygen below the soil surface uniformly due to its plug-flow characteristic. Since CGA has a hydrophobic layer that can act as a partitioning medium for hydrophobic contaminants it is known to facilitate desorption of soil-sorbed contaminants. In addition, bioaugmentation and biostimulation are possibly achieved by using CGA when generated from a solution containing BTEX-degrading microorganisms and appropriate nutrients. In this study, we presented the physico-chemical characteristics of CGA generated from a solution composed of microorganisms and nutrients. The applicability of CGA as an in situ aerobic bioremediation technology of BTEX will be further evaluated.

The adhesion of hydrocarbon degrading bacteria(HDB) differing in surface hydrophobicity was investigated. Cell wall hydrophobicity was modified chemically and physiologically. Modified adhesion deficient mutant of HDB was selected in a soil column assay. Physiologically and chemical modification increased cell surface hydrophobicity. Cell surface characteristics including BATH and FTIR were measured. Physiological modification using ampicillin was not stable, but chemical modification was stable. Hydrocarbon degrading efficiency was measured of TPH modified and unmodifed HDB.

TCE and PCE, suspected carcinogens, are the most common groundwater pollutant from extensive use as a solvent and degreaser. Escherichia coli TGI pBSKAN TOM Green and E. coli TGI pBSKAN ToMO, which were used DNA shuffling technique, produce Toluene-o-monooxygenase(TOM) and toluene-o-xylene- monooxygenase(ToMO). These cells and enzymes are degrading TCE and PCE, TOM and ToMO are needed to cofactor, such as NADH, NADPH and other cofactors. Used TCE and PCE degrading microorganisms experiment the contaminated material removal efficiency. A shunting test used NAD and Hydrogen peroxide.

폐기물 매립시설물은 지진에 의해 파괴될 경우 시설물 파괴로부터 인명 및 경제적인 피해와 더불어 복구하기 어려운 환경적인 문제가 발생한다. 따라서 지진시 지반 및 구조물의 거동을 정확히 예측하기 위한 신뢰성 있는 지반 가속도의 증폭현상 평가가 필요하다. 본 연구에서는 1차원 지반응답특성 평가 프로그램인 SHAKE91과 유한차분 프로그램인 FLAC을 이용 하여 폐기물 매립지에서의 지진거동 특성을 분석하였다. 1차원 해석결과 연약층이 존재하는 곳에서 지반변형이 많이 이루어졌고, FLAC 해석결과 폐기물층 사면부에서 뚜렷한 변위벡터가 발생하였으나 내진 2등급 매립지의 허용변위 30cm 이내이므로 해석 대상 구조물은 안전함을 알 수 있었다.

On site, In situ soil remediation technologies are very important among the remediation technologies and in general efficiency of these technologies are turned to site characterization and environmental condition. specially using of only one technology has so many limitation factors. for example, existing state of tailing and channeling and so on. actually, filled land have high concentration cation exchange capacity because of existence in abundance soil organic matter. Therefore we used various on site in Situ technologies by phase for overcome the limitation factors. Target site is petroleum (diesel) impacted filled land and using technologies are SVE(Soil Vapor Extraction), BV(Bioventing), Bioremediation, Soil flushing, Chemical oxidation.

Heavy metal contamination has been increased in aqueous environments near many industrial facilities, such as metal plating facilities, mining operations, and tanneries. The soils in the vicinity of many military bases are also reported to be contaminated and pose a risk of groundwater and surface water contamination with heavy metals. The biological removal of metals through bioaccumulation has distinct advantages over conventional methods; the process rarely produces undesirable or deleterious chemical byproducts, it is highly efficient, easy to operate and cost-effective in the treatment of large volumes of wastewater containing toxic heavy metals. In addition, a recent development of molecular biology shed light on the enhancing the microorganism's natural remediation capability as well as improving the current biological treatment. In this study, characteristics of the cell growth and heavy metal accumulation by Saccharomyces cerevisiae strains expressing phytochelatin syntahse (PCS) gene were studied in batch cultures. The AtCRFI gene was demonstrated to confer substantial increases in metal tolerance in yeast. PCS-expressing cells tolerated more Cd$^{2＋}$ than controls.

It was revealed that leaching of elements were partly inhibited because seawater contains plenty of dissolved ions than fresh water. On the other hands, the low activity coefficient and the formation of complex with chloride and sulfate play roles in enhancing element leachability. However, the pH buffaring capacity of seawater is the most important factor that makes the leaching of elements and its chemical behavior in the seawater system different from those in the fresh water environments. In general, the leaching from the weathered ash was smaller than that from the fresh ash. However, it was revealed that the leaching of Si, Fe, Al, Mn, phosphate, and some other elements were independent of ash weathering. They were dependant only on the pH of the solutions.

댐수몰 예정지 상류에 일반적으로 분포하는 폐광산, 축산단지, 군사격장 등의 점오염원에 의하여 댐수몰 예정지 상류지역의 지하수 및 토양이 오염된 사례가 많으며, 이러한 오염은 댐 건설을 위한 적지선정시 장애요소로 작용하고 있고, 댐 건설중에도 댐저수지 수질을 지속적으로 악화시키는 요인들로 알려져 있다. 특히, 지하수내에 잔존하는 오염물들은 지하수 유동특성상 장기간에 걸쳐 서서히 진행되므로, 댐건설이 완료된 담수후에도 지속적으로 수질에 영향을 미치게 된다. 이에 따라 국내외에 수행되었거나 진행중인 댐수몰 예정지의 오염조사 평가 및 복원ㆍ정화 사례를 조사하는 한편, 현재 댐건설이 예정된 지역에 대하여 직접적인 현장조사를 실시함으로써 국내에 적합한 조사ㆍ평가 기법과 복원ㆍ정화 기법을 개발, 제안하고자 한다.

Probabilistic approaches are applied to the problem of groundwater remediation design to consider the risk of design and heterogeneity of real condition. Hydraulic conductivity fields are generated by two methods. First, the homogeneous domains which have the hydraulic conductivity with log-normal distribution are constructed by using Latin Hypercube method. Second, random fields with a certain spatial correlation are also generated. The optimal solutions represented by cumulative distribution function (CDF) of relative cost are calculated by three different manners. The one uses the homogeneous domains with the optimal design of base condition. It shows that ver)'wide range of cost and the influences of different penalty values. The other one uses the random field with same design and shows narrow range of cost. These CDF can reflect on the risk of optimal solution in a simple exampie condition and be effective in estimating the cost of groundwater remediation.

The unsaturated zone is a significant pathway of the surface contaminant movement and is a highly heterogeneous medium. Therefore, there are limitations in applying conventional convection-dispersion equation(CDE). Artificial neural network(ANN) is considered to be a versatile tool for approximating complex functions. For evaluating the applicability of ANN, numerical tests using ANN were conducted with training set generated by HYDRUS-2D which is based on CDE. The results represent that ANN can estimate the solute transport and the choice of network parameters and generation of training set patterns are important for efficient estimation.

Single-well tracer tests, especially push pull tracer tests, are more effective to estimate hydraulic parameters and microbial metabolic activities in terms of duration and cost compared to multi-well tracer tests. However, there are some drawbacks in accuracy, complicated data analysis and uniqueness. These shortages are thought to be derived from the applied conditions which affect mass recovery curve and breakthrough curve. Factors such as extraction rate, resting period, hydraulic conductivity and hydraulic gradient are considered as the major factors determining the mass recovery rate and shape of the breakthrough curve. The results of the sensitivity analysis are summarized as follows: 1) the significant change in concentration of breakthrough curve is obtained when the extraction rate increases. This effect would also be much higher if the hydraulic conductivity is lower; 2) the mass recovery rate decreases with the increase of resting time, and the difference of mass recovery rates for different resting times is inversely proportional to the hydraulic conductivity; 3) the sensitivity values decrease with time. The hydraulic conductivity affects not only the early period, but the later period of the breakthrough curves; 4) The influence of the hydraulic gradient on the breakthrough curves is greater at earlier stage than at later stage. The mass recovery rate is inversely proportional to the hydraulic gradient.

정압주입시험(Constant Head Injection Test, CHIT)은 결정질 암반의 구간별 수리전도도 및 투수계수를 구하는 전통적인 수리시험방법이다. 본 연구에서는 Visual Modflow 수치코드를 사용하여 정압주입시험에 대한 부정류 모의를 수행하였다. 수치모의 결과 주입공에서 매질로 시간별 주입되는 유량은 30분이 경과한 후부터 거의 일정하게 유지되는 양상을 확인할 수 있는데, 현장에서 정압주입시험을 할 때 적어도 30분 이상의 시첩을 실시해야 함을 알 수 있었다. 시험구간에 따른 수리전도도 값은 시험구간의 크기에 상관없이 거의 일정한 값을 보이고 있어, 시험구간의 크기는 정압주입시험에서 크게 유의하지 않아도 된다고 판단된다. 그러나, 시험구간별 주입 압력에 따른 수리전도도 값의 변화를 살펴본 결과, 시험 구간의 크기와 주입 압력 값이 클수록 산출되는 수리전도도 값이 매질의 수리전도도 값과 차이가 나는데, 현장조사에서 시험구간과 주입 압력 값에 대한 고려가 있어야 함을 지시한다. 매질의 수직적 이방성에 따른 모의결과 $K_{zz}$ / $K_{xx}$ and $K_{yy}$ 값이 작아질수록 수리전도도 값이 작아지는데, 현장조사 결과를 해석함에 있어 매질의 수직적 이방성은 주의를 기울여야 한다.

국내 충적층의 철, 망간 문제는 지속적으로 지적되어오던 수질항목이다. 충적층 지하수 내 철과 망간의 용존 특성을 확인하고자 강변여과수 부지에서 지하수의 수리지화학적 특성을 조사하였다. Fe와 Mn에 의해 오염된 관정은 D-2와 DS-3로 모두 3월에 채취한 시료이며 NO$_3$-N는 모두 0 m/L 이다. NO$_3$-N에 대해 다른 관정은 2 mg/L NO$_3$-N를 넘고 있으며, DS-8와 DS-3에서 11.30과 20.2 mg/L NO$_3$-N의 값으로 먹는물 수질기준을 초과하고 있다. Mn에 대해 오염된 관정은 SJ-3이다. 10월에 채취한 시료에서 DS-2+l8 m에서 채취한 시료가 1.16 mg/L인 것을 제외하고 대부분의 시료가 2 mg/L를 초과하고 있고, DS-6+l3 m과 SJ-3＋10 m에서 채취한 시료가 각각 10.71과 10.31 mg/L NO$_3$-N로 먹는물 수질기준을 초과하고 있다. DO 검층 자료와 NO$_3$-N 농도를 이용하여 Fe와 Mn이 먹는물 수질 기준을 초과하는 D-2와 DS-2 관정의 지하수 체의 혐기성 상태임을 확인하였다. 강변여과수 지역은 전반적으로 NO$_3$-N에 대해 인위적인 오염이 발생하고 있으며, 혐기성 상태 구간이 존재함에 따라서 Fe와 Mn이 먹는물 수질 기준을 초과하여 용존 상태로 존재한다.

The groundwater system of the Cheonggyecheon watershed is very complicated because it is influenced by many factors such as pumping out, groundwater leakages into subway stations, civil use of groundwater, and leaking water from water supply and sewage lines. So the characterization and evaluation of the groundwater flow and contaminant transport in the Cheonggyecheon water system is quite a difficult task. The purpose of this study is to analyze the influence on the‘groundwater’ below the Cheonggyecheon watershed by the‘maintenance water’on the Cheonggyecheon stream after the restoration. We have so far collected groundwater quality data, hydrogeologic aquifer parameters, and the amount of leakages into subway stations and its influence on the groundwater system. Results show that groundwater level was influenced by the direction and depth of subway tunnel. This study will continue to monitor groundwater quality, a water level fluctuation relation between rainfall and groundwater recharge for further investigation of the groundwater flow system in the Cheonggyecheon watershed.

국내 폐금속광산 일대에서 비소 및 중금속의 발암 및 비발암 위해성을 근거로 복원 기준치를 설정하였다. 폐금속광산일대의 주요한 노출 경로는 부지내 폐광석과 광미로부터 직접적인 오염물 흡입과 지하수를 통한 부지내 및 외 섭취의 경로로 구분된다. 지하수의 오염원은 폐광석과 광미 침출로부터의 오염과 갱구 유출로부터의 오염 및 지질매체 자체에 의한 오염이 설정되었다. 높은 오염 수준에 대해서 높은 오염성분감소비와 폐광산일대의 다양한 배경농도로부터 복원기준치를 설정 했을때, 토양 및 지하수의 복원기준치는 비소 위해도의 영향이 매우 큰 것으로 평가되었다. 비소의 높은 독성은 복원 기준치를 매우 낮게 형성했고, 위해도가 낮은 아연과 카드늄은 높게 설정되었다. 궁극적으로 오염성분 감소비에 따른 복원기준치 설정은 오염성분의 노출 경로 차단이 복원 목표치를 현실화시킬 수 있음을 보여주었다.

Groundwater chemistry in Namwon area, Korea, was investigated to understand the contribution of geochemical processes on groundwater chemistry. For this study, a total of 279 groundwater samples were collected from 93 wells distributed over the study area. Higher concentrations of major ions are generally encountered in the shallow alluvial wells, suggesting that these chemicals are originated from the surface contamination sources. Mass balance analysis based on reaction stoichiometry reveals that the water chemistry is regulated by three major chemical processes: weathering of silicate/ carbonate minerals, input of C1/SO$_4$ salts, and nitrate generating processes. The results show that mineral weathering is the most dominating factor regulating the groundwater chemistry. However, the groundwaters with the higher salt concentration indicate the larger mineral weathering effect, suggesting that some part of the mineral weathering effect is also associated with the anthropogenic activities such as limes applied to the cultivated lands, carbonates (CaCO$_3$) in the cement materials.

This study was carried out to understand the geochemistry of saline water circulating in an ash disposal pond of Seocheon power plant, Korea. For this study, ash pond waters, slurry water and seawater samples were collected and analyzed for major ions and trace elements. Results show that ash pond waters and slurry water are alkaline in nature due to high calcium content, and have high concentration of Ca, B, Li, As, Ba, Al, Si and Mn over seawater, suggest that these elements leached from fly ash even at high alkaline condition and ionic strength. Slurry water has high concentration of B, Ba, Li, Mn, Si and Sr compare to ash pond waters, expresses that these elements seem to be easily reached at initial stage fly ash-water interaction, and also might be associated with the surface of the fly ash particles. Additionally, PHREEQC program predicted several secondary solid phases, which are also influenced in the leaching of elements in to the saline water.

국내에 산재해 있는 휴ㆍ폐광산은 주변의 하천이나 농경지에 지속적인 중금속 오염원을 제공하면서 많은 문제점을 발생시키고 있다. 여러 종류의 중금속으로 오염된 토양에 대하여 안정화 공법의 적용가능성을 알아보기 위한 실험을 실시하였다. 오염토양에 적절한 복토첨가제로 생석회와 석회석을 사용하여 첨가제를 넣지 않은 dh염토양과 중금속 용출율을 비교 ㆍ분석하였다. 이 결과 안정화 첨가제들이 Cd, Pb, Zn등의 중금속 용출을 억제하는데 높은 효율을 보여줌을 확인할 수 있었으며, 첨가제를 넣지 않은 토양과 비교한 결과 약 40배 이상의 용출율 감소를 보였다. 또한 실험 시에 첨가제 각각의 함량을 1%, 2%, 5%로 설정하여 현장 적용시 복토에 첨가할 적절한 양을 산출해 낼 수 있도록 하였다. 첨가제 주입으로 인한 용출율 감소는 하나의 중금속에 국한되는 것이 아니라 여러 원소를 동시에 효과적으로 안정화시킬 수 있는 것으로 나타났다. 본 연구 결과는 오염토양에 토양안정화공법을 적용 시에 중요한 자료로 이용될 수 있을 것으로 판단된다.

국내에 자연 방치된 폐광산에 대한 문제가 대두되면서 폐광산 주변지역에 대한 산성광산폐수와 중금속 광산폐기물의 오염실태조사가 활발히 진행되고 있다. 본 연구는 폐광산의 유출수와 광산폐기물에 주변 오염지하수 내의 중금속 As, Cd, Pb, Fe, Mn, Zn, Cu에 대하여 무기 응집제의 첨가와 pH의 조절에 의한 제거효율을 .실내 배치실험을 통하여 규명하였다. 본 실험을 통하여 황산알루미늄(Al$_2$(SO$_4$)$_3$ㆍ13～14$H_2O$), 염화 제2철(FeCl$_3$ㆍ6$H_2O$), 황산 제2철(Fe$_2$(SO$_4$)$_3$ㆍ n$H_2O$)을 이용하여 오염수내 중금속을 90%이상 제거할 수 있었으며, 폐광산 침출수나 오염 지하수의 중금속 제거에 0.1 wt%의 응집제 첨가만으로 응집제를 이용한 화학적 처리 방법이 효과적으로 사용될 수 있을 것으로 판단되었다.

in order to develop a new technique for the removal of arsenic compoundsfrom acidified water, the removal of arsenic compounds by an acidophilic moss, Jungermannia vulcanicola Steph. was investigated in this study. The result of vial tests for arsenic removal is dependent on the biological activity of moss. The presence of phosphate inhibited the arsenic removal. And the acclimatization of moss by the media containing arsenic increased the its capability of arsenic remova.

방사성폐기물 처분 연구의 일환으로 대전 유성북부 화강암 지역내 200～500m 심도를 갖는 9개의 심부 시추공이 착정되었으며, 이중 3개 시추공에 대하여 다중패커시스템이 설치되어 장기적으로 심도별지하수의 수리특성, 화학특성 및 동위원소 특성이 모니터링 되고 있다. 다중패커시스템이 설치되기 전의시추공 지하수의 수리 및 지화학 특성은 심도에 따라 별다른 특성이 보이지 않지만, 다중패커시스템 설치 후, 심도에 따라 특징적인 수리 및 지화학특성을 보여주고 있다. 또한, 다중패커시스템이 설치된 시추공의 경우, 최상부 구간을 제외하고 모든 구간 지하수의 수리화학특성은 일정기간이 경과한 후에는 각 구간별로 거의 일정한 값으로 유지되고 있음을 보여준다. 그러나, 지하수의 함양특성이 크게 변하는 우기 동안에는 지하수 수두압이 심도 약350m의 구간까지 변화되는 특성을 보여주고 있다. 동위원소특성 역시 심도구간에 따라 특징적인 값을 보여주며, 장기적으로 일정한 구간별 특정 값을 보여주고 있다.

This study presents the hydrogeochmical investigation to know the effect of geology and sources for water quality in small potable water supply system at rural area. The results of water quality in Geumsan area showed the 3.2% of water samples exceeded the limit of drinking water standard by bacteria. The hydrochemical investigation results indicated the high EC, Ca and HCO$_3$ in surface water and metasedimentary rocks and this is caused by the dissolution of calc-slicate minerals of metasedimentary rocks.

To investigate the vertical petrological and hydrological characteristics of fractured rock, geophysical and chemical logging were executed at 5 boreholes installed in the study area. The geophysical and hydrochemical logging data were analysed by using principal components analysis (PCA). Three main variables from PCA explained 86.4% of total variance of geophysical log data. The PCA results showed that PCl is closely related to groundwater properties and PC2 and PC3 are influenced by rock and fracture properties. Hydrochemical analysis indicated the presence of highly fractrued zone at the depth of 60m.

To identify the effect of landfill waste for groundwater and unsaturated air environment, soil gas survey and hydrogeochemical study were executed. The geology of the study area is granite and aquifer is mainly composed of sandy soil. The results of spatial distribution from soil gas showed the boundary of buried waste and processes and degree of waste decomposition. Groundwater contamination by leachate from landfill is controlled by groundwater flow attributed by the original topography and liner.

To know the occurrence and distribution of MTBE in groundwater, the analysis of groundwater around petroleum spill area was executed. The groundwaters of the 4 study sites are severely contaminated with MTBE and has the highest values of 650mg/L. The plume length of MTBE is longer than that of BTEX in D site and it is caused by the high solubility and low sorption capacities of MTBE.

임기납석광산 폐석적치장 상부의 계곡수로부터 폐석적치장 하부인 수영강 합수지점까지 수계를 따라 물시료 12개 지점을 대상으로 수질 및 안정동위원소 분석을 수행하였다. 폐석적치장으로부터 pH가 2.83이고 Fe, Al, Mn 등으로 심하게 오염된 산성배수가 유출되어 계곡수를 오염시키며 수계의 수질은 $Ca^{2＋}$-SO$_{4}$$^{2－}$ 형태로 변화되고 폐석적치장 주변 수로에 적화현상을 유발하고 있다. 또한 안정동위원소 분석결과 임기납석광산 인근 수계에 가장 큰 오염부하를 유발하는 요소인 침출수(산성배수)의 기원은 강수기원으로 판단된다. 이는 폐석침출수 오염원 평가 및 처리에 유용한 자료로 이용 될 수 있을 것이다.

This study was carried out to evaluate the acid producing potential of geological materials such as pit wall, waste rock and stream sediments near the abandoned Imgi mine. The 17 samples used in this study were collected and then treated by static test such as Acid Base Accounting and etc. Samples of pit wall and waste rocks with high S content display a NAGpH values below 4.5 and net acid potential. Therefore some cost effective measures such as capping and groudwater flow barriers, will be required to reduce the impacts of ARD from the waste rock impoundment and the pit wall on near the stream.

This study was carried out to plan the prevention of the generation and discharge of acid mine drainage (AMD). Hydraulic characteristics were tested with the disk tension infiltrometer around the waste rock dump of the Imgi abandoned pyrophyllite mine in Busan, Korea. Because the waste rock dump of the Imgi mine have very low infiltration rate, most of rain was expected flowing into adjoined stream through the slope or plane as surface flow rather then throughflow or ground water. But slopes of the waste rock dump have many 'V' type erosion gullies and consist multi-layers. These gullies and multi-layers have coarse clastic particle layer which have very large hydraulic conductivity. So through these coarse clastic particle layers a large part of rain flow into ground. And also these layers could be played a function of aeration path, which induced oxidation of sulfide minerals and generation of AMD continuously.tinuously.

An aquifer thermal energy storage (ATES) model is simulated by FEFLOW according to the scenario of heat pump operation in two layered confining aquifer. The scenario is consisted of 4 steps: 90 days pumping (west well) and waste water injection (east well: 35 $^{\circ}C$), 90 day s stop, 90days pumping (east well) and waste water injection (west well: 5 $^{\circ}C$), and 95 days stop. The injection of the waste water is limited in the second layer and the first layer is aquitard. The temperature distribution at the surface shows low difference with reference temperature and opposit aspect with that of the second layer because the thermal transition through the first layer is very slow. Even though the simulated thermal transition in the aquifer system have a difference with real ATES system, optimal design and operate system can be developed with field tests and operational experience.

일반적으로 폐광산 지역에 방치되어 있는 광미와 오염토양에 함유된 중금속원소는 자연 상태에서 물리ㆍ화학적 환경의 변화에 따라 자연정화 되거나, 또는 재용출되어 점 또는 비점오염원으로의 역할을 하기 때문에 광미와 오염된 토양에 존재하는 중금속의 존재형태를 규명 또는 예측하는 것은 매우 중요하다. 이에 따른 중금속의 오염평가와 존재형태를 규명하기 위해 서성 연ㆍ아연 폐광산 주변 경작토를 대상으로 Tessier et at. (1979)가 제시한 연속추출을 실시하였다. 그 결과는 As와 Cr이 잔류형태가 우세하여 안정한 상태로 존재하는 것으로 평가되었으며, 이에 반하여 Zn, Pb, Cu, Cd, Ni 및 Mn 등은 상대적으로 존재형태가 불안정한 것으로 평가되었다. 특히, As는 모두가 잔류형태로만 존재하는 것이 확인되어 As의 오염이 야기되지 않는 것으로 밝혀졌다.

최근 Lee et al.$^{l-2)}$ 은 화강암질 편마암내 균열면의 방해석이 Eu의 변화에 큰 영향을 주며, 아울러 Eu 은 Am의 유사체로서 매우 적합한 원소라고 제안하였다. 이 논문에서는 1)희토류원소와 액티나이드 원소의 이온반경, 배위수 등의 상호비교와 2) 응집력(cohesive energy)의 유사성과 물리적/화학적 특성 그리고 3) 희토류원소 지구화학의 최근 연구결과를 토대로 하여, 고준위 방사성 핵종원소인 Am의 지질매체내 거동을 예측하기 위한 유사체(analog)로서 Eu이 매우 유용한 역할을 해준다는 가설2)을 검증한 결과를 보고하고자 한다. 연구방법으로서, 핵종원소의 지질매체별 흡착특성을 밝혀내기 위해 금번 실험에서는 희토류원소 암상별 분포의 특성을 고려하여 4종류(화강암질 편마암류 2종, meta-basalts, 응회암)의 시료를 선별하였다. 방사화학적 흡탈착 실험의 핵종동위원소로서는 152Eu와 241Am을 선택하였다. 이는 본 연구팀의 연구결과, Eu과 Am의 밀접한 물리적/화학적 상관관계 그리고 지질환경내에서의 거동특성을 고려한 것이다. 실험결과 양 동위원소의 지질매체와의 흡착 반응 특성을 비교해 볼 때, 시간의 경과에 따라 서로간에 매우 유사한 양상의 증감을 보여주면서 변화함을 알 수가 있었다. 이 결과는 희토류원소가 액티나이드 원소의 지질환경내 거동예측을 위한 유사체로서 매우 훌륭한 도구라는 것을 입증해 주는 것이라 할 수 있다.

한반도남부에 분포하는 중생대의 화강암류는 경기육괴지역을 중심으로 분포하는 쥬라기의 대보화강암류와 옥천대 이남지역에 주로 분포하는 백악기의 불국사 화강암류로 크게 분류할 수가 있다. 우리나라의 4$0^{\circ}C$ 이상의 고온성 온천수는, 이암층으로 덮여있는 포항지역을 제외하고는 대부분이 상기의 화강암류 지역에 분포하는 특성을 지닌다. 이 논문에서는 우리나라의 고온성 온천수의 지구화학적특성, 특히 희토류원소의 분포특성을 화강암류의 분포지역과 비교하여 고찰해보고자 하였다. 화학분석에 이용된 온천수 시료는 2004년도 2월의 건기에 채취되었다. 이 연구결과에 의하면, 아산온천(구 온양온천), 덕산온천, 포천지구 및 속초지구와 같이 쥬라기 대보화강암류지역에 주로 분포하는 온천수는 PAAS(Post-Archean Australian Shale)로 규격화하였을 경우 경희토류(La-Sm)이 결핍되어 있고, 중희토류는 편평한 분포양상을 보여주었다. 그리고 Eu의 이상(anomaly)이 거의 존재하지 않으며, Ce의 경우 부(-)의 이상 (Ce netative anomaly)을 보여주기도 한다. 반면에 옥천대 이남에 분포하는 백암, 덕구, 부곡, 마금산, 동래, 해운대, 포항지구의 온천수들은 전반적으로 편평한 분포특성을 보여준다. 그리고 대체적으로 Eu 과 Ce의 강한 정(+)의 이상을 보여준다. 이와 같은 Eu과 Ce의 이상은 온천수와 대수층간의 반응에 따른 결과로서 사료된다.

TOC(total organic carbon)분석은 폐수 및 강수의 오염특성을 평가하기 위한 도구로서 BOD(biochemical oxygen demand), COD(chemical oxygen demand) 와 함께 사용되어 왔다. TOC 측정시간은 10분 정도로 BOD(5～6일), COD(2～3시간)에 비해 아주 짧은 시간에 측정할 수가 있으며, 전처리과정이 단순하고 정확도도 높은 것으로 알려져 있다. 본 연구는 지하수의 잠재오염성을 밝혀내기 위한 도구로 TOC를 활용하여 신뢰성 있는 분석 값을 얻기 위해서 시료의 채취, 보관, 측정까지의 최적 조건을 도출하는데 목적을 두었다. 아울러 시료 채취 후 일정 경과 시간에 따른 TOC의 변화를 관찰하였다. 시료채취 용기, 채취 후 산성화, 보관방법 및 기간에 대한 실험 결과, 대상 변수에 따라서 TOC의 농도변화에 커다란 차이점을 볼 수 있었다. TOC 농도가 낮은 지하수시료의 측정에서는 빛을 차단시킨 불투명 유리병을 사용해야만 하고 채취 즉시 산도를 높여(pH<2)주며 4$^{\circ}C$ 이하에서 보관하여야 한다. 지하수중 TOC 측정시료는 가능한 보관 기간에 있어서 채수 후 24시간 이내에 측정하는 것이 좋으나 1) 본 연구에서는 채취현장과의 거리를 고려하면 현실적으로 불가능하므로 기간에 따른 TOC 변화를 30일까지 측정, 조사하였다.

Self-potential (SP) survey was carried out at Pohang geothermal field. SP measurement showed clear positive anomaly at northern part of the test wells, which can be a up-flow zone of the deep geothermal water due to electrokinetic potential generated by hydrothermal circulation. To give a clearer image of the fluid flow pattern around the test wells, a two-dimensional numerical simulation was applied to construct a numerical block model of the fluid flow system based on SP and magnetotelluric survey results. The result suggests existence of two high permeability zones including the main manifestation area in the northern part of the test wells.

To understand runoff Phenomena in Jeju island, some streams are monitored automatically about stream stage, and water quality in Jeju Provincial Water Resources Management Office. Rating curves for stream discharge are reviewed. Stream stages respond very quick to some rainfall events, and parameters influencing runoff phenomena such as landuse, soil condition, preconditoned rainfall, and vegetables will be studied. A few thousand to ten thousand ml/day are estimated from 6 permanent streams in Jeju island.

In aquifers connected hydraulically, the levels of groundwater respond to stream stages. Analytical solutions by Laplace transform and convolution integral are used to get some response patterns about hydrogeoiogic parameter such as hydraulic conductivity, specific storage in confined aquifer. This method has the advantage to do hydrogeologic parameter estimations only with stream stage changes.

To understand the stratigraphy for a hydrogeological setting, borehole logging data are used. The test site is located in Mangyeong-river bank area in Dodeok-dong Jeonju. 11 boreholes are developed to monitor groundwater level and quality. Based on the borehole data, SOLID model is used to get the distribution of each layer.

남원에서 2002년 1월부터 2003년 12월까지 총 2년에 걸쳐 수행된 ‘남원지역 지하수 기초조사’는 ‘지하 수법’과 ‘지하수관리 기본계획’에 의하여 추진하는 ‘정밀 지하수 기초조사’로서 주요 조사 내용 중 세부지하수 조사에 속하는 장기적인 지하수 수위 변동 특성 및 지하수 수질 특성 규명을 위한 지하수 수위/수질 관측망 조사ㆍ분석이 실시되었으며 남원지역의 수위/수질 특성은 다음과 같다. 지하수 수위는 '02 년 6월부터 9월 사이에 수위가 급격히 상승하고 이후 수위가 점차 하강하다가 '03년 6월부터는 다시 수위가 상승하는데, 이는 강수의 영향을 받아 수위가 변동하는 것으로 해석된다. 지역적으로 상승 및 하강 양상이 크게 나타나기도 하는데, 이는 주변 관정에서의 양수나 관개수로로부터의 영향이 반영되는 것으로 보인다. 지하수 수질을 살펴보면, pH는 5～8 범위에 분포하고 있으며 EC는 주로 500$\mu$S/cm 이하이다. 수질유형은 절반 이상의 시료가 Ca-HCO$_3$ 유형을 보이고 나머지는 농업활동에 의한 오염의 영향으로 대부분 Ca-Cl유형을 보인다. 암반지하수와 충적층/풍화대 지하수의 수질 특성 차이는 크지 않다.

본 연구는 대천 유성지역 유성천 소유역에서 강우시 유출수문곡선으로부허 기저유출성분과 강우성분을 분리하여 동적 평형에 의한 강우의 지하수 함양률을 추정하기 위해서 수행되었다. 보존적인 산소동위원소(18O) 추적자를 이용하여 2성분(기저유출성분과 강우성분) 유출수문곡선 분리하였으며 이로부터 추정된 지하수 함양률은 강우의 0.13이었다. 추적자를 이용한 유출수문곡선분리는 지하수 함양률을 정량적으로 나타낼 수 있다는데 의의가 있다.

High resolution geophysical imaging to delineate costal aquifer and seawater- freshwater interface has been applied in Baesu-eup, Yeonggwang-gun, Jeolla province Electrical resistivity information from vertical electrical sounding and 2-D electrical resistivity survey is key parameter to map equivalent Nacl concentration map over the survey area. Seismic velocity from refraction tomographic survey, on the other hand, gives more reliable information on the subsurface stratagraphy than electrical resistivity methods which frequently suffer from low resolution due to masking effect. We imaged high-resolution 3-D structure of costal aquifer by correlating the electrical resistivity with seismic velocity, and mapped equivalent NaCl concentration map using resistivity and hydro-geological information from well logging.

Using factor analysis and bivariate comparisons of major components in ground water, three geochemical processes were identified as controlling factors of ground water chemistry; 1) natural mineralization by water rock interactions, 2) effect of seawater which includes salinization by seawater near seashores and deposition of sea salt, and 3) nitrate contamination by N fertilization. Contribution of rainfall was also estimated from the measured composition of wet deposition. The geochemical processes were separated using total alkalinity as an indicator for natural mineralization, Cl for effect of seawater, and nitrate for N fertilization. Relatively high correlation of major components with nitrate suggests that nitrification of nitrogenous fertilizers significantly affects ground water chemistry. Total cations derived from nitrate sources have good linearity for nitrate in equivalent basis with a slope of 1.8, which is a mean of proton production coefficients in nitrification of two major compounds in nitrogenous fertilizers, ammonium and urea. Contribution of nitrate sources to base cations, Cl, and SO$_4$ in ground water was determined considering maximum contribution of natural mineralization to estimate a threshold of the effect of N fertilization for ground water chemistry, which shows W fertilization has a greatest effect than any other processes in ground water with nitrate concentration greater than 50 mg/L for Ca, Mg, Na and with concentration greater than 30 mg/L for Cl and SO$_4$.

Hydrogeochemical and isotopic characteristics were investigated for groundwater of Tertiary basin in southeastern part of Korea where deep drilling is in progress for geothermal investigation. According to geology, aquifer was distinguished as alluvial, tertiary sedimentary bedrock (bedrock groundwater), and fractured volcanic rock (deep groundwater). Groundwater of each aquifer is distinctively separated in Eh-pH conditions and concentrations of Cl, F, B and HCO$_3$. Deep groundwater has very low level 3H and 14C whereas alluvial groundwater has those of recent precipitation level. However one of deep groundwater show mixed characteristics in terms of hydrochemistry which indicates effect of pumping. Deep groundwater have temperature of 38 to 43$^{\circ}C$ whereas bedrock and alluvial groundwater have temperature less than 2$0^{\circ}C$. Fractured basement rock aquifer has different hydrogeologicalsetting from bedrock and alluvial aquifer considering hydrogeochemical and isotopic characteristics, and temperature.

환경동위원소 기법을 쓰레기 매립장의 침출수 및 주변 지하수에 적용해본 결과 미생물의 활동에 의한 유기물의 분해과정에 대한 정보를 얻을 수 있었다. 특히 유기물 분해로 생성된 이산화탄소는 일차적으로 침출수의 알칼리도를 높이고 이차적으로 일어나는 이산화탄소의 환원작용에 의하여 메탄가스가 형성되었다. 이러한 과정에서 침출수에 잔류하는 용존무기탄소(DIC)의 탄소 동위원소 조성이 크게 부화되었으며, 아울러 생성된 메탄과의 수소동위원소 교환반응에 의하여 물의 수소 동위원소 조성이 크게 부화되는 특징이 국내에서 처음 관찰되었다.