1,4-Dioxane is an EPA priority pollutant often found in contaminated ground waters and industrial effluents. Conventional water treatment techniques are limited to decompose this compound effectively. Therefore, an advanced oxidation process system (AOP) was used for the degradation of 1,4-dioxane. This research investigates the effect of adding oxidants, such as ozone, air, and $H_2O_2$ during the UV irradiation of 1,4-dioxane solution. In order to analyze 1,4-dioxane, a modified 8270 method, which is an improved method of U.S EPA 8720, was used. Degradation efficiencies of 1,4-dioxane by only UV irradiation at various temperatures were not significant. However, The addition of oxidants and air bubbling in the UV irradiation system for 1,4-dioxane decomposition showed the higher 1,4-dioxane degradation rate. And, during AOP treatment the tendency of TOC changes was similar to that of 1,4-dioxane decomposition rate.