As raw materials, the inorganic pigments, such as mica, talc and some metal oxides were mainly used in Make-Up cosmetics. Some other polymerics, organics and functional pigments were also used to cope with the various consumer's demends. Recently, excellent sliding, adhensivness, coverture and UV cutting properties were strongly required in Make-Up cosmetics. According to these demends, it needs to understand the functional properties of each pigment and consider the proper use for some purpose. And so, this report introduce the properties of inorganics, polymerics and functional pigments and their application fields for Make-Up cosmetics.

Oil and fats has been using as the important raw materials in the coating industry from ancient time to date. This article was prepared with the aim of helping to the forward development trend for coating uses of oil and fats, as understand together the history using oil and fats for coatings, composition and classification coatings, types and composition of oil and fats using for coatings nowaday, how to use oil and fats for coating, film for coatings, film forming mechanism.

I am going to survey major topics relating to the title by analyzing the following statistical data. 1 : Global trend of production and import of oil and relating materials 2 : Global trend of major oil production 3 : Capacity of Japanese factory for oil production 4 : Situation of mechanical expression based on raw materials 5 : Change of production amounts of Oil products 6 : Oil production of each items 7 : Imported amounts of oil products 8 : Vegetable oil meals, production, import and global trend 9 : Production of mayonnaise, dressing and edible processing oils 10 : Intake of nutrients, supply of lipids, and consumption of oils 11 : Global production of oleochemicals 12 : Sales amount of oleochemicals 13 : Capacities of fatty acid and fatty alcohol factories 14 : Oleochemical production in 1995 15 : Oleochemical procuction in asia 16 : Production of surfactants for industrial use 17 : Sales amount of detergents and washing materials 18 : Production of soap and synthetic detergent in Japan 19 : Consumption of soap. detergent, and synthetic detergent 20: Relation beween synthetic detergent production and popularization 21 : Biodegradability of soft detergent

Vibrio vulnificus에서 lipopolysaccharide(LPS)를 추출하여 지방산 조성을 분석한 후 이 결과를 Escherichia coli LPS와 Salmonella typhimurium LPS의 것들과 비교하였다. Vibrio vulnificus LPS의 주 지방산은 myristic acid(C14:0, 41.37%)이었고 Escherichia coli LPS는 lauric acid(C12:0, 37.03%), Salmonella typhimurium LPS는 capric acid(C10:0, 48.60%)로 서로 달랐으나 이 세가지 지방산이 각 LPS의 주성분이었다(70%이상).

Durable softening water repellents for nylon fiber were synthesized, using two compounds: quaternized octadecyl methacrylate-2-diethylaminoethyl methacrylate copolymer as a mother resin of water repellent and quaternized fatty carbamide for improving softness and hydrostatic pressure, of which syntheses were studied in the previous papers. They were blended with waxes and emulsifiers in a variety of ratios and synthesized into water repellent PADWC, and it was nylon taffeta treated with and without textile finishing resin. The synthesized water repellents can be used either or without resin. The optimum curing temperature was 150 to 160$^{\circ}C$ and the optimum concentration was 3 to 5wt%. In the independent and conjunct treatment, the water repellency of nylon taffeta samples have no remarkable changes between initial value and that after three times washing, so these prove that the synthesized compounds are durable water repellent. The water repellency of PADWC-3 and -4 were around 90. Also, comparison of crease recovery and tear strength after repelling treatment showed that the synthesized water repellents have a very high softening effect.

The metal complexes containing amino acidic ligands were prepared by using 11 kinds of amino acids as ligands and Ni, Cu, Co, Zn, Fe as a central metal. The starting was continued for 4hrs at room temperature. But Bis(D,L-Serine)Ni (II), and (D,L-Serine)Co (II) were prepared by heating method($80^{\circ}C$). In order to investigated reaction activity of Bis(D,L-Aspartato) Metal(II), stirring time was varied and Bis(D,L-Tyrosine ) Metal(II) used different divalent metal salts. We anticipate getting a great value from these prepared complexes as a monomer and a catalyst of polymerization which has peculier characteristics.

Ultra thin organic films, (3-docosyl benzimidazolium)-TCNQ(1:1)complex, were deposited onto ordinary microscope slide glass substrates with a Langmuir-Blodgett technique. II-A isotherms were studied to find optimum conditions of deposition by varying temperature. Anisotropic de electrical conductivities were measured at room temperature. They are about $5.21{\times}10^{-12}S/cm$ along the direction of film surface, and $(2.73{\sim}4.40){\times}10^{-16}S/cm$ in the vertical direction.

A Stability to spreading solvent, which is acetonitrile, dichloromethane, benzene, chloroform, and acetonitrile-benzene (1:1, v/v) of (N-docosyl quinolinium)-TCNQ(1:2) complex was investigated by UV-visible spectrometer and was confirmed stabilized on acetonitrile, dichloromethane, and acetonitrile-benzene(1:1, v/v) for 7 hours. Using buffer solution($ph{\doteqdot}6.0$) as subphase for Langmuir-Blodgett(LB) film, it was achieved successively to fabricate the Y type LB films of (N-docosyl quinolinium)-TCNQ(1:2) complex. For the identification of deposition of (N-docosyl quinolinium)-TCNQ(1:2) complex, UV-visible spectra was recorded on HP 8452A spectrometer.

A stability to the spreading solvent, which is acetonitrile, benzene, chloroform and acetonitrile-benzene(1:1, v/v) of (3-Alkyl benzimidazdium)-TCNQ(1:2) complex was investigated by UV-visible spectrometer and was confirmed stabilized on acetonitrile, acetonitrile-benzene (1:1, v/v) for five hours. Using Ultra pure water as subphase for Langmuir-Blodgett(LB) films, it was achived successively to fabricate the Y-type LB films of (3-Alkyl benzimidazolium)-TCNQ(1:2) complex. For the identification of (3-Alkyl benzimidazolium)-TCNQ(1:2) complex, UV-visible spectra was recorded on HP 8452A spectrometer.

Intermediates, 1-benzyl-2-substituted-3-carboxaldehyde[I]-[II], were prepared by the reaction of 2-substituted indole-3-carboxaldehyde with benzyl chloride. Indolylacrylophenone derivatives[III]-[X] were prepared from 1-benzyl-2-substituted-3-carboxaldehyde with acetophenone derivatives. They are as follows; 3-(1'-benzylindole-3'-yl)-1acrylophenone [III] 3-(1'-benzylindole-3-yl)-1(p-methoxy)acrylophenone [IV] 3-(1'-benzylindole-3-yl)-1(p-bromo)acrylophenone [V] 3-(1'-benzylindole-3-yl)-1(p-chloro)acrylophenone [VI] 3-(1'-benzyl-2'-methylindole-3'-yl)-1-acrylophenone [VII] 3-(1'-benzyl-2'-methylindole-3'-yl)-1-(p-methoxy)acrylophenone [VIII] 3-(1'-benzyl-2'-methylindole-3'-yl)-1-(p-bromo)acrylophenone [VIII] 3-(1'-benzyl-2'-methylindole-3'-yl)-1-(p-chloro)acrylophenone [X]

Amphoteric surfactants were synthesized by the cyclization of 1-(2-hydroxyethyl)-2-undecyl-2-imidazoline [I] with acrylic acid ethyl ester. Compound [I] was easily hydrolyzed with water, especially in the presence of a alkali, to afford amidoamines. After [I] was hydrolyzed, the reaction mixture was allowed to react with acrylic acid ethyl ester and then soapoinfied. Only sodium salts of N- -(2-carboxyethyl)-N'-(2-hydroxyethyl)aminoethyl]dodecanoyl amide[III] was obtained. However, when the reacton of [I] with acrylic acid ethyl ester was carried out in the presence of water, followed by soapnification, ring cleavage of [I] occurred at 2, 3 position, different from hydrolysis of [I] where the cleavage occurred at 1, 2 position, to give sodium salts of N-[N'-(2-carboxyethyl)aminoethyl]-N-(2-hydroxyethyl)dodecanoyl amide [IV] and N-[N', N'-bis(2-carboxyethyl)aminoethyl]-N(2-hydroxyethyl)dodecanoyl amide [V] as main products.

1-(2-hydroxyethyl)-2-undecyl-2-imidazoline[I] was converted into various types of sulfonated or sulfated amphoteric surfactants as following. 1-(2-hydroxyethyl)-1-(3-sulfonatedpropyl)-2-undecyl-2-imidazolium[III] 1-(2-sulfatedethyl)-1-methyl-2-undecyl-2-imidazolium[IV] 1-dioxylethylene methyl sulfonated-1-methyl-2-undecyl-2-imidazoliun[V] N-[N'-(2-hydroxyethyl)-N-(3-sulfonatedpropylammonio]ethyl dodecanoyl amide[VI] Mono sodium N-[N'-(2-hydroxyethyl)-N'-disulfonatedpropylammonio]ethyl dodecanoyl amide[VII] N-[N'-(2-hydroxyethyl-N'-(2-hydroxypropl-N'(3-sulfonatedpropyl)ammonio] ethyl dodecanoyl amide[VIII] The alkylimidazolines could be readily hydrolyzed to give amidoamines, but by quaternerization, hydrolysis stability of imidazoline and amide type amphoteric surfactantes were increased in the alkali and acid conditions. Also, at least three carbon chains introduce to the main group, water solubility was sparingly increased.

In order to investigate of the Influence of $Mg^{2+}$, $Ca^{2+}$ on ${\alpha}$-linolenic acid converted into the eicosapentaenoic acid(EPA) and docosahexaenoic acid(DHA) forming in plasma lipid and in liver microsomes of rabbit, the animals were fed on the perila oil rich ${\alpha}$-linolenic acid or sardine oil rich EPA and DBA diet for 4 weeks were examined. In plasma, liver lipid, $Mg^{2+}$ was influenced on arachidonic acid(AA), EPA, DHA formative from ${\alpha}$-linolenic acid in perilla oil, but stearic acid was increased, $Ca^{2+}$ was Influenced on stearic acid increased and DHA was decreased. In phospholipid, $Mg^{2+}$, $Ca^{2+}$ was influenced on stearic acid increased and DHA was decreased in perilla oil.

MDABM and MDAEW, as a accelerating weight loss agents, were prepared by adding water to myristyldimethylbenzylammonium bromide(MDAB) and myristyldimethylethylammonium ethyl sulfate (MDAE) synthesized. As a result of weight loss finishing of the MDABW and MDAEW with NaOH on PET fiber, the ratio of weight loss of MDABW was very larger than that of MDAEW. This result showed that quaternary ammonium bromide had higher weight loss effect than quaternary ammonium sulfate, and the ratio of weight loss was greatly varied with the kind of quaternary ammonium salts used. In these conditions, proper treatment concentration, treatment time, and treatment bath ratio were about 8g/l, $6O{\sim}90min$, and $40:1{\sim}50:1$, respectively.

Ultra thin films of HDSM-CuPc(Tetra-3-hexadecylsulphamoylcopperphthalocya-nine) were formed on various substrates by Langmuir-Blodgett method, where HDSM-CuPc was synthesized by attaching long-chain alkylamine(hexa-decylamine) to CuPc. The reaction product was identified with FT- IR, UV-visible absorption spectroscopies, elemental analysis and thin layer chromatography. The formation of ultrathin films of HDSM-CuPc was confirmed by FT-IR and UV-visible spectroscpies.

Polyamic acid alkylamine (N, N-dimethylhexadecylamine)(PAAS)염을 합성하여 그 합성여부를 확인하였으며 PAAS염의 Langmuir막의 ${\pi}-A$ 등온선 및 표면 전위 특성 등을 조사 하였다. Langmuir-Blodgett법에 의하여 PAAS염의 LB막을 여러종류의 기관에 누적하였으며 누적여부를 자외선 흡수 스펙트럼 및 적외선 투과 스펙트럼을 이용하여 조사하였다. 그리고 PAAS LB막을 열처리에 의하여 이미드(imide)화시켜 폴리이미드 LB막을 제조하였으며 그 이미드화 여부를 자외선 및 적외선 스펙트럼을 이용하여 조사하였다.