한국지하수토양환경학회:학술대회논문집 (Proceedings of the Korean Society of Soil and Groundwater Environment Conference)
- 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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- Pages.124-127
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- 2003
불포화 토양내에서 가스상 오존 이동특성에 대한 Multiphase liquids의 영향
초록
Laboratory scale experiments on in-situ ozonation were carried out to delineate the effects of liquid phases, such as soil water and nonaqeous phase liquid (NAPL) on the transport of gaseous ozone in unsaturated soil. Soil water enhanced the transport of ozone due to water film effect, which prevent direct reaction between soil particles and gaseous ozone, and increased water content reduced the breakthrough time of ozone because of increased average linear velocity of ozone and decreased air-water interface area. Diesel fuel as NAPL also played a similar role with water film, so the breakthrough time of ozone in diesel-contaminated soil was significantly reduced compared with uncontaminated soil. However, ozone breakthrough time was retarded with increased diesel concentration, because of high reactivity of diesel fuel with ozone. In multiphase liquid system of unsaturated soil, the ozone transport was mainly Influenced by nonwetting fluid, diesel fuel in this study.