Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference (한국전기전자재료학회:학술대회논문집)
The Korean Institute of Electrical and Electronic Material Engineers
- Annual
2003.07b
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The characteristic prediction and analysis of 3-dimensional (3-D) solenoid-type embedded inductors is investigated. The four different structures of 3-D inductor are fabricated by using low-temperature cofired ceramic (LTCC) process. The circuit model parameters of the each building block are optimized and extracted using the partial element equivalent circuit method and HSPICE circuit simulator. Based on the model parameters, predictive modeling is applied for the structures composed of the combination of the modeled building blocks. And the characteristics of test structures, such as self-resonant frequency, inductance and Q-factor, are analyzed. This approach can provide the characteristic conception of 3-D solenoid embedded inductors for structural variations.
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The crystalline and dielectric properties on
$Al_2O_3$ filled glass frit ($CaO-Al_2O_3-SiO_2-MgO-B_2O_3$ ) with admixtures of$TiO_2$ have been investigated. The dielectric constant value of$7.5{\sim}7.8$ , quality factor value of 700 were obtained for glass frit :$Al_2O_3$ (50 : 50 wt%) ceramics. As the amount of$TiO_2$ increased, temperature coefficient of dielectric constant were decreased. -
This work presents the design, fabrication and microwave performance of distributed analog phase shifter (DAPS) fabricated on
$(Ba,\;Sr)TiO_3$ (BST) thin films for X-band applications. Ferroelectric BST thin films were deposited on MgO substrates by pulsed laser deposition. The DAPS consists of high impedance coplanar waveguide (CPW) and periodically loaded tunable BST interdigitated capacitors (IDC). In order to reduce the insertion loss of DAPS and to remove the alteration of unloaded CPW properties according to an applied dc bias voltage, BST layer under transmission lines were removed by photolithography and RF-ion milling. The measured results are in good agreement with the simulated results at the frequencies of interest. The measured differential phase shift based on BST thin films was$24^{\circ}$ and the insertion loss decreased from 1.1 dB to 0.7 dB with increasing the bias voltage from 0 to 40V at 10 GHz. -
Non-linear behaviors of multilayer piezoelectric ceramic actuator (MCA) were investigated under electrical and mechanical stress. DC 100 V bias was applied to the MCA to obtain displacement. Laser vibrometer, which using Doppler effect, was employed to characterize displacement caused by
$d_{33}$ mode of MCA. To understand this non-linear behavior of MCA, displacement was measured and compared under different load states. By increasing load, electric field-induced strain and piezoelectric constant($d_{33}$ ) of MCA was decreased. We attribute this phenomenon to the domain wall motion and depoling of MCA under heavy load. -
The BLT thin-films were one of the promising ferroelectric materials with a good leakage current and degradation behavior on Pt electrode. The BLT target was sintered at
$1100^{\circ}C$ for 4 hours at the air ambient.$Bi_{3.25}La_{0.75}Ti_3O_{12}$ (BLT) thin-film deposited on$Pt/Ti/SIO_2/Si$ wafer by rf magnetron sputtering method. At annealed$700^{\circ}C$ , (117) and (006) peaks appeared the high intensity. The hysteresis loop of the BLT thin films showed that the remanent polarization ($2Pr=Pr^+-Pr^-$ ) was$16uC/cm^2$ and leakage current density was$1.8{\times}10^{-9}A/cm^2$ at 50 kV/cm with coersive electric field when BLT thin-films were annealed at$700^{\circ}C$ . Also, the thin film showed fatigue property at least up to$10^{10}$ switching bipolar pulse cycles under 7 V. Therefore, we induce access to optimum fabrication condition of memory device application by rf-magnetron sputtering method in this report. -
In this paper, 2.4 GHz WLAN BPF(Band Pass Filter) using LTCC(Low temperature cofiring ceramic) multilayer technology was simulated and manufactured. A modified
${\lambda}/4$ Hair-pin resonator with shunt-to ground loaded capacitor is used to shorten resonator length and improve circuit Q factor. Proposed BPF has a combline structure. Electro-magnetic Coupling between coupled strip-line resonators is controlled to provide attenuation poles at finite frequencies. The overall size of the filter is$3.2{\times}1.6{\times}1.3mm^3$ . The measured result shows good agreement with simulated data. -
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$(Ba,Sr,Ca)TiO_3$ ] powders, prepared by the sol-gel method, were mixed with organic vehicle and the BSCT thick films were fabricated by the screen printing techniques on alumina substrates. The dielectric properties were investigated for various composition ratio and$Nb_2O_5$ doping contents. All the BSCT thick films, sintered at$1420^{\circ}C$ , showed the typical XRD patterns of a perovskite polycrystalline structure. The Curie temperature and the relative dielectric constant decreased with increasing Ca content and$Nb_2O_5$ doping amount. The relative dielectric constant, dielectric loss and tunability of the BSCT(50/40/10) thick films doped with 1.0wt%$Nb_2O_5$ were 1410, 0.65% and 17.29% respectively. -
As industrial technology was developed, necessity for small size motor was increased on various fields such as medical treatment and robotics. The motor should be simple structure, and it has easy process of manufacture to overcome the limit of miniaturization. So, "the windmill type ultrasonic motor" is enough to satisfy these conditions. In this paper, windmill type ultrasonic motor which was proposed by B.Koc and K.Uchino, was analyzed and fabricated with modified endcap shape. Displacements of arms of the proposed endcap were compared with the previous endcap, using the finite element analysis program (ANSYS). Better rotational characteristics was expected in proposed model as result of FEA. Experimentally, rotary motors of 3.5 [cm] diameter were fabricated, and the speed and torque of the motor were measured. As a result, speed and torque were changed in proportion to the electrical input voltages. And low efficiency which was different from an expectation was obtained in this motor. So, various problems should be improved for practical use.
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The ferroelectric properties of PZT(53/47) thin film was investigated by methoxy enthanol solution based on sol-gel method. The thickness of each layer by spincoating 0.25M sol at one time was
$0.1{\mu}m$ and crack-free film was formed.$LaNiO_3/Si(100)$ electrode and$Pt/Ti/SiO_2/Si(100)$ electrode was coated by PZT sol at several times. PZT orientation was confirmed as a method of XRD and coercive field(Ec) as well as remnant polarization(Pr) was investigated from hysterisis curve. As a result of XRD analysis, we can know that the orientation of on PZT/LNO/Si(100) is better than on$Pt/Ti/SiO_2/Si(100)$ . The remnant polarization(Pr) in LNO electrode was$87.5{\mu}C/cm^2$ and$39.8{\mu}C/cm^2$ in Pt. From this figures, it is investigated that the Pr in LNO electrode was better than in Pt. -
In this paper, Small scaled multilayered piezoelectric transformer of Rosen type has been fabricated and tested for the purpose of PDA backlight. Turn on characteristics of PDA backlight has been traced with different voltages.
$22{\times}4.5{\times}1.1[mm^3]$ multilayered transformer shows full turn-on behavior starting from 4.3[V]. -
Fine
$LaAlO_3$ powders were successfully synthesized from$La_2O_3$ and${\gamma}-Al_2O_3$ powders milling for$10{\sim}50hrs$ via the high energy milling technique (mechanochemical methode) in room temperature and air. The particle size of$LaAlO_3$ powder were estimated from XRD patterns and SEM images to be$160{\sim}180nm$ . The$LaAlO_3$ ceramics are derived for the synthesized powders (milling for 10, 30 and 50hrs) by sintering at$1400^{\circ}C$ . The micrographs of grains showed a agglomeration and the degree of agglomeration increased with the milling time. The$LaAlO_3$ made from synthesized powders milling for 30hrs can be sintered to 98% of theoretical density at$1,400^{\circ}C$ for 4hrs. -
In this paper, step-down piezoelectric transformer is studied. The piezoelectric transformer, made of lead zirconate titanate solid solution ceramic, is operated by a fundamental contour-extensional vibration mode. The transformer of 14mm length, 14mm width and 4.5mm thickness was made up two shape(Type I and II). The resonant frequency (fr) is 144kHz and 128kHz at the load resistant of
$7.5{\Omega}$ that is a similar to calculating matching impedance. The gain (G) obtained 0.19 and 0.08 at each resonant frequency, when applied input voltage is 25V. The temperature difference with the variation of load resistant was increased with increasing load resistant and was the lowest at$7.5{\Omega}$ near the matching of output impedance. -
In this study, in order to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, dielectric and piezoelectric properties of PSN-PZT ceramics were investigated according to Zr/Ti ratio. As Zr/Ti ratio is increased, coupling factor(kp) and dielectric constant were increased and then decreased after the ratio of Zr/Ti=50/50. And also, mechanical quality factor were decreased and then increased after the ratio of Zr/Ti=50/50.
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In this Study, lead-free
$Bi_{0.5}(Na_{0.84}K_{0.16})_{0.5}TiO_3$ system ceramics were fabricated with the variations of Sr substitution and their dielectric and piezoelectric characteristics were investigated. With the increase of Sr substitution, dielectric constant increased linearly and Curie temperature decreased slightly. Also, the temperature dependence curve of dielectric constant was moved to left-ward. At 4mol% Sr substitution, Tc of 292, kp of 34.03%, kt of 45.32% and${\epsilon}r$ of 868 were shown, respectively. -
Transducer for ultrasonic linear motor with the symmetric and anti-symmetric modes was studied. The ultrasonic linear motor consists of two Langevin type piezoelectric vibrators that cross at right angles with each other in tip. In order to excite symmetric and anti-symmetric modes, the transducer must have a phase shift of 90 degree in space and time. Therefore, the tip of transducer moves on an elliptical motion. In this paper, the finite element analysis was used to optimize dimension and displacement of the transducer. The ultrasonic motor was fabricated using the simulated result and the driving characteristics were measured. No-load velocity was 0.28[m/s] and the maximum efficiency was 30[%] in resonance frequency.
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With the advances on wireless internet technology, many research on minimization of wireless LAN is on the progress. To apply passive components in MCM, characteristic analysis of passive components is essential. In this paper, three square spiral inductors were modeled by HSPICE using PEEC (Partial Element Equivalent Circuit) method. Afterwards, Monte-Carlo analysis was performed to evaluate the optimized parameters. This work will give an idea on PEEC modeling of spiral inductor, and enable researchers with predictive data before large scale manufacturing.
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This paper describes the modeling and experimental results for Bulk Acoustic Wave(BAW) Resonator using PolyVinyliDene Fluoride(PVDF). We measured the input reflection coefficient (
$S_{11}$ ) of resonators using vector network analyzer and experimental results were measured fundamental resonance at 2.3 GHz with a return loss of -29 dB. Because of fabricated resonator without etching process, we can confirm a possibility of resonator application as using a PVDF. -
The effect of
$B_2O_3$ addition on the sintering behavior and microwave dielectric properties of$(Zn_{0.8}Mg_{0.2})TiO_3$ ceramic system were investigated. Highly dense samples were obtained at the sintering temperatures below$900^{\circ}C$ . Temperature coefficient of resonance frequency(${\tau}_f$ ) changes to a positive value with increasing the amount of$B_2O_3$ because of the increased amount of rutile phase. The$Q{\times}f_o$ values were determined by the microstructures and sintering shrinkages which are affected by the rutile or second phase. When 6.19 mol.% of$B_2O_3$ added and sintered at$900^{\circ}C$ for 5h, it exhibits${\epsilon}_r$ =23.5,$Q{\times}f_o$ = 67,500 GHz, and${\tau}f=-1.42ppm/^{\circ}C$ . -
Piezoelectric motors have been successfully developed for various applications like autofocus drives in camera lenses and handling equipment for high-accuracy positioning. In this paper, the travelling-wave motor which used in the camera lense, using bending vibration of a ring was studied. The basic structure of the motor is same but we suggested a few parameters for considering their design. The parameter is different from sine and cosine region of the voltage of the ceramic surface, displacement according to the wave number difference, and the phase difference. Same size of ceramics and aluminium ring were used for the stator. As a result, the displacement is dependent on the wave number.
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[
$(Ba,Sr,Ca)TiO_3$ ] powders, prepared by the sol-gel method, were mixed with an organic vehicle and the BSCT thick films were fabricated by the screen printing techniques on alumina substrates. The grain size decreased with increasing amounts of$MnO_2$ , and the BSCT(50/40/10) thick film doped with 1wt%$MnO_2$ showed a value of 6.5mm. The thickness of thick films by four-cycle on printing/drying was approximately 100mm. The relative dielectric constant, dielectric loss and tunability of the BSCT(S0/40/10) thick films doped with 1.0wt%$MnO_2$ were 1296, 0.61% and 11.18%, respectively. -
The Design and fabrication of K-Band Bandpass Filters Using the Photoimageable Thick Film Technology본 논문에서는 개방된 양 끝이 Loading 캐패시턴스로 연결된 새로운 행태의 1/2 파장 공진기를 이용해서 3단 대역통과 여파기를 설계, 제작하였다. 제안한 공진기의 전파지연효과(Slow-Wave Effect)때문에, 넓은 상향저지대역을 갖으며, 사이즈(Size)가 축소된 협대역 여파기 설계가 가능하다. 설계한 대역통과 여파기는 미세라인 구현이 가능한 후막 리소그라피 공정 기술을 이용하여 제작하였다.
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Piezoelectric ceramics were made by a doctor blade methode and piezoelectric fans were fabricated by sandwiched a slim and long metal between two layers of ceramics. A maximum displacement of piezoelectric fan occurs in the resonance frequency of a long metal and the resonance frequency of them is in inverse proportion to the square of a length of metal. The piezoelectric fan made from a wide and thin piezoelectric ceramics(
$13{\times}0.2{\times}30mm^3$ ) showed a maximum displacement in all samples, and the maximum displacement was about 20mm in a commercial power (200V, 60Hz of sine wave). -
This paper presents design and analysis of step-down piezoelectric transformer for application to AC-adapters. These transformers are consist of rectangular type and disk type multilayered piezoelectric ceramic plate. This piezoelectric transformer operated in third thickness resonance vibration mode. Finite element methode(FEM) was used for analysing transformer. Vibration mode and electric field of piezoelectric transformer were simulated at resonance frequency. As results, rectangular type transformer's output voltage was higher than the disk type. But disk type transformer's current was lagger than rectangular type. These results are assumed that disk type transformer's mixed vibration mode influence transformer's output characteristics. From these results, we expect that disk type piezoelectric transformer is more adoptable than rectangular plate type piezoelectric transformer for AC adapters.
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In this study, to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, PSN-PNN-PZT system ceramics were manufactured as a function of CuO addition. Its dielectric and piezoelectric characteristics were investigated. With increasing the amount of CuO addition, grain size was increased and density increased until 0.3wt% CuO. Taking into consideration electromechanical coupling factor(kp) of 0.53, mechanical quality factor(Qm) of 423 and
${\epsilon}r$ of 1759, it can be cincluded that the CuO 0.5wt% added composition sintered at$920^{\circ}C$ is suitable for piezoelectric transformer application if Qm is improved. -
The microstructure and electrical properties of the
$Pr_6O_{11}$ -based ZnO varistor ceramics, which are composed of Zn-Pr-Co-Cr-Tb oxides, were investigated with$Tb_4O_7$ amount. The varistor ceramics exhibited very high densification based on increasing density in the range of$5.73{\sim}5.85g/cm^3$ as$Tb_4O_7$ amount is increased. The calculated nonlinear exponent(${\alpha}$ ) in varistor ceramics without$Tb_4O_7$ was only 8.9, whereas the${\alpha}$ value of the varistor ceramics with$Tb_4O_7$ was abruptly increased in the range of 18.6 to 42.0. In particular, the maximum value(42.0) of${\alpha}$ was obtained by doping of 1.0 mol%$Tb_4O_7$ . The measured leakage current($I_{\ell}$ ) in varistor ceramics without$Tb_4O_7$ was$40.1{\mu}A$ , whereas the$I{\ell}$ value of the varistors with$Tb_4O_7$ was very abruptly decreased below$5{\mu}A$ . It is estimated that$Tb_4O_7$ additives will is applied usefully in development of varistors possessing high performance. -
The PZT(KP12) powder was synthesized by sintering at
$1250^{\circ}C$ for 2hrs and wet milling for 24 hrs. The PZT composite mixed with PVdF was fabricated into bulk, sheet, and plate type and the characteristics of three types were estimated. The bulk type which has PZT volume percent of 70 showed the best piezoelectric constant. Dielectric constant increased exponentially as an increase of PZT volume percent. The figure of merit of bulk and plate type was better than pure PZT over PZT volume percent of 50. -
Usually for the commercial preparation of barium titanate films or ceramics the reaction atmosphere must be preferably in air. However, normally air is not used because it contains carbon dioxide, which can easily react with barium to form the undesired product barium carbonate, leading to unwanted second-phase formation in the (mal stages of the process. In the present work a series of perovskite barium titanate films was prepared by the sol-gel method, using a metal alkoxide solutions in the electrophoretic deposition (EPD). The influence of several process parameters, like sintering temperature of sol preparation before EPD and heat-treatment temperature and non-oxidized atmosphere, on the film properties is described.
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Ferroelectric
$Pb(Zr_{1-x}Ti_x)O_3$ (PZT) films were deposited on (001) MgO single crystals using sol-gel method. Structural properties and surface morphologies of PZT films were investigated using an X-ray diffractometer and a scanning electron microscopy, respectively. The dielectric properties of PZT films were investigated with the dc bias field using interdigitated capacitors (IDC) which were fabricated on PZT films using a thick metal layer by photolithography and dry etching process. The small signal dielectric properties of PZT films were calculated by a modified conformal mapping method with low and high frequency data, such as capacitance measured by an impedance gain/phase analyzer at 100 kHz and reflection coefficient (S-parameter) measured by a HP 8510C vector network analyzer at 1 -20 GHz. The IDC on PZT films exhibited about 67% of capacitance change with an electric field of 135 kV/cm at 10 GHz. These PZT thin films can be applied to tunable microwave devices such as phase shifters, tunable resonators and tunable filters. -
[
$Sr_xBa_{1-x}Nb_2O_6$ ] (SBN,$0.25{\leq}x{\leq}0.75$ ) ceramic is a ferroelectric material with tetragonal tungsten bronze (TTB) type structure, which has a high pyroelectric coefficient and a nonlinear electro-optic coefficient value. In spite of its advantages, SBN has not been investigated well compared to other ferroelectric materials with perovskite structure. In this study, SBN thin film was manufactured by ion beam sputtering technique using the prepared SBN target in$Ar/O_2$ atmosphere. SBN30 thin film of$1000{\AA}$ was pre-deposited as a seed layer on$Pt(100)/TiO_2/SiO_2/Si$ substrate followed by SBN60 deposition up to$3000{\AA}$ in thickness. As-deposited SBN60/SBN30 layer was heat-treated at different temperatures of 650, 700, 750, and$800^{\circ}C$ in air, respectively The crystallinity and orientation behavior as well as electric properties of SBN60/SBN30 multi-layer were examined. The deposited layer was uniform and the orientation was shown primarily along (001) plane from XRD pattern. There was no difference in the crystal structure with heat-treatment temperature, but the electric properties depended on the heating temperature and was the best at$750^{\circ}C$ . In electric properties of Pt/SBN60/SBN30/Pt thin film capacitor prepared, the remnant polarization (2Pr) value was$15{\mu}C/cm^2$ , the coercive field (Ec) 75 kV/cm, and the dielectric constant 1075, respectively. -
This paper deals with a flat type ultrasonic motor, which uses a longitudinal-bending multi mode vibrator of rectangular form. A linear ultrasonic motor was designed by combination of the first longitudinal and eighth bending mode, and the motor consisted of a straight aluminum alloy bar bonded with piezoelectric ceramic elements as a driving element. The geometrical dimensions of the rectangular aluminum vibrator were determined by Euler-Bernoulli theory ANSYS was used to analyze the resonance frequency and the displacement of the stator vibrator. The resonance frequency of the motor provides the elliptical motion. and ANSYS was used to analyze elliptical motion and elliptical trajectory of stator vibrator when thickness of piezoelectric ceramics was varied respectively 0.763, 1.526, 2.289[mm] and width of stator vibrator was varied respectively 16, 12, 8, 4[mm]. When thickness of piezoelectric ceramics was decreased, the displacement of the stator vibrator was increased. And when width of stator vibrator was decreased, the displacement of the stator vibrator was increased.
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A solvothermal synthetic method to
$BaTiO_3$ nanoparticle has been investigated in toluene solution with$BaTi(OR)_6$ as precursor. A precursor prepared from barium metal with toluene, isopropanol and titanium isopropoxide was used as a starting material. Weight ratio of precursor to solvent prepared in the mixture are 5/100, 10/100, 20/100 and 50/100wt%. At the weight ratio of 50/100wt%,$BaTiO_3$ butterfly twin crystalline(${\fallingdotseq}100nm$ ) was obtained after synthesis at$250^{\circ}C$ for 20hrs in an autoclave. X-ray diffraction and transmission electron microscopy showed that the product of 50/100wt% has crystallization. At 5/100, 10/100, and 20/100wt%, however, red colloidal solution was obtained after synthesis and crystalline phase of$BaTiO_3$ was not produced. -
Downsizing electronics requires precision position control with an accuracy of sub-micron order, which demands development of ultra-fine displacive devices. Piezoelectric transducer is one of devices transferring electric field energy into mechanical energy and being capable for fine displacement control. The transducer has been widely used as fine Position control device Multilayer piezoelectric actuator, one of typical piezo-transducer, is fabricated by stacking alternatively ceramic and electrode layers several hundred times followed by cofiring process. Electrode material should be tolerable in the firing process maintaining at ceramic-sintering temperatures up to
$1100{\sim}1300^{\circ}C$ . Ag-Pd can be used as stable electrode material in heat treatment above$960^{\circ}C$ . Besides, adding small quantity ceramic powder allow the actuator to be fabricated in a good shape by diminishing shrinkage difference between ceramic and electrode layers, resulting in avoidance of crack and delamination at and/or nearby interface between ceramic an electrode layers. This study presents synthesis of nano-oxide-added Ag/Pd powders and its feasibility to candidate material tolerable at high temperature. The powders were formed in a co-precipitation process of Ag and Pd in nano-oxide-dispersed solution where Ag and Pd precursors are melted in$HNO_3$ acid. -
[
$Ba_2NaNb_5O_{15}$ ], hereafter BNN, thin films are attractive candidates for nonvolatile memory and electro-optic devices. In the present work, thin films that have different contents of Ba, Nb and Na have been prepared by H-MOD technique on silicon and Pt substrates. XRD and SEM were used to investigate the phase evolution behavior and the microstructure of the films. It was found that the films of about 500nm thick were crack-free and uniform in microstructure. Nb content strongly influenced the phase formation of the films, where unwanted phases were always formed at the stoichiometric BNN composition. However, the unwanted phases decreased with the increase of excess Nb content, and the single phase (tetragonal tungsten bronze structure) BNN thin film was obtained when the niobium content reached some point. From this study, the sub-solidus phase diagram below$850^{\circ}C$ for$BaO-Na_2O-Nb_2O_5$ ternary system is proposed. -
A ZnO varistor with reference voltage 250V/mm was fabricated through the control of particle size in slurry and the variation of sintering conditions. It was found that to measure the flatness of the V-I characteristic curve in the small-current region and the flatness of the V-I characteristic curve in a large-current region was improved nonlinearity of the fabricated ZnO varistor. According to the IEC 60099-4 was measured the accelerated aging test and high current test of the distribution class surge varistor which is excellent in respect to the property of ZnO varistor.
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The microstructure and nonlinear properties of ZPCMR-based varistors were investigated with various additives. The density of varistors were gradually decreased for the same R in order of NiO, MgO, and
$Cr_2O_3$ , respectively. The ZPCR-based varistors were not affected by NiO and MgO additives in nonlinear properties, whereas greatly affected by$Cr_2O_3$ . Among the ZPCCR-based varistors, ZPCCD varistor exhibited the highest nonlinear properties, in which the nonlinear exponent is in the range of$40.5{\sim}67.4$ and the leakage current is in the range of$1.2{\sim}2.7{\mu}A$ . -
In this paper, We proposed compact multi-layer LTCC (Low Temperature Cofired Ceramic) bandpass filter for Bluetooth module. A
${\lambda}/4$ coupled stripline resonators are designed, which composed of coupled strip-line section and loading capacitance. This resonator with a loading capacitor has slow-wave characteristics. Due to the slow-wave effect of the proposed resonator, it is possible to design and fabricate a compact bandpass filter with a wide upper stop band. Attenuation poles in the lower stop band are achieved using controlling of electro-magnetic coupling between resonators. Using multi-layer LTCC technology, we designed and fabricated band pass filter with a finite attenuation pole and wide upper stopband. The overall size of the filter is$1.2{\times}2.0{\times}1.0mm^3$ . -
In this study, an ultrasonic transducer is fabricated with a 1-3 type composite resonator. Pulse-echo responses of an ultrasonic transducer are investigated in underwater with the designated water-levels. LED output signals of a level limit switch with changing a water level are obtained by using the currently developed self-made 1-3 type composite transducer and electric measuring unit. LED is turned on at above the up-limit level with increasing a water level, and LED is turned on at less than the down-limit level with decreasing a water level.
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Low Temperature Cofired Ceramics (LTCC) technology is a promising technology to integrate many devices in a module by embedding passive components. For the module substrate, most LTCC structures have dielectric constants below 10 to reduce signal delay time. Some components, which need high dielectric constants, have not been yet embedded in LTCC module. So, embedding capacitor with high capacitance by applying another dielectrics with high dielectric constants in LTCC is an important issue to maximize circuit density in LTCC module. In this study, electrical properties of embedded capacitor fabricated by dielectric paste of high dielectric constants (K-100) and co-firing behavior with LTCC were investigated. To prevent camber development of co-fired structure, constrained sintering process was tested. Dielectric properties of embedded capacitors were calculated from their capacitance and impedance value. Temperature coefficient of capacitance were also measured.
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Nowadays, the study on the ceramic components and modules using LTCC is being peformed and on the passives included in modules is being done also. Especillay frequency dependent components like capacitor and inductor are studied by many groups, but the behavior of embedded resistor in MCM-C module are not studied vigorously. The characteristics of embedded resistor in modules is different from that of resistor alone. In our research, behavior of embedded resistor is examined in the variation of position and geometrical parameters.
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Nowadays, the study on the ceramic components and modules used in telecommunication system is being performed. Duplexer is the one of the most important components and has the role of dividing Rx and Tx signal. Duplexer including the FBAR is being done vigorously LTCC is used for package like SAW package, duplexer package. In our research, LTCC material is used for FBAR duplexer package and photo-lithography for the fine line phase shifter. The good characteristics, low loss and good isolation, of duplexer is obtained by the fine line phase shifter having high characteristic impedance of stripline.
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The development of new improved type of dielectric materials on the conception of multiphase structure has been carried out in this paper. Metal alkoxides solutions were used for application of thin film by electrophoretic deposition technique. We succeeded in preparation of amorphous and composite dielectric films from Al alkoxides. Specific features of the preparation technique were considered. Microstructure of the films was examined as well as their dielectric properties. TEM analyses reveals that films deposited from aging sols and heat-treated at temperatures as low as
$400^{\circ}C$ contain small whiskers of${\delta}-Al_2O_3$ . -
In the paper, the novel linear ultrasonic motor for precision position control was designed and fabricated. It was composed of two piezoelectric actuators with longitudinal ultrasonic fluctuations and shaking beam. When two AC electric fields (
$Usin{\omega}t$ ,$Ucos{\omega}t$ ) were applied in two piezoelectric actuators respectively, the middle part of shaking beam had an elliptical trajectory. According to experimental results, good symmetrical characteristic of two piezoelectric actuators were obtained. -
Hot filament 플라즈마 화학기상 증착법 (HFPECVD)를 사용하여 전처리 조건에 따른 탄소나노튜브의 성장 특성을 관찰하였다. 암모니아 (
$NH_3$ )를 희석가스로 사용하였고, 아세틸렌 ($C_2H_2$ )를 탄소 원료가스로 각각 사용하였다. 암모니아 가스 플라즈마를 사용하여 전처리 된 니켈 촉매 층의 SEM (Scanning Electron Microscopy) 이미지를 관찰하여 본 결과, 나노 사이즈의 촉매 그레인(grain)을 발견할 수 있었다. 그리고 탄소 나노튜브의 직경과 성장 밀도 또한 전처리 된 촉매 층에 따라 다른 양상을 보였다. TEM (Transmission Electron Microscopy)를 사용하여 탄소나노튜브를 관찰한 결과 공동구조(hollow)를 한 다중벽 탄소 나노튜브(MWCNT)를 관찰할 수 있었다. 성장된 나노튜브는 끝에 금속팁을 가지고 있으며, 나노튜브의 팁은 촉매로 사용한 것과 같은 물질로 구성되어 있었다. Raman spectroscopy를 사용하여 측정된 B-밴드와 G-밴드의 피크들은 각각$1360cm^{-1}$ 와$1598cm^{-1}$ 부근에서 나타났으며, 전처리 조건을 달리하여 성장시킨 탄소나노튜브 필름에서 이들 두 피크의 위치는 이동하지 않았고, 두 피크의 강도 비율 ($I_G/I_D$ )은 전처리 조건에 따라 변하였다. -
Thin films of vanadium oxide(VOx) have been deposited by r.f. magnetron sputtering from
$V_2O_5$ target in gas mixture of argon and oxygen. The oxygen/(oxygen+argon) partial pressure ratio of 0% and 8% is adopted. Crystal structure and optical properties of films sputter-deposited under different oxygen gas pressures and in situ annealed in vacuum at$400^{\circ}C$ for 1h and 4h are characterized through XRD and optical absorption measurements. The films as-deposited are amorphous, but$0%O_2$ films annealed for time longer than 4h and$8%O_2$ films annealed for time longer than 1h are polycrystalline. The optical transmission of the films annealed in vacuum decreases considerably than the as-deposited films and the optical absorption of all the films increases rapidly at wavelength shorter than about 550nm. Indirect and direct optical band gaps were decreased with increasing the annealing time. -
A rf triode magnetron sputtering system is designed and installed its construction in vacuum chamber. In order to calibrate the rf triode magnetron sputtering for thin films deposition processes, the effects of different glow discharge conditions were investigated in terms of the deposition rate measurements. The basic parameters for calibrating experiment in this sputtering system are rf power input, gas pressure, plasma current, and target-to-substrate distance. Because a knowledge of the deposition rate is necessary to control film thickness and to evaluate optimal conditions which are an important consideration in preparing better thin films, the deposition rates of copper as a testing material under the various sputtering conditions are investigated. Furthermore, a triode sputtering system designed in our team is simulated by the SIMION program. As a result, it is sure that the simulation of electron trajectories in the sputtering system is confined directly above the target surface by the force of
$E{\times}B$ field. Finally, some teats with the above 4 different sputtering conditions demonstrate that the deposition rate of rf triode magnetron sputtering is relatively higher than that of the conventional sputtering system. This means that the higher deposition rate is probably caused by a high ion density in the triode and magnetron system. The erosion area of target surface bombarded by Ar ion is sputtered widely on the whole target except on both magnet sides. Therefore, the designed rf triode magnetron sputtering is a powerful deposition system. -
DLC thin films were prepared by microwave plasma-enhanced chemical vapor deposition method on silicon substrates using methane (
$CH_4$ ) and hydrogen ($H_2$ ) gas mixture. The negative DC bias ($-450V{\sim}-550V$ ) was applied to enhance the adhesion between the film and the substrate. The films were characterized by Raman spectrometer. The surface morphology was observed by an atomic force microscope (AFM). And also, the friction coefficients were investigated by AFM in friction force microscope (FFM) mode, which were compared with the pin-on-disc (POD) measurement. -
Toxic organics are of great environmental concern primarily because they are toxic to mammals and birds, and are relatively soluble in water to contaminate surface water and groundwater. In this study, the decomposition of phenol, a widely used organic, in aqueous solutions by Boron doped diamond(BDD) electrode was examined. Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped diamond (BDD) were used as anode for generating ozone gas by electrolysis of acid solution. In this work. we have studied ozone generating system using BDD electrode. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable for electrolyte while
$PbO_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte. Decomposition of phenol concentration in the reaction solution by photolytic ozonation($UV/O_3$ ) was analyzed by HPLC epuipped with a UV detector. -
[
$LaNiO_3$ ](LNO) thin films were deposited on various substrates as Si and$Al_2O_3$ by sol-gel process using lanthanum nitrate and nickel acetate. The structure and orientation of the films were characterized by X-ray diffraction. The orientation factors of films on Si(100), Si(111),$SiO_2/Si(100)$ and$Al_2O_3$ were 97%, 63%, 73%, and 24% respective. The conductivity was$7.6{\times}10^{-3}{\Omega}{\cdot}cm$ with 10 times coating at Si(100) substrate. -
The impedance of the positive active material
$LiMnO_2$ is measured by the changeable trend following the time. The charge capacities of single cell and each cells of four made with thin film prepared in the dry box are measured after measuring the impedance with the interval of 0, 24, 48 and 72 hours. In result, the impedance through the delaying time is not enhanced continuously as result of the time. The variation of capacity enhanced is not watched as the result of the delaying time that all together of the positive thin film and the reference is soaked in the solution of electrolyte of 1M PC$LiClO_4$ . But it can be known to increase the discharge capacities as that the impeditive value is decrease. -
금속 평행판 전극 사이에 주입된 액체 유전체의 움직임에 의해서 발생되는 차동 전기용량 변화를 이용하여 기울기 측정센서를 개발하였다. 기울기
$0^{\circ}{\sim}{\pm}90^{\circ}$ 의 범위에서 직선에 대한 상관계수가 0.999 99로 분석이 되어 우수한 선형성을 보였다. 센서의 전극구조를 완벽한 3-전극형 전기용량기로 설계하였기 때문에 외부로부터의 전자기 잡음 및 전기장의 영향에 관계없이 기울기를 정밀하게 측정할 수 있었다. 또한 안정된 디지털 출력을 이용하여 기울기의 정밀측정 뿐만 아니라 장치나 구조물 등의 기울기를 원격조정 또는 monitoring에도 적용이 가능하다. -
We investigated the electrical properties of self-assembled (4,4'-Di(ethynylphenyl)-2'-nitro-1-thioacetylbenzene), which has been well known as a conducting molecule having possible application to molecular level negative differential resistance(NDR)[1]. Generally, the phenomenon of NDR can be characterized by the decreasing current with the increasing voltage[2]. To deposit the SAM layer onto gold electrode, we transfer the prefabricated nanopores into a 1mM self-assembly molecules in THF solution. Au(111) substrates were prepared by ion beam sputtering method of gold onto the silicon wafer. As a result, we measured the voltage-current properties and confirmed the negative differential resistance properties of self-assembled organic thin film and measured, using Scanning Tunneling Microscopy(STM).
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As additive Pt of a little to
$SnO_2$ that gas sensing property is superior oxide-semiconductor material to fabricate gas sensor that operation is possible at room temperature and fabricated ceramic gas sensing devices. And, the change amount and sintering temperature of addition material investigated gas sensitivity by change of operation temperature, humidity relativity, Long-term stability and hysteresis. And achieved SEM and XRD analysis for characteristics searching examination of devices. -
Ozonic use of sterilization and heat treatment of raw material to extend the conservation period of food recently is increased by hard vegetable or microorganism sterilization purpose of fruit. If ozone can create as is easy comparatively because do air or oxygen by raw material and schedule period passes, there is advantage that do not leave the second contaminant because being gotten restored by oxygen. Also, because the effect is big to decolorization beside sterilization effect about microorganism, deodorization, disjointing of venomousness hazardous substance, food save, indoor air purge, good hand processing, hydrospace agricultural chemicals processing etc. the use extent is wide. This research ran parallel a sterilization experiment of E.coli colitis germs by ozone that manufacture ozonizer that use doped diamond maund electrode (BDD) by boron and searched special quality electrochemistry enemy of the ozonizer and is created. E.coli. After cultivate E.coli colitis germs during 37C 1 day is LB ship, after do ozonation, was sterilized more than 90% by ozone as result that examine sterilizing power by substance microscope and could confirm excellency of diamond electrode.
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Maxwell displacement current (MDC) measurement has been employed to study the dielectric property of Langmuir-films. A method for determining the dielectric relaxation time
$\tau$ of floating monolayers on water surface is presented. WC flowing across monolayers is analyzed using a rod-like molecular model. It is revealed that the dielectric relaxation time$\tau$ of monolayers in the isotropic polar orientational phase is determined using a liner relationship between the monolayer compression speed${\alpha}$ and the molecular area Am. Compression speed${\alpha}$ was about 30, 40, 50mm/min. -
Metal/chalcogenide glass semiconductor(CGS) thin film devices were produced in the vacuum evaporator by the methode of vacuum thermal evaporation. We investigated the influence of the correlations of thickness of metal and CGS upon the concentration of Metal in a CGS thin film. It has shown that M/CGS thin film devices were very sensitive to temperature.
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This paper describes the fabrication and characteristics of 3C-SiCOI sotctures by SDB and etch-back technology for high-temperature MEMS applications. In this work, insulator layers were formed on a heteroepitaxial 3C-SiC film grown on a Si(001) wafer by thermal wet oxidation and PECVD process, successively. The pre-bonding of two polished PECVD oxide layers made the surface activation in HF and bonded under applied pressure. The wafer bonding characteristics were evaluated by the effect of HF concentration used in the surface treatment on the roughness of the oxide and pre-bonding strength. Hydrophilic character of the oxidized 3C-SiC film surface was investigated by ATR-FTIR. The strength of the bond was measured by tensile strengthmeter. The bonded interface was also analyzed by SEM. The properties of fabricated 3C-SiCOI structures using etch-back technology in TMAH solution were analyzed by XRD and SEM. These results indicate that the 3C-SiCOI structure will offers significant advantages in the high-temperature MEMS applications.
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In this study, Ohmic contacts make on 3C-SiC using TiN. Ohmic contact resistivity of TiN/3C-SiC was evaluated. Specific contact resistance was calculated by Circular-TLM(transmission line model) method and physics properties were measured using XRD, SEM, respectively. TiN contact is stable at high temperatures and a good diffusion barrier material. The TiN/3C-SiC contacts are thermally stable to annealing temperatures up to
$1000^{\circ}C$ . The TiN thin-film depostied on 3C-SiC substraes have good electrical properties. Therefore, the TiN/3C-SiC contact can be usefully applied for high-temperature MEMS applications over$500^{\circ}C$ . -
Jong, Jung-Youn;Kim, Yong-Chun;Kim, Sang-Jong;Kim, Kyung-Hwan;Yoon, Seok-Jin;Choi, Hyung-Wook 838
The aim of the study is to scrutinize the relationship between the area of resonance and insertion loss by analyzing the characteristics of 2-port resonator. This was done through designing an air-gap type Film Bulk Acoustic Resonator (FBAR) by using CAD model for the application of bandpass filter of high-frequency band with piezoelectric thin film. Moreover, through the design of ladder-type BPF, we were able to observe changes in bandwidth, resonation, out-of-band rejection depending on the number and area of resonator. -
DLC thin films were prepared by microwave plasma-enhanced chemical vapor deposition method on silicon substrates using methane (
$CH_4$ ) and hydrogen ($H_2$ ) gas mixture. The negative DC bias ($-450V{\sim}-550V$ ) was applied to enhance the adhesion between the film and the substrate. The films were characterized by Raman spectrometer. The surface morphology was observed by an atomic force microscope (AFM). And also, the friction coefficients were investigated by AFM in friction force microscope (FFM) mode, which were compared with the pin-on-disc (POD) measurement. -
Thin film
$SnO_2$ Gas Sensor was fabricated by using ion beam sputtering and ultra thin film Pt catalyst of$45{\AA}$ was deposited on$SnO_2$ thin film. The effects of annealing temperature on the structural properies of$SnO_2$ were investigated using the X-ray diffraction. Using SEM, microstructures of thin film were investigated. The good gas sensitivity is shown when annealing condition is$650^{\circ}C$ , 5hr and ultra thin film Pt catalyst thickness is$45{\AA}$ . -
Lee, Nam-Yeal;Yoon, Sung-Min;Lee, Won-Jae;Shin, Woong-Chul;Ryu, Sang-Ouk;You, In-Kyu;Cho, Seong-Mok;Kim, Kwi-Dong;Yu, Byoung-Gon 851
We have investigated the material and electrical properties of$Bi_{4-x}La_xTi_3O_{12}$ (BLT) ferroelectric thin film for ferroelectric nonvolatile memory applications of capacitor type and single transistor type. The 120nm thick BLT films were deposited on$Pt/Ti/SiO_2/Si$ and$SiO_2/Nitride/SiO_2$ (ONO) substrates by the sol-gel spin coating method and were annealed at$700^{\circ}C$ . It was observed that the crystallographic orientation of BLT thin films were strongly affected by the excess Bi content and the intermediate rapid thermal annealing (RTA) treatment conditions regardeless of two type substrates. However, the surface microstructure and roughness of BLT films showed dependence of two different type substrates with orientation of (111) plane and amorphous phase. As increase excess Bi content, the crystallographic orientation of the BLT films varied drastically in BLT films and exhibited well-crystallized phase. Also, the conversion of crystallographic orientation at intermediate RTA temperature of above$450^{\circ}C$ started to be observed in BLT thin films with above excess 6.5% Bi content and the rms roughness of films is decreased. We found that the electrical properties of BLT films such as the P-V hysteresis loop and leakage current were effectively modulated by the crystallographic orientations change of thin films. -
Tin doped indium oxide(ITO) and Al doped zinc oxide(ZnO:Al) films, which are widely used as a transparent conductor in optoelectronic devices such as solar cell, liquid crystal display, plasma display panel, thermal heater, and other sensors, were prepared by using the capacitively coupled DC magnetron sputtering method. The electrical and optical properties of both the ITO and ZnO:Al thin films were investigated as functions of substrate temperature, working gas pressure and deposition time. ITO and ZnO:Al films with the the present experimental conditions of temperature and pressure showed resistivity of
$2.36{\times}10^{-4}{\Omega}-cm,\;9.42{\times}10^{-4}{\Omega}-cm$ and transmittance of 86.28%, 90.88% in the wavelength range of the visible spectrum, respectively. -
In this work, the preparations and characteristics of capacitors and inductors for RF IC as a integrated devices are investigated. These kinds of capacitors and inductors can be applicable to the passive components utilized in voltage controlled oscillator(VCO), low noise amplifier(LAN), mixer and synthesizer for mobile telecommunication of radio frequency band(900 MHz to 2.2GHz), and in a library of monolithic microwave integrated circuit(MMIC). The results show that these inductors and capacitors array for RF IC may be applicable to the RF IC passive components for mobile telecommunication.
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Since the development of semiconductors, various related research has been conducted. During research, silicon diodes have been commonly used because of their simplicity and low cost in the manufacturing process. This research deals with p-n junction threshold voltages from silicon diodes due to transport current at a cryogenic temperature. At a cryogenic temperature(77K) we could get minimum current which junction threshold voltage becomes constant. This is experimented on GPIB communication and it consist of programmable current source, multimeter which gauge the threshold voltage in a very low temperature caused by transport current from 5nA to 1mA and
$LN_2$ (77K) for coolant. This experiment is programmed all process using Measurement studio(Lab window) tool. -
In recent years, silicon carbide has emerged as an important material for MEMS application. In order to fabricate an SiC film based MEMS structure by using chemical etching method, high operating temperature is required due to high chemical stability. Therefore, dry etching using plasma is the best solution. SiC film was deposited by thermal CVD at the temperature of
$1000^{\circ}C$ and pressure of 10 torr. SiC was dry etched with a reactive ion etching (RIE) system, using$SF_6/O_2$ and$CF_4/O_2$ gas mixture. Etch rate have been investigated as a function of oxygen concentration in the gas mixture, RF power, and working pressure. Etch rate was measured by surface profiler and FE-SEM.$SF_6/O_2$ gas mixture has been shown high etch rate than$CF_4/O_2$ gas mixture. Maximum etch rate appeared at 450W of RF power.$O_2$ dilute mixtures resulted in an increasing of etch rate up to 40%, and the superior anisotropic cross section was observed. -
Carbon nitride(
$CN_x$ ) thin films were deposited on quartz substrates using reactive RF magnetron sputtering system at uarious deposition conditions and investigated dielectric characteristics. Samples for capacitance measurements were of the MIM(Metal-Insulator-Metal) type devices. Aluminum film electrodes were prepared by a vacuum thermal evaporation method before and after the deposition of carbon nitride films. Capacitances were measured by a FLUKE PM6306 RCL Meter at room temperature. Current-voltage(I-V) characteristics and resistivity were measured by a CATS CA-EDA semiconductor test and analyzer. The carbon nitride films showed${\alpha}-C_3N_4$ and${\beta}-C_3N_4$ etc. peaks through Raman and FTIR. Observed surface of film and side structure using SEM(Scanning Electron Microscope), and measured thickness of film by${\alpha}-step$ . We can find that the dielectric constant was the lowest value in 50% nitrogen ratio and the resistivity was the highest value in 70% nitrogen ratio. -
The principal problems in development of dielectric paste materials for PDP(plasma display panel)are PbO free paste and low melting temperature. We prepared PbO free paste from glasses in the system
$BaO-ZnO-B_2O_3-V_2O_5$ . DTA, XRD and SEM were used to study and characterize$BaO-ZnO-B_2O_3-V_2O_5$ glasses. PbO free paste developed at this paper has thermal expansion of$74{\times}10^{-7}/^{\circ}C$ , DTA transformation point of$460^{\circ}C$ , and firing condition of$560^{\circ}C$ , 10min. -
ZnO thin films for Film Bulk Acoustic Resonator(FBAR) were prepared by FTS (Facing Target Sputtering) system. The FTS methode enable to generate high density plasma, and it has a high deposition rate at 1mTorr pressure. Therefore, the ZnO thin films were deposited on
$AZO/SiO_2/Si$ substrates with oxygen gas flow rate, and the other sputtering conditions were fixed such as a sputtering current of 0.8A, a substrate temperature at room temperature. AZO bottom electrode were deposited on$SiO_2/Si$ substrate and by Zn:Al(Al:2wt%) metal target. ZnO thin film thickness and the c-axis preferred orientation of ZnO thin film were evaluated by${\alpha}-step$ and XRD. -
Strain gages were widely used transducers. Essentially a strain gage was an electric element to which an appropriate type was attached. Strain was sensed by gages and provided electrical output proportional to applied forced. This paper describes the recent development of a thick film strain gage ceramic pressure sensors. The thick film resistors as strain gage in the Wheatstone bridge were fabricated with a novel mixture of ruthenium. The thick-film technology of resistors were printed on the ceramic diaphragm back side by screen printing and cured at
$850^{\circ}C$ . The mechanical measurements were performed with the computer simulation results(ANSYS 5.1). The output sensitivity was 1.2mV/V, of which max. nonlinearity was less than 0.29%, hysteresis was less than 0.38%FS. -
This paper describes on the fabrication and characteristics of micro ceramic thin-film type pressure sensors based on Ta-N strain-gauges for high-temperature applications. The Ta-N thin-film strain-gauges are deposited onto thermally oxidized Si diaphragms by RF sputtering in an argon-nitrogen atmosphere(
$N_2$ gas ratio: 8 %, annealing condition:$900^{\circ}C$ , 1 hr.), Patterned on a wheatstone bridge configuration, and use as pressure sensing elements with a high stability and a high gauge factor. The sensitivity is$1.097{\sim}1.21mV/V.kgf/cm^2$ in the temperature range of$25{\sim}200^{\circ}C$ and the maximum non-linearity is 0.43 %FS. The fabricated pressure sensor presents a lower TCR, non-linearity than existing Si piezoresistive pressure sensors. The fabricated micro ceramic thin-film type pressure sensor is expected to be usefully applied as pressure and load sensors that is operable under high-temperature environments. -
This paper describes on RIE(Reactive Ion Etching) characteristics of 3C-SiC(Silicon Carbide) grown on Si(100) wafers. During RIE of 3C-SiC films in this work,
$CHF_3$ gas is used to form of polymer as a side wall for excellent anisotropy etching. From this process, etch rates are obtained a$60{\sim}980{\AA}/min$ by various conditions such as$CHF_3$ gas flux,$O_2$ addition ratio, RF power and electrode distance. Also, approximately$40^{\circ}$ mesa structures are successfully formed at 100 mTorr$CHF_3$ gas flow ratio, 200 W RF power and 30 mm electrode distance. Moreover, vertical side wall is fabricated by anisotropy etching with 50%$O_2$ addition ratio and 25 mm electrode distance. Therefore, RIE of 3C-SiC films using$CHF_3$ could be applicable as fabrication process technology for high-temperature 3C-SiC MEMS applications. -
Using hi plasma and Fe-Phthalocyanine, carbon nanofibers have been synthesized a low temperature. The carbon nanofibers had about In nm diameter and up to
$10{\mu}m$ length. These were grown in random orientation. There are two shapes in the CNFs, screw and straight line shapes. Furthermore, we found the selective growth of nanofibers on the scratched substrates. -
Using
$DV-X{\alpha}$ method, it is calculated that nickel reduces the energy band gap of manganese oxide in 3 additives of titanium, nickel and tin. Therefore, it is estimated that the electrical conductivity of manganese-nickel oxide has the lowest value in 3 kinds of manganese oxide. The manganese oxide and manganese-nickel oxide which were produced by anodic deposition under$30mA/cm^2$ at room temperature in manganese sulfate and manganese-nickel sulfate solution were thermal-analyzed by DTA and TGA. The weight change of manganese oxide continuously decreased below$508^{\circ}C$ and kept constant at$518{\sim}600^{\circ}C$ . However, the manganeses-nickel oxide transformed at the temperature range of$510{\sim}537^{\circ}C$ . It is observed that the nickel addition to manganese oxide increases transformation temperature and its range. -
We synthesized dendrimers containing light switchable units, azobenzene group. To apply to the molecular level devices or data storage system using Langmuir-Blodgett(LB) film, we firstly investigated the monolayer behavior using the surface pressure-area(
${\pi}-A$ ) isotherms at air-water interface. And then the surface pressure shift of monolayer by light irradiation was also measured to the dendrimer with azobezene group. As a result, the monolayer of dendrimer with azobenzene group showed the reversible photo-switching behavior by the isomerization of azobenzene group in their periphery. This results suggest that the dendrimers with azobenzene group can be applied to high efficient nano-device of molecular level. And we measured the electrical properties by MIM and STM. The dendrimer with azobenzene group compared trans form and cis form at electrical properties. -
비대칭 마그네트론 스퍼터링법을 사용하여 실리콘 기판위에 hydrogenated amorphous carbon (a-C:H) 박막을 성장시켰다. DC Power 와
$Ar/C_2H_2$ 의 분압을 변화시켜 증착조건을 형성하고 성장된 다이아몬드상 카본박막의 물성을 관찰하였다. DC 전압에 따라 증착율과 표면 거칠기는 감소하는 한편 박막의 경도는 증가한다. 또한$Ar/C_2H_2$ 의 분압이 낮을 때 박막의 특성을 보여주는 G 피크가 낮은 wavenumber로 이동하는 것을 알 수 있다. -
In the electronic components and devices fabrication, thin film resistors with low TCR(temperature coefficient of resistance) and high precision have been used over 3 GHz microwave in recent years. Ni-Cr alloys thin films resistors is one of the most commonly used resistive materials because it has low TCR and highly stable resistance. In this work, we fabricated thin film resistors using Evanohm alloys target(72Ni-20Cr-3Al-4Mn-Si) of s-type with excellent resistors properties by RF-sputtering. Also we reported best deposited conditions of thin film resistors for microwave to observe microstructure and electronic properties of thin film according to deposited conditions(between target and substrate, power supply)
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The electrochemical behavior of vilogen self-assembled monolayer has been investigated with QCM, which has been known as ng order mass detector. The self-assembly process of viologen was monitored using resonant frequency(
${\Delta}F$ ) and resonant resistance(R). The QCM measurements indicated a mass adsorption for viologen assembling on the gold surface with a frequency change about 300, 135 Hz and calculated its surface coverage($\Gamma$ ) to be$5.02{\times}10^{-9}$ and$1.64{\times}10^{-9}mol/cm^2$ . Also a reversible redox process was observed and analyzed with an ionic interaction at the Viologen/solution interface using${\Delta}F$ . -
The interest of self-organization materials that have uniform and regular structure in nano scale has been grown due to their utilization in various fields of nanotechnology. An attractive candidate among these materials is anodic aluminum oxide film, which are formed by anodization of aluminum in an appropriate acid solution. The anodic aluminum oxide film has a highly ordered porous structure with very uniform and nearly parallel pores that can be organized in an almost precise close-packed hexagonal structure. In this study, we attempt to make Au dot arrays, which were fabricated using anodic aluminum oxide film as an evaporation mask. The Au dot arrays have a uniform sized dots and spacing to its neighbors and the average diameter of Au dots is about 60 nm corresponding to them of the mask.
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The dissolved oxygen sensor of thick film type was fabricated by screen print method and measured the characteristic, reference electrode used Ag/AgCl, and working electrode used Pt. The devices are continuously powered at potential of
$0.7V{\sim}0.8V$ versus Ag/AgCl reference electrode and results indicated that the response characteristic of sensor was$1.002{\mu}A{\sim}19.792{\mu}A$ for thirty seconds. we can know that it is good linearity when compared with of existent dissolved oxygen meter. Therefore sensor fabricated excels sensitivity for dissolved oxygen and will be considered to be applied typically because the price is costly. -
The electrochemical oxidation of ascorbic acid(AA), serotonin(StT) and epinephrine(EP) have been performed ae poly N,N-dimethylanliline(PDMA) film coated diamond electrode. This cationic polymer film is electrochemically deposited on boron-doped diamond electrode surface. Unlike the bard electrode, the polyaer film-coated diamond electrode can well separate the oxidation potential of AA by 330mV. Thus this electrode can be successfully used for the simultaneoud detection of both species. Increases in the concentration of AA donot affect the reponse of EP and ST.
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Glasses in the system
$CuO-P_2O_5-V_2O_5$ were prepared by a press-quenching method on the copper plate. The glass-ceramics from these glasses were obtained by post-heat treatment, and the crystallization behavior and DC conductivities were determined. The conductivities of the glasses were range from$10^{-6}s.Cm^{-1}$ at room temperature, but the conductivities of the glass-ceramics were$10^{-3}s.Cm^{-1}$ increased by$10^3$ order. The crystalline product in the glass-ceramics was$CuV_2O_6$ . Heat-treatment conditions influenced the crystal growth of$CuV_2O_6$ and conductivity. The linear relationship between in (${\sigma}T$ ) and$T^{-1}$ suggested that the electrical conduction in the present glass-ceramics would be due to a small polaron hopping(SPH) mechanism. -
It is well known that the state of existence of molecules on the surface of water changes during compression of the molecules. Electric methods, such as measurement of the surface potential or displacement current are also useful for investigating dynamic changes of molecular state on the water surface during compression and Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic thin film that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. In this paper Langmuir (L) that is one of basis technology to manufacture of organic matter device using biology material PBDG that is kind of polypeptide that have biology adaptedness. The Experiment method used
${\pi}-A$ isotherm and BAM(Brewster Angle Microscopy), using the BAM, we can to the molecular orientation of monolayer on the water surface and directly see the morphology of the films on water subphase as well as that of the films. -
Choi, Nak-Jin;Ban, Tae-Hyun;Baek, Won-Woo;Lee, Woo-Suk;Kim, Jae-Chang;Huh, Jeung-Soo;Lee, Duk-Dong 942
Nerve gas sensor based on tin oxide was fabricated and its characteristics were examined. Target gas was dimethylmethylphosphonate($C_3H_9O_3P$ , DMMP) that is simulant gas of nerve gas. Sensing material was$SnO_2$ added${\alpha}-Al_2O_3$ with$4{\sim}20wt.%$ and was physically mixed. And then it was deposited by screen printing method on alumina substrate. Sensor device was consisted of sensing electrode with interdigit(IDT) type in front and heater in back side. Total size of device was$7{\times}10{\times}0.6mm^3$ . Crystallite size of fabricated$SnO_2$ were characterized by X-ray diffraction(XRD, Rigaku) and morphology of the$SnO_2$ powders was observed by a scanning electron microscope(SEM, Hitachi). Fabricated sensor was measured as flow type and sensor resistance change was monitored real time using LabVIEW program. The best conditions as added$Al_2O_3$ amounts and operating temperature changes were 4wt.% and$300^{\circ}C$ in DMMP 0.5ppm, respectively. The sensitivity was over 75%. Response and recovery times were about 1 and 3 min., respectively. Repetition measurement was very good with${\pm}3%$ in full scale. -
This paper reports on the fluid flow simulation results of a multilayer type piezoelectric valve. The mechanical and fluidic analysis are done by finite element method. The designed structure is normally closed type using buckling effect, which is consist of three separate structures; a valve seat die, an actuator die and a MLCA(Multilayer Type Ceramic Actuator). It is confirmed that the complete laminar flow and the lowest flow leakage are strongly depend on the valve seat geometry. In addition, turbulent flow was occurs in valve outlet according to increase seat dimension, height and inlet pressure. From this, we was deducts the optimum geometry of the valve seat and diaphragm deflection that have an great influence fluid flow in valve. Thus, it is expected that our simulation results would be apply for piezoelectric applications such as valve and pump, fluidic control systems.
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This paper have been studied fabrication and characteristics of disposable pH sensor using MEMS technology. The sensor has two open-well structure, the container for the internal electrolyte and electrode were formed by anisotropically etching a silicon substrate. unlike currently used KCI saturated solution, the structure was introduced hydrogel which take an advantage of miniaturization, bulk product, a low price. PU and CA/TP used to measurement ion detection, one is reference membrane and the other is pH. fabricated sensor is encapsulated entirely with epoxy, finally sensor was estimated various ion sorts and pH ranges.
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Transparent conductive ZnO:Ga thin films were deposited on glass substrates using rf magnetron sputtering method for flat panel display. The ZnO:Ga films were preferentially oriented to c-axis (002) of on substrates. The surface morphology was smooth and had not porous whatever substrate temperature was. The electrical conductivity of the thin films were in the range of
$1.6{\times}10^2{\sim}6.7{\times}10^3\;{\Omega}^{-1}cm^{-1}$ at the growth temperature from 50 to$400^{\circ}C$ , whereas has a maximum at around$250^{\circ}C$ . By combining of XRD and EXAFS, the crystallinity and grain size decreased with increasing substrate temperature corresponding to the reduction of the grain-boundary scattering. The optical transmittance of sputtered ZnO:Ga thin films had an improved about 86% in the UV-visible region. -
We have studied the influence of rubbing directions on electro-optic characteristics of the fringe field driven hybrid aligned nematic liquid crystal (LC) cell by computer simulation. When a LC with positive dielectric anisotropy is used, the results show that the driving voltage and transmittance decreases as the rubbing direction with respect to horizontal electric field direction increases. The reason for decrease in light transmission is the reduction of twist angle and increase of tilt angle on the center of common electrode. In this paper, we have studied how the rubbing angle effects on the transmittance of the cell by investigating a distribution of electric field and LC director.
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This paper presents the temperature annealing effect on the dark current of the InGaAs waveguide photodiodes, which are developed for high-speed optical receivers. The interesting experimental phenomena were observed that the dark current is significantly decreased and the breakdown voltage is slightly increased after annealing at
$250^{\circ}C$ whereas the dark current and the breakdown voltage are almost constant after annealing at$200^{\circ}C$ . Based on the experimental results, the long-term annealing is more effective for the dark current improvement than the conventional curing process. -
Czochralski pulling method에 의해 성장된 고농도 도핑 Nd:LSB의 광학적 특성을 조사하였다. 결정 성장조건에 의해 달라지는 space group은 지금까지 C2/c, R32, Cc와 C2등 4가지가 보고되었으며, 기본적으로 6방정계의 구조를 가지고 비선형 광학 결정으로서의 특성을 보였다. x선 회절 분석계를 이용하여 구조를 분석하였고, 도핑 농도에 따른 형광 수명의 변화, 분산곡선 특성을 조사하였다. 또한 흡수 및 저온 형광 스펙트럼을 이용하여 도핑 농도 및 space group의 변화에 따른 에너지 준위의 변화를 관찰하고 비교하였다.
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Due to a low efficiency of phosphor with large Stoke shift in Vacuum Ultra Violet (VUV) excitation environment, new PDP phosphors which can be excited in UV excitation environment need to be developed. In this study,
$Zn_2SiO_4:Tb$ phosphor was synthesized by solid-state reaction method at$1300^{\circ}C$ with varying Tb concentration, and its cross relaxation effect was observed by Photoluminescence (PL) measurement. In order to decrease$^5D_3{\to}7F_j$ transition with blue emission in$Zn_2SiO_4:Tb$ phosphor, Dy, co-activator element, was added to$Zn_2SiO_4:Tb$ phosphor. In 254nm excitation environment, broad-emission peak was observed around 524nm, green emission. -
We have performed computer simulation to obtain electro-optic characteristics of reflective hybrid aligned nematic liquid crystal displays driven by fringe field. The results show that the optimal retardation value of the cell is
$0.289{\mu}m$ , which allows for the cell to have a practical cell gap of larger than$3{\mu}m$ when manufacturing. A reflectance of the dark state is only 0.114% for an incident light 550nm. At this condition, the light efficiency of white state reaches 92.7%. Further, we have studied a new reflective display with polarizer, optical compensation with half plate, LC plus reflector. The display with optimized cell parameters shows low wavelength dispersion and the contrast ratio greater than 5 over exists about$120^{\circ}$ in vertical direction and$160^{\circ}$ in horizontal direction. -
Lee, Jung-Tae;Mun, Jang-Won;Yeo, Cheol-Ho;Shin, Kyung;Gu, Dae-Sung;Kim, Jong-Bin;Chung, Hong-Bay 976
In this study, we formed the 2-dimensional holographic grating in order to mamufactured 2-dimensional photonic crystal in amorphous$As_{40}Ge_{10}Se_{15}S_{35}$ and$Ag/As_{40}Ge_{10}Se_{15}S_{35}$ thin film which have the excellent optical sensetivity using by He-Ne laser(632.8nm). The intensity of incident beam was 2.5mW and incident angle that$2{\theta}$ is$20^{\circ}$ . We formed the holographic grating after had formed the 1-dimansional holographic grating and then rotate the sample. We confirmed that 2-dimensional holographic grating result of the figure of diffracted beam and AFM(Atomic Forced Microcopy) image. -
The preparation of ZnS:Mn,Cl phosphor has been carried out by combustion method. Manganese nitrate was decomposed with an organic fuel at
$500^{\circ}C$ to give fine sized crystallites in presence of alkali metal halides at a lower temperature than the conventional synthesis. The phosphors thus obtained were then heated at 900 to$1200^{\circ}C$ in an inert atmosphere, for 3hours to get better luminescent properties. The phosphors were prepared at different temperatures and at different doping concentrations of manganese to determine the optimal conditions for synthesizing the phosphors with superior optical properties. Scanning electron microscopy (SEM) investigations have been carried out to observe the particle morphology and the grain size. Powder X-ray diffraction(XRD) was also performed to characterize the phosphors. -
유기발광소자 안에 존재하는 비발광영역(dark spot)의 전압에 대한 영향을 근접장 마이크로파 현미경(near-field scanning microwave microscope)을 이용하여 관찰하였다. 유기발광소자는 glass/indiumtin oxide(ITO)/Cu-Pc/tris-(8-hydroquinoline)aluminum(Alq3)/aluminum(Al) 의 기본구조로 제작하였다. Dark spot은 ITO 기판을 부분적으로 에칭하여서 형성시켰다. Dark spot에
$0{\sim}l5 V$ 까지 전압을 인가시키면서 인가 전압에 따른 전기적 특성을 근접장 마이크로파 현미경 image의 변화와 반사계수인$S_{11}$ 측정을 통하여 연구하였다. -
기존의 FED 용 MIM cathode 에 쓰이는 다층금속상부 전극을 열처리하였을 때 생기는 문제점에 대하여 살펴보았다. 먼저 열처리 후에 상부전극자체가 열변형이 일어나면서 나타나는 비저항의 증가, 표면 형상의 악화 등이 문제점으로 나타났고, 여기에 하부전극의 변형이 이러한 현상을 더욱 악화시키는 것을 확인할 수 있었다. 특히, 상부전극의 경우 그 두께가 극히 얇아 열변형이 매우 취약한 탓에 대체 물질의 개발이 시급하였다. 산화물전극은 열변형에 대해 매우 안정하여 열처리 후, 비저항이나 표면 형상의 변화가 적으며, 얇은 두께에서도 균일하게 박막이 형성되어 그 특성이 다층금속전극에 비해 매우 뛰어남을 확인하였다.
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Electronic Paper용 무기소재로
$TiO_2$ 나노입자를 적용하기 위해서는 분산시 침전문제, 입자의 전기영동 속도향상을 위한 충분한$\xi-potential$ 확보, 분산제 첨가시 안정적 결합을 위한 acidic site의 확보등의 문제가 해결되어야 한다. 이를 위해 저온균일침전법으로$TiO_2$ 나노입자를 제조하였고, 폴리머 체인을 통하여 encapsulation하여 최적의 분산과 전기영동조건 확보를 위한 공정조건에 대해 연구하였다. 실험결과 다양한 분산매에 계면활성제를 1.0wt% 첨가시 유전율상수가 2.5인 분산매에서 가장 좋은$\xi-potential$ 을 얻을 수 있었으며 이를 바탕으로 acidic site에 따른 폴리머 체인의 흡착실험 결과 pH$1{\sim}2$ 의 조건에서 제조된$TiO_2$ 나노입자의 경우가 체인과의 흡착정도가 가장 좋아 분산특성을 향상시킬 수 있었다. -
This paper presents the deposition of poly-Si thin-film and fabrication of a solar cell by VHF-PECVD method. The poly-Si thin films. and pin-type solar cells are fabricated using multi-chamber cluster tool system. A 7.4% conversion efficiency was achieved from poly-Si thin film solar cells with total thickness less than
$5{\mu}m$ . The physical characteristic was measured by Raman spectroscopy, solar cell characteristic was measured under AM1.5 illumination. -
Electrooptical (EO) characteristics of a new multidomain vertical-alignment (MVA) liquid crystal display (LCD) with negative dielectric anisotropy on a homeotropic photopolymer were studied. Good voltage-transmittance (V-T) curves of the new MVA-LCD on the homeotropic photopolymer were obtained. Also, the stable response time of the new MVA-LCD on the homeotropic photopolymer was achieved. The viewing angle of the new MVA-LCD could be improved by a crossed stripe grating-groove surface as the alignment layer using a photolithograph method on the photopolymer.
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We have investigated the effect of hole-injection buffer layer and cathodes in organic light-emitting diodes u sing poly (3,4-ethylenedioxythiophene) : poly (stylenesulfonate) (PEDOT: PSS) in a device structure of
$ITO/PEDOT:PSS/TPD/Alq_3/Cathode$ . Polymer PEDOT:PSS buffer layer was made using spin casting method. Current-voltage, luminance-voltage characteristics and efficiency of device were measured at room temperature with a variation of cathode materials. The device with LiF/Al cathode shows an improvement of external quantum efficiency approximately by a factor of ten compared to that of Al cathode only device. Our observation shows that the energy barrier-height in cathode side is important in improving the efficiency of the organic light-emitting diodes. -
Chung, Dong-Hoe;Kim, Sang-Keol;Jeong, Joon;Jang, Kyung-Uk;Hong, Jin-Woong;Lee, Joon-Ung;Kim, Tae-Wan 1007
We made use of$Alq_3$ which is the representative light-emitting material. Electric conduction mechanism and luminance characteristics were analyzed in this paper. We have also measured current density-thickness-voltage characteristics with thickness variation from 60 to 400nm. we analyzed the low electric and the high electric field in theoretically. Also, maximum luminous efficiency is the thickness 200 nm of$Alq_3$ in luminous-thickness characteristics. -
대개의 Nd형 레이저 광소자는
$^4F_{5/2}$ 의 준위로 펌핑하여 양자효율이 떨어지며, 소모적 열의 발생으로 마이크로칩 레이저의 높은 펌핑 밀도에 의한 열발생을 유도한다. 그러나$^4F_{5/2}$ 준위로의 직접 펌핑은 소모적 열발생을 획기적으로 줄일 뿐 아니라 이로 인한 레이저 발진 효율의 증가를 가능하게 하였다. Nd:LSB 마이크로칩 레이저의 경우 공진기 구성에 따라 6-11%의 기울기 효율이 상승하였다. -
열증착법을 이용하여 copper(II) phthalocyane (CuPc)의 박막을 제작하였다. 기판의 예열 온도를 달리하여 제작된 CuPc의 박막은
${\alpha}-phase$ 와${\beta}-phase$ 로 구분할 수 있으며 phase에 따른 결정 구조를 관찰하기 위해 x-ray diffraction을 사용하고 peak의 위치를 관찰하였다. 또한 SEM, UV visible absorption spectra의 변화를 통해 온도에 따라 상전이가 이행해 가는 모습을 구체적으로 관측하였다. 이러한 결정 구조의 변화는 CuPc 박막의 전기전도 특성에 영향을 달리하여 유기발광 소자에 응용이 가능할 것으로 예상된다. -
We have synthesized poly(3-hexylthiophene) and studied the optical properties of P3HT for applying to the red emitting materials of organic electroluminescent device. Usually, an organic EL device is composed of single layer like anode/emitting layer/cathode, but additional layer such as hole transport, electron transport and buffer layer is deposited to improve device efficiency. In this study, Multilayer EL devices were fabricated using tris(8-hydroxyquinolinate) aluminum(
$Alq_3$ ) as electron transport material, (N,N'-diphenyl-N,,N'(3-methylphenyl)-1,1'-biphenyl-4,4'diamine))(TPD) as hole transport/electron blocking materials and LiF as buffer layer. That is, a device structure of ITO/blending layer(TPD+P3HT)/$Alq_3$ /LiF/Al was employed. In the Multilayer device, the luminance of$10{\mu}W/cm^2$ obtained at 10V. And, we present the experimental evidence of the enhancement of the Foster energy transfer interaction in emitting layer. -
본 연구에서는 저온 동시 합성법을 이용하여 ITO 나노 분말을 제조하였다. 저온 동시 합성법은 기존의 염화 인듐 및 염화 주석 염이 아닌 인듐 및 주석 유기물 염들을 사용하므로 기존의
$600{\sim}700^{\circ}C$ 가 아닌$300^{\circ}C$ 이하에서 공정이 가능하고, 이로써 초미세급의 나노 분말을 얻을 수 있다. 또한 두가지 유기물 염을 동시에 산화시킴으로써 한번에 동시 합성이 가능하다. 이러한 저온 동시 합성법으로 제조한 나노 분말을 분석한 결과 분말의 크기는 평균 5 nm, 비 표면적은 약$104m^2/g$ 이었다. 또한 EDS 및 XRD 분석 결과 분말의 결정상은$In_2O_3$ 격자 내에$3{\sim}8%$ 의 Sn이 고용된 [222], [400], [440]의 입방정 구조인 고품질의 ITO 나노 분말을 제조할 수 있었다. -
Polycarbazole derivatives have been investigated for emitting materials of PLED. We synthesized two polymers containing carbazole chromophor, which are different from bonding position. We investigated the spectra of their absorption, photoluminescence, electroluminescence.
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This paper presents the deposition characterization of polycrystalline silicon films by the HWCVD(Hot-wire Chemical Vapor Deposition) method at low substrate(
$300^{\circ}C$ ). The filament temperature, pressure and$SiH_4$ concentration were determined to be a critical parameter for the deposition of poly-Si films. Series A was deposited under the conditions of$1380^{\circ}C$ (Tf), 100 mTorr and$2{\sim}10%\{SiH_4/(SiH_4+H_2)\}$ for 60 min. Series B was deposited under the conditions of$1400{\sim}1450^{\circ}C$ (Tf), 30 mTorr and$2{\sim}12%$ for 60 min. The physical characteristics were measured by Raman and FTIR spectroscopy, dark and photoconductivity measurements under AM1.5 illumination. -
Microcrystalline silicon(c-Si:H) thin-film solar cells are prepared with intrinsic Si-layer by hot wire CVD. The operating parameters of solar cells are strongly affected by the filament temperature (
$T_f$ ) during intrinsic layer. Jsc and efficiency abruptly decreases with elevated$T_f$ to$1400^{\circ}C$ . This deterioration of solar cell parameters are resulted from increase of crystalline volume fraction and corresponding defect density at high$T_f$ . The heater temperature ($T_h$ ) are also critical parameter that controls device operations. Solar cells prepared at low$T_h$ ($<200^{\circ}C$ ) shows a similar operating properties with devices prepared at high$T_f$ , i.e. low Jsc, Voc and efficiency. The origins for this result, however, are different with that of inferior device performances at high$T_f$ . In addition the phase transition of the silicon films occurs at different silane concentration (SC) by varying filament temperature, by which highest efficiency with SC varies with$T_f$ . -
Lee, Han-Jin;Park, Doo-Sung;Han, Jeong-Min;Park, Jeong-Kuk;Bae, Kyung-Woon;Kim, Seo-Yoon;Kim, Yun-Ho;Lim, Young-Jin 1038
LED(Light Emitting Diodes)를 이용한 LCD 백라이트는 현재까지 모바일용의$2{\sim}3$ 인치정도의 소형모델에서 상용화되고있다. 현재 동종분야에서$5{\sim}7$ 인치 이상의 중대형에서는 아직 검토나 개발단계인 것으로 파악되고 있다. LED의 특징인 장수명, 고색순도, Robustness 등의 장점에도 불구하고 광효율이나 경제적측면에서 아직 형광램프 Type 에 비해 개선점이 남아있는 것도 개발지연 이유중의 하나다. 최근에 일부 광원업체에서 소비전력 5W로 높은 출광효율을 갖는 고휘도를 가진 LED가 개발되고있다. 고색재현성을 요구하는 TV등의 민수용 디스플레이시장이 커지는 현 추세에 한 방법으로 3색의 고휘도 LED광원을 사용한 백 라이트를 개발했다. R(Red), G(Green), B(Blue)의 3색 점광원 다수를 이중도광판 구조의 장변에 일정 간격으로 배열하여 최종 출사면에서 백색이 되도록 소정의 구성비로 설계하였다. 점광원간의 간격으로 인해 발생되는 혼색도를 보완하기위해 광원과 출사면까지의 광경로를 점광원이 아닌 튜브형의 형광광원 사용시보다 일정량 길게 설계해야 되는데, 이것으로 인해 출광효율이 형광램프구조에 비해 떨어지는 결과로 나타났다. 본 연구에서는 17인치 모니터구조의 백라이트에서 색재현성 105%와 소비전력 67W에서 표면휘도$2000cd/m^2$ 정도를 달성하였다. -
Park, Chang-Joon;Hwang, Jeoung-Yeon;Kim, Jong-Hwan;Seo, Dae-Shik;Ahn, Han-Jin;Baik, Hong-Koo 1043
We investigated the EO performances of the UV aligned twisted nematic liquid crystal display (TN-LCD) with the UV exposure on a-C:H thin film surface. LC alignment using UV exposure on the a-C:H thin film surface was achieved. Monodomain alignment of the UV aligned TN-LCD can be observed. An good EO characteristics of the UV aligned TN-LCD was observed with oblique ion beam exposure on the a-C:H thin film surface. Therefore, the EO property of the UV-aligned TN-LCD with UV exposure on the a-C:H thin film surface is almost the same as that of the rubbing-aligned TN-LCD on a polyimide (PI) surface. -
Stibenequinone(SQ) derivative which was electronic transportation materials in Poly(N-vinylcarbazole) (PVK)-based on organic EL and an optical characteristic of organic EL which is mentioned previously was investigated. The Photoluminescence highest pick with blending TBSQ with PVK was shifted from 439nm to 517nm. This result indicates that an energy gap of a PVK/TBSQ blended sample is less than an energy gap of PVK. According to the electrochemistry characteristic, the ionization energy(Ip) and the electro affinity(Ea) decreased from 5.79eV to 5.63eV and 2.23eV to 2.63eV, respectively.
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Polymer dispersed liquid crystal mode can be classified into two cases, normally scattering mode (NS) and normally transparent (NT) mode according to an initial state. Electro-optic characteristic NS/NT PDLC mode can be improved by controlling the factors to influence the phase separation. In case of NS PDLC mode, we inspected change of a phase separation as a function of curing temperature for the mixture of E7 and NOA65 with different ratios. When the LC concentration is less than polymer such as LC : NOA65 = 40 : 60wt%, the PDLC cell is influenced strongly by the curing temperature. However, when LC concentration is much less than polymer such as LC : NOA65 : 80 : 20wt%, it is influenced slightly by the curing temperature. In case of NT PDLC mode, we observed change of a phase separation as a function of the ratio of the mixture and UV conditions such as curing temperature, UV intensity The cell made with strong UV intensity and curing temperature of
$20^{\circ}C$ , in case that the ratio of LC to polymer is 70:30wt%, showed good electro-optic characteristics. -
We have studied
$90^{\circ}$ twisted nematic (TN) mode driven by fringe electric field, where two polarizers are parallel each other such that the cell shows a black state before a voltage is applied. According to the studies by computer simulation for a LC with negative dielectric anisotropy, the LC twists perpendicular to the horizontal field direction of fringe electric field and the degree of tilt angle is very low, when a voltage is applied. Therefore, the new device exhibits wide viewing angle characteristic due to in-plane switching and high transmittance since the LC director aligns parallel to the polarizer axis. -
In this thesis, we observed the optical characteristic of amorphous chalcogenide thin films by He-Cd laser. Also, grating formation by He-Ne laser and He-Cd laser. After analyze diffraction efficiency of the time on the
$Ag(200{\AA})/As_{40}Ge_{10}Se_{15}S_{35}$ thin films. The result diffraction efficiency of Maximun 0.2% reduced according to time grating formation by He-Ne laser. Diffraction efficiency of Maximun 0.1% showed stabiliy characteristic according to time grating formation by He-Cd laser. -
본 연구에서는 초미세
$Y_2O_3:EU^{3+}$ 분말을 이용하여 나노 형광체를 제조하였다. 나노 형광체는 소량의 Eu가 도핑된$Y_2O_3$ 재질로 구성되어 있다. 형광체 분말의 결정화를 위해$500{\sim}900^{\circ}C$ 의 온도로 열처리하였다. 제조된 나노 형광체를 HRTEM으로 관찰한 결과 입자 크기가 열처리 온도에 따라 약$4{\sim}30nm$ 의 분포를 나타내었다. 또한 XRD로 결정상을 분석한 결과 주로 입방정 구조로 되어 있고 소량의 단사정 구조가 포함된$Y_2O_3$ peak가 검출되었다. EDS 분석 결과 약$6.7{\sim}7.5%$ 의 Eu가 검출되었다. 약 4nm 크기의$Y_2O_3:EU^{3+}$ 분말로 제조한 나노 형광체의 발광 특성은 주요 파장대가 612nm인 PL spectrum이 관찰되어, 적색 형광체로서의$Y_2O_3:EU^{3+}$ 나노 분말이 제조되었다. -
요즘, LCD TV 가 등장하면서 LCD 백라이트로써 LCD TV 에 적용하기 위해서는 무엇보다도 휘도특성의 개선이 요구되고 있다. TV 대응 LCD Panel 은 Monitor 대응 제품에 비해서 일반적으로 해상도가 낮으므로, 투과율면에서 장점은 있으나, 현재의 백라이트 구조로는 만족할만한 성능을 낼 수 없는 상황이다. 그러므로 고휘도 백라이트를 위해서 EEFL(External Electrode Fluorescent Lamp) 혹은 CCFL(Cold Cathode Fluorescent Lamp) 의 복수 사용을 전제로 한 직하방식에 대한 개발 검토가 활발히 이루어지고 있다. 직하방식에 의한 고휘도화는 램프수는 증가되지만 프리즘시트를 사용하지 않아서 가격 경쟁력이 있다. 따라서 본 연구에서는 EEFL 16등을 이용하여 17인치 직하형 백라이트를 제작하여 기구적, 전기적, 광학적 특성을 분석하였으며, 그 결과 11,700 nit 의 휘도를 달성하여 TV 대응 수준을 확보하였다.
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We have studied the characteristics of organic light-emitting diodes(OLEDs) with the PTFE buffer layer. The OLEDs have been based on the molecular compounds, N,N'-diphenyl-N,N'-bis (3-methylphenyl)-1, 1'- biphenyl-4, 4'-diamine (TPD) as a hole transport, tris(8-hydroxyquinolinoline) aluminum (III) (
$Alq_3$ ) as an electron transport and the Polytetrafluoroethylene (PTFE) as a buffer layer. The devices of structure were fabricated ITO/PTFE/TPD(40nm)/$Alq_3$ (60nm)/Al( 150nm) to see the effects of the PTFE buffer layer in organic EL devices. The thickness of the PTFE layer varied from 0.5 to 10[nm]. We were measured Current-Voltage-Luminance Characteristics and Luminance efficiency due to the variation of PTFE thickness. the PTFE layer was reported that helped to enhance the hole tunneling injection and effectively impede induim diffusion from the ITO electrode. We have obtained an improvement of luminance efficiency when the PTFE thickness is 0.5[nm] is used. The improvement of efficiency of is expected due to a function of hole-blocking of PTFE in OLEDs. -
우리는 AC-PDP에서 휘도와 효율을 향상시키기 위하여 Ne-Xe(4%)와 He(7)-Ne(3)-Xe(3%)에 소량의 Ar 또는 Kr를 첨가하여 최적의 페닝 방전가스 혼합비를 연구하였다. 우리는 이것을 증명하기 위해 효율과 Q-V 방법을 이용하여 벽전하를 계산하였으며, 2차원 시뮬레이션에서의 결과값과 비교하였다. 200 Torr 압력에서 He-Ne-Xe 또는 Ne-Xe에 소량의 Ar(0.01-0.1%) 또는 Kr(0.01-0.1%)을 첨가시켰을 때, 우리는 20% 이상의 휘도의 증가와 25% 이상의 효율 증가를 발견하였고, 또한 벽전하도 25% 이상의 증가를 보였다. 400 Torr 압력에서 He-Ne-Xe-Kr(0.005%)에 소량의 Ar(0.005-0.1%)를 첨가시켰을 때는 8% 이상의 휘도의 증가와 18% 이상의 효율 증가, 12% 이상의 벽전하 증가를 확인하였다. 결론적으로 이 결과는 He, Ne, Ar, Kr 사이에 추가적인 페닝효과가 휘도와 효율을 향상시켰다는 것을 보여준다.
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Lee, Sang-Keuk;Lee, Joon-Ung;Han, Jeong-Min;Hwang, Jeoung-Yeon;Paek, Seung-Kwon;Seo, Dae-Shik 1078
The polar anchoring strength and surface ordering in a NLC, 4-n-pentyl-4'-cyanobiphenyl (5CB), on a rubbed polyimide (PI) surface containing trifluoromethyl moiety were studied. The large extrapolation length de of 5CB for washing process of water was measured at RS=114 mm. The polar anchoring energy of 5CB on the rubbed PI surface is decreased by the washing process. Also, the polar anchoring energy of 5CB increases with the rubbing strength on the PI surface. The surface ordering of 5CB for all washing processes is smaller than the non-washing process; it is attributed to the washing process. -
본 연구에서는 고분자를 사용하여 만든 유기EL소자인 PLED (Polymer Light Emitting Diode)의 제조공정 변화에 따른 소자성능을 연구하였다. PLED의 제작은 크게 ITO 기판 제작, 발광층 및 전극 증착 등의 공정으로 나누어진다. ITO 기판은 사진식각공정으로, 발광층의 증착은 스핀코팅법으로, 전극은 진공증착법으로 각각 제작하였다. 코팅 시 스핀속도 및 점도 조절을 통하여 발광층의 두께를 조절하였고, 스핀코팅 후 건조방법에 따라서 표면의 uniformity와 발광특성을 비교해 보았다. 실험결과 특정 두께에서 발광특성이 우수하게 나타나는 것을 확인할 수 있었다. 그리고 건조방법에 따라 발광층의 표면 uniformity에 차이가 있었으며, 표면 uniformity에 따라 diode의 I-V 특성 경향이 달리 나타났다.
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We investigated the electro-optical (EO) performances of the super twisted nematic liquid crystal display (STN-LCD) on the polyimide (PI) surface using polymer film. Monodomain alignment of the plastic STN-LCD can be observed. A stable voltage-transmittance (V-T) curve of the plastic STN-LCD was observed on the polyimide (PI) surfaces using polymer film. Also, a faster response time for the plastic STN-LCD on the polyimide (PI) surfaces using polymer film can be achieved. Therefore, the EO performances of the plastic STN-LCD on the polyimide (PI) surfaces using polymer film is almost the same as that of the glass STN-LCD on a polyimide (PI) surface.
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Lee, Ho-Sik;Shin, Hoon-Kyu;Kwon, Young-Soo;Lee, Won-Jae;Lee, Sung-Il;Park, Jong-Wook;Kim, Tae-Wan 1090
최근에 각광을 받고 있는 전기 발광 소자를 Langmuir-Blodgett(LB)법을 이용하여 제작하였다. 사용 시료는 본 연구팀에서 합성을 하였으며, 시료는 PECCP[poly(3,6-N-2-ethylhexyl carbazolyl cyanoterephthalidene)]이며, 이 물질은 반복되는 주쇄에서 강한 전자 주게 그룹과 강한 전자 받게 그룹을 가지고 있다. PECCP 발광층을 제작하는데는 Langmuir-Blodgett(LB)법을 사용하였으며, 누적 층수에 의해 금속/고분자 계면의 특성을 조사하였다. 소자의 구조는 ITO/PECCP LB/Al과 ITO/PECCP LB/$Alq_3$ /Al이며, ITO와$Alq_3$ 사이에 발광층으로써 PECCP LB막을 도입하였다. 여기서$Alq_3$ 는 전자 전달 층으로 사용되었다. PECCP LB막의 UV/visible 흡수 피크는 약 410mm에서, PL 피크는 약 536mm에서, 그리고 EL 피크도 역시 약 536nm에서 관찰되었다. 또한$Alq_3$ 를 도입한 구조에서의 EL 피크 측정 결과 다양한 발광피크가 관측되었으며, Fowler-Nordheim 분석법을 이용하여 금속의 유기 막에 대한 일함수 값을 계산하였으며, 금속의 유기 막에 대한 일함수 값은$0.18{\sim}0.26eV$ 이 계산되었다. -
In this paper, the cavity-length-dependent spectral and temporal characteristics of a V-groove AlGaAs-GaAs quantum wire (QWR) laser at each subband were investigated. At short cavity lasers less than
$300{\mu}m$ , a discrete wavelength switching from the n=1 to the n=2 subband occurred due to the increased threshold gain, resulting from the increased cavity loss. Using the characteristic of the wavelength shift from n=1 to the n=2 subband with shortening the cavity length, ultrafast lasing behaviors under gain switching at the n=1 and the n=2 subband transition were demonstrated and compared. -
Chung, Dong-Hoe;Kim, Sang-Keol;Chung, Taek-Gyun;Hur, Sung-Woo;Lee, Ho-Sik;Song, Min-Jong;Kim, Tae-Wan 1098
Complex impedances with frequency and voltage variation were analyzed in ITO/$Alq_3$ /Al device structure at thickness 100 nm and 200 nm of$Alq_3$ , respectively. At low frequency, complex impedance is mostly expressed by resistive component, and at the high frequency by capacitive component. Also, we have evaluated resistance, capacitance and permittivity. -
Energy distribution function for electrons in
$SF_6$ -Ar mixtures gas used by MCS-BEq algorithm has been analysed over the E/N range$30{\sim}300[Td]$ by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2(%) and 0.5(%)$SF_6$ -Ar mixtures were measured by time-of-flight(TOF) method, The results show that the deduced electron drift velocities, Electrons Drift Velocities for a rang of E/N values. As a consequence, it was known that the spatial growth rates and the dielectric behaviors in$SF_6$ -Ar mixtures are strongly dependent on the addition rate of$SF_6$ gas but the transport coefficients of electrons are insensitive to the addition rate of$SF_6$ gas. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules. -
The electrical characteristics of
$A{\sim}C's$ ZnO varistors fabricated according to variable sintering condition, which sintering temperature is$l130^{\circ}C$ and speeds of pusher are A: 2mm/min, B: 4mm/min, C: 6 mm/min, respectively, were investigated. The varistor voltage of$A{\sim}C's$ ZnO varistors sintered at$1130^{\circ}C$ increased in order A < B$A{\sim}C's$ ZnO varistors exhibited below 2mA at rated voltage. Lightning impulse residual voltage of A's ZnO varistor suited standard characteristics, which is 3.85kV at 2.5kA, 4.4kV at 5kA and 5.16kV at 10kA. After multi lightning impulse residual voltage test of A's ZnO varistor exhibited good discharge characteristics which ZnO varistor reveals no evidence of puncture, flashover, cracking in visual examination. After high current impulse test of A's ZnO varistor exhibited good discharge characteristics, which variation rate of residual voltage is 0.4% before and after test, and revealed no evidence. -
In this paper, electrical characteristics of inductively coupled plasma in an electrodeless fluorescent lamp were investigated using a Langmuir probe with a variation of argon gas pressure. The RF output was applied in the range of
$5{\sim}50W$ at 13.56MHz. The internal plasma voltage of the chamber and the probe current were measured while varying the supply voltage to the Langmuir probe in the range of$-100V{\sim}+100V$ . When the pressure of argon gas was increased, electric current was decreased. There was a significant electric current increase from l0W to 30W. Also, when the RF power was increased, electron density was increase. This implies that this method can be used to find an optimal RF power for efficient light illumination in an electrodeless fluorescent lamp. -
A great part of flint fuel is Hydrogen and carbon's combination. they should be generated steam and carbon gas when combine with oxygen for perfect combustion in the inside of engine, but the pollutive material especially NOx and Soot are exhausted, even though fuel is combine perfectly. In this paper the characteristics of exhaust material from diesel engine is investigated for the corona discharge-EGR hybrid plasma reactor, which combined corona discharge with EGR system. NOx is decreased in all load and applied voltage to plasma reactor. However Soot is increased as increasing EGR rate and it is decreased as increasing applied voltage.
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In this paper, the electric field distribution in dielectric tube with one layer and spherical dielectric in water was simulated. The reactor was made up of the spherical dielectric that is diameter 2.5[mm],
${\epsilon}_r$ : 5, 100, 1000, 5000 respectively and one glass plate being 2[mm] thickness,${\epsilon}_r$ : 5 as electrode. The discharge gap was 7[mm]. As a result of the simulation, in case of being about the same value between the dielectric constant of spherical dielectric and water, when the reactor was applied to high voltage dielectric polarization characteristic was trending toward disappearance. To get more strong electric field, the dielectric constant should be higher comparatively, Increasing the spherical dielectric constant, the location of equippotential line was shifting from the interior to the exterior. -
In this paper, the emission properties of electrodeless fluorescent lamp were discussed using the inductively coupled plasma. To transmit the electromagnetic energy into the chamber, a RF power of 13.56MHz was applied to the antenna and considering the Ar gas pressure and the RF electric power change, the emission spectrum, Ar- I line, luminance were investigated. At this time the input parameter for ICP RF plama, Ar gas pressure and RF power were applied in the range of
$10{\sim}60m$ Torr,$10{\sim}300W$ respectively. -
In the last several centuries, humankind have been experienced the material abundance with a development of technical civilization and being industrialized quickly. During the process of this, environmental pollutant have occurred naturally so that humankind have more interests for environment pollutant. Air pollution caused by exhaust from a car is very harmful for human. Most of exhaust from a gasoline engine are
$CO_x(CO+CO_2),\;NO_x(NO+NO_2)$ , and THC(Total Hydrocarbon). The method to remove these kinds of noxious gases are so many thing such as the three catalysts,$NO_x$ catalysts, Filter and so on. However, although air pollution caused by exhaust from motorcycle have also occurred very much, there is no regulation for motorcycle. In this paper, we studied to remove$CO_x(CO+CO_2),\;NO_x(NO+NO_2)$ , THC exhaust from a motorcycle using non-thermal plasma In the result,$NO_x(NO+NO_2)$ concentration was decreased approximately 70% and THC(Total Hydrocarbon) was removed about 40%. -
이 논문은 현재 국내에서 사용하고 있는 배전용 케이블 열화진단장치인 완화전류 측정장치의 진단기준 개선을 위한 것이다. 현재까지 사용되던 직류 고전압을 이용한 누설전류 측정법을 대체하기 위해 사용되는 완화전류 측정장치는 국내 배전선로에서 수년간 현장적용을 실시하여 많은 케이블을 교체하였다. 하지만 완화전류 측정을 통해 교체한 케이블의 상태에 대해서는 검증되지 않은 상태이므로 완화전류 측정을 통한 교체기준이 국내 케이블에 적절한지 확인할 필요가 있다. 이는 케이블 유지보수에 있어서 중요한 사항으로서 교체기준이 부적절할 경우 열화진단을 통한 고장방지 목적을 달성할 수 없거나 건전한 케이블을 교체하여 불필요한 예산을 낭비하는 원인이 된다. 본 논문에서는 현장운전중인 선로를 선택하고 열화된 케이블의 절연성능 향상을 위해 실리콘을 주입하였다. 그리고 실리콘 처리후 케이블의 운전시간에 따른 열화진단 결과와 케이블 절연파괴강도를 비교하여 진단장치의 신뢰성을 검증하고자 하였다. 이것은 1년 동안의 현장시험 결과를 정리한 것이다.
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The transformer is major equipment in power receiving and substation facilities. Necessary conditions required for the transformer are compactness, lightness, high reliability, economic advantages, and easy maintenance. The pole-mount transformer installed in distribution system is acting direct role in supply of electric power and it is electric power device should drive for long term. Most of modem transformer are oil-filled transformer and accident is happening considerable. The mold transformers have been widely used in underground substations in large building and have some advantages in comparison to oil-transformer, that is low fire risk, excellent environmental compatibility, compact size and high reliability. In addition, the application of mold transformer for outdoor is possible due to development of epoxy resin. The mold transformer generally has cooling duct between low voltage coil and high voltage coil. A mold transformer made by one body molding method has been developed for small size and low loss. One body molding transformer needs some cooling method because heat radiation between each winding is difficult. In this paper, The thermal analysis of pole mount mold transformer with one body molding by duct condition is investigated and the test result of temperature rise is compared with simulation data.
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NOx, Soot and other exhausted components already became a dangerous state as principal materials of the air pollution. Therefore, the exhausted regulations are getting strict in the many countries. In this paper, reduction characteristic of NOx, Soot and CO from diesel engine are investigated, when MF plasma-EGR hybride system is put to the diesel engine. NOx is decreased in all measured load and applied voltage to plasma renter However Soot is increased as increasing EGR rate and it is decreased as increasing applied voltage.
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This paper was simulated the electric field distribution in dielectric tube with two layers and spherical dielectric in water. The reactor was made up of the spherical dielectric that is diameter : 2.5[mm],
${\epsilon}_r$ : 5, 25, 100, 1000, 5000 respectively and two glass plate being 2[mm] thickness,${\epsilon}_r$ : 5 as electrode. The discharge gap was 9[mm]. As a result of the simulation, in case of being about the same value between the dielectric constant of spherical dielectric and water, when the reactor was applied to high voltage, dielectric polarization characteristic was trending toward disappearance. To get more strong electric field, the dielectric constant should be higher comparatively, Increasing the spherical dielectric constant, the location of equippotential line was shifting from the interior to the exterior. -
The RF inductive discharge or inductively coupled plasma (ICP) continues to attract growing attention as an effective plasma source in many industrial applications, the best known of which are plasma processing and lighting technology Although most practical ICPs operate at 13.56 (MHz) and 2.65 (MHz), the trend to reduce the operating frequency is clearly recognizable from recent ICP developments. In an electrodeless fluorescent lamp, the use of a lower operating frequency simplifies and reduces cost of rf matching systems and rf generators and can eliminate capacitive coupling between the inductor coil and plasma, which could be a strong factor in wall erosion and plasma contamination. In this study, the configuration of ferrite and fixture which operates at the frequency of 2.65 (MHz) will be discussed, by using the electromagnetic simulation (Maxwell 2D).
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Ultraviolet rays, OH H O radical and
$O_3$ produced by the streamer discharge in water are widely used to deactivate microorganisms and remove organic contaminants in water and the dominant factor of these decomposition is the oxidized reaction of hydrogen peroxide and dissolved$O_3$ in water. In this paper, the barrier discharge was used to create plasma in a gas, liquid and solid medium and the electrode with the reactor combined barrier with packed type(BPR) was made as noncontact way against water so that the effect of water characteristic change by the erosion of electrodes exposing in water should be minimized. The active radical and$O_3$ gas generated in plasma region were reacted into the water as electrode so that at the same time a dissolved$O_3$ and hydrogen peroxide were formed in water and The change of pH and conductivity were measured. -
In this paper, we studied on the electrical characteristics of insulation material of elastomer epoxy. As the results of test, properties of epoxy represent differently according to elastomer contents. Also, its permittivity, tan
${\delta}$ and BDV(Break-Down Voltage) strength show big difference when those compare before moisture absorption test and after moisture absorption test. From this test we find results that mush elastomer contents can cause insulation properties to degrade. -
Recently we suffered lot of failures of polymer surge arresters made by same manufacture after one year field operation. In order to set up countermeasures we investigated the causes of failures. We extracted faulted arresters and sound ones which were installed in same pole with faulted ones for the electrical test and dissection. 44 arresters were removed from 8 branch offices. Almost all of faulted arresters hadtracking damage on the interface between inner module and housing and the surface of inner module was very rough and irregular. It was possible to occur moisture ingress into the interface between inner module and housing due to the void of the interface and non tight sealing caps. Lots of sound arresters were failed during the moisture ingress test. This result must relate with tracking damage of faulted arresters. Therefore we can say that arresters had poor interface and sealing system. But we could not found aging and defects of ZnO elements because the electrical performance except moisture ingress test of arresters showed good.
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As a PD classification method, statistical distribution parameters have been used during several ten years. And this parameters are recently finger print method, NN(Neural Network) and etc. So in this paper we studied finger print method and NN with BP(Back propagation) learning algorithm using the statistical distribution parameter, and compared with two method as classification method. As a result of comparison, classification of NN is more good result than Finger print method in respect to calculation speed, visible effect and simplicity. So, NN has more advantage as a tool for PD classification.
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In contrast to a conventional transformer, the flat transformer is made using a number of small ferrite cores. Two cores for transformer and one core for inductor, which composed one module. Many modules can be connected together to form a flat matrix transformer. This structural arrangement eliminates the single hot spot problem in conventional transformers and permits high current density pertains at high frequency. In this study, the ferrite magnetic cores of Mn-Zn system for the Flat transformer were manufactured and the electrical and magnetic characteristics of its tested. The power loss of sample FO2(Mn-Zn ferrite) sintered at
$1350^{\circ}C$ was$350kW/m^3$ in test conditions of 250kHz, 200mT and$100^{\circ}C$ , which showed the good power loss property in high frequency. The power loss of FO2 samples has been studied as a function of magnetic flux density and frequency. Steinmetz exponent was 2.82 at 250kHz and 2.73 at 500kHz. These results illustrated the switching of power loss mechanism in ferrite core from hysteresis losses to eddy current losses or others. -
The characteristics and change of electrode surface about Gap type surge arrester for protect DC subway rail were investigated with moisture absorption. Compared that tested about DC/AC discharge commencement voltage, residual voltage, Impulse, square wave impulse for DC rail surge arrester about Gap type surge arrester of moisture absorption state. The AC discharge commencement voltage acted greatly effect of moisture absorption than the DC discharge commencement voltage test.
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Low-Pressure inductively coupled RF discharge sources have important industrial applications mainly because they can provide a high-density electrodeless plasma source with low ion energy and low power loss. In an inductive discharge, the RF power is coupled to the plasma by an electromagnetic interaction with the current flowing in a coil. In this paper, the experiments have been focussed on the electric characteristic and carried out using a single Langmuir probe. The internal electric characteristics of inductively coupled Ar RF discharge at 13.56 [MHz] have been measured over a wide range of power at gas pressure ranging from
$1{\sim}70$ [mTorr]. -
170kV GIS(Gas Insulated Switchgear) is widely used in large industrial factory-electrical facilities of private use because has many benefits. But Other equipments's failures are occurred by GIS failures and give rise economic problems to user. Therefore we will examine the actual condition of the 170kV GIS-electrical facilities of private use and are able to confirm the distribution characteristic analysis of disconnecting switchgear. In this paper, we presents the actual condition investigation of the disconnecting switchgear of 170kV GIS-electrical facilities of private use by post - failure pattern, inspection method, test equipments and so forth.
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Electrochemical capacitors are becoming attractive energy storage systems particularly for applications involving high power requirements such as hybrid systems consisting of batteries and electrochemical capacitors for electric vehicle propulsion. A new type electric double layer capacitor (EDLC) was constructed by using carbon nanofibers (CNFs) and DAAQ(1,5-diaminoanthraquinone) electrode. Carbonaceous materials are found in variety forms such as graphite, diamond, carbon fibers etc. While all the carbon nanofibers include impurities such as amorphous carbon, nanoparticles, catalytic metals and incompletely grown carbons. We have eliminated of Ni particles and some carbonaceous particles in nitric acid. Nitric acid treated CNFs could be covered with very thin DAAQ oligomer from the results of CV and TG analyses and SEM images. DAAQ oligomer film exhibited a specific capacity as 45-50 Ah/kg in 4M
$H_2SO_4$ . We established Process Parameters of the technique for the formation of nano-structured materials. Furthermore, improved the capacitive properties of the nano structured CNFs electrodes using controlled solution chemistry. As a result, CNFs coated by DAAQ composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system with respect to specific capacity and scan rate dependency. -
In this paper, we focus our attention on the improvement of locking time and jitter parameter and propose the new structure of PLL which combined with the FVC, FOVI Matcher(FVC-Output and VCO-input Matching Circuit), Control Circuit and the conventional charge pump PLL. Using fast operation characteristics of the FVC, the circuit matching FVC-Output and VCO-input (FOVI Matcher) made to synchronize very fast. Fast locking time is usually required for application where the PLL has to settle rapidly if they switch from an idle mode to a normal mode and to track high-frequency data bit rate in data recovery systems. After a fast acqusition is achieved by the using the FVC, the conventional PLL operates for removing the phase error between the reference signal and the feedback signal. Therefore this structure can improve the trade-off between acquisition behavior and locked behavior.
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A highly condensed ozone gas be transferred to the superconductor thin film growth chamber because ozone is strong oxidizing gas. In order to obtain high quality oxide thin films, higher ozone concentration is necessary. In this paper an ozone condensation system was evaluated from the viewpoint of an ozone supplier for oxide thin film growth. Ozone was condensed by an adsorption method and the ozone concentration reached 8.5 mol% in 2.5 h after the beginning of the ozone condensation process, indicating high effectiveness of the condensation process. Ozone was continuously desorbed from the silica gel by the negative pressure.
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Recently, the development of diagnosis technique with high confidence is important on power equipment, for this reason is use for measurement and analysis of PD with prior appearance of insulation breakdown. In this paper, we presents the analysis of trouble signal to use
${\phi}-Q$ method which display 2D and 3D Equipment of simulation has made independently DS for 170kV GIS of one phase with same on field. The detected signal through the sensor of Induction and Acoustic Emission is classified to use characteristic neural network algorithm and then it is analysis. -
The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were applied to Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased, the stronger breakdown strength became at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher. Finally, according to Weibull distribution analysis, reducing breakdown probability of equipment insulation lower than 0.1% level requires the allowable field allowable field intensity values to be kept under 21.5 MV/cm.
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BiSrCaCuO superconducting thin films have been fabricated by co-deposition using IBS(ion Beam Sputtering) method. Despite setting the composition of thin film Bi2212 or Bi2223, in both cases, Bi2201, Bi2212 and Bi2223 phase were appeared. It was confirmed the obtained field of stabilizing phase was represented in the diagonal direction of the right below end in the Arrhenius plot of temperature of the substrate and
$PO_3$ , and it was distributed in the rezone. -
High quality
$Bi_2Sr_2Ca_nCu_{n+1}O_x$ superconducting thin films fabricated by using the evaporation method at various substrate temperatures,$T_{sub}$ , and ozone gas pressures,$pO_3$ . The correlation diagrams of the$Bi_2Sr_2Ca_nCu_{n+1}O_x$ phases with$T_{sub}$ and$pO_3$ are established in the 2212 and 2223 compositional films. In spite of 2212 compositional sputtering, Bi2201 and Bi2223 as well as Bi2212 phases come out as stable phases depending on$T_{sub}$ and$pO_3$ . From these results, the thermodynamic evaluation of${\Delta}H$ and${\Delta}S$ , which are related with Gibbs' free energy change for single Bi2212 or Bi2223 phase, was performed. -
In this study, the
${\pi}/4$ shift QPSK(quadrature phase shift keying) with NEC(nonredundant error correction) on the multipath channel can detect the burst error as well as random error one by using the second and L-th order phase difference. Therefore, the BER(bit error rate) performance in${\pi}/4$ shift QPSK is more improved than that of the${\pi}/4$ shift QPSK without NEC structure. Also, this performance become a bit better in Rayleigh fading channel. -
상용화되어 있는 이동통신 기기의 Front-end 부분은 듀플렉서와 필터를 포함하는 수동소자로 구성되어 있다. 듀플렉서의 임피던스 정합선로는 전송선로 이론으로부터 설계하며, 단순하게
${\lambda}=1/4$ 파장 길이의 정합 선로를 설치하는 것이기 때문에 정합선로를 이용한 듀플렉서 성능을 극대화하기 위한 설계의 융통성이 없는게 현실이다. 이런 문제점을 해결하기 위하여 집중소자(lumped element)인 R L C를 탄성 표면파 듀플렉서 대신 스위치 모들에 적용하게 된다면 여러 가지 다양한 형태의 회로를 구현할 수 있고 회로망 내에 위치하는 집중소자의 정격을 최적화하여 스위치 모듈의 성능을 향상시킬 수 있는 가능성이 있다. 본 연구에서는$900 MHz{\sim}2.2 GHz$ 의 대역에서 소형화 집적화에 적용 가능한 디바이스를 개발하기 위하여 고주파, 저진압, 저손실 스위치 모듈의 제조와 구성되는 커패시터와 인덕터의 제조와 특성에 관하여 연구하였다. -
A new type electric double layer capacitor (EDLC) was constructed by using carbon nanofibers (CNFs) and DAAQ(1,5-diaminoanthraquinone) electrode. Carbonaceous materials are found in variety forms such as graphite, diamond, carbon fibers etc. While all the carbon nanofibers include impurities such as amorphous carbon, nanoparticles, catalytic metals and incompletely grown carbons. We have eliminated of Ni particles and some carbonaceous particles in nitric acid. Nitric acid treated CNFs could be covered with very thin DAAQ oligomer from the results of CV and TG analyses and SEM images. A crystalline supramolecular oligomer of 1,5-diaminoanthraquinone(DAAQ) was successfully prepared as a thin film by electrochemical oxidation from an acidic non-aqueous medium. DAAQ oligomer film exhibited a specific capacity as 45-50 Ah/kg in 4M
$H_2SO_4$ . Its electrochemical characteristics were investigated by cyclic voltammetry. And compared with different electrolyte of aqueous type. During ultrasonic irradiation CNFs was to disperse in 0.1M$H_2SO_4$ . As a result, CNFs coated by DAAQ composite electrode showed relatively good electrochemical behaviors. -
본 연구에서는 canopy가 없는 stadium에서의 야간조명 실태를 조사하고 국내에 설치된 각 stadium의 조도를 측정하여 그 결과를 KS, FIFA기준 및 방송국 기준을 비교하고 stadium의 전체적인 조도분포를 분석하였다. 4pole 배치의 stadium에 있어서 조도는 KS 기준에는 대체로 만족하나 FIFA 및 방송국 기준에는 미흡함을 알 수 있었다. 특히 4pole 배치 방식에 있어서 수평면 및 수직면 조도의 균일도는 국제기준에 많이 미흡하여 원활한 경기진행 및 TV 중계에 많은 어려움이 있었다. 이러한 결과로부터 stadium의 조명시설을 고려한 설계과정의 필요함을 알 수 있었고, 또한 KS기준이 국제기준과 비교하여 많은 차이가 있어 stadium의 특성을 고려한 제도적인 보완을 통하여 철저한 설계가 이루어져야 하겠다.
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In this paper, we propose a pose estimation method using local map acquired from 2d laser range finder information. The proposed method uses extended kalman filter. The state equation is a navigation system equation of Nomad Super Scout II. The measurement equation is a map-based measurement equation using a SICK PLS 101-112 sensor. We describe a map consisting of geometric features such as plane, edge and corner. For pose estimation we scan external environments by laser rage finer. And then these data are fed to kalman filter to estimate robot pose and position. The proposed method enables very fast simultaneous map building and pose estimation.
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A sample procedure has been described to room temperature synthesis, mesoporous aluminosilicate materials with strong surface acidity by using a cationic surfactnat cetyltrimethylammonium bromide(CTABr) as the template agent. All samples were charecterized by X-ray diffraction(XRD) and nitrogen adsorption. The crystallinity and surface area of MCM-41 type aluminosilicats decrease with decreasing of Si/Al ratio. The influence of the aluminum contents of MCM-41 on the coordination of Al and on the acidity is studied by
$^{27}Al$ MAS NMR and temperature programmed desorption of ammonia(TPD). It was shown that the incorporation of Al atoms into the framework causes increasing of acid site surface. And then Al atoms in the framework were incorporated tetrahedrally in structure, which gave a rise to cationic sites in the framework. -
선박이 배출하는 안정수(ballast water)는 외부로부터 유해 생물들이 유입되어 전파해 오는 주요경로로써, 해양환경 변화를 초래하는 매우 중요하고 위험한 일중의 하나이다. 그러나 이에 대한 효과적인 처리방법은 아직까지도 미흡한 상태이다. 선박 안정수에 포함되어 타지역으로부터 옮겨지는 외래침입생물 처리방안의 하나로, 강 전리방전 기술을 적용하여 고 밀집 산소와 물분자로부터 고농도 수산자유기(OH: hydroxyl radical)를 전리, 발생시켜서 활성입자를 신속히 확산시켜 비교적 낮은 수산기농도하에서 유해성 침입생물을 소멸 처리하는 환경 친화적 녹색 청정처리방법을 제안하였다. 제안된 기술은 대상물의 처리 후 부수적으로 발생할 수 있는 처리잔류물이 전혀 발생하지 않으며, 화학 약제를 사용하지 않는 저렴한 처리방법으로 선박안정수의 침입생물을 안전하게 처리할 수 있는 자연치유적 신기술이다.
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The materials showing high structure dispersity are developed on the natural quartz base and they are obtained by mechano-chemical technology. Depending on the processing conditions and subsequent applications the materials produced by mechano-chemical reaction (MCR) show concurrently magnetic, dielectric and electrical properties. The obtained magnetic-electrical powders classified by aggregate complex of their features as segnetomagnetics, contain a dielectric material as a carrying nucleus, particularly the quartz on that surface one or more layers of different compounds are synthesized having thickness up to
$10{\sim}50nm$ and showing magnetic, electrical and other properties.