The current-voltage characteristics at annealed Be-Cu alloy(1.8-2 wt% Be, 0.2 wt% Co+Ni) interfaces have been studied by means of the cyclic voltammetric method. The specimens were annealed in nitrogen gas($N_{2}$) furnace at 36$0^{\circ}C$ for 1.5 hours. After annealing, the vickers hardness(HV) was increased from 210 to 385. The used solutions were distilled water(H$_{2}$O), 10$^{-3}M\;CsNO_{2},10^{-2}M\;KCl,10^{-2}M\;KOH,10^{-4}M\;H_{2}SO_{4}$ aqueous electrolytes, and ethylalcohol ($C_{2}H_{5}OH$), etc. The cyclic voltammograms showed significant current-voltage characteristics between the annealed and unannealed specimens at the same conditions. The age hardening and the related surface potential barrer and dissolution effects have been observed during the whole experimental process. The dissolution process of annealed Be-Cu alloys was effectively retarded by the age hardening phenomenon. The age hardening effect also raised the surface potential barrier of Be-Cu alloys. The interfacial phenomena of Be-Cu alloys seem to be one of good models for understanding the activation process.