수소 station에서 수소분리정제를 위한 compact형 PSA 공정 설계를 위하여 활성탄으로 충진된 dual bed의 흡착동특성을 연구하였다. 기존 PSA 공정의 흡착탑이 차지하는 시스템의 공간을 줄이기 위하여 하나의 흡착탑 안에 다른 흡착탑을 넣어 흡착탑이 차지하는 공간을 최소화하고, 흡착탑 간의 열교환을 효과적으로 할 수 있도록 고안하였다. 수소 혼합물에 대한 dual bed에서의 흡착, 탈착 실험 실시하였으며, 시간에 따른 농도와 온도의 변화를 측정하였다. 수소 혼합물로는 $H_2/CO/CH_4/CO_2$ (69:2:3:26vol.%)를 사용하였으며, 흡착유량은 7LPM, 흡착압력은 9atm 조건에서 운전하였다. Inner bed와 outer bed의 수소 농도 파과곡선의 형태에 있어 차이를 보였으며, 이는 각 탑에서 열교환 효과로 인한 내부 온도 차이에 기인하여 발생하였다.

We performed molecular dynamics simulations on the conventional MOF, IRMOF-14 and the catenated MOF with two MOF chains, IRMOF13, to find out rational design and synthetic strategies toward efficient hydrogen storage materials. The molecular dynamics calculations were done using Universal force fields and the analysis of result was performed during the NVE dynamics after preliminary NVT dynamics at 77K. The results showed the density of adsorbed hydrogen molecules was increased in the various pores created by catenation of MOFs while the large amount of volume in conventional MOF was not effectively utilized to store hydrogen. Those calculation results commonly showed the proper control of pore si Be for hydrogen storage into MOF by catenation would be one of the efficient ways to increase hydrogen capacity of MOFs.

Electro-electrodialysis (EED) experiments were carried out for the HI concentration from HIx $(HI-H_2O-I_2)$ solution to improve the Hl decomposition reaction in the thermochemical water-splitting is (iodine-Sulfur) process. EED cell is composed of the collector electrode and electrolyte. Nafion 117 which was cation exchange membrane used as an electrolyte, and the activated carbon cloth used as an electrode. The HI concentration experiment was carried out using the HIx solution and molar ratio of the $I_2$ were varied from 1 to 3 mole. The cell voltages were decreased as temperature increase. And, membrane properties such as transport number of proton and electro-osmosis coefficient were decreased as temperature increase

한국에너지기술연구원에서는 가정용 고분자연료전지 열병합 발전시스템을 위한 통합형 천연가스 연료처리 시스템을 개발해 왔다. 가정용 시스템으로서 필수적인 소형화와 고효율을 현실화하기 위해, 연료처리 시스템의 각 단위 공정 즉 수증기 개질, 수성가스 전이, 선택적 산화 공정 등을 이중 동 심관형 반응기에 통합하여 상호 열교환이 용이하도록 반응기를 설계하였다. 현재 시험 운전 중인 Prototype-I 연료 처리 시스템은 1kW급 고분자 연료전지 열병합 발전 시스템에 개질 가스를 공급하기 위해 설계되었으며, 기초 성능은 정격 부하 운전시 열효율 78% (HHV 기준), 메탄 전환율 91%이다. 개질 가스 내 일산화탄소 농도는 고분자 연료전지 전극의 피독을 피하기 위해 10ppm 이하로 유지되어야 하며, Prototype-I 연료 처리 시스템은 백금과 루테늄 촉매를 적용한 선택적 산화 반응기를 통해 개질 가스 내 일산화탄소 농도를 10ppm 이하로 제거하였다. 일반 가정에서는 고분자 연료전지 시스템의 부하 변동이 예상되기 때문에 연료 처리 시스템의 부하 변동 운전 특성도 살펴보았다 정격 부하에서 80%, 60%, 40%로 부하를 변동하며 운전하였고, 각 부하에서 안정한 메탄 전환율과 10ppm이하의 일산화탄소 농도를 보였다. 80%까지는 열효율이 77%로 큰 변화를 보이지 않았으며, 60%에서는 76%, 40%에서는 72%로 열효율이 감소하는 현상을 보였다 연료 처리 시스템의 일일 시동-정지 운전시 내구성을 테스트 중이다. 현재까지 50여회의 일일-시동 정지를 시도하였다 시동 후 약 세 시간가량의 정력 부하 운전을 실시한 후 부하 변동을 실시하였고, 총 운전 시간 8시간 정도 운전한 후 시스템을 정지하였다 메탄 전환율과 일산화 탄소 농도, 열효율을 모니터링 하고 있으며, 현재까지 초기 성능을 그대로 유지하고 있다. 앞으로 일일시동-정지 운전 시험을 지속하면서 초기 시동 특성 및 부하 변동에 따른 응답 특성 개선, 그리고 연료전지와의 연계 운전을 실시할 예정이다

수소의 소규모 분산 생산 기술은 본격 적 인 수소 인프라가 도입되기 전에 연료전지 자동차의 수소 충전용이나 분산 발전형 연료전지의 수소 공급을 위해 필요하다. 생산 용량은 수소 기준으로 $20{\sim}100 Nm^3/hr$ 정도로 현재로선 천연가스의 수증기 개 질법이 가장 경제적인 공정으로 알려져 있다. 소규모 생산에 따른 열효율 저하를 줄이 기 위해 단위 공정들이 통합된 컴팩트 개질 시스템의 개발이 필요하다. 연료전지 자동차용 수소 인프라 조기 구축을 위하여 수소충전소 구축과 국산화 천연가스 수증기 개질기 개발을 병행하여 진행하였다. 수소 충전소 구축 부분은 충전소 부지 확보, 건물 건축, 각종 유틸리 티 설치의 토목 부분과 천연가스 개질형 수소 제조 유닛 설치, 수소 압축, 저장, 디스펜싱 시스템 설치를 포함하고 있으며 고압 설비에 대한 인허가 대응 및 안전대책 작업도 진행하였다. 구축된 수소충전소는 향후 연료전지 자동차 연계 실증 프로그램에 활용할 수 있다. 국산화 핵심 기술 개발을 위하여 열 및 시스템 통합 설계에 의 해 천연가스 수증기 개질기를 제작하고 내부 열교환 구조에 따른 개질기의 성능을 평가하였다. 개발된 개질기는 개질온도 $720^{\circ}C$, 수증기 대 카본 비 2.7의 운전조건에서 $23Nm^3/h$ 이상의 수소 생산이 가능하였으며 73% 이상의 개질 효율을 나타내었다. 개발된 천연가스 수증기 개질기는 향후 수소 정제용 PSA(Pressure Swing Adsorption) 시스템과 연계하여 수소충전소 국산화 엔지니어링 설계 패키지 개발의 핵심 기 술로 사용할 계획이다.시간 정도 운전한 후 시스템을 정지하였다 메탄 전환율과 일산화 탄소 농도, 열효율을 모니터링 하고 있으며, 현재까지 초기 성능을 그대로 유지하고 있다. 앞으로 일일시동-정지 운전 시험을 지속하면서 초기 시동 특성 및 부하 변동에 따른 응답 특성 개선, 그리고 연료전지와의 연계 운전을 실시할 예정이다 한다. 단위 전지 운전 온도 $130^{\circ}C$, 상대습도 37%의 운전 조건에서도 상당히 우수한 전지 성능을 보임에 따라 고온/저가습 조건에서 상용 Nafion 112 막보다 우수한 막 특성을 나타냄을 확인하였다.소/배후방사능비는 각각 $2.18{\pm}0.03,\;2.56{\pm}0.11,\;3.08{\pm}0.18,\;3.77{\pm}0.17,\;4.70{\pm}0.45$ 그리고 $5.59{\pm}0.40$이었고, $^{67}Ga$-citrate의 경우 2시간, 24시간, 48시간에 $3.06{\pm}0.84,\;4.12{\pm}0.54\;4.55{\pm}0.74 $이었다. 결론 : Transferrin에 $^{99m}Tc$을 이용한 방사성표지가 성공적으로 이루어졌고, $^{99m}Tc$-transferrin의 표지효율은 8시간까지 95% 이상의 안정된 방사성표지효율을 보였다. $^{99m}Tc$-transferrin을 이용한 감염영상을 성공적으로 얻을 수 있었으며, $^{67}Ga$-citrate 영상과 비교하여 더 빠른 시간 안에 우수한 영상을 얻을 수 있었다. 그러므로 $^{

수소는 청정에너지로서 미래에너지의 대안으로 여겨지고 있기 때문에 수소에너지 관련 기술은 미래 국가 경쟁력을 좌우할 것으로 예상되며 이러한 수소에너지의 핵심인 수소스테이션 관련 기술은 국가연료전지 시장을 비롯한 수소자동차 사업 전반에 커다란 영향을 미칠 것으로 예상되고 있다. 이에 따라 전 세계적으로 수소에너지를 차세대 에너지원으로 개발하기 위하여 전력을 다하고 있으며, 수소연료전지자동차 개발과 아울러 수소스테이션 개발에 대한 인프라 구축 및 실증연구가 본격적으로 이루어지고 있다. 국내에서도 가스공사를 비롯한 에너지 관련 기업에서 수소스테이션 건설이 추진되고 있으며, 본 연구에서도 수소인프라 구축의 일환으로 추진되고 있는 수소스테이션 개발 현황에 대하여 논의하고자 한다.

Recently, many researches of the alternative and renewable energy have introduced due to the increasing oil price, the limited natural resources and the environmental pollution. In case of hydrogen energy, it has some merits, which can be substituted the existing the fossil fuel because of no contaminants from the combustion and the chemical reaction. We have been developing 1kW Hydrogen Linear Generator. In this paper, the thermal characteristic of this prototype linear generator has been investigated and obtained reliable analysis results comparing with experimental measurements. Especially, it is predicted that in case of 1kW, 60Hz test sample, the results satisfy with the temperature standards of H type insulation, which is shown average $69.0^{\circ}C$ temperature distribution at the coil.

The effective thermal conductivities of $Mm\;(La_{0.6-0.8})\;Ni_{4.0}Co_{0.6}Mn_{0.2}Al_{0.2}$ (TL-492) with hydrogen and helium have been examined. Experiment results show that pressure has great influence on effective thermal conductivity in Low pressure range (below 0.5 MPa). And that influence decreases rapidly with increase of gas pressure. The reason is at low pressure, the mean free path of gas becomes greater than effective thickness of gas film which is important to the heat transfer mechanism in this research. And, carbon fibers have been used to try to enhance the poor thermal conductivity of TL-492. Three types of carbon fibers and three mass fractions have been examined and compared. Naturally, the highest effective thermal conductivity has been reached with carbon fiber which has highest thermal conductivity, and highest mass fraction. This method has acquired 4.33 times higher thermal conductivity than pure metal hydrides with quite low quantity of additives, only 0.99wt% of carbon fiber. This is a good result comparing to other method which can reach higher effect ive thermal conductivity but needs much higher mass fraction of additives too.

In this study, $20Nm^3/hr$ scale compact hydrogen generator which can be apply to the hydrogen station was tested for hydrogen station application. $20Nm^3/hr$ scale compact hydrogen generator was developed by upgrading concept of stacking plate reactor from former $20Nm^3/hr$ scale plate hydrogen generator. concepts for improving system efficiency and performance include such as idea of heat recovery from the exhaust, exhaust duct which is especially design for plate type reactor reinforcement of insulation, enlargement of heat exchange area of reactor, introduction of desulphurizer reactor and PROX rector in a compact design, introduction of back fire protection structure of plate burner and so on, We can learn that final prototype of scale-up $20Nm^3/hr$ scale compact hydrogen generator can be operated steadily in 100% road at which over 94% of methane conversion(S/C=3.75) was obtained. In case of making up the weak point, we expect that it is possible to apply to hydrogen station by way of showing an example.

본 연구는 페라이트의 Fe 양이온 일부를 Ni, Mn, Co등으로 치환하여 M-ferrites를 제조하여 열화학적 2단계 물 분해 반응의 특성을 비교 평가하였고, XRD, SEM, GC등의 분석으로 각 금속산화물의 특성을 확인하였다. M-ferrites는 고상법으로 제조하였다. 각각의 M-ferrites에 대한 열적환원은 1573K에서 진행하였고 물 분해 반응은 1273K에서 실시하였다. 이 반응에서 생성된 가스는 전량 포집하여 GC를 통해 분석하였다. 반응 전후의 시료에 대하여 SEM, XRD를 분석하여 GC결과와 함께 금속산화물의 산화환원반응 특성을 고찰하였다. 그 결과로서 물 분해 반응 후 M-ferrite (M=Co, Ni, Mn)의 생성을 XRD를 통하여 확인할 수 있었고, 물 분해 반응과의 비교결과 격자상수의 증대가 M-ferrite내의 산소의 환원에 영향을 미치는 것을 알 수 있었다. SEM결과에서는 4cycle의 물 분해 반응 후 Mn-ferrite의 심한 sintering 현상을 확인 할 수 있었다.

현재의 화석연료-기반 사회에서는 지구 온난화와 고유가 추세가 야기하는 경제적 피해, 에너지 안보우려, 세계 평화 위협 등에 자주 노출되고 있는 실정이다. 세계 각국은 이러한 화석연료 에너지원을 대체하는 환경-청정하고 기술-신뢰할 수 있으며 경제-감당할 수 있는 에너지 공급원인 수소를 기반으로 하는 미래의 수소-기반 사회로의 진입에 노력하고 있다. 특히, 청정한 에너지 운반체인 수소의 생산 기술 상업화가 더욱 더 절실히 요구되고 있다. 이 예비 연구에서는 이산화탄소 포획/저장 기술과 결합된 다양한 수소 생산 기술의 정량적인 예비 비교 평가가 수행되었다. 예비적인 비교 평가 기준으로 1) 이산화탄소 배출량: 2) 에너지 이용률; 3) 토지 점유율: 4) 수소 생산비용 등이 고려되었다. 이러한 기준에 따라 수소 생산 기술 가운데 네 가지 예비 기술 대안인 1) 원자력: 2) LNG; 3) 석탄: 4) 태양광 등이 비교되었다. 대안 기술의 비교 평가 체제로 계층 망형 구조-기반 되먹임 모델이 개발되었다. 이러한 수소생산 기술의 우선순위 선정 결과는 개별 대안 기술의 상대적인 장단점 및 기술적인 갭을 정량적으로 인식하는 데에 활용될 수 있다. 그러므로 이 예비 연구는 수소 생산 기술 연구자나 수소 경제 기획자한테 뿐만 아니라 이산화탄소 포획/저장 기술 개발자한테 도움이 되리라 본다.

Cathode material, $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$, for low temperature SOFC was prepared by the glycine-nitrate synthesis process (GNP). The characteristics of the synthesized powders were studied with controlling pH of a precursor. The synthesis BSCF powders with pH were agglomeration state and calcinations temperature has not influence on particles. Highly acidicprecursor solution increased a single phase forming the temperature. Also, synthesis BSCF powder was show result for thermal analysis and alteration of difference crystal with pH. It is considered that Ba and Sr cannot complex by carboxylic acid group of glycine, because under highly acidic condition the caboxylic group mainly combined with $H^+$ insead of alkali and alkaline earth cations. In case of using precursor solution with pH $2{\sim}3$, a single perovskite phase was obtained at $1000^{\circ}C$. Polarization resistance of $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ was measured by AC impedance spectroscopy from the two electrode symmetric cell. Area specific resistance of the $(Ba_{0.5}Sr_{0.5})_{0.99}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ air electrode at $500^{\circ}C\;and\;600^{\circ}C$ were $0.96{\Omega}?cm^2$ and $0.16{\Omega}?cm^2$, respectively.

An experimental study is performed to evaluate the performance and the efficiency by humidifying MEA and by making the double-layered catalyst in a fuel cell system which is taken into account the physical and thermal concept. An electrical output produced by PEMFC(Polymer Exchange Membrane Fuel Cell) is measured to assess the performance of the stack and the efficiency is also evaluated according to the different situation in which is placed with and without the humidification of MEA(Membrane Electrolyte Assembly). Subsequently, It is found that the measured values of MEA voltage and current are influenced by the MEA temperature, humidification, and the double-layered catalyst which gives more enhanced values to apply for electric units.

Formability is requested to successfully develop of a metal bipolar plate for mass production. From this point of view, wider channel and land width is more helpful to improve formability. But the performance of the fuel cell can be affected by its channel and land shape. So it is very important to select proper channel and land shape not to deteriorate the fuel cell performance. In this work, 3-dimensional, non-isothermal numerical simulation was performed to analyse the effects of channel and land width on the fuel cell performance. 3 types of straight channel were selected for the numerical simulation. The simulation results reveal that wide channel and land width lower fuel cell performance and decrease voltage at a high current density region. Water activity, temperature, oxygen concentration distributions were investigated to find the reasons of performance degradation. The results show that wide channel and land width give an bad effect on fuel cell performance because of low cool ins efficiency and lack of oxygen gas under the land.

A long term deactivation study was carried out with commercial MEA provided by Hyundai Motor Co. The deactivation phenomena were observed only at high voltage region where there is no diffusion-limited reaction. A rapid deactivation was observed up to 40h owing to the sintering of Pt particles. This was followed a gradual increase in the activity up to 300 h, which is probably caused by improvement in the electrode properties in the presence of current during the reaction. After 300 h, monotonic decrease in the activity was observed owing to dissolution of Pt particles especially in the cathode. The presence oxygen is the cause of oxidation and dissolution of Pt. The dissolution rate can be somewhat retarded by generation of current, which reduces Pt ion back to Pt in the cathode.

Blower as an air supply system is one of the most important BOP (Balance of Plant) system fur FCV(Fuel Cell Vehicle). For generating and blowing compressed air, the motor of air blower consumes maximum 25% of net power and fuel cell demands a clean air. Considering the efficiency of whole FCV, low friction lubrication of high speed rotor is needed. For the purpose of reducing electrical power and supplying clean air to Fuel cell, oil-free air foil bearings are applied at the each side of brushless motor (BLDC) as journal bearings which diameter is 50mm. The normal power of driving motor has 1.7kW with the 30,000rpm operating range and the flow rate of air has maximum 160 SCFM. The impeller of blower was adopted a mixed type of centrifugal and axial which has several advantages for variable operating condition. The performance of turbo-blower and parameters of air foil bearings was investigated analytically and experimentally. From this study, the performance of the blower was confirmed to be suitable far 80kw PEM FC.

본 연구에서는 독일 율리히 연구소에서 도입된 면적 200mm*200mm의 연료극 지지체 평판형 SOFC 셀 및 금속 분리판 40장을 적층하여 5kW급 SOFC 스택을 제작하고 연속운전을 수행하여 운전특성을 분석했다. 본 연구를 통해 도입된 5kW급 SOFC 스택은 외국에서 시도된 적이 없는 평판형 SOFC스택의 가압운전을 시도해 보는 것으로서, 스택의 임계압력 특성을 확인하고, 이를 바탕으로 가스터빈-연료전지 하이브리드 시스템에서의 SOFC 스택 가압 운전기술을 확보하는 것이다 이러한 목적을 위해 본 연구에서는 상압형 5kW급 SOFC 스택 운전시스템에 대한 구성과 설계, 전반적인 운전 특성평가 (40셀 스택 운전 열 사이클 시험 연료 전환 $(H_2{\rightarrow}pre-reformed\;gas)$, 1200시간 연속운전 등)가 이뤄졌다.

Chloromethylated polysulfone(CMPSf) and a number of mono- and diamine compounds were used to prepare anion-exchange membranes(AEMs) and an ionomer binder solution. The properties of the AEMs were investigated such as $OH^-$ conductivity, water content and dimension stability. Chloromethylation and amination of PSf were optimized in terms of the properties. Membrane-electrode assemblies were fabricated using anion-exchange membranes and the ionomer binder for solid alkaline fuel cells and direct borohydride fuel cells.

To investigate the characteristics of water droplet on the gas diffusion layer from both upper-view and side-view of flow channel, a rig test apparatus was designed and fabricated with L-shape acryl plate in a $1mm{\times}1mm$ micro-channel. This experimental device is used to simulate the single droplet growth and its transport process under fuel cell operating condition. As a first step, we investigated the growth and transport of single water droplet with working temperature and air flow velocity. The contact angle and its hysteresis of water droplet at departing moment are measured and analyzed. It is expected that this study can provide the basic understanding of liquid water droplet behavior in gas flow channel and GDL interface during the PEM fuel cell operation.

A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2$-free hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The propane decomposition rate used carbon black N33O as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600{\sim}800^{\circ}C$, paropane gas velocity of $1.0 U_{mf}\;3.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The carbon which was by-product of methane decomposition reaction was deposited on the catalyst surface that was observed by SEM. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

수소에너지는 화석연료 사용의 증가로 인한 환경오염 및 자원고갈의 문제점을 해결해 줄 수 있는 미래의 청정한 에너지이다. 현재 주 에너지원인 화석연료의 사용에 의하여 배출된 오염물질이 지구온난화와 같은 문제점들을 일으킨다. 이러한 문제점들을 없애줄 수 있는 대안 중 하나가 수소에너지이다. 수소에너지는 자원이 풍부하며 연소시에 오염물질이 배출되지 않는 장점이 있다. 수소에너지는 수소를 연소시켜서 얻는 에너지로써, 수소를 태우면 같은 무게의 가솔린 보다 3배나 많은 에너지를 방출한다. 수소를 생산하는 방법 중 가장 이상적인 방법은 물을 분해하는 방법이다. 그러나 이 방법은 수소를 대량으로 생산하기에는 아직 기술에 대한 확보가 되어있질 않으며, 경제성도 떨어진다는 단점이 있다. 현재 많이 쓰이는 방법 중 탄화수소류의 메탄을 수증기 개질하는 방법이 있다. 메탄 수증기 개질방법은 환경오염물질인 CO나 $CO_2$를 배출한다는 것과 높은 열원이 필요하다 본 연구에서는 C-H결합에너지가 낮아 메탄보다 분해하기 쉬운 부탄의 직접분해로 수소를 생산하고자 한다. 부탄 직접분해는 환경오염물질인 CO나 $CO_2$가 발생되지 않는 장점이 있다. 부탄 분해반응은 $500{\sim}1100^{\circ}C$의 범위에서 이루어 졌으며, 촉매는 탄소계인 카본블랙을 사용하였고, 촉매의 성능을 비교하기 위하여 열분해반응이 동시에 수행되었다.

도시가스, LP 가스, 가솔린 등의 수증기 개질의 반응온도가 $700^{\circ}C$이상의 고온에서 이루어지는 것에 비해 DME 수증기 개질의 반응온도는 $400^{\circ}C$ 이하의 낮은 온도에서 이루진다는 점에서 우수하다. 또한 황 성분을 함유하지 않기 때문에 원료로부터 탈황 과정이 필요 없다. 특히 DME 수증기 개질의 경우 반응온도가 낮은 것과 개질 촉매가 일반적으로는 Cu 계 촉매이기 때문에 도시가스 등의 개질장치와 달리 CO 변성 장치가 불필요하다. 이 때문에 수소제조를 위해 개질장치가 소형화 가능하고 연료전지 자동차로의 탑재가 용이하여 가능성이 높다 개질장치가 소형화 가능한 것으로 메탄올의 수증기 개질이 있지만 메탄올은 독성이 있다는 점이 문제시되고 있다. 그 점에서 메탄올의 수증기 개질 보다 반응 온도는 다소 높게 되지만 독성 없는 DATE는 기존의 LP가스 인프라를 이용할 수 있는 ME는 특히 우수한 수소제조를 위한 원료이고 수소저장체로 사료된다. 본 연구에서는 가능성 높은 촉매를 사용하여 DME로부터 수소 전환율, 수소 생성속도와 양에 대한 실험실적 결과를 고찰하고자 수행하였다

Proper water management is vital to achieve high performance and durability of PEFC (Polymer Electrolyte Fuel Cell). The effects of the residual water from PEFC after purge in shut-down processes on GDL/MEAs were investigated with freeze/thaw cycles Freeze/thaw cycle tests were conducted with single cells which were designed from transparent acryl plates. Single cells which contain several amount of residual water were cycles from $80^{\circ}C$ to $-28^{\circ}C$. The resistance changes of the single cells which have various amount of residual water were evaluated by ac-impedance analysis with 24 times of freeze/thaw cycles. Also, after the freeze/thaw cycles, the property changes were characterized by visual methods such as SEM, EPMA. Though it was difficult to observe noticeable property changes in the visual characterizations, the resistance of cells dramatically increased with the amount of remained water.

Optimal flow-field design of bipolar-plates for a commercial class PEM(polymer electrolyte membrane) fuel cell stack was carried out on the basis of three-dimensional computational fluid dynamics(CFD) simulation. A three-dimensional CFD model originally developed by Shimpalee et al., has been utilized for performing large-scale simulation of a single fuel cell consisting of bipolar-plates gas diffusion layers, and a membrane-electrode-assembly(MEA). The CFD model is able to predict the current density, pressure drops, gas velocities, vapor and liquid water contents, temperature distributions, etc. inside a single fuel cell. Depending on simulation results from the CFD modeling of a PEM fuel cell, several flow-fields of bipolar-plates were designed and verified. The final design of the bipolar-plate has been chosen from the simulations and experimental tests and showed the best performance as expected from the simulation results under a normal operating condition. Thus, the CFD simulation approach to design the optimal flow-field of the bipolar-plates was successful. The final design was adopted as the best flow-field to build a commercial scale PEM fuel cell stack, the performance of which shows about 42% higher than that of the older bipolar-plate design.

The Plate reformer consisting of combustion chamber and reforming chamber for 25 kW MCFC stack has been operated and computational fluid dynamics was applied to estimate reactions and thermal fluid behavior in the reformer. The methane air 2-stage reaction was assumed in the combustion chamber, and three step steam reforming reactions were included in the calculation. Flow uniformity, reaction rate and species distribution, and temperature distribution were analyzed. In particular, temperature distribution was compared with the measurements to show good agreement in the combustion chamber, however, inappropriate agreement in the reformer chamber

This study focuses on a determination of amount of Pt in the Pt/C for catalysts of polymer electrolyte membrane fuel cells (PEMFC). PEMFC offer low weight and high power density and being considered for automotive and stationary power applications. The PEMFC performance is influenced by several factors, including catalysts and structure of electrode and membrane type. Catalyst of electrode is important factor for PEMFC. One of the obstacles prevent ing polymer electrolyte membrane fuel cells from commercialization is the high cost of noble metals to be used as catalyst, such as platinum To effectively use these metals, they have to be will dispersed to small particles on conductive carbon supports. The optimal amount of Pt in Pt/C for cathode catalyst was investigated by using polarization curves in single cell with $H_2/O_2$ operation.

Membrane electrode assembly (MEA) for polymer electrolyte fuel cell (PEFC) are commonly prepared in the research laboratory by spraying, screen-printing and brushing catalyst slurry onto membrane or other support material like carbon paper or polyimide film in a batch style. These hand applications of the catalyst slurry are painstaking process with respect to precision of catalyst loading and reproducibility. It has been generally mentioned that the adoption of continuous process is very helpful to develop the reliable product. In the present work, we report the results of using continuous type coater with doctor-blade to coat catalyst slurry for preparing the MEA catalyst layers In a faster and highly reproducible fashion. We show that while expectedly faster than batch style, the machine coater requires the use of slurry of appropriate composition and a properly selected transfer decal material in order to achieve superior MEA plat lnw loading reproducibility. To make highly viscous catalyst slurry that is imperative for using coater, we use 40wt.% Nafion solution and minimize the content of organic solvent. And the choice of proper high surface area catalyst is important in the viewpoint of making well-dispersed slurry. After catalyst coating onto the support material, we transferred the catalyst layer to both sides of Nafion membrane by hot-pressing In this case, the degree of transfer was Influenced by hot-pressing condition including temperature, pressure, and time. To compare the transferring ability, we compared so many films and detaching papers. And among the support, polyethylene terephthalate(PET) film shows the prominent result.

In this paper an integrated model of PV-AF (Photovoltaic-Active Filter) and PV-SPE(Photovoltaic Solid Polymer Electrolyte) system using PSCAD/EMTDC were explained in detaiil. The main concept of PV-AF system starts from the 'harmonics'. In order to deliver power to utility, PV system essentially needs a converter system. Here PV-AF system adds the function of active filter to the converter system installed in PV system, which was introduced already in several papers. PV-SPE system has been studied as a replacement of existing hydrogen production technology that emits large amount of carbon dioxide into atmosphere. Until now, these two systems, PV-AF and PV-SPE, have been considered separately However, in this paper, characteristics and advantages of combined system are discussed in detail.

In the newly developed control method, the current flowing into SPE cell is the only one considerable factor. So, the structure of control circuit becomes simple and the manufacturing cost of the control device decreases. In conventional power comparison MPPT control method however, a voltage and current coming out from PV cell should be feedbacked to chase maximum power point at every moment. Then, the structure of control circuit becomes so complex and the risk of control failure is much higher than the novel MPPT control method. Therefore, PV generation system by a novel MPPT control method is especially operated much more safely in case of a huge system, because the voltage coming out from PV-cell is not needed to be feedbacked. In this paper, the PV-SPR system was actually manufactured based on the simulation model of PSCAD/EMTDC program and the results tested were shown. Authors are sure that it is the most useful method to maximize power from PV to SPE with only a feedback of SPE input current.

This paper presents the isolation and performance evaluation of PV systems installed at Tibet area of China in order to identity the key factors that determines system operation at a severe climate conditions and promote the cooperation of PV technology between Korea and China. The installed systems consist of 100kW on-grid connected PV systems, BOS(balance of systems), data acquisition and transmission equipments. The Korea side supplied the solar cell, BOS like as inverter, control box and monitoring system. And the Chinese side assembled solar module by using Koreans solar cells, constructed site and built control house.

Solar Photovoltaics (SPV) In India has become an important renewable source of energy particularly for rural and remote areas. The vastness of the country and the requirements of electricity in far-flung villages makes SPV very attractive, with inherent technological advantages providing additional boost. This has been recognized very early by Govt. Of India and Ministry of Non-Conventional Sources of Energy (MNES) has been entrusted with promoting SPV usage in the country. Rural electrification through SPV systems is one of the programmes which is expected to provide fillip to PV industry in the country. PV Industry in India is very well established with capability of solar cell fabrication and module fabrication as well as Balance of System design and fabrication. There several R&D groups in the academic institutions who are involved in improving solar cells efficiency, thin film solar cells and PV instrumentation. Thus, India provides a ready market for large scale utilization of solar energy through SPV technology.

The equipment of PV system is composed of PV Modules, inverters, DC combiner boxes, transformer protective equipment etc,. And, These equipment be combined Power transformation, Monitoring, Protect ive function The primary concern in designing any PV system is the determination of its optimum size and combination.

The application of photovoltaics into building as integrated building components has been paid more attention worldwide. Photovoltaics or solar electric modules are solid state devices, directly converting solar radiation into electricity; the process does not require fuel and any moving parts, and produce no pollutants. And the prefab building method is very effective because the pre-manufactured building components is simply assembled to making up buildings in the construction fields especially the sandwich panel. So, the purpose of this research is to integrated prefab building materials depending on the cooling type of PV modules. It is concluded that the prediction of BIPV system's performance should be based on the more accurate PV module temperature. From the basis of these results on the correlation of temperature and irradiation were obtained.

태양광발전기술의 국내 보급 및 세계 시장 진출에 있어서 표준화는 매우 중요한 요소이다 국제 표준화에 대응하여 국제 표준화 동향을 국내에 신속히 적용하고 국내 기술을 국제 규격에 제안하는 것이 그 핵심 내용이라고 할 수 있다. 국제 표준화는 IEC TC 82에서 담당하고 있으며 용어, 태양전지 모듈 시스템 주변기기 등 분야별로 WG에서 구체적인 논의를 진행하고 있다 현재까지 국내의 국제 표준화 대응은 미미하다고 할 수 있으나, 2004년도부터 정부에서 태양광을 포함한 신재생에너지 3대 중점분야 국제 표준화 5개년 계획을 수립하여 현재 추진하고 있다. 태양광 분야의 경우도 태양광 표준화 사업을 통해 태양광 표준화 전문가 회의를 구성하고 참가 전문가들이 IEC TC 82 총회 및 분야별 WG에 참석하고 있다 이후 계속적인 활동을 통해 국제표준화 동향을 국내 규격에 적응하고 규격 개정 작업에서부터 IEC TC 82 WG에서의 주도적인 활동이 전개되어야 한다

The protocrystalline silicon (pc-Si:H) multilayer solar cell is very promising owing to its fast stabilization with low degradation against light irradiation. However, the pc-Si:H multi layers have not extensively been investigated in detail on its material characteristics yet. We present the material characteristics of pc-Si:H multilayer using a transmission electron microscopy(TEM), and Raman spectroscopy. In addition, we present the superior light-soaking behavior of the pc-Si:H mutt i layer solar cell. A TEM micrograph shows that a pc-Si:H multilayer has a repeatedly layered structure and crystalline-like objects in a-Si:H matrix. A Raman spectra introduces improved short-range-order and medium-range-order in pc-Si:H multilayer. As a result the excellent metastability of the pc-Si:H multilayer solar cell is primarily due to the repeatedly layered structure that improves a structural order in absorber layer.

Cu계 $I-III-VI_2$화합물은 직접천이형 반도체로 광흡수계수가 매우 높아 박막형 태양전지 제조에 매우 유리하다. 또한 화학적으로 안정하며 Ga, Al 등을 첨가하면 에너지 금지대폭을 조절할 수 있어 Wide Bandgap 태양전지 및 탠덤구조 태양전지를 제조하기에도 용이하다 $CulnSe_2(CIS)$ 물질에서 In을 20-30% 정도 치환한 $Cu(In,Ga)Se_2(CIGS)$ 태양전지의 경우 19.5%의 세계 최고 효율을 보고하고 있으며 이는 다결정 실리콘 태양전지의 효율과 비슷한 수준이다. 본 연구에서는 동시 진공증발법을 이용하여 증착한 CIGS 박막을 이용하여 태양전지를 제조하였다. 공정의 재현성 및 결정립계가 큰 광흡수층 제조를 위하여 실시간 기판온도 모니터링 시스템을 도입하였으며 버퍼충으로는 용액성장한 CdS 박막을 사용하였다. SLG/MO/CIGS(CGS)/CdS/ZnO/Al 구조의 태양전지를 제조하여 면적 $0.5cm^2$에서 각각 17.5%의 효율을 얻었다.

The new approach to buffer layer design for CIGS solar cells that permitted to reduce the buffer absorption losses in the short wavelength range and to overcome the disadvantages inherent to Cd-free CIGS solar cells was proposed. A chemical bath deposition method has been used to produce a high duality buffer layer that comprises thin film of CdS and Zn-based film. The double layer was grown on either ITO or CIGS substrates and its morphological, structural and optical properties were characterized. The Zn-based film was described as the ternary compound $ZnS_x(OH)_y$. The composition of the $ZnS_x(OH)_y$ layer was not uniform throughout its thickness. $ZnS_x(OH)_y$/CdS/substrate region was a highly intermixed region with gradually changing composition. The short wavelength cut-off of double layer was shifted to shorter wavelength (400nm) compared to that (520 nm) for the standard CdS by optimization of the double buffer design. The results show the way to improve the light energy collection efficiency of the nearly cadmium-free CIGS-based solar cells.

The counter electrode widely used in DSCs (Dye-sensitized Solar Cells) is constructed of conducting glass substrates coated with Pt films, where the platium acts as a catalyst. Pt counter electrodes in DSCs are one important component. It is expected that characteristics of Pt electrodes strongly depend on fabrication process and its surface condition. In this study, Pt counter electrode surface of DSC is deposited by reactive RF magnetron sputtering under the conditions of Ar 5mtorr, RF power of 120w and substrate temperature of $100^{\circ}C$. Surface morphology of Pt electrodes was investigated by FE-SEM and AFM. And this paper shows our recent results and technology to fabricate the new designed cell with Pt electrodes deposited by sputtering method. We have achieved fill factor 65% and photoelectric conversion efficiency around 2.6% as the best results of new designed DSCs structure.

Superstrate pin amorphous silicon thin-film (a-Si:H) solar cells are prepared on $SnO_2:F$ and ZnO:Al transparent conducting oxides (TCO) In order to see the effect of TCO/P-layers on a-Si:H solar cell operation. The solar cells prepared on textured ZnO:Al have higher open circuit voltage $V_{oc}$ than cells prepared on $SnO_2:F$. Presence of thin microcrystalline p-type silicon layer $({\mu}c-Si:H)$ between ZnO:Al and p a-SiC:H plays a major role by causing improvement in fill factor as well as $V_{oc}$, of a-Si:H solar cells prepared on ZnO:Al TCO. Without any treatment of pi interface, we could obtain high $V_{oc}$, of 994mv while keeping fill factor (72.7%) and short circuit current density $J_{sc}$ at the same level as for the cells on $SnO_2:F$ TCO. This high $V_{oc}$ value can be attributed to modification in the current transport in this region due to creation of a potential barrier.

AZO (ZnO:Al) were fabricated by RF magnetron sputtering In $H_2/Ar(5%\;H_2)$ atmosphere, and structural, electrical and optical properties were investigated. The substrate temperatures were varied at RT, $100^{\circ}C,\;150^{\circ}C$ and$200^{\circ}C$. The resistivity of the films grown in $H_2/Ar(5%\;H_2)$ were reduced from $7.67{\times}10^{-4}{\Omega}\;cm$ to $5.95{\times}10^{-4}{\Omega}\;cm$ comparing that Ar (100%) and the transmittance of the ZnO:Al films in the visible range was 85%.

We fabricated hexagonal copper sulfide $Cu_2S$ nanowires to obtain a larger contact area of $Cu_2S/CdS$ solar cell. Copper sulfide nanowires were grown on Cu foil at room temperature by gas-sol id reaction. The size, density and shape of nanowires seemed to be affected by the change or reaction time temperature, crystallographic orientation of Cu foil, and molar ratio of the mixed gas. We controled the length and the diameter of the nanowires and we obtained suitable nanowire arrays which has fitting size for uniform deposition with n-type CdS. CdS layer was deposited on the nanowire array by electrodeposition and it seemed to be uniform. The $Cu_2S/CdS$ nanowires/CdS junction showed diode characteristics, A large contact area is expected with the $Cu_2S/CdS$ nanowire structure as compared with the $Cu_2S/CdS$ thin film.

[ $CuInS_2$ ] filims were appeared from 0.84 to 1.27 of Cu/In composition ratio and sulfur composition ratios of $CuInS_2$ thin films fabricated, Also when Cu/In composition ratio was 1.03, $CuInS_2$ thin film with chalcopyrite structure had the highest XRD peak (112). And lattice constant (a) of and grain size of the film tin s ambient were appeared a little larger than those in only Vacuum The films in S ambient were p-type with resistive of around $10^{-1}{\Omega}cm$ and optical energy band gaps of the films in S ambient were appeared a little larger than those in only Vacuum. Analysis of the optical energy band gap of $CuInS_2$ thin films a value of 1.53eV.

Solid-state dye-sensitized solar cells were fabricated using a polymer matrix in electrolyte in the purpose of the improvement of the durability in the dye-sensitized solar cell. In these dye-sensitized solar cells, the polymer electrolyte consisting of $I_2$, LiI, ionic liquid, ethylene carbonate/propylene carbonate and polymer matrix was casted onto $TiO_2$ electrode impregnated Ruthenium complex dye as a photosensitizer. Photovoltaic properties of solid-state dye-sensitized solar cells using polymer matrix (PMMA, PEG, or PAN) were investigated. Comparing photovoltaic effects of cells using hole conducting polymers (BE or 6P) instead of polymer matrix, we investigated the availability of the solid-state polymer electrolyte in dye-sensitized solar cells.

The effect of electron beam irradiation on dye sensitized solar cell (DSSC) has been studied to examine degradation of DSSC. The high-energy electron beam irradiation affects on the materials and performance of dye sensitized solar cells. We have checked the effects of electron beam irradiation of $TiO_2$ substrate with and without dye adsorption on the photovoltaic performances of resulting DSSCS and also studied the structural and electrical properties of polymers after irradiation. All solar cells materials were irradiated by electron beams with an energy source of 2MeV at different dose rates of 60 kGy, 120 kGy 240 kGy and 900 kGy and then their photoelectrical parameters were measured at 1 sun $(100 mW/cm^2)$. It was shown that the efficiency of DSSC was decreased as increasing the dose of e-beam irradiation due to lowering in $TiO_2$ crystallinity, decomposition of dye and oxidation of FTO glasses. On the other hand, the performance of solid-state DSSC with polyethylene oxide based electrolyte was improved after irradiation of e-beam due to enhancement of its conductivity and breakage of crosslinking.

Reduction of optical losses in crystalline silicon solar cells by surface modification is one of the most important issues of silicon photovoltaics. Porous Si layers on the front surface of textured Si substrates have been investigated with the aim of improving the optical losses of the solar cells, because an anti-reflection coating and a surface passivation can be obtained simultaneously in one process. We have demonstrated the feasibility of a very efficient porous Si AR layer, prepared by a simple, cost effective, electrochemical etching method. Silicon p-type CZ (100) oriented wafers were textured by anisotropic etching in sodium carbonate solution. Then, the porous Si layer were formed by electrochemical etching in HF solutions. After that, the properties of porous Si in terms of morphology, structure and reflectance are summarized. The surface morphology of porous Si layers were investigated using SEM. The formation of a porous Si layer about $0.1{\mu}m$ thick on the textured silicon wafer result in an effective reflectance coefficient $R_{eff}$ lower than 5% in the wavelength region from 400 to 1000nm. Such a surface modification allows improving the Si solar cell characteristics.

Sputter deposition followed by surface treatment was studied using reactive RF plasma as a method for preparing titanium oxide $(TiO_2)$ films on the FTO $(SnO_2: F)$ substrate for dye-sensitized solar cells (DSCs). Anatase structure $TiO_2$ films deposited by reactive RF magnetron sputtering under the conditions of $Ar/O_2(5%)$ mixtures, RF power of 600W and substrate temperature of $400^{\circ}C$ were surface-treated by inductive coupled plasma (ICP) with $Ar/O_2$ mixtures at substrate temperature of $400^{\circ}C$, and thus the films were applied to the DSCs. We have chosen a solar cell width as a variable of a large-scaled DSCs and confirmed electric characteristics of an individual cell. As a result, the higher the internal resistance of DSC becomes, the wider the width gets. Internal resistance makes it difficult to collect photoelectron generated from dye. Ultimately up sizing DSC causes the increase of internal resistance and then has a bad effect on the cell characteristics.

To elucidate possible challenges for outdoor practical use of dye-sensitized solar cells(DSC), compared with conventional Si solar cells. DSC modules still need the larger area than conventional Si solar modules to attain the same rated output because of lower photoelectron-chemical conversion efficiency. However, using batteries backup systems, the measured data shows that DSCs gathered over 12% more electricity than Si solar cells of the same rated output power in same outdoor condition. Moreover, battery charging time of DSC is about 1 hour faster than same rate of Si solar module. In this paper, 12 single DSC cells prepared for 4 serialized DSC cells was connected in 3 row parallel which have same output power rate of Si solar module. This DSC module was practiced generating characteristic experiment over outdoor daylight condition and applied with PV battery charger by using DC-DC converter. The main advantages of DSC module battery charger as compared with conventional Si solar module one are shorter charge time and lower cost.

The technology of Solar Power conversion System is defined as a solar cell that changes the sol ar energy into the direct electric energy, power conversion and control technology that convert the dc power into ac power The solar cell module, power conversion, and a control part in component parts consisting a solar power conversion system have influence on its performance. The roles of power conversion and a control part supply the direct current generated by solar cell module for a load with high efficiency as conveniently as possible in this study, the power conversion systen that can generate solar power using DSC module was developed and its characteristics was experimented. The characteristics of the DSC power conversion system including MOSFET and DSP micro processor, high speed devices, was simulated using Psim. According to the results, converter and inverter was manufactured in detail and the performance characteristics were studied.

A lot of researches and experiments have been performed to make more efficient dye-sensitized solar cell. Among them, insertion of a grid electrode in DSC is one method to increase overall performance as being shortened distance of electrons' movement by diffusion. In this paper, we measured overall characteristics which is included voltage-current characteristic curve, efficiency, fill factor by comparison between DSC without and with grid electrode. As a result, we got maximum 1.8 times increase of efficiency and approximately 1.7 times rise of fill factor. And we experimented 8, 10, 12, 14mm of grid gap and compared their results to optimize grid gap which is able to incite the most effective movement of electrons. Consequently, we got the result that electrons' movement is the most effect ive when grid gap is approximately 12mm.

In the PV power system, output of the PV array must contain inherent ripples due to the single-phase inverter. So the function of maximum power point tracking to increase the output efficiency of PV system is degraded. Therefore, to overcome this problem, this paper presents a control strategy for the reducing ripples of the PV array output in grid-connected photovoltaic power system. The proposed control system consists of two loops the maximum power point tracking loop using the perturbation and observation method is used to calculate the reference solar array terminal voltage(Vref) for reducing ripples of the PV array output and the PI control loop is used to regulate the solar array output voltage according to the Vref. The performance of proposing control strategy is analyzed by means of the PSCAD/EMTDC simulation. As a result, we may obtain the high performance of the proposed control strategy.

In this paper, I try to measure the electrical characteristics of PV cell for lanterns with solar simulator and simulated with PC1D software. I keep my eye on the characteristics variation of PV cell as a temperature change. Therefore, I try to increase a temperature of controlled block from $10^{\circ}C$ to $50^[\circ}C$ while measuring the FV cell. As a result, A variation caused by voltage have an effect on the efficacy of PV cell. Hence it is an important variable when a designer plan to make a solar cell for lanterns.

나노입자를 이용하여 치밀한 $Cu(In,\;Ga)Se_2$ 태양전지용 광흡수층을 제조하기 위해 먼저, 콜로이달 방법으로 합성된 20nm이하의 CIGS 나노입자를 저가의 스프레이 법을 이용하여 CIGS 막을 제조하였다. 제조된 CIGS막을 two-zone RTP (rapid temperature Process) 방법으로 Se 분위기 안에서 열처리를 행하였다. 입자의 치밀화를 위해 기판의 온도, Se 증발온도와 수송가스의 유량을 조절하여 CIGS 입자성장을 행하였다. 그러나, Se의 증발온도가 높을수록 CIGS와 MO 박막 사이에서 $MoSe_2$ 층이 형성되었다. 형성된 $MoSe_2$층의 부피 팽창으로 인해 하부의 유리기판과 Mo층 사이에서 peeling off 현상이 발생했다. 이러한 Peeling off현상을 억제하면서 CIGS 나노입자 성장을 하기 위해, Se 공급을 빨리 할 수 있도록 Se의 증기압을 높였으며, 최적조건에서 급속 열처리 공정을 통해 CIGS 나노입자 성장과 치밀화를 위한 소결거동을 관찰하였다.

p-type 비정질 실리콘 에미터와 n-type 실리콘 기판의 계면에 intrinsic 비정질 실리콘을 증착함으로써 계면의 재결합을 억제하여 20%가 넘는 효율을 보이는 이종접합 태양전지가 Sanyo에 의해 처음 제시된 후 intrinsic layer에 대한 연구가 많이 진행되어 왔다. 하지만 p-type wafer의 경우는 n-type에 비해 intrinsic buffer의 효과가 미미하거나 오히려 특성을 저하시킨다는 보고가 있으며 그 이유로는 minority carrier에 대한 barrier가 상대적으로 낮다는 것과 partial epitaxy가 발생하기 때문으로 알려져 있다. 본 연구에서는 partial epitaxy를 억제하기 위한 방법으로 증착 온도를 낮추고 QSSPC를 사용하여 minority carrier lifetime을 측정함으로써 각 온도에 따른 passivation 특성을 평가하였다. 또한 SiH4에 H2를 섞어서 증착하였을 경우 각 dilution ratio(H2 flow/SiH4 flow)에서의 passivation 특성 또한 평가하였다. 기판 온도 $100^{\circ}C$에서 증착된 샘플의 lifetime이 가장 길었으며 그 이하와 이상에서는 lifetime이 감소하는 경향을 보였다 낮은 온도에서는 박막 자체의 결함이 증가하였기 때문이며 높은 온도에서는 partial epitaxy의 영향으로 추정된다. H2 dilution을 하여 증착한 샘플의 경우 SiH4만 가지고 증착한 샘플보다 훨씬 높은 lifetime을 가졌다 이 또한 박막 FT-IR결과로부터 H2 dilution을 한 경우 compact한 박막이 형성되는 것을 확인할 수 있었는데 radical mobility 증가에 의한 박막 특성 향상이 원인으로 생각된다.

The photovoltaic properties of CIES cells on alumina substrate were improved by using the Na-doped Mo as theabotom layer of hilo back contact. Na was supplied to the CIGS bulk region from alumina/Na-doped Mo/Mo/alumina? structure, as same assimilar to the Na diffusion from soda-lime glass. The content diffusion of Na from Na-doped bfo was smaller more controlled than that from SLG. These Our results indicate that Na-doped bfo act as Na source material and contents of Na amount can be controlled without the use of an alkali barrier layer. The best CIGS solar cell with conversion efficiency of 13.34%, $J_{sc}=34.62mA/cm^2,\;V_{oc}=0.58V$ and FF=66% for an active area of $0.45cm^2$ on the alumina substrate was obtained in the condition of for 100nm Na-doped Mo/1000nm Mo.

A non-vacuum process for $Cu(In,Ga)Se_2$ (CIGS) thin film solar cells from nanoparticle precursors was described in this work CIGS nanoparticle precursors was prepared by a low temperature colloidal route by reacting the starting materials $(CuI,\;InI_3,\;GaI_3\;and\;Na_2Se)$ in organic solvents, by which fine CIGS nanoparticles of about 20nm in diameter were obtained. The nanoparticle precursors were mixed with organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of CIGS with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents ud to burn the organic binder material. Subsequently, the resultant (porous) CIGS/Mo/glass simple was selenized in a two-zone Rapid Thermal Process (RTP) furnace in order to get a solar ceil applicable dense CIGS absorber layer. Complete solar cell structure was obtained by depositing. The other layers including CdS buffer layer, ZnO window layer and Al electrodes by conventional methods. The resultant solar cell showed a conversion efficiency of 0.5%.

The demand for developing the compact and cost effective commercial version of the photovoltaic power conditioning system(PCS) is now increasing and several commercial products are on the markets. In this paper, several design results of 10kW rated grid-tied photovoltaic PCS system are introduced, and several test results for the system evaluation are also described. The test results verified the validity of the proposed photovoltaic PCS system.

This paper briefly introduces silicon based thin film solar cells: amorphous (a-Si:H), microcrystalline ${\mu}c-Si:H$ single junction and $a-Si:H/{\mu}c-Si:H$ tandem solar cells. The major difference of a-Si:H and ${\mu}c-Si:H$ cells comes from electro-optical properties of intrinsic Si-films (active layer) that absorb incident photon and generate electron-hole pairs. The a-Si:H film has energy band-gap (Eg) of 1.7-1.8eV and solar cells incorporating this wide Eg a-Si:H material as active layer commonly give high voltage and low current, when illuminated, compared to ${\mu}c-Si:H$ solar cells that employ low Eg (1.1eV) material. This Eg difference of two materials make possible tandem configuration in order to effectively use incident photon energy. The $a-Si:H/{\mu}c-Si:H$ tandem solar cells, therefore, have a great potential for low cost photovoltaic device by its various advantages such as low material cost by thin-film structure on low cost substrate instead of expensive c-Si wafer and high conversion efficiency by tandem structure. In this paper, the structure, process and operation properties of Si-based thin-film solar cells are discussed.

In this paper, I try to measure characteristic transmission-reflection by environmental change or solar cell. I keep my eye on the characteristics variation of solar cell as environmental change. As a result, A variation caused by voltage by an effect on the efficiency of solar PV cell. Hence, it is an important variable when a designer plan to make a solar cell.

Recently wind turbines become large, constructed as farms and going out to offshore. Different design approach from onshore is needed for offshore wind turbine. At this paper concept and preliminary design of an offshore wind turbine of 3MW rated power are performed. The concept design started from modelling of the generator and gearbox. With these modelling the optimum specifications was acquired. Integrated type of drive train is designed with all parts are mounted on the tower top as the offshore maintenance strategy. At the preliminary stage control system, power production algorithm and safety system are designed. Load calculation is also performed. The 3MW offshore wind turbine concept/preliminary design and the process of design are obtained as results.

The first of korean 750kW gearless type wind turbine is developed. The wind turbine is designed, manufactured and tested by GE regulation and obtained the design certificate by GL. And the performance test is being performed at the demonstration site now. This paper presents the history of development and performance test for 750kW gearless type wind turbine.

Wind turbine gearbox is a complex mechanical system that includes gear trains, shafts, bearings, and gearbox housings. All these component are interacting with each other therefore changing certain design parameter will affect other components. RomaxDesigner enables a reduction in development period by simulating the full gearbox system. The gear pairs, bearings and shafts are represented as analysis objects and the complex components are modelled by means of reduced stiffness matrices. The software allows durability analysis and advanced contact analysis including the effects of system misalignments in gear and bearing. In this paper the 2MW wind turbine gearbox was model led and a study on optimum design was conducted

This paper shows operating characteristics of DFIG(Double Fed Induction Generator) for wind turbine. The back to back PWM voltage-fed inverter connected between the rotor and grid network operated sub and super-synchronous operating mode, and the vector-controlled DFIG enables the decoupling between active and reactive power as well as between torque and power factor. This paper is validated by simulations and experimental results.

This paper presents electromagnetic finite element analysis of power cables for wind turbine application. Eddy current losses are calculated due to high currents along metallic part, and dielectric strength on power cables is investigated for case study, which suggests the optimal cabling configuration for wind turbine construction.

In this paper, doubly-fed induction-type wind power generation system simulation model for grid connection is developed. The simulation model is based on PSCAD/EMTDC and consists of rotor-blade, blade controller, generator power converter and generator controller Blade controller controls the blade pitch angle for starting, peak power limiting and emergency condition. Generator controller controls the generator output power to maximize the system efficiency. Simulation results are shown for the variable wind speed conditions. The simulation model can be utilized for study of actual interaction between wind turbine and grid for reliable operation and protection of power system.

인버터의 개발에 앞서 살펴야 할 것 중 하나로 부하의 종류이다 여기에서는 유체부하를 가지는 경우이다 경제적인 측면과 성능을 고려하여 마이크로컨트롤러(PIC18F4431)를 결정하였다. 또한 여기에서는 전반적인 인버터의 제어를 다루기보다는 유체부하에서 발생하기 쉬운 과부하상태시의 간단한 제어방안을 다루었다 유도기제어에 있어서 유체부하를 가지는 경우 갑작스러운 유체부하의 증가가 발생할 수 있다. 유도기에서 이와 같은 과부하가 발생할 경우 전압과 전류의 위상차는 줄어들게 되고 전류는 증가하게 되며 유도기의 실제 속도와 인버터의 지령치는 벌어지게 된다. 지속적으로 위상차를 감시하여 과부하 상태를 판별할 수 있으며 과부하 상태 시 속도를 변화시켜 실제 속도를 정상상태와 비슷하게 유지시켜준다.

Numerical analysis of wind turbine scale effect was performed by using computational fluid dynamics. For the numerical analysis of wind turbine. Three dimensional Navier-Stokes solver with various turbulence models was tested and realizable k-e turbulence model was selected for the simulation of wind turbines. To validate the present method, performance of NREL (National Renewable Energy Laboratory) Phase VI wind turbine model was analyzed and compared with experiment and blind test data. Using the present method, numerical simulations for various size of wind tunnel model were carried out and characteristics were observed in detail. The power loss due to the interference between wind turbine and nacelle was also computed for relatively larger nacelle installation in wind tunnel test. The present results showed good correlations with experimental data and reasonable trends of scale effect of wind turbine.

To generate electricity from wind energy, wind turbine generally has a rotor blade. Since this rotor blade is a kind of the rotating machinery, the wake from the rotor is very Important role in the side of the aerodynamic performances. Thus the study about wake is essential to analyze wind turbine aerodynamics. In this study wake characteristics are analyzed by hot-wire probe in the K.A.F.A(Korea Air Force Academy) wind tunnel. It is possible to analyze the wake characteristics by hot-wire probe from acquiring the velocity fluctuations at given positions in the flow. This velocity data are arranged by trigger signal at same azimuth of the blade in periodic manner of the rotor blade. From this various wake characteristics are found : radial and axial position of the tip vortex, vortex core characteristics in the flow etc.

Using yaw system, Wind turbine can face the wind to make it's electricity generating maximum and to make it's fatigue load minimum. So, in wind turbine design process, selecting optimum yaw system is very important work. In this paper, the yaw moments on yaw bearing, yaw drive and yaw brake were calculated. and From the result, the duty cycle was obtained. At last, using this duty cycle, optimum yaw system is selected.

본 연구의 목적은 차세대 대체에너지로 각광받는 풍력발전 중에서 육상발전보다 여러 가지 이점이 있는 한국형 해상풍력터빈 블레이드의 최적형상설계를 위한 알고리즘을 구현하는 것이다. 블레이드 단면 익형의 양력과 항력 분포는 XFOIL을 이용하여 예측하였다. 첫 번째 수준의 설계변수인 각각의 블레이드 지름과 축 회전수에서 익형의 공력변수들과 최소에너지손실 조건을 이용하여 두 번째 설계변수인 각 블레이드 단면에서의 시위길이와 피치각 분포를 최적화하였다. 그리고 성능결과를 바탕으로 반응면을 구성하고, 확률적 방법을 이용하여 타당성 있는 설계공간까지 첫 번째 설계변수를 이동시키고 구배최적화 기법을 통해 각각의 제약함수를 만족하면서 목적함수를 죄대로 하는 최적블레이드 형상을 구현하였다. 설계된 최적형상에 대해 탈설계점 해석을 수행하여 성능을 구하였다.

The IEA Wind agreement for co-operation in the R&D of wind energy system was founded in 1974. The Korea has been a contracting party to the IEA wind energy program since 2003. The contracting parties are designated by the 20 member countries and the EC. IEA Wind agreement is for member countries to exchange information, knowledge and to organize international collaboration on R&D projects called Taskes and Annexes. The Executive Committee approves and controls the R&D Tasks, and its meetings are held twice a year. This paper describes the status of current 7 implementing Tasks that were reported to the recent 57th Executive Committee meeting this year in Brussels, Belgium.

2005년 말 현재, 국내의 상업운전 중인 풍력발전기는 93.5MW(KPX 2005)에 불과하여 민간의 풍력에너지 개발 참여를 위한 사업타당성 조사에서 상업운전에 이르는 풍력발전단지 개발절차에 대한 사례 연구가 미비하다. 최근 신재생에너지 보급을 위한 정부의 강력한 의지와 맞물려 민간의 대규모 풍력발전단지 개발 계획이 속속 진행되고 있는 여건에서, 국내 최초의 대단위 상업용 풍력발전단지인 영덕풍력발전의 개발 및 운영사례를 통해 국내 풍력발전단지 개발 시 고려사항과 발생 가능한 문제점 및 해결방안을 제시한다.

In order to support wind power development, the wind resource database of Jejudo has been established by meteo-statistical analysis on meteorological-mast measurements of KIER. Analysis processes contain correlation of monthly wind speed and power-law exponent among neighboring sites, Measure-Correlated-Predict for long-term correlation, classification of exposure category using satellite image and so forth. It is found that the monthly variations of wind speed and power-law exponent depend on seasonal winds and characterize wind system of Jejudo.

CDM(Clean Development Mechanism) is one of three Kyoto mechanisms. As a non-annex I party of UNFCCC, Korea can host CDM projects. Currently eight CDM projects are hosted in Korea under Kyoto protocol. Six of these CDM projects are related to renewable energy power generation. Renewable energy power plants assumes zero GHGs emission and has great potential to become CDM projects which is very environmental friendly energy Gangwon wind park CDM project is the first renewable CDM project in Korea. In this research, emission factors and additionality proving process are studied, which are important procedures of doing CDM project.

Recently, as the global warming by fossil fuels and the steep rise of the oil price become social issues, the interest for renewable energy producing system is increasing rapidly. Among these, the wind turbine is most highlighted because of its economic competitiveness. The tower is one of the main components of wind turbine, which occupying about 20% of overall turbine costs. The tower access door located to base part of the tower, is used to enter the tower. This is the main structural weak points because of door hole, weldment, etc. And so are the weldments between the cans and the flanges. In this study, for the top flange part of the tower, by FEM using ANSYS, we retrieved the maximum von Mises stress on that and carried out fatigue analysis using stresses at such weak points.

A vibration monitoring is performed on a 1kW class stand alone wind turbine(W/T). When a W/T model is developed, general performance under various wind condition should be verified to introduce the product in the market. Especially, vibration characteristics within operating speed range are very important in the aspect of structural stability as well as generator's electrical efficiency. This paper examines the vibration performance of a home made 1kW W/T Various data of the W/T model are acquired in real time using a remote vibration monitoring system installed in Daekwanryung test site. Vibration stability of the W/T structure is diagnosed based upon the data and the result is used to estimate the applicability of the W/T model.

포항공과대학교의 포항풍력에너지연구소(PoWER Center)가 개발에 참여했던 750kW급 직접구동형 국산화 풍력발전시스템(KBP-750D)은 그 개발이 완료되어 2005년 말경 대관령의 풍력실증단지에 설치되었고 현재는 시험운전이 수행되고 있다. KBP-750D의 상용화를 위하여 출력성능 및 하중측정을 통한 실증연구가 진행되고 있으며, 현재는 KBP-750D에 대한 출력성능 및 하중 측정을 수행하기 위하여 계측장치가 설치되어 시험 측정이 진행되고 있다. 본 발표에서는 풍력발전시스템에 설치된 계측장치의 구성 및 설치 결과를 상세히 보고한다.

포항풍력에너지연구소에서는 에너지 관리공단의 지원으로 2004년부터 풍력터빈 KBP-2000M에 사용될 발전기를 개발해 오고 있다. KBP-2000M에 사용되는 발전기는 기어비가 24인 기어박스를 가진 가변속도형식의 발전기이다. 발전기의 직경은 1.87m 이고 축 방향의 길이는 1.288m 로 영구자석을 사용하여 여자하는 형식으로 설계되었다. 이러한 설계는 풍력발전기에서 요구하는 주요 요구조건인 고효율, 고 신뢰성을 만족시키기 위해서 매우 중요하다 이 보고에서는 발전기의 물리설계에서 얻어진 사양을 기준으로 하여 열 해석에서 얻어진 열 손실을 이용하여 냉각시스템 설계를 하였으며 펌프 및 라디에이터 선정에 관해서 논의한다.

Under the national project for the development of 2MW wind energy convert system, we are under development of the prototype of 2MW wind turbine with low speed gearbox. This system adopts low speed gear box with planetary and spur gear and is pitch regulated variable speed type with the synchronous permanent magnet generator. The compromised size of generator in diameter and width are adopted to meet the structural design requirements. In this paper, the concept study for the type, the aerodynamic design for the blade and the details of load calculation will be presented. The detailed characteristics of the system will also be introduced.

In the present paper a forecasting system of wind power generation for Walryong Site, Jejudo is presented, which has been developed and evaluated as a first step toward establishing Korea Forecasting Model of Wind Power Generation. The forecasting model, KIER forecaster is constructed based on statistical models and is trained with wind speed data observed at Gosan Weather Station nearby Walryong Si to. Due to short period of measurements at Walryong Site for training statistical model, Gosan wind data were substituted and transplanted to Walryong Site by using Measure-Correlate-Predict technique. Three-hour advanced forecast ins shows good agreement with the measurement at Walryong site with the correlation factor 0.88 and MAE(mean absolute error) 15% under.

현행 농어촌전화촉진법에 의한 10호이상 도서전화사업이 2006년 말까지 완료될 예정임에 따라 전국적으로 43개에 달하는 10호미만 미전화유인도서 및 벽지지역에 대한 전화사업의 필요성이 제기되었다. 10호미만 도서지역의 전화사업을 위하여 도서전화사업의 기본취지인 전력정책의 보편공급목표를 달성하면서 사회적 경제적비용을 최소화할 수 있는 방법의 채택이 요구되었다 본 연구에서는 대부분의 도서지역이 채택하고 있는 기존의 디젤방식과 최근 활발한 보급이 이루어지고 있는 태양광 풍력 등 신재생에너지에 의한 발전방식의 기술적 옵션에 대한 타당성 분석을 실시하였다. 10호미만 도서지역과 5호미만 벽지지역에 디젤엔진과 태양광 등 신재생에너지를 보급할 경우 발생될 기술적, 경제적 비용의 분석을 실시하였으며 연구 결과 소규모 도서지역과 벽지에서는 태양광이 디젤엔진보다 경제적인 대안으로 판명되었다.

본 연구는 현재 디젤발전기를 전원으로 사용하고 있는 도서지역에 신 재생에너지원의 조합으로 구성 된 발전시스템 보급의 경제성 분석을 검토해 보았다. 분석 대상 도서는 에너지 기술연구원의 풍속분포자료를 근거로 추자도, 거문도, 영산도를 선정하였으며, 풍속 그 외 일사량, 부하 자료는 부분적으로 실측된 자료를 바탕으로 재구성하고 시스템 구성 발전기 들의 비용 자료는 해외 시장의 자료를 이용하였다. 분석을 위한 도구로는 도서지 역 에서 단독으로 운영되는 신 재생복합 전력시스템의 최적 설계 및 운영을 위한 프로그램으로 해외의 여러 곳에서 활용 중인 Homer를 사용하였다. 분석 결과, 추자도와 거문도 지역에 신 재생복합 전력시스템을 도입 할 경우에는 도서지역의 신 재생복합 전력시스템 보급이 경제 적인 사업으로 나타났지만 신 재생에너지 원인 풍속이 낮은 값을 가지는 영산도의 경우에는 신 재생복합 전력시스템의 보급이 디젤발전기만 운영 할 경우보다 발전 단가를 높인다. 즉, 신 재생에너지 원이 조건에 맞을 경우에는 도서지역의 신 재생복합 전력시스템 보급이 경제 적인 사업이라고 볼 수 있지만 영산도의 경우와 같이 그렇지 않을 경우엔 기존의 시스템보다 발전단가를 높일 수 있으므로 도서지역에 대한 충분한 모니터링을 거친 후에 부지를 선정 해야 한다.

The power outputs of renewable energy such as wind turbines and solar energy powers depend on natural sources. Accordingly, the power outputs of renewable energy is different from capacity rate at the time of peak load. Because of this gap, long term electricity power plan can have over-estimated reserve margin. So, this paper suggests the chronological approach to calculate the reliability assessment of renewable energy.

Although renewable energy sources are more environmentally friendly than fossil energy sources, it is far more costly, considering current technological standards. It would not present many competitive advantages in the power market. If the renewable electricity is viable in the market, the government should take 'visible' actions to compensate production costs. Popular policies, such as Feed-In-Tariff and Renewable Portfolio Standards, can help to attract investors into generators of renewable electricity. But presently, they are mainly financed through a undifferentiated increase of electricity bills and occasionally confronted with the opposition of the electricity consumers. And most policies tend to focus on increasing the supply of renewable electricity with little consideration toward elevating the motivation of consumers. This study evaluates the potential of environmentally friendly energy consumption and examines the 'green pricing' program which realize the potential.

21세기에 들어서서 새로운 신에너지원으로 각광을 받는 연료전지는 지구온난화의 영향으로 청정에너지를 더욱더 필요로 하는 에너지를 부상시켰다. 2000년을 기점으로 다양한 연료전지기술들이 다양한 응용분야에 기술개발이 이루어지고 있으며 2004년에는 11,000기 이상의 연료전지제품이 출시되는 등 급속한 발전을 거두고 있다. 특히 연료전지 제품의 시장화에 앞장서고 있는 수송용 연료전지는 차세대자동차의 대체 상품으로 지목받으면서 메이커 중심으로 상용화에 노력을 배가하고 있는 실정이다. 본 논문에서는 연료전지의 전반적인 시장구조를 살펴보고, 특히 수송용 연료전지의 시장과 산업에 관하여 분석하고 틈새시장 진입을 위한 전략을 제시하였다.

풍력에너지 연구개발은 1970년대 에너지 위기 이후 시작되어 1980년대 초반까지 가격 경쟁력과 기술 부족으로 상용화에 이르지 못하였다. 그러나 1980년대 중반 미국을 시작으로 상업발전에 성공하여 100kW급 풍력발전시스템이 대량 보급되기 시작하였다. 1990대에는 덴마크, 독일, 스페인 등에서 대규모 풍력시장이 형성되었고, 2000년대 들어 대형화에 성공하여 기존 발전에 대한 시장경쟁력을 확보하게 되었다. 본 논문에서는 풍력에너지 보급 확산을 촉진하기 위해 풍력발전 시장의 동향분석과 함께 기술 특성을 분석하였으며 보급 촉진을 도모할 수 있는 확산 전략들을 제시하였다.

Regester & Larkin(2005) suggest the issue and risk lifecycle analysis method in risk management, made up of the potential, emerging, current, crisis, and dormant stages. Investment on New & Renewable Energy is meaningful in effect ive risk management for diminishing or reducing the shock of a energy current, at the potential stage. In this study, we survey the risk of traditional fossil fuel projects and develop the risk analysis model for new & renewable energy projects specially geothermal energy resources and gas-hydrate resources.

가스하이드레이트는 최근 고유가 시대에 기존화석에너지를 대처할 수 있는 가능성이 높은 에너지원이다. 이와 같은 이유로 정부는 2005년부터 본격적으로 가스하이드레이트 개발사업단을 발족시켜 국내의 부존형태와 매장량 평가를 위해 노력하고 있다. 2005년 2차원 정밀 물리탐사, 심해 퇴적물 채취 및 다각적 분석연구사업이 수행되었고, 2006년도에는 3차원 물리탐사, 심해 퇴적물 채취, 개발기술을 위한 연구 및 지질재해 안정성 연구등이 수행될 예정으로 있다. 사업단은 정부의 가스하이드레이트 개발 기본계획을 토대로 3단계 10개년 계획을 수행함으로써 미래 에너지원의 확보 및 자원 강국으로 가는 초석을 마련하려하고 있다. 향후 가스하이드레이트에 대한 관심사는 상업적 개발 가능성이다. 또한 대체 에너지들의 공통적 문제점인 막대한 비용 소요와 장기적 시간을 요한다는 점에서 여전히 문제점을 지니고 있다. 하지만 급속도로 발전하는 과학기술이 보조를 맞추어 준다면, 꿈의 에너지원인 가스하이드레이트가 모든 산업체와 가정에서 인류의 편안함을 지켜줄 시기가 도래할 것으로 기대해 본다.

본 연구의 목적은 동해 울릉분지의 제4기 후기 퇴적물 내의 유기물, 공극수와 메탄의 특징 및 상호작용을 규명하는데 있다. 연구지역에서 채취한 코어퇴적물을 원소 분석한 결과 C/N 및 C/S 비(wt. %)는 퇴적물 내 유기물이 주로 해양조류 기원을 가지고, 일반적인 해양 또는 정체 환경에서 퇴적되어Tdam을 지시한다. 그러나 Rock-Eval 열분석 결과는 유기물 기원이 육상식물(Type III)이고, 열적 성숙단계가 미성숙단계임을 보여준다. 이러한 원소분석과 열분석간의 상반된 결과는 유기물이 침강하는 동안 또는 퇴적 후 이루어진 강한 산화작용에 기인한 것으로 추정된다. 퇴적물 내 공극수의 황산염 농도가 퇴적물의 심도가 증가할수록 감소하며, 감소하는 경향은 크게 두 가지 (적선성, concave down)로 나누어진다. 이는 모든 코어에서 황산엽 환원작용이 일어나고 있음을 지시한다. 또한 직선선의 황산엽농도 구배는 무산소 메탄 산화작용(AMO)의 전형적인 특징이다. 황산염 농도의 수직적 구배를 이용하여 SMI(sulfate-methane interface) 심도를 계산하면, 남부울릉분지의 코어 (03GHP-01, 03GHP-02; <3.5mbsf)가 북부울릉분지 코어(01GHP-05, 01GHP-07, 03GHP-03, 03GHP-04, 03GHP-05; > 6mbsf)보다 낮은 값을 갖는다. 위와 같은 SMI 심도차는 메탄의 상부 분산량과 밀접한 관련있는 것으로 추정된다. 메탄가스의 탄소 안정동위원소 $({\delta}^{13}C)$ 분석값들은 -83.5%o에서 -69.5%o의 범위를 가지고 있고, 이산화탄소 환원작용($CO)_2$ reduction)에 의한 생물 (biogenic) 기원임을 지시한다.

A seismic survey for gas hydrate have performed over the East sea by the KIGAM since 1997. General indicator of gas hydrate in seismic data is commonly inferred from the BSR(Bottom Simulating Reflector) that occurred parallel to the sea floor, amplitude decrease at the top of the BSR, amplitude blanking at the bottom of the BSR, decrease of the interval velocity and the reflection phase reversal at the BSR. In this paper we had analyzed optimum parameters of the field data to detect the 9as hydrate. Shot delay correction is applied 95ms, spherical divergence correction is applied velocity library 3, bandpass filter is applied 25-30-115-120Hz deconvolution operator length is applied 60ms, lag is 6ms and accurate velocity analysis NMO correction, stack is performed. Geobit 2.11.0 developed by the KIGAM was used for all data processing. Processing results say that the BSR occurred parallel to the sea floor were shown at 3,150m/s of two way travel time from the sea floor through shot point 5,000-5,610, and identified the interval velocity decrease around BSR and the reflection phase reversal corresponding to the reflection at the sea floor.

한국지질자원연구원은 1997년부터 새로운 에너지 자원으로 활용 가능성을 포함하고 있는 가스 하이드레이트를 조사하기 위해 동해 일원에서 탄성파탐사를 실시하고 있다. 탄성파 반사 자료로부터 가스 하이드레이트 부존여부를 확인하는 방법은 해저면과 평행하면서 위상이 반대로 나타나는 고진폭 반사파 BSR (Bottom Simulating Reflection)과 BSR상부에서의 진폭감소, 하부에서 진폭증가와 구간속도 감소 등을 들 수 있다. 여기에서는 가스 하이드레이트 탐사자료에 대한 일반자료처리와 함께 BSR을 포함하고 있는 탄성파 반사자료에 대해 코드 병렬화된 PSPI를 이용하여 깊이영역 구조보정을 실시하였다. 고용량 탐사자료로 구성된 탄성파 반사자료에 깊이영역 구조보정을 적용하기 위해서는 고성능 컴퓨터와 병렬처리 기술이 필요하다. PSPI(Phase Shift Plus Interpolation)법은 적은 컴퓨터 계산량과 효율성 그리고 주파수 영역에서 구조적으로 병렬화가 용이한 특성을 지니고 있어 구조보정에 많이 이용되고 있다. 여기에서는 MPI(Message Passing Interface)-LAM을 이용하여 병렬코드화된 PSPI를 개발하고 인공합성모델과 동해 가스 하이드레이트 깊이영역 구조보정에 적응하였다.

We report here that under strong attacksof external $CH_4$ guest molecules the sII and sH methane hydrates are structurally transformed to the crystalline me framework of sI, leading to favorable change of the lattice dimension of the host-guest networks. The High Power Decoupling $^{13}C$ NMR and Raman spectroscopies were used to identify structure transitions of the mixed $CH_4+C_2H_6$ hydrates (sIIl) and hydrocarbons (methylcyclohexane, isopentane) + $CH_4$ hydrates (sH). The resulting spectra indicate that most of the synthesized sII and sH hydrates were transformed to methane hydrate of sl under 110 bar and particularly the coexistence of sl with sII or sH appear according to the surrounding methane-rich gas conditions. The present findings might be expected to Provide rational evidences regarding the preponderant occurrence of naturally-occurring sI methane hydrates in marine sediments.

Growth characteristics of methane-propane clathrate hydrate, growing under different undercooling conditions, was investigated. After the water within pressurized vessel was fully saturated with guest gas molecules by agitation, medium was rapidly undercooled and maintained at the constant temperature. The growth of hydrate was always Initiated with film formations at the upper bounding surface of liquid pool. The visual observation using microscope revealed detailed features of subsequent crystal nucleation, migration, growth and interference occurring within liquid pool. A number of small crystals ascended and settled at the hydrate film. When undercooling was small $({\Delta}T=3.2K)$, some of the settled crystals slowly grew into faceted columns. As the undercooling increased, the downward growth of crystals underneath the hydrate film became dendritic and occurred with greater rate and with finer arm spacing. The shapes of the floating crystals were diverse and included octahedron and triangular or hexagonal platelet When the undercooling was small, the octahedral crystals were found dominant. As the undercooling increased, the shape of the floating crystals also became dendritic. The detailed characteristics of floating crystals were reported in this study.

동일한 조건에서 순수한 물과 계면활성제인 DBS(dodecyl bezebe sulfonic acid) 25ppm을 첨가한 물에 대해 천연가스 하이드레이트를 제조시 가스의 함유량은 각각 80배와 160배로 2배의 차이가 발생한다. 이에 대해 본 연구에서는 결정 생성 형태의 관찰 및 $^{13}C$ NMR을 사용한 분광학적 구조 분석으로부터 이의 원인을 찾고자 하였다. 순수한 물과 DBS를 미량 함유한 물을 사용하여 whiskery 결정을 생성시킨 결과, 순수한 물을 사용한 경우보다 섬유 다발 형태가 매우 활발한 형태의 결정 형태로 가스하이드 레이트가 생성됨을 알 수 있었다. 또한 400MHz의 NMR을 사용한 분광학적 구조 분석으로부터 천연가스하이드레이트는 구조-I과 구조-II가 혼재된 결정 구조를 이루고 있음을 알 수 있었다. 또한 DBS를 함유한 물에 의해 제조된 천연가스하이드레이트는 arge cage를 많이 생성시키는 역할을 하는 분석 결과를 보였고 이것이 가스 함유량을 증대시키는 원인 중의 하나임을 알 수 있었다.

[ $1m^3$ ] solid hydrate contains up to $200m^3$ of natural gas, depending on pressure and temperature. Such large volume of natural gas hydrate can be utilized to store and transport large quantity of natural gas in a stable condition. So, in the present investigation, experiments carried out for the formation of natural gas hydrate governed by pressure, temperature, and gas compositions, etc.. The results show that the equilibrium pressure of structure II natural gas hydrate (is approximately 65% lower and the solubility is approximately three times higher than structure I methane hydrate). Also, the subcooling conditions of the structure I and II must be above 9K and 11K in order to form hydrate rapidly regardless of gas components, but the pressure increase is more advantageous than the temperature decrease in order to increase the gas consumption. And utilizing nozzles for spraying water in the form of droplets into the natural gas dramatically reduces the hydrate formation time and increases its solubility at the same time.

최근 막대한 매장량으로 인해 미래의 비재래형 에너지원으로 주목받고 있는 천여가스 하이드레이트는 고압 저온 환경에서 수소결합을 하는 고체상 격자 내에 객체분자인 가스분자가 포획되어 형성된 가스하이드레이트의 일종으로 영구 동토지역과 심해저의 퇴적층에 광범위하게 분포되어 있다. 본 연구에서는 이러한 가스하이드레이트의 개발기술과 천연가스의 저장과 운송기술에 관한 미국 일본 유럽 등 특허 3극 및 한국 특허 총 357건을 추출하고 특허정보 분석을 실시하여 국내외 기술개발 동망 및 기술변화 추이를 살펴보았다. 특허 검색에 사용된 DB와 분석도구는 특허청 선행기술 전문조사기관 등으로 지정된 (주)윕스사의 WIPS와 ThinKlear이며, 미국/일본/유럽 등 특허 3극과 한국에서 공개 또는 등록된 특허를 검색대상으로 하였다 자원으로서 천연가스 하이드레이트를 개발하는 기술과 관련하여 총 193건의 특허가 추출되었으며, 이 때 사용하는 방법에는 감압법, 열처리법, 억제제 주입법 등이 있었다. 또한 연료용 가스, 특히 메탄가스의 수송 및 저장에는 통상 액화하여 액화천연가스로 수송하는 방법이 사용되고 있으나 가스하이드레이트를 이용할 경우 액화천연가스를 이용하는 것보다 더 경제적임이 보고되면서 이와 관련된 연구가 활발히 진행 중이며, 총 164건의 특허가 추출되었다. 상기 추출된 총 357건을 대상으로 연도별 출원동향, 국가별 점유율 및 시계열 분석, 분류기술별 출원동향 등의 특허정보 분석을 수행하였다.

Geochemical analyses carried out on samples collected from cores on and near the southern smit of Hydrate Ridge have advanced understanding by providing a clear contrast of the two major modes of marine gas hydrate occurrence. High concentrations (15%-40% of pore space) of gas hydrate occurring at shallow depths (0-40 mbsf) on and near the southern summit are fed by gas migrating from depths of as much as 2km within the accretionary prism. This gas carries a characteristic minor component of C2-C5 thermogenic hydrocarbons that enable tracing of migration pathways and may stabilize the occurrence of some structure II gas hydrate. A structure II wet gas hydrate that is stable to greater depths and temperatures than structure I methane hydrate may account for the deeper, faint second bottom simulating reflection (BSR2) that occurs on the seaward side of the ridge. The wet gas is migrating In an ash/turbidite layer that intersects the base of gas hydrate stability on the seaward side of and directly beneath the southern summit of Hydrate Ridge. The high gas saturation (>65%) of the pore space within this layer could create a two-phase (gas + solid) system that would enable free gas to move vertically upward through the gas hydrate stability zone. Away from the summit of the ridge there is no apparent influx of the gas seeping from depth and sediments are characterized by the normal sequence of early diagenetic processes involving anaerobic oxidation of sedimentary organic matter, initially linked to the reduction of sulfate and later continued by means of carbonate reduction leading to the formation of microbial methane.

On the continental margins and in permafrost regions, natural gas, which has been expected to replace petroleum energy, exists In solid hydrate farm. World hydrate reserves Including natural gas are estimated at about twice as much as the energy contained In total fossil fuel reserves. Because of its vast quantities, the efficient recovery of natural gas from natural gas hydrate becomes the most important factor on evaluating the economic feasibility in the sense of commercialization. It has been noted that carbon dioxide, one of the well-known green house gases, possibly can be stored in the ocean floor as a carbon dioxide hydrate. If the natural gas hydrate could be converted into carbon dioxide hydrate, natural gas hydrate deposits would serve as energy sources as well as carbon dioxide storage sites in the deep ocean sediments. In this study, we first attempted to examine the real swapping phenomenon occurring between guest molecules and various structures of gas hydrate through spectroscopic identification such as NMR spectroscopy.

In this study, an experimental apparatus has been designed and set up to analyze the dissociating phenomena of hydrate in porous rock. Experiments with the depressurization ion scheme have been carried out to investigate the dissociation characteristics of methane hydrates and the productivities of dissociated gas and water. From the experiments, it has been provided a determination of volume of gas produced and the progress of the dissociation front, as a function of time when hydrate is depressurized. Also, it has been investigated the flowing behavior of the dissociated gas and water in porous rock and the efficiency of the production

In Japan, research and development were undertaken on gas hydrate-side industrial processes associated with power generation system connections that may particularly be necessary to develop gas hydrated technology-based industrial systems. In so doing, data and engineering technologies useful n formulating guidelines on design of practical process were accumulated. In addition, basic research into theoretical evidence were carried out to promote and support the development of technological elements for those processes. In basic research designed to promote and support the research and development of elemental technologies microanalyses were conducted to understand the decomposition mechanism of mixed gas hydrate. Moreover, measurement technologies that can be applied in industrial processes, such as numerical analyses and concentration ion measurement, were examined. Japan has developed a highly efficient gas hydrate formation process using micro-bubbles with a tubular reactor. Higher formation rate over conventional systems has been obtained by the process. As mentioned above, the technical problems were clarified and the economics were studied from a view point of the NGH technology in this study. The results can be applied for utilization and must contribute to popularization of gas hydrate production.

Basic studies on natural gas hydrates in the East Sea were been carried out by the Korea Institute of Geoscience and Mineral Resources (KIGAM) from 2000 to 2004 involving 2D multichannel seismic lines and piston coring. 27 piston cores recovered from the deed-water Ulleung Basin of the East Sea were analyzed in this study. In piston cores cracks generally developed parallel to bedding suggest significant gas content. The core analyses showed high total organic carbon (TOC) content, sedimentation rate and heat flow of sediments. The cores recovered from the southern study area show also high residual hydrocarbon gas concentrations for the formation of natural gas hydrates. This study indicates that there is the potential for the generation of biogenic gas and the formation of natural gas hydrates in the near seafloor sediments of the study area.

Natural gas hydrate has been a major problem for its plugging nature in the pipeline. With the demand of deep-water production, the importance of flow assurance technology, preventing hydrate, asphaltene and wax in the pipeline becomes bigger Kinetic models combined with the flow simulator are being developed to explain the nature of hydrate plug formation in the pipeline. To simulate the hydrate plug formation, each stage including the nucleation, growth and agglomeration should be considered. The hydrate nucleation is known to be stochastic and is believed hard to be predicted. Recent publications showed hydrate growth and agglomeration can be observed rigorously using a particle size analyzer. However properties of the hydrate should be investigated to model the growth and agglomeration. The attractive force between hydrate particles, supposed to be the capillary force, was revealed to be stochastic. Alternative way to model the hydrate agglomeration is to simulate by the discrete element method. Those parameters, particle size distribution, attractive force, and growth rate are embedded into the kinetic model which is combined Into the flow simulator. When compared with the flowloop experimental data, hydrate kinetic model combined into a flow simulator showed good results. With the early results, the hydrate kinetic model is promising but needs more efforts to improve it.

Accurate information on the ground surface temperature is essential for design of a borehole heat exchanger and thus ensuring the performance of a ground source heat pump system along with knowledge on thermal diffusivity and conductivity of ground. In this study we analyzed the shallow subsurface temperature monitoring data of 58 Korea Meteorological Administration synoptic stations. As a result, we compiled mean annual ground surface temperature distribution map using multiple regression analysis of the monitoring data.

Though numerous drilling has been performed in Jeju Island for development of ground water, the wells are mostly located along the coast lines or at low altitude area, and can hardly be found on the mid-mountain area. Two-dimensional magnetotelluric (MT) surveys have been carried out to cover the lack of geological Informal ion on the mid-mountain area and to figure out any possible structures or evidences for deep geothermal energy remained. Two-dimensional (2-D) inversion of MT data for four survey lines surrounding the Halla mountain show a thick layer having around 10 ohm-m in the depth of a few hundred meters throughout the survey area, which can be considered as the unconsol idated sedimentary layer. And they also show a conductive anomaly extending to more than 2km depth at the central part of each survey lines, which can possibly be related with old volcanic activities during the formation of Halla Mt.. Further seological/geophysical investigations should be followed.

The groundwater level was originally above the surface at the Onyang spa area. However, it is now 98-138m depth below the surface deu to the artificial pumping from boreholes. The fluctuations of the piezometric head were observed in 4 boreholes. Transmissivity estimated from the pumping rate and the drawdown is about $577.51 m^2/day$ The transmissivity of Onyang spa area is much larger than common values of fractured aqui for the drawdown of the piezometric head by artificial pumping is widely spreaded out in that area. The drawdown related to each pumping rate was analyzed and the formula between drawdown and pumping rate was made by a regression analysis. The formula can be applied for the condition of enough groundwater flowing into the Onyang spa area

On long time scale and over large areas ground surface temperatures (GSTs) track surface air temperatures (SATs). Additionally, GST changes penetrate into the subsurface and are recorded as transient temperature perturbation to the background thermal filed. Therefore, climate change can be reconstructed from borehole temperature measurements We present GST hi story reconstructed from temperature measurements in a borehole at Pocheon The result shows that GST cold period in the late 19th century and then increased by about 2K to 1990. GST history matches well with surface air temperatures measured from 1907 to 2001 at the Seoul Meteorological Station and GST history reconstructed from temperature measurements in three boreholes at Ulsan.

유출지하수나 지표수를 열원으로 하는 지열히트펌프의 기초자료로 활용하기 위하여 Pond Loop형 열교환기를 설계, 제작하여 유동이 없는 수조 내에서 수조의 온도가 변화함에 따라 일정한 열교환기 입구온도를 유지하면서 열전달량을 측정하였다. 그 결과 수조를 Heat Source로 사용하는 경우 $5,500{\sim}4,500kcal/h$의 열량이 전달되었고, 수조를 Heat Sink로 사용할 경우 $5,200{\sim}3,500 kcal/h$의 열량이 전달되었다. 또한 열교환기 관내 유속이 증가함에 따라 열전달량이 증가하는 경향성을 확인할 수 있었고, 이는 동시에 열교환기 입출구의 차압을 증가시킴을 알 수 있었다. 열교환기의 설계단계에서 사용하였던 열전달관계식으로 구한총괄열전달계수, U와 실험값을 통해 유추한U값을 비교한 결과 실험에 의해 유추된 U값이 $24{\sim}27%$ 설계치보다 크게 나타났다. 본 연구를 통하여 유출지하수 뿐만 아니라 하수 및 하천수를 이용한 지열히트펌프의 기초자료를 확보할 수 있었다.

Fiber optic distributed temperature sensing and thermal line sensor are applied in an observation borehole and a loom deep borehole heat exchanger. For the case of permanently installed system fiber optic DTS is very useful. By comparing with TLS, fiber optic DTS shows good accuracy and reliability. Ground water flow can give influences at heat exchange rate of the heat pump system. According to the hydraulic characteristics and temperature-depth profile, we consider that temperature-depth profile do not seem to be dependent on ground water flow. A permanent installation of fiber optic cable is expected as a reliable temperature measurement technique in a borehole heat exchanger system.

본 연구는 자연에너지를 이용하는 모든 냉 난방기술 중에서 에너지효율이 가장 높은 것으로 알려져 있으며 에너지 자원이 부족하고 에너지비용이 높은 상황에서 반드시 필요한 기술인 지하수를 이용한 건물의 냉 난방을 수행하는 스탠딩컬럼웰 지열히트펌프 기술을 운영함에 따른 지하수에 미치는 환경영향을 평가하기 위해 수행되었다. 즉 스탠딩컬럼웰을 적용한 지열히트펌프 시설이 가동되고 있는 주변지역의 지하수질 및 지하수위의 변화를 평가하기 위하여 지하수 환경영향평가를 실시하였다. 연구결과, 히트펌프의 유입수 및 유출수, 그리고 주변 지역의 수질은 지하수 수질기준 및 공업용수, 생활용수 수질기준에 적합한 안정적인 수질을 나타내었으며, 시설 운영에 따른 지하수 오염은 거의 없는 것으로 판단된다. 또한 지열히트펌프에 이용되는 4개의 양수정에 의한 주변 지역의 지하수위 변화등의 영향을 예측하기 위하여 취수가 없는 상태와 양수정당 취수량을 $50m^3/day$로 증가시켰을 경우를 가정하여 지하수두를 분석한 결과 취수량을 증가시켰을 경우 지하수두가 약2,.2m 감소하는 것으로 나타나 조사지역내의 지하수 거동은 양수정 가동조건과 주변지역에 분포되어 있는 정천의 취수량 변화에 따라 민감하게 반응하는 것으로 나타났다.

현재 남한의 지열류량 측정값으로는 총 363개 지점의 자료가 측정 및 수집되어 있다. 이것은 Mizutani et at. (1970), 장정진 외(1970), 그리고 서정희(1976) 등의 자료, 총 35개의 자료도 추가된 것이다. 1989년 이후부터 측정된 지열류량 자료는 217개 자료이며(임정웅 외, 1989; 임정웅 외, 1996; Lim and Kim, 1997; 염병우 외, 1997), 모두 직접 측정한 것이나, 1989년 이후 보고된 지열류량 자료에 약간의 오류가 있어 이번 연구에서 수정 보완하였다. 또한 과거의 자료 35개 자료는 이미 지열류량 측정치가 논문화 되어 있는 것으로 암석시료는 없다 1989년 이후 2004년까지 자료 217개 2005년도 추가 자료 111개의 지열류량 자료는 암석시료도 있으며, 측정기기가 서로 달라 오차가 있을 수 있어 서로 보정을 해야 할 필요가 있어 시추공 주변 암석을 새로 수집해서 신장비로 다시 측정 보정하였다. 지열류량 D/B 구축은 각 자료의 일련번호, 고유번호 (Sn.), 위경도 좌표 (longitude, lattitude), 암석의 열전도도(thermal conductivity), 지온경사 (thermal gradient), 지열류량 (heat flow)등으로 구성되어 있다. 지열류량 자료 공간 데이터베이스는 점 속성을 가지며 자료형태는 각종 소프트웨어와 호환성이 좋은 shape 파일 형태로 작성하였다. 또만 최근 천부 토양 및 암석 열물성을 이용한 냉난방시스템 즉, Heat Pump System 설계를 위하여 반드시 들어가야 하는 요소인 열확산율, 공극율, 밀도, 비열 등 열물성 특성을 추가하여 GIS 공간 D/B구축하였다. 대륙붕 자료 4개 자료를 제외하고 359개의 지열류량 자료를 이용하여 한반도 남부, 즉 남한의 지열류량 분포도를 작성 분석해 본 결과(그림 1), 우리나라의 지열류량 이상대는 아산만 주변, 보령, 유성, 진안, 울진, 포항, 부산 지역과 포천, 속초, 충주, 수안보 등 지역에서 나타난다 이러한 이상대 주변에는 대개 온천이 발달되어 있었거나 새로 개발되어 있는 곳이다. 온천에 이용하고 있는 시추공의 자료는 배제하였으나 온천이응으로 직접적으로 영향을 받지 않은 시추공의 자료는 사용하였다 이러한 온천 주변 지역이라 하더라도 실제는 온천의 pumping 으로 인한 대류현상으로 주변 일대의 온도를 올려놓았기 때문에 비교적 높은 지열류량 값을 보인다. 한편 한반도 남동부 일대는 이번 추가된 자료에 의해 새로운 지열류량 분포 변화가 나타났다 강원 북부 오색온천지역 부근에서 높은 지열류량 분포를 보이며 또한 우리나라 대단층 중의 하나인 양산단층과 같은 방향으로 발달한 밀양단층, 모량단층, 동래단층 등 주변부로 NNE-SSW 방향의 지열류량 이상대가 발달한다. 이것으로 볼 때 지열류량은 지질구조와 무관하지 않음을 파악할 수 있다. 특히 이러한 단층대 주변은 지열수의 순환이 깊은 심도까지 가능하므로 이러한 대류현상으로 지표부근까지 높은 지온 전달이 되어 나타나는 것으로 판단된다.

Two mesophilic trickling bed bioreactors filled with two different types of media, hydrophilic- and hydrophobic-cubes, were designed and tested for hydrogen production via anaerobic fermentation of sucrose. Each reactor consisted of a column packed with polymeric cubes and inoculated with heat-treated sludge obtained from anaerobic digestion tank. A defined medium containing sucrose was fed with changing flow rate into the capped reactor, hydraulic retention time and recycle rate. Hydrogen concentrations in gas-phase were constant, averaging 40% for all conditions tested. Hydrogen production rates increased up to $10.5 L{\cdot};h^{-1}{\cdot}L^{-1}$ of reactor when influent sucrose concentrations and recycle rates were varied. Hydrophobic media provided higher value of hydrogen production rate than hydrophilic media at the same operation conditions. No methane was detected when the reactor was under a normal operation. The major fermentation by-products in the liquid effluent of the both trickling biofilters were acetate and butyrate. The reactor filled with hydrophilic media became clogged with biomass and bio gas, requiring manual cleaning of the system, while no clogging occurred in the reactor with hydrophobic media. In order to make long-term operation of the reactor filled with hydrophilic media feasible, biofilm accumulation inside the media in the reactor with hydrophilic media and biogas produced from the reactor will need to be controlled through some process such as periodical backwashing or gas-purging. These tests using trickling bed biofilter with hydrophobic media demonstrate the feasibility of the process to produce hydrogen gas in a trickle-bed type of reactor. A likely application of this reactor technology could be hydrogen gas recovery from pre-treatment of high carbohydrate-containing wastewaters.

생물학적 수소생산을 위해 토양으로부터 새로운 균주인 Enterobacter asburiae SNU-1이 분리되었다 이 균주의 경우 다른 균주와는 달리 미생물 생장과 수소생산 phase가 분리되는 특징을 가지고 있다. 이러한 정지기에서의 수소생산은 미생물 내에 존재하는 formate hydrogen lyase를 사응하여 formate 분해에 의해 일어난다. 따라서 본 연구에서는 미생물 생장 phase에서 formate hydrogen lyase가 발현된 미생물을 얻고 이를 formate만 있는 배지에서 수소생산 가능성에 대한 연구를 수행하였다. 앞으로 formate분해를 위한 조건을 최적화한다면 높은 수소생산성을 나타낼 것이라 기대된다. 또한, 이는 formate로부터 미생물촉매를 이용하여 수소를 생산하고 이를 연료전지로 공급하는 생물학적 reformer로써의 이용 가능성을 보여준다.

유동형 급속열분해기((fluidized bed type fast pyrolyzer, 용량 300g/h)를 이용하여 너도밤나무와 침엽수 흔합재(독일가문비나무/전나무, 50:50)로부터 바이오오일을 생산하였다. 목질바이오매스의 열분해는 약 $470{\pm}5^{\circ}C$에서 1-2초 간 진행되었다. 목질바이오매스의 열분해 생성물의 조성을 살펴보면, 너도밤나무는 바이오오일이 약 60%, 탄이 약 9% 피리 고 가스가 31% 가량 생산되었으며, 침엽수 혼합재는 49%의 바이오오일, 9%의 탄, 그리고 42% 가량의 가스가 생성되었다. 두 종류의 목질바이오매스에서 생산된 바이오오일에는 약 17-22% 가량의 수분이 포함되어 있었으며, 비중은 약 1.2kg/L 이었다. 바이오오일의 원소 조성은 탄소가 45%, 산소가 47% 수소가 7%, 그리 고 질소가 1% 로서 일반적 인 목질바이오매스와 큰 차이는 없는 것으로 나타났다. 그러나 화석자원에서 생산되는 오일류와 비교하여 산소함량은 매우 높았으나 황은 전혀 포함하고 있지 않았다. 바이오오일의 GC분석 결과 총 90여종의 고리형, 또는 비고리형 저분자량 화합물이 검출되었으며 이들의 함량은 바이오오일 전건중량의 31-33% 정도로 측정되었다.

Energy is vital to global prosperity, yet dependence on fossil fuels as our primary energy source contributes to global climate change environmental degradation, and health problems. Hydrogen $(H_2)$ offers tremendous potential as a clean renewable energy currency. Hydrogen has the highest gravimetric energy density of any known fuel and is compatible with electrochemical and combustion processes for energy conversion without producing carbon-based emission that contribute to environmental pollution and climate change. Numerous methodologies have been developed for effective hydrogen production. Among them, the biological hydrogen production has gained attention, because hydrogen can be produced by cellular metabolismunder the presence of water and sunlight. The green alga Chlamydomonas reinhardtii is capable of sustained $H_2$ photoproduction when grown under sulfur deprived condition. Under sulfur deprived conditions, PSII and photosynthetic $O_2$ evolution are inactivated, resulting in shift from aerobic to anaerobic condition in the culture. After anaerobiosis, sulfur deprived algal cells induce a reversible hydrogenase and start to evolve $H_2$ gas in the light. According to above principle, we investigated the effect of induction parameters such as cell age, cell density. light intensity, and sulfate concentration under sulfur deprived condition We also developed continuous hydrogen production system by sulfate re-addition under sulfur deprived condition.

대마에 대한 분석 결과, 인피 섬유의 경우 리그닌 함량은 7.6%로 다른 목질계 바이오매스나 일년생 초본류와 비교하여 매우 낮은 리그닌 함량을 나타냈으며 탄수화물 함량은 65.4%로 목질계 바이오매스와 유사하고, 초본류보다는 오히려 높았다. 목부는 리그닌 및 탄수화물 함량이 활엽수와 유사한 경향을 나타내었는데 특히 높은 자일란의 함량이 확인되었다. 또한 회분 함량이 인피섬유와 목부에서 각각 5.0%와 2.3%로 낮은 값을 나타내어 당화 및 발효 공정에 적용될 때 회분에 의한 공정 장애(스케일링 등)의 가능성을 낮추어 줄 것으로 사료되었다. 최종적으로 이러한 화학적 분석을 통해 대체에너지 생산을 위한 자원으로서 대마의 가능성을 확인할 수 있었다.

In order to investigate the possibility of waste mushroom logs as biomass resource chemical and physical characteristics of normal woods and waste mushroom logs such as crystallinity value, energy consumption, total sugar yield after hydrolysis chemical compounds and molecular weight distribution after acid hydrolysis, were examined. In the results, crystallinity of waste mushroom logs which were three year passed after the inoculation was decreased drastically from 49% to 33% during the cultivation. Lignin contents as chemical compounds of normal woods and waste mushroom logs were 21.07% and 18.78%, respectively. By the results of measurement of energy consumption, the size reduction of normal woods required a significantly higher energy than that of waste mushroom logs. In the hydrolysis, total sugar yield by enzyme and acid hydrolysis were high in waste mushroom logs(53% 57.5%) than in normal woods(42.9%, 47.17%). According to the molecular weight distribution using GPC, low molecular weight compounds were distributed in waste mushroom logs. Based on these results, waste mushroom logs have enough potential as material for developing alternative energy because of easily conversion to sugar by various hydrolysis methods and requirement of low energy consumption during size reduction.

The output performance characteristics for surveyed sites were analyzed, using developed model. It consists of two main parts, the deciding flow duration characteristic of river and performance prediction model to estimate the output characteristics of small hydropower plants. As a result, it was found that the flowrate concerning with 25% of time ratio on flow duration curve can be selected to design flowrate of small hydropower plants, and the output characteristics of small hydropower plants having overflow dam are different from large scale hydropower plants.

The Kaplan turbine model has been tested and analyzed. The blade angle and the guide vane opening of the turbine model were designed to be varied according to the best combination of guide vane and runner blade opening. When the changes in head and output were comparatively large, the efficiency drop were small, so the efficiency characteristics and stability of the entire operating condition were maintained in good condition. These results showed that the developed model in this study will be suitable for small hydropower stations with large changes In head and load such as agricultural reservoir.

This paper presents computed results of FEM analysis on the tribological contact behaviors of a primary sealing components of mechanical face seals for a small hydro-power turbine. The FEM computed results present that the contact area between seal rings and seal seats is very important for a good tribological performance such as low friction heating, low wear, high contact normal stress in a primary seal ing components. Based on the FEM computation, model III in which has a small sealing contact area shows low dilatation of primary sealing components, and high contact stress between a seal ring and a 1)seal seat.

Recently, concern for tidal power is being increased by newly recycled energy. It is important to decide on the maximum power estimate operation and it's stop by applying the difference of water level between tide level and artificial reservoir for the administration of tidal development. For maximum output of power through turbine generator, administrative variables and process on efficiency of hydraulic turbine and inflow discharge of reservoir is quite complicated because it is run through the connection of discharge-gate and turbine On the development of this model, the administrative process is decided, Operation block is presented for it's maximum power estimate.

국내 대형 기력발전단지에서 냉각수로 사용되고 방류되는 해수는 약 150cms로 (100Mwe 당 약 5cms) 약 3,000kW 이상의 수력에너지를 보유하고 있으나, 현재 활용되지 못하고 그대로 해양으로 방류되고 있다. 발전소 방수로는 흐름조건이 비교적 균일하고, 파랑 내습이 없으며 부유사 해조류, 부유물 충돌 등의 문제가 발생하지 않아 자연 해양조건보다 조류력 발전에 매우 유리하나 수심이 낮고, 순환수 계통에의 영향으로 다수의 수차를 설치하기는 어려운 조건을 지니고 있다. 따라서, 인공수로의 균일하고 양호한 흐름조건에 적합한 보다 경제적인 수차를 개발하고, 발전량을 증대하기 위한 수차 배치 기술, 수차 및 발전기 지지구조물의 설계 기술, 계통 연결기술 등을 개발할 필요가 있으며, 이를 위하여 시험용 조류식 발전시스템을 제작하여 수차의 성능 및 전체 발전시스템의 성능을 평가하여 발생되는 문제점을 해결하고자 한다. 본 연구에서는 시험용 조류식 발전시스템을 하동화력발전소 방수로에 적용하기 위하여 현장 특성 분석, 형식 선정, 발전량 산정 등의 시스템 설계를 수행하였다.

The feasibility study for tidal power plant (TPP) has been carried out for the Siwha area inside the Kyunggi bay of the Kyunggi Bay of the Yellow and East china Seas, by KORDI (Korea Ocean Research and Development Institute) and continuing research works for tidal energy development are under progress in the several sites inside the Kyunggi Bay. In this paper we describes some results of the modeling efforts in relation the tidal regime change by Siwha TPP operation, as well as other coastal oceanographic research works involved in TPP development in the coastal region.

The Korean peninsula has a number of coastal sites where the rhythmic rising and lowering of water surface due to tides results in strong tidal current. The kinetic energy of these currents can be efficiently exploited by use of tidal current turbines. The pilot tidal current power plant is to be constructed at the Uldolmok narrow channel between J info and Haenam, Our ins next Year, and extensive coastal engineer ing research works have been carried out. This paper describes and analyzes some observation results of field test about the efficiency of Helical turbine for tidal current power plant. The efficiency of turbine, which is diameter 2.2m and height 2.5m, is evaluated meximum RPM, torque, and current velocity. The tested turbines had the maximum efficiencies of the bounds of 25 to 35% in the current velocity range between 1.4 and 2.6 m/s. This result shows that the pilot tidal current power plant needs three helical turbines with diameter 3.0m and height 3.6m to produce electric power 500kW.

The target of this work was the process development of demonstration plant to produce the high quailty alternative fuel oil by the pyrolysis of mixed plastic waste. In the first step of research, the bench-scale units of 70t/y and the pi lot plant of 360 t/v had been developed. Main research contents in this step were the process performance test of pilot plant ot 360ton/year and the development of demonstration plant of 3 000 t/y which was constructed at Korea R & D Company in Kimjae City. The process performance of pilot plant of 360 t/v showed components in PONA group appeared at between that of commercial gasoline and kerosene. On the other hand, HO product was mainly paraffin and olefin components and also appeared at upper temperature distribution range than commercial diesel. Gas product showed a high fraction of $C_3\;and\;C_4$ product like LPG composition, but also a high fraction of $CO_2$ and CO by probably a little leak of process.

Because price of fossil fuel rises, necessity about alternative energy was risen. Studied co-combustion of RPF to coal fluid bed boiler by necessity of these althernative energy. Purpose of this study to coal fluid bed bioler RPF when did co-combustion, change operating condition and characteristic of air pollutant examine according to change of fuel characteristic, operating condition examined about combustion chamber temperature, oxygen content etc. and air pollutant examined about material that is included to allowable exhaust standard and dioxin. Co-combustion condition was 5%. It was no peculiar under test result operating condition. Concentration of Co and HCl rose according as do RPF co-combustion and the other pollutants had hardly changed. Dioxin is low concentration level more than $0.1ng-TEQ/Sm^3$. There was no pollutant that exceed akllowable exhaust standard for boiler but $SO_x,\;NO_x$ were exceeded about allowable exhaust standard for incinerating facility.

The first RDF production plant in Korea is going to start commercial operation at Won-Ju city in October this year, where municipal solid waste is treated and converted to RBF. Korean government is preparing the quality standard of RDF and starting a new waste policy of RDF promotion instead of general waste treatment technologies such as incineration or landfill. In Europe the EU member states have decided the united quality standard of RDF to increase the amount of new & renewable energy through the promotion of RDF utilization. New quality standard of RDF and trade market of RDF in Europe is introduced in this paper.

Many researches about next generation vehicles are trending toward HEV which has better fuel economy than an internal-combustion engine. But existing HEV has some defects at specific running states(eg. highway running It is possible that dual-mode hybrid system overcomes that defects. Mode change parameter, ${\gamma}$ helps to analyse the mode changing of dual mode hybrid and is applied at a numerical analysis on testing the performance. There is an additional constraint when vehicles drive on engine mode. No power assistance of battery applies on engine mode. Because vehicles must be sustained by only engine power while vehicle drives on constant speed mode. At the conclusion of this paper, graphs show the ability of motors that satisfy the equilibrium of the lever system. Designers can roughly determine capacities of the motors, parameters of the lever system by this analysing method.

최근 여러 연구에서 다양한 종류의 멀티 모드 하이브리드 동력 전달계가 제안되고 있다. 멀티모드 동력전달계는 두 개 이상의 다른 유성기어식 하이브리드 시스템으로 이루어져 있으며 클러치를 사용하여 각 상황에 유리한 유성기어 시스템을 사용하여 주행한다. 각 유성기어 시스템의 단점들을 보완할 수 있기 때문에 단일 모드를 사용하여 주행했을 때보다 여러 면에서 높은 성능을 보인다. 일반적으로 유성기어식 하이브리드 시스템은 크게 입력, 출력, 복합 분기식의 세 가지 종류로 나눌 수 있는데 이 논문에서는 입력 및 복합 분기식 구조의 특징을 분석해 보았다. 또한 시뮬레이션을 통해 입력, 복합 분기식 구조를 사용하여 듀얼 모드를 구성하였을 때 단일 모드와 비교하여 어느정도의 성능을 보이는지 알아보았다.

The power split hybrid power train is considered to be one of the most prospective configuration for the hybrid electric vehicle (HEV). Toyota Prius, representing this type of vehicle, showed outstanding performances in fuel efficiency, emission reduction and acceleration. The excellence is largely due to the fact that it utilizes almost all operation modes of HEV. Those modes include ZEV (Zero Emission Vehicle) driving, idle stop, fuel cut-off, power assist, active charging, regenerative braking and so forth. In this paper, a few of the mode operations were simulated using AVL Cruise. Also, control logics to operate the powertrain in each mode were developed. The states of powertrain components were displayed and analyzed. By controlling the three components (engine, motor and generator), it was possible to run the powertrain in several hybrid operation modes.

An inverter system which consists of three bi-directional buck-boost converters, is proposed for motor driving. Three phase sinusoidal output voltages can be generated by utilizing three buck-boost converters. The advantage of this scheme is that it does not require a separate DC-DC converter for motor driving, i.e. inverter function is combined into the three DC-DC converters. This topology is suitable for inverters for hybrid or fuel cell vehicles where DC link voltage is subject to change depending upon charging status or output power. So the proposed system is capable of driving motor at high speed. The converter system is controlled by PI controller and simulation results done by MATLAB SIMULINK are provided.Ҙ?⨀ሉȀ̀㘰々K䍄乍?ጊ츀Ѐ㔹〻Ԁ䭃䑎䴀

A low-temperature solar thermal system assisting a biological nitrogen treatment reservoir was designed and field-tested. A large tank whose temperature was maintained at about $25{\sim}30^{\circ}C$ to enhance the performance of a biological nitrogen treatment process was heated by an array of flat plate solar collectors. Test results revealed that the overall collector efficiency was above 50% for the most cases tested. This high efficiency was possible owing to the relatively low collector temperature that can be traced back to the reservoir temperature. A substantial enhancement in nitrogen treatment was observed as a result of maintaining the reservoir temperature higher.

An investigation has been carried for the thermal characteristics of the seasonal storage installation in Cheju. It features the solar collector area of $340m^2$ and the storage capacity of $600m^3$. Four different types of solar collector systems are compared for their performance of collecting solar energy throughout the year. Of these, two are made of tubular shaped vacuum collectors and the others are flat plate collectors. Results indicate that each system could play an important role in exploiting solar energy depending on the temperature range in its operation. Especially, the vacuum collectors outperformed the others when the inlet temperatures of the collector loop were raised beyond $40m^2$. This became more conspicuous as the return temperatures from the storage tank rose reflecting the seasonal variation. Due to the large heat capacity of the storage tank, temperature changes were rather small compared to those in the collecting loop regardless of seasonal fluctuations.

A numerical study has been carried out for a solar water heater which consists of double skin solar vacuum tubes. Water is heated as it flows through the coaxial fluid conduit inserted in each tube. The space between the exterior of the fluid conduit and the glass tube is tilled with antifreeze solution. This is to facilitate heat transfer from the solar heated absorber surface to water and to prevent the functional problems due to freezing in frigid weather conditions. A one-dimensional steady state model is fully described which will be used to develop three-dimensional model using STAR-CD. These models could be used efficiently in designing double skin solar collector tubes with different geometrical parameters other than those considered in the present analysis. Results show a good agreement when compared with other experimental data demonstrating the reliability of the one-dimensional model employed.

To improve economic of solar power generation, stirling engine is required continuous operation and the receiver has to be provided with an additional combustion system. The hybrid receiver with a specially adapted combustion system is possible to 24 hr/day operation by solar and gas-fired. The inner cavity and external wall serve as absorber surfaces using collected irradiation and heat transfer surfaces for the gas heat flow, respectively. The hybrid receiver was designed and fabricated for the dish/stirling system. The analytical method for pridicting natural convective heat loss from receiver is used. The Koenig and Marvin model is used to estimate convection heat loss and heat transfer coefficiency.

This paper describes characteristics and procedure of the basic design of large scale solar thermal power plant system. The evaluation is based on the operating data of CESA-I, solar central receiver plant. In order to evaluate the solar irradiation on the receiver, it is necessary to calculate the amount of thermal energy consumption at steam turbine and storage system in the STPPS. Especially, it is need to take into account of the storage and operating time to design a plant efficiently. In addition, basic design is performed for the CESA-I using the software tool of THERMOFLEX program. Based on the results, It is at lowed to use the program to investigate detail performance of each units of the STPPS by varying the operating conditions.

A small-scale solar concentrating system was developed and demonstrated for supplying process heat required in solar thermo chemical reaction. The concentration system consists of a heliostat equipped with a solar tracking device and a dish concentrator. From the initial thermal test of the concentrating system it was found that the system works very well with around 500-600 concentration ratio capable of supplying about 3kW therml energy to the reactor. Once the concentration system was turned on, the reactor temperature rapidly increased over $1,000^{\circ}C$ and could be maintained high enough for solar chemical reaction.

An energy generating greenhouse based on fluoropolymer envelope and fresnel lens is proposed. The outstanding properties of the fluoropolymer films make them very suitable for large scale solar applications. Extremely high optical transmission over the whole solar spectrum, combined with mechanical strength, and durability allows us to design a highly optimized greenhouses for both plant growing and energy generation. Systems such as photovoltaic triple junction cells are especially attractive since they have up to 35% efficiency with much less cell material when the sun beam is focused with concentrators such as fresnel lenses. Cooling such devices will enhance the efficiency and provide useful thermal energy that could be further utilized for various applications depending on the local demands. This article introduces the basic ideas and principles of the energy generating greenhouses as a first step towards the actual deployment of such systems under Korean environment.

PV Thermal combined system produces the electricity and thermal energy which are needed for buildings. The system removes heat from PV module through air or liquid, so that its efficiency will be improved. The heat as the forms of hot air or hot water can be utilized for building use, like space heating and hot water. This paper describes the concept of PV Thermal combined system and its research and development trend at local and international levels. This materials can be used as a fundamental study source about PV Thermal combined system to apply fur building space heating.

This paper introduces various natural energy systems installed at the Eco-Science Center in Geumsan near Taejon. The center, especially, features different solar energy systems to harvest the solar energy to its full extent. Such passive schemes as direct gain and at lacked sun space are applied along with active solar ingredients using flat plate and double skin solar collectors. Space and water heating depends very little on the conventional means. Also a number of photovoltaic modules deployed within its premise supplies power to drive a water pump for the biotop. Combined with other natural energy utilizing systems, the solar energy systems make an exemplary model of a self sustainable public facility which is the first of its kind in Korea.

The advantages of solar energy are that it is renewable, infinite supplied and environmentally safe energy source. However, solar energy related products have the problems such as the limitation for installation, problems in maintenance and insufficient reliability which have been the barrier to consumers to satisfy the purchase need for solar heat related products. In this regard, in order to support the solar energy related companies the necessity for various technical information required for the commercialization of new products such as various performance test necessary for the certification of solar energy system, standardization for facilities and products, performance evaluation method and the measurement of performance is suggested. The purpose of this paper is to design the monitoring system for positive tests of system linked household hot water system using solar heat out of various solar energy systems, to establish an analysis and monitoring system for performance maintenance and operation technique, and to configure the centralized detection network by utilizing remote monitoring system. This research also aims at conducting monitoring for operation and performance evaluation in relation to database establishment and analytical evaluation and at describing the method of enhancing the reliability of solar energy system through the development of performance evaluation program.