The Alternative energy has lately attracted considerable attention due to the high oil price and environment problem. In this study, pilot test facility for using the geothermal energy source from riverbank filtration was constructed and monitoring devices are installed to estimate the efficiency of this system. Initial installation cost can be saved efficiently by connect ing a heat pump system into the exist ing pumping well in Changwon riverbank filtration site. One set of monitoring results during summer was presented and analyzed.

Open loop or ground water heat pump systems are the oldest of ground-source systems. Standing column wells can be used as highly efficient ground heat exchanger in geo-thermal heat pump systems, where hydrological and geological conditions are suitable. These systems require some careful considerations for well design, ground water flow, heat exchanger selection etc This paper describes 9round water temperature variations, performances in heat ins and cool ing mode and the results of ground water analysis.

유출지하수나 지표수를 열원으로 하는 지열히트펌프의 Pond Loop형 열교환기를 개발하기 위하여 미국에서 상용화된 Slim-Jim 열교환기와 본 연구에서 자체설계, 제작한 Pond-loop type의 열교환기를 유동이 없는 유출수조 내에서 수조온도가 변화함에 따라 일정한 열교환기 입구온도를 유지하면서 열전달량의 변화를 측정하였다. 그 결과 유출수를 Heat Source로 사용하는 경우 Slim-Jim에서는 $8,000{\sim}11,000 kcal/hr$의 열량이 전달되었고, 자체 제작한 열교환기에서는 $11,000{\sim}16,000kcal/hr$의 열량이 전달되었다. 유출수를 Heat Sink로 사용할 경우 Slim-Jim에서는 $2,500{\sim}7,000 kcal/h$의 열량이 전달되었고, 자체제작한 열교환기의 경우, $6,800{\sim}14,00 kcal/hr$의 열량이 전달되었다. 측정된 열전달량을 바탕으로 총괄열전달계수를 구한 결과 Slim-Jim 열교환기의 경우 $210{\sim}340 kcal/hr\;m^2{\circ}C$, 자체개발한 열교환기의 경우 $350{\sim}590 kcal/hr\;m^2{\circ}C$로 나타나 자체 개발한 열교환기의 열전달 성능이 비교적 우수함을 입증하였다.

Geothermal energy is the natural heat of the Earth. Enormous amounts of thermal energy are continuously generated by the decay of radioactive isotopes of underground rocks and stored in the Earth's interior. Therefore, geothermal energy is one of the most important sustainable energy resources. Recent trends of geothermal energy exploitation technologies focus on the Earth scientific approach to geothermal heat pump system, enhanced geothermal system, aquifer thermal energy storage, underground thermal energy storage, and fluid/heat flow model ing for geothermal wells. Geothermal heat pump distribution in Korea is still in its starting phase in terms of areal utilization sense, we, however, expect to come up with national supply of over 1,000,000 toe by 2020

16개 기상관측소에서 채취한 토양 시료에 대한 토양 물성 및 열특성를 측정하였으며 이를 통하여 공극률, 함수비, 충적밀도, 입도 분포, 유기물 함량, 토양구성광물의 종류 및 함량이 열전도도에 미치는 영향을 파악하였다. 상관성 분석결과 입도분포, 유기물함량 및 토양 구성광물의 종류 및 함량은 낮은 상관성을 보였으며 용적밀도 $(R^2=0.60)$, 함수비$(R^2=0.54)$와 공극률$(R^2=0.56)$은 높은 상관성을 보였다. 또한 함수비(2%)와 토양의 종류에 따른 다중회귀 분석을 통하여 토양의 열전도도를 추정할 수 있는 회귀식을 제시하였다.

It is require to construct geothermal database to develop geothermal energy as renewable energy policy. It must be consist of geologic data, borehole data and geophysical data for geothermal database. In aspect of geology, there are included the distribution of geology, structural geology, geological time, rock name, density of rock, porosity, thermal diffusivity, specific capacity and thermal conductivity In order to calculate the heat general ion, it is needed to analysis the radioactivity elements as U, Th and K of rock. In aspect of borehole data, there are included temperature of depth, surface temperature and geothermal gradient And also there is geotherrnornetry using chemical components of groundwater as Na Ca, K and $SiO_2$. In aspect of geophysical data, there are some thematic map as booger gravity anomaly data and magnetic survey data and etc. In addition, it is important to descript the distribution of hot spring and water temperature.

The validation of a groundwater source heat pump system installation site is estimated by bydrogeothermic model ing. The hydraulic characteristics of the aquifer system is evaluated from pumping and recovery tests. In addition, the temperature distribution by the pumping and the injection of groundwater, and water level fluctuations are simulated by numerical modeling. The total cooling and heating load for the building is designed as 120RT(refrigeration ton) and the ground water source heat pump system covers 50RT as a subsidiary system The scenario of heat pump operation is organized as pumping and inject ion of groundwater that is performed for 8 hours per day in cooling mode for 90 days during the summer season The heat transfer by the injected warm water is limited near the inject ion wells in the simulated temperature distribution. The reason is that the given operation time is too short to expect broad thermal diffusion in large volume of the aquifer in the simulation time The simulated groundwater level and temperature distribution can be used as important data to develope an energy effective pumping and injection well system. Also it will be very useful to evaluate the hydraulic capacity of a target groundwater reservoir.

To evaluate the effect of groundwater flow on the outlet temperature of a geothermal heat pump, 3 dimensional numerical simulations are performed considering both groundwater flow and pipe flow in the U-tube using TOUGHS, The present study involved the following 4 simulation cases (1) no groundwater flow, (2) slow groundwater flow (hydraulic conductivity: $1.0{\times}10^{-9}m/s)$, (3) fast groundwater flow (hydraulic conductivity, $1.0{\times}10^{-7}m/s$), and (4) groundwater flow varying with the depth (hydraulic conductivity: $1.0{\times}10^{-7}-1.0{\times}10^{-10}m/s$). The effect of groundwater flow on the outlet temperature is significant where hydraulic conductivity of aquifer is $1.0{\times}10^{-7}m/s$. Where hydraulic conductivity of aquifer is $1.0{\times}10^{-10}m/s$, however, that effect is negligible.

Public demand for the heat pump system as a next generation energy equipment is increasing for its eco-friendly and cost-effective advantage. Many researches have been concentrated on how to calculate and develop its own efficiency, while the possible effect of the heat pump operation on the whole subsurface temperature distribution is relatively less considered, During the current study, subsurface temperature disturbance caused by seasonal surface temperature cycle in Busan area and general W-tube heat pump operation is simulated in 3-dimensional heterogeneous medium. It shows that subsurface deeper than 10m from the surface remains nearly unchanged throughout the 4 seasons and groundwater convect ion in highly permeable layer near the surface acts like a main path of heat plume from heat pump system, This implies the significance of detail descript ion in shallow sedimentary layer or highly permeable layer which plays an important role on the regional flow advection and heat transfer. Also, the effect of groundwater convection increases when the arrangement of the 2 injection pipes and 2 extract ion well is maintained parallel to groundwater flow. Therefore, more careful and detail investigation is required before installation and operation of heat pump system that it may not cause any possible change of microbial ecosystem in the shallow subsurface environment or 'contamination of temperature' for groundwater use as well as the loss of efficiency of the equipment itself. This can also help to design the optimized grouting system for heat pump.

The Sea of Okhotsk is the unique area providing the highest methane production rate of the northern hemisphere. The area of focused fluid venting offshore the NE Sakhalin continental slope was investigated during the CHAOS (Hydro-Carbon Hydrate Accumulations in the Okhotsk Sea) expeditions onboard of RV "Akademik Lavrentyev" In 2003, 2005 and 2006. The International Research Project CHAOS (Russia-Korea-Japan) aimed at the study of gas hydrate formation processes associated with the fluid venting in the Sea of Okhotsk. Several new gas hydrate accumulations were discovered during the cruise. Hydrate-associated structures have been named as KOPRI, VNIIOKeangeologia, POI and KIT (the names of cruise participant institutes) Some of hydrate-bearing cores contain big amount of gas hydrates: massive gas hydrate layers (up to 35cm thick) were recovered. The shallowest submarine gas hydrate accumulations in the world (at the depth less then 400m) were discovered during the cruise.

Regional geophysical surveys and geological cal studies on natural gas hydrate (NGH) in the East Sea were carried out by the Korea Institute of Geoscience and Mineral Resources (KIGAM) from 2000 to 2004. 16 piston cores, 2270 L-km of multi-channel reflection seismic (MCRS) data and 730 L-km of 3.5kHz Chirp data obtained from the southwestern part of the deep-water Ulleung Basin were analyzed in this study. In piston cores, cracks generally developed parallel to bedding suggest significant gas content. The core analyses showed high total organic carbon (TOC) content, sedimentation rate and heat flow of sediments. These are in favor of the general ion of substantial biogenic methane, which can form the NGH within the stability zone of the near seafloor sediments in the study area. The cores generally show also high residual hydrocarbon gas concentrations for the formation of natural gas hydrates The geophysical indicators of the presence of gas and/or NGH such as bottom simulating reflectors (BSRs), seismic blank Bones, pockmarks and gas seeping features were well defined on the MCRS and Chirp data.

Structure H formation experiments were conducted in a semi-batch stirred vessel using methane as the small guest substance and neohexane(NH), tert-butylmethylether(TBME) and methylcyclohexane(MCH) as the large molecule guest substance (LMGS). The results indicate that the rates of gas uptake and induction times are generally dependent on the magnitude of the driving force. When tert-butyl methyl ether is used as the LMGS rapid hydrate formation, much smaller induct ion time and rapid decomposition can be achieved. Liquid-liquid equilibrium (LLE) data for the above LMGS with water have been measured under atmospheric pressure at 275.5, 283.15K, and 298.15K. It was found that TBME is the most water soluble followed by NM and MCH. The solubility of water in the non-aqueous liquid was found to increase in the following order: MCH

n-Pentane and n-hexane, previously regarded as non-hydrate formers, are found to form structure H hydrate in mixtures with 2,2-dimethylbutane. Even though they are thought to be too large to fit into the largest cage of the structure H hydrate, powder XRD and NMR measurements show that they form gas hydrates in mixtures with other sH hydrate former. These findings are of fundamental interest and also will impact the composition and location of natural gas hydrates and their potential as global energy resource and climate change materials.

가스하이드레이트의 국내 부존 가능성이 확인됨에 따라 가스하이드레이트 개발기술 및 부존 정보의 확보를 위한 가스하이드레이트 연구개발사업이 추진 중에 있다. 가스하이드레이트 개발사업과 같은 국가주도 연구개발사업의 경우 사업의 타당성 확보와 효율적인 추진을 위해서 사업 및 개발기술의 가치를 객관적으로 평가해야 할 필요성이 높아지고 있다. 본 연구에서는 가스하이드레이트 개발사업의 가치평가를 위한 주요 속성들을 결정하고 속성별 쌍대비교를 통해 중요도를 도출 할 수 있는 Fuzzy AHP 방법론을 사용하여 상대적 가중치를 도출하였다 연구 결과 가스하이드레이트 개발사업 및 기술의 가치는 상위계층으로 직접가치와 유발가치로 나눌 수 있고, 하위계층으로 총 8개의 속성으로 분류 할 수 있는 것으로 분석되었다. 중요도 분석결과 가스하이드레이트를 직접 개발함으로써 얻을 수 있는 개발가치가 사업시행으로 인한 탐사개발 기술의 확보로 유발되는 가치보다 높은 중요도를 가지는 것으로 평가 되었다. 또한 개발가치의 세부항목 중에는 에너지 안보 증진 효과가, 유발가치의 세부항목 중에는 인력양성효과가 가장 중요한 가치평가 요소로 나타났다

The idea of $CO_2$ sequestration in the ocean is proposed to be an effective mitigation strategy to counteract potential global warming due to the greenhouse effect Therefore, in the present study, calculations of the dissolution behavior of $CO_2$ hydrate when liquid carbon dioxide is released at 1,000m and 1,500m in depth are performed. The results show the liquid $CO_2$ injected in the ocean becomes $CO_2$ bubble at between 350m and 500m in depth, and the injection from a moving ship is a more effective method of dissolution than through a fixed pipeline. It so also noted that the ultimate plume generated from $CO_2$ bubbles repeats expansion and shrinking due to the peel ins from a fixed pipeline.

With the increasing environmental consideration and stricter regulations waste gasification is considered to be more attractive technology than conventional incineration for energy recovery as well as material recycling. The experiment for combustible waste was performed In the fixed bed gasifier to investigate the gasification behavior with the operating conditions in a 5ton/day fixed bed gasifier The experiments of operation with 10-50 hours were carried out to determine the effects of bed temperature and oxygen/waste rat io on the syngas composition, calorific value and carbon conversion. The calorific values of the produced syngas decreased with an Increase of bed temperature because combust ion reaet ion more act ively happened. The syngas composition of wood waste gasification is CO: 34.4%, $H_2: 10.7%,\;CH_4: 6.0%,\;CO_2: 48.9%$ and that of RPF is CO: 33.9%, $H_2: 26.1%,\;CH_4: 10.7%,\;CO_2: 29.2%$. The average calorific values of produced gas were about $1,933kcal/Nm^3,\;2,863kcal/Nm^3$, respectively

Fueled by ballooning oil prices, waste plastics are now regarded as being cheap and abundant renewable sources, removing their stigma of dirty wastes Catalytic pryolysis of plastics in liquid phase allows recovery of light fuel oil as well as green treatment of polymerics wastes, and therefore significant efforts have been devoted to this research field. In this study, catalytic Pyrolysis of LDPE was carl ied out in semi-batch reactor which equipped a unit of separation and recirculation. The effect of react ion conditions were examined by analyzing liquid oil yield and carbon number distribution of products

In this study, the syngas producing facility that consists of pulverized coal feeding/gasification and hot gas clean-up system was tested for Indonesian subbituminous coal. And the DME conversion facilities have been developed and tested for converting syngas to DME by reactions with catalysts. So, the entrained-bed slagging type pi lot scale coal gasifier was operated normally in the temperature range of $1,400{\sim}1,450^{\circ}C,\;7{\sim}8kg/cm^2$ pressure. And Roto middle coal produced syngas that has a composition of $36{\sim}38%$ CO, $14{\sim}16%\;H_2,\;and\;5{\sim}8%\;CO_2$. Particulates in syngas were 99.8% removed by metal filters. $H_2S$ composition in syngas was also desulfurized by the Fe chelate system to yield less than 0.1 ppm level. When the clean syngas $70{\sim}100 Nm^3/h$ was provided to DME conversion rector, normally operated in the temperature range of $230{\sim}250^{\circ}C$ and $60kg/cm^2$ pressure, 4.5% DME was yielded.

The experimental study has been done for two kinds of pelletized RDFs to Investigate the carbonization effect to the chlorine concentrations, the heating value and the yield of Produced char in variable conditions of the carbonizing temperature and reaction time. One(RDF-1) is made of 100% wasted plastics and the other(RDF-2) is made of 60% wasted paper with 40% wasted plastics. The screw type carbonizer heated Indirectly by oil burner was used for the experiment and RDF feeding rate was 3kg/hr. The carbonizing temperature was 300, 350 400 and $45^{\circ}C$ and the reaction tine was 5, 10 and 15 minutes respectively. As the increase of carbonizing reaction time and temperature, the chlorine reduction rate was increased and oppositely the yield of char was decreased At the temperature of $400^{\circ}C$ and reaction time of 10 minutes the chlorine reduction rate was 60% and the char yield rate was 80% for the RDF-1 and those of RDF-2 were 80% and 75%, respectively. Additional activation experiment to the char produced from RDF-2 was done in the activation reactor by hot steam supply. As the increase of activation time the iodine number was increased. At the activation time of 20 minutes the iodine number was 552mg/g and the yield of activated carbon was 16%.

PEMFC(proton exchange membrane fuel cell) is most applicable to automobile in various types of fuel cell. However, to improve system dynamics and logn term Performance fuel cell is supported by auxiliary power unit forming hybrid system. The operating strategy of hybrid system influences on efficiency and stability. In this paper the proper strategies are compared each other considering power distribution and stable system operation. The chosen strategy is simulated by MATLAB simulink to forecast realization of fuel cell hybrid vehicle

Accelerating ability is one of the most important performance of the vehicle. Unlike conventional internal combustion vehicles and power-assist hybrid vehicles, the maximized acceleration of dual mode hybrid vehicles is not simply. achieved by maximizing engine or motor torque Because of the dynamic stability of planetary gear, speeds and torques control of engine, motor 1 and motor 2 is essential and according to control value, acceleration performance is changed There are two control values which are velocity and torque for each component totalling six. These six values can be variables for an objective function. However, because three velocity variables can be regarded as only one variable speed ratio and the remaining three torque variables can be solved analytically, without complicated numerical algorithm the solution for the objective function can be obtained. This optimized solution shows the best performance possible to the specified dual mode system.

Water management is considered to be one of the main issues to be addressed for the performance improvement of proton exchange membrane (PEM) fuel cell. For good water management, the detailed information on the water distribution inside an operating PEM fuel cell should be available to main an adequate level of hydration in the PEM While avoiding performance decline due to liquid rater flooding. For the PEM fuel cell to be commercially viable as vehicle applications, the flooding on the cathode side should be minimized during the fuel ceil operation. In this study to investigate cathode flooding and its relation with temperature distribution in flow channels, visualization study was performed on the cathode side of a PEM fuel cell. For the direct visualization of temperature field and water transport in cathode flow channels, a transparent cell was designed and manufactured using quartz window. Water transport and its two-phase flow characteristics in flow channels were investigated experimentally. Also, the visualization of temperature distribution In cathode flow channels was made by using IR camera. Results indicated that the temperature rise near the exit of cathode flow channel was found. It is found that this area corresponds to the flooding area from both temperature and flooding visualization results It is expected that this study can effectively contribute to get the detailed data on water transport linked with heat management during the operation of a PEM fuel cell

The fuel cell is one of the promising environment-friendly energy sources for the next generation. The fuel cell provides good energy efficiency above 40% without pollution or noise. Different fuel cell types are usually distinguished by the kind of electrolyte. Among these, the proton exchange membrane fuel cell (PEMFC) has advantages of high power density. low operating temperature, relatively quick start-up, and rapid response to varying loads. The bipolar plate is a major component of the PEM fuel cell stack, and it takes a large portion of stack volume, weight and cost. In this study, as alternative materials for bipolar plate of PEM fuel cells, graphite composites were fabricated by compression molding and by machining. Graphite particles mixed with epoxy resin were used as the main substance to provide electric conductivity. Flow channels were fabricated by compression molding with design of experiments (DOE) to evaluate moldability. The cost for compression molding of graphite-composite bipolar plate was compared with machining cost to make the same bipolar plate.

In the recent studies, various types of multi mode electric variable transmission for hybrid electric vehicle have been proposed. Multi mode electric variable transmission consists of two or more different type planetary gear hybrid powertrain system(PGHP), which can change its power flow type by means of clutches for improving transmission efficiencies. Generally the power flows can be classified into three different types such as Input split, output split nd compound split. In This paper, we present velocity and torque equations of the input-split powertrain and analyze its optimal Performances. There are six combinations of the input-split powertrain, each combination has various lever length. We find optimal planetary gear ratios for fuel economy and acceleration performance, and compare performances of each combination.

This paper Is for development of cooling module in order to maintain heat and water balance in fuel cell vehicle. Thermal management system for fuel cell is disadvantage because the temperature of coolant is lower than that of ICE and heat duty of radiator is higher. By CFD simulation, cool ing module was developed for water balance of system. Hot chamber test and hot area/high altitude test on cool ing module was completed.

국내외에 아직 적용 실적이 없는 발전소의 해수방류수를 이용한 조류식발전시스템의 개발을 위하여 하동화력발전소 방수로에 시험용 조류식 발전시스템을 설계 및 제작하여 현장시험이 진행 중이며, 이를 확장하여 상업용 발전을 위한 총 개발 규모를 산정하고 경제성을 분석하였다. 조류식발전구조물의 형상 설계, 가이드 베인을 이용한 출력 조정을 통하여 방수로의 수류상태를 적절히 조절하여 설계하는 것이 가능할 것으로 판단되며, 조류식발전구조물 설치시 방수로의 수류특성 수치계산 결과로 판단할 때 발전출력에 의한 에너지 회수뿐만 아니라 조류식발전구조물의 단면축소 효과 및 수두손실이 방수로의 수위 변화에 상당한 규모로 영향을 주고 있음을 확인하였다. 조류식발전구조물 설치 이전의 유속 관측 결과를 이용하여 발전량을 산정한 경우 소수력발전 단가 적응시 경제성이 떨어지지만, 조류식발전시스템의 설치시 유속 증가 효과가 나타날 뿐만 아니라 가이드 베인 등을 이용하여 발전량 증대를 꾀하면 충분한 경제성을 확보할 수 있는 조류식발전시스템의 설치가 가능할 것으로 판단된다.

In order to transmit energy generated through the stator winding of a doubly-fed Induct ion generator (DFIG), we need to synchronize the generated voltage vector with the grid voltage vector. However, the existing synchronization method works only when the encoder is installed at a specific Position and equivalent constant is precise. In order to solve this Problem, a new synchronization method has been proposed and a way of applying the method to existing doubly-fed induction generator control algorithm has been also proposed. The validity of the proposed methods have been verified using a prototype converter for the control of a 1.5MW-class doubly-fed induction generator

It is well-known that the resources for tide and tidal current energy are abundant in Korea. The south coast in Korea is recognized as one of the most appropriate places in the world for developing tidal current energy. The target site for harnessing tidal current energy is the Uldolmok, where the strongest tidal current in Korea occurs. In order to commercialize and industrialize the tidal current power generation, the construction of pilot tidal current power plant of 1MW has been started in April 2006, and is expected to be completed by May 2007. Extensive works including field investigation, field experiment for evaluating the efficiency of helical turbine and numerical analysis have been performed. This paper present the several design parameters for constructing the Uldolmok pilot tidal current power plant.

Tidal power can use conventional technology to extract energy from the tides. It is usually best deployed in areas where there i s a high tical range which includes Western and Southern coastal areas in Korea. However, to extract tical energy, a barrage across an estuary or a bay is to be constructed that is now very hard due to severe environmental impact on local estuary. The recent technology of application of tidal stream provides a new window to extract power minimizing the adverse environmental impact Tidal stream technology which directly exploits these currents is relatively new but is presently generating considerable interest Turbine rotors can be used to extract energy from the flows. Prototype devices currently on test in the UK include the 300kW SeaFlow turbine. In this paper, the recent technology and research on ocean tical stream power are addressed

해양 신 재생에너지 개발에 의해 생태계에 미치는 영향을 최소화하기 위한 방안을 모색하기 위하여 환경변화 사례와 예측하였다 해양에너지의 개발은 필수적으로 해양환경 및 생태계에 변화를 초래하여 조력발전시설의 경우 조간대에 서식하는 저서생물의 종다양성을 감소시키고 철새 등의 조류의 종수 및 개체수의 변화를 가져오고 조력 및 조류발전 터빈시설은 수생생물의 기계적 충돌에 의한 사망률을 증가시킨다 이러한 해양 신 재생에너지의 개발과 더불어 생태계의 영향을 최소화하기 위한 조사 및 연구가 병행되어야 개발 후 상용화단계에서 가장 합리적인 자연보전의 방안을 제시하고 지역사회와의 갈등을 최소화 할 수 있는 과학적인 자료를 도출 할 수 있다.

The tidal pi lot plant is being built in the Uldolmok waterway using Its strong tidal current with maximum current of about 12knots, which is revealed from the first direct observation using ADCP, on February, 2002. a serious of field observations (for example, ADCP observation was tarried out both at February 2002 and September, 2003), along with numerical modeling, have been carried out over the last several years, in order to understand the tidal dynamics and to examine the related variables according to the tidal current power plant (TCPP) operation.

New and renewable energy information becomes one of the greatest issues because of serious environment problems and limited fossil resources However, There are few system to manage and utilize new and renewable energy information efficient. Therefore this study establish the GIS based Resource Map System to save and analyze new and renewable energy Informal ion about solar energy, wind power, small hydro, biomass, and geothermal. This Resource Map System is composed of the management system, practical system, field system and Web-service system. This System can Provide var ious spatial analysis tools such as data searching, treating thematic maps, evaluating location requirements for energy facilities.

The domestic solar radial ion data have been measured at 16 different sites all over the country since the beginning of 1980. It is very important that the fundamental data for the estimation and assessment of local solar radiation can be secured this project. In order to estimate available energy resource from solar radiation, it is necessary to have enough data, more than 30 years In any country. However since we have collected solar radiation(global radial ion including direct normal radiation) data only for 10 years we still need to measure insolation to secure the reliability and standardization of measured local solar radial ion data. In brief, the major activities on this R&D include rout me maintenance of the national network for insolation data measurement, evaluation of the collected data, and reliability enhancement for assessing the quality of solar radiation data as well.

The Dish/Stirling system with the Stirling engine is currently used to convert solar energy directly to electrical energy successful operation of dish/Stirling system is supported by hybrid system, which will allow continuous operation driven by solar and combustion heat ins. The hybrid Receiver has to be provided with an additional combustion system. The heat pipe receiver and conbustion system were manufactured and tested for thermal characteristics of receiver. Maximum temperature difference along the heat pipe surface is $200^{\circ}C$. Emission measurements showed low NOx values of 28 to 46 ppm and very high CO values of 18 to 201 ppm.

This paper introduces a preliminary work for the design of a mini-dish cluster system for power general ion. Each mini-dish (typically has a 20 to 30cm in diameter) is designed with a simple parabolic profile, concentrating sun light (after the glass glazing cover to avoid dust deposition on the reflector and facilitate cleaning) onto a centrally located small plane(or concave) mirror which is placed on the bottom side of the transparent glass cover. The mirror with a mini-dish concentrator is designed to focus beam radiation onto a focal point before it enters a bundle of optical fibers connected to a remote receiver for power generation different options are considered In designing a mini-dish concentrator to maximize its effectiveness for the collection and use of solar energy.

On our return to India from Germany, we have worked on the development of parabolic solar concentrators with input and collaboration of German and Austrian inventors. We have gradually improved the solar technologies to include food processing based on inputs and feedback from users to fulfill their specific requirements. We will discuss the acceptability and commercialisation of various systems that we have successfully developed, their implications and their benefit. These success stories can work as multipliers. These concentrators can have various other applications. The Global Treaty Kyoto Protocol's CDM (Clean Development Mechanism) can result in a win-win situation for both developing and developed nations and the world environment at large - whereby developed nations get carbon credits by supporting renewable energy projects in developing nations. North-South dialogue and South-South dialogue can effectively foster global co-operation meaningfully to benefit People and environments ensuring sustainable development and protection of Our planet Earth, our only HOME!!!

The Korean Solar Thermal Industry hopes to realize 1 Million Solar Thermal Roofs. According to the 2nd Renewable Basic Plan : 2003-2012 the Government showed a very aggressive Solar Thermal Deployment Plan including Solar Thermal Apartment Housings Program. Owing to the Vision Statement such as Million Solar Thermal Roofs Program Korean Solar thermal Industry also can bring another shinny days Especially the more solar thermal applications such as to the Apartment Housings and Green Villages could bring a sustainable Solar Society Korea The RPA Program by the 9 Major Non-Private Energy Corporal ions and the RPS Program for the Solar Thermal Energy shall be another useful policy for the realization of Million Solar Korea era.

Steam reforming of methane using Xe-arc solar simulator was studied for converting solar radiation into energy foam that one can readily utilize. The Xe-arc lamp produce a spectrum similar to that of the sun. SiC ceramic foam, resist high temp.$(>900^{\circ}C)$, is used to catalytically active foam absorber, and to support of reforming catalyst. The catalyst on the surface of foam were directly irradiated with solar simulated xe-light in order to carry out the steam reforming of methane. The reactor was made of stainless steel and quartz window was located on a place of the xe-light irradiation and temperature was controlled using K-type thermocouple in contact with catalyst located inside the reactor. The result show that a possibility of solar reforming using catalytically active foam absorber is exist.

This paper describes the procedure of the basic design and transient variation of performance for a 1MWe large scale solar thermal power plant system (STPPS) by using the commercial software tool of TRNSYS. In order to simulate the transient variation of STPPS's performance, the basic design of STPPS are preceded by using the THERMOFLEX, Three different days of DNI weather data of Daejeon in 2005 are used to calculate the performance. For a high DNI data values, the general ing power of 1.1 MWe and flow rate of 1.4kg/s at $804W/m^2$ are good agreement with the basic design value of 1.0 MWe, 1.36 kg/s at $800 /m^2$. Using the other weather data of low and sudden decreasing DNI values, the results show that the output power and flow rate follow well the DNI variation. Based on the results, it is allowed to use the Program to estimate the performance of STPPS for variety of DNI data.

As a final step for developing a small-scale solar thermal power generation technology, a demonstration project for a dish-stirling power system has been carried out by KIER. During the two years project period, 10kW solar-only power system was built in Jinhae city and successful solar operations were demonstrated. In this paper an example of typical clean day operation and analysis results was introduced.

The heat transfer characteristics of solar tower receivers are experimentally investigated with receiver shapes. Generally the heat transfer characteristics become different according to the shapes and materials of the volumetric air receiver. In order to study these effects, The experimental apparatus adopting laminated mesh and honeycombs as the volumetric air receiver is proposed. The receiver consists of laminated mesh (diameter; 100mm, thickness; 1mm), honeycombs (diameter; 100mm, thickness; 30 mm) inserted out the heat transfer characteristics of the laminated mesh the air temperatures are obtained by installing 3 thermocouples on each layer, dividing ceramic tube into 4 layers. Also, a radiative shield is installed to measure the only air temperature. The data for laminated mesh and honeycomb thickness of 30, 60, 90mm are obtained. The results show that the temperature of layer 3 is higher than those of layer 2 and layer 1.

This study is conducted to improve efficiency of thermal storage tank. The thermal storage tank was designed to store heat energy that obtained from solar or the others heat sources. However, it has difficulties in storing heat with uniform temperature through the entire tank with respect to vertical direction. This kind of maldistribution of the supplied heat to the storage tank effects on the system performance. In this study is focused on utilization of the thermal stratification to improve thermal comfort for people in the house. To enhance temperature stratification of the tank, a distributor was designed and Installed in the middle of the tank. The distributor is supplies hottest water to the top side of the tank which is very close to inlet of the supply line to the heating load. The hottest water that is accumulated on top side of the tank is firstly supplied to the load with higher temperature. Reminder water takes a little time to warming up until desired supply temperature reached. This kind alternating selection of the supply temperature is improve thermal comfort with moderated system performance.

신재생에너지의 발전산업은 지구온난화가 우려되는 현시점에 적극적으로 적응되길 요구하고 있으며 전 세계적으로 태양광발전(PV), 풍력발전, 연료전지발전 등 기타 신재생에너지 발전 산업이 전력수급의 역할을 해 나가고 있다 PV산업은 국내외적으로 독립형시스템에서 연계형시스템으로 옮아가는 추세에 있으며 이들의 시장 확장 및 보급을 위해서는 틈새전략이 필요하며 특히 국가의 정책 드라이브와 규제가 필요한 시장이다. 본 연구에서는 현존하는 각 국의 태양광발전 시스템 보급의 활성화를 위해 각 국가 및 주요 지원 정책에 대하여 논하여 향후 태양광발전산업의 시장개척에 대한 방향제시 하고자 한다.

최근 지열원 열펌프 시스템 설치가 해마다 평균 10-30%젓도 꾸주히 증가하고 있다 주요 연구동향은 토양열전도 측정, 지열히트펌프 시스템 전주기 성능평가 하이브리드 시스템의 초기비용 저감과 이러한 지열원 열펌프 시스템 설계방법분야 개발에 대해 초점이 맞춰지고 있다. 특히 국내에서 현재 시공되어진 많은 시스템들이 부실시공의 문제에 노출되고 있으며 이러한 시점에서 현재의 저가 입찰제도 보다는 외국 사례와 같은 성능확인 제도로의 전환 및 많은 연구가 필요하다. 성능확인제도는 사전 성능 예측과 사후 성능 확인 검증으로 구성되며 본 기술현안 보고서는 최근 국내외 연구동향 및 사전 성능 예측과 사후 성능 검증 관하여 정리하여 본다.

최근 세계 전력시장은 시장개방 및 통합, 환경규제 강화, 기술개발에 따라 신재생에너지 시장이 매우 빠른 속도로 성장하고 있다. 이와 발맞추어 최근 국제에너지 가격의 급등과 미국, 중국 등의 에너지안보 강화에 따라 신재생에너지는 미래 에너지원의 큰 축을 차지할 것으로 전망됨에 따라 EU 전력시장 내 전력회사들은 신재생에너지 시장을 핵심 사업영역의 하나로 추진하고 있다. 반면 국내 신재생에너지 시장은 정부 보급목표와 비교할 때 미미한 수준에 머무르고 있다. 이는 국내 신재생에너지 지원정책의 한계와 시장의 구조적인 문제점에 기인하는 것으로 분석된다. 따라서 본 논문에서는 EU 신재생에너지 시장의 분석을 통해 국내 신재생에너지 시장 확대를 위한 대안과 국내 전력회사들의 역할 및 시장진입전략을 살펴보고자 한다.

풍력발전의 보급확대는 전력시장의 특성으로 인하여 국가적 차원의 정책에 의존될 수밖에 없는 태생적 한계를 지니고 있다. 역설적으로, 풍력발전은 정부기획에 의하여 시장조성(설계)이 가능하고, 따라서 풍력발전과 관련한 설비제조업, 발전사업 단지건설업 및 서비스업 등으로 구성되는 '풍력산업' 은 국가적 차원의 적정한 정책 수단으로 육성될 수 있는 새롭게 부상하는 산업부문이다 선진 외국의 전력시장에서 관찰되는 풍력산업의 출현 및 성숙과정을 참고로, 우리나라에서의 풍력발전의 보급확대를 위한 전략을 원론적 차원에서 모색하고자 하였다. 기술경영학적 관점에서 풍력산업의 육성도 결국 '기술주도'가 아닌 '시장주도에 의한 것이 효과적일 수밖에 없으며, 풍력발전의 보급확대를 통한 수요의 창출은 에너지믹스(Energy Mix)와 관련한 국가차원의 정책적 의지와 선택의 문제일 뿐이다

목질계 바이오매스는 신재생에너지원에 비해 국내 잠재량이 가장 풍부한 에너지원 가운데 하나이다. 그러나 주요 공급원인 간벌목 부산물의 10%, 폐목재의 1/3 정도만 활용되고 있다. 따라서 향후 관련법제도 개선 및 지원을 통해 바이오매스의 에너지 활용도를 높일 필요가 있다. 목질계 바이오매스를 이용하여 에너지를 생산할 경우 잠재적 기여도는 2005년 신재생에너지 공급량의 29.4%에 달하며, 신재생에너지의 일차에너지 소비대비 2.13%에서 2.76%로 증가시킬 수 있는 잠재력을 갖고 있다. 본 연구는 전국 16개 시도별로 잠재되어 있는 목질계 바이오매스 생산 가능량을 추정하고 이를 바이오열병합발전소의 주연료로 이용할 경우 지역별 경제적 파급효과를 분석해 보았다. 그 결과 경기, 서울, 전남, 경북, 강원, 충남 등에서 파급효과가 크게 나타났다. 지역별 파급효과를 합할 경우 부가가치 파급효과가 15,736억원, 고용효과가 2,630명으로 나타났다.

본 논문에서는 국내 기술을 활용하여 Sunbelt 지역에 설치된 50kW급 PV 실증 단지에서의 태양광발전을 대상으로 경제성을 분석하였으며, VLS-PV로의 성공적인 확장 가능성을 발견하였다. 이를 바탕으로 2008년부터 2017년까지의 10년 동안 연간 10MW급의 단계적 시스템설치를 통한 최종 100MW급의 VLS-PV 개발을 가정하여 경제성 분석을 수행하였다. 이 과정에서 과거 누적 PV 설비용량과 PV 시스템 가격사이의 관계를 경험곡선을 활용하여 분석하였으며, 이에 기초하여 2017년까지의 PV 모듈 및 PV시스템의 가격을 예상하였다. 현재 실증 단계에서의 발전단가는 567.2원/kWh으로 나타나 국내 태양광발전보다 낮은 발전단가를 보였으며, 가격 하락 효과를 적용한 100MW급의 VLS-PV 시스템 개발시에는 최종 305.4원/kWh이 될 것으로 전망되었다. 향후 기술혁신에 따른 모듈의 효율향상과 시스템 수명의 증가는 경제성을 더욱 향상시킬 것이며, 환경적인 이점 및 정책적인 효과까지 고려할 경우 향후 20년 이내에 기존의 발전원과 비교하여 충분한 경쟁력을 확보할 수 있을 것으로 예상된다.

현재 직면하고 있는 고유가 고착화, $CO_2$ 저감 의무화에 대비하기 위해서는 신재생에너지 보급 확대는 필수적이며, 현재로서는 신재생에너지 시설중 보급효과가 큰 분야가 바로 태양열시스템이다. 그런데 태양열시스템 보급을 확대하기 위해서는 시스템의 신뢰성 향상은 물론이고 보급이 효과적으로 확대될 수 있는 분야에 대한 시스템 적용기술의 개발에 따른 산업화이다. 여기서는 지금까지의 보급문제점, 기술개발 현황 및 산업육성 정책 분석을 통해 국내 태양열산업 발전방향을 살펴보았다.

Small hydropower, one of renewable energies, is the clean energy which emits no carbonic acid gas. It has noting to do with global warming. It is a useful resource to contribute to the dispersion of power. Because of ballooning oil prices, the need for small hydropower is increasing. Recently small hydropower development using dams, small rivers, reservoirs, water pipes, sewage treatment plants and cool ing water of thermal power plants is conducting. By suggesting the strategy of the enlargement revitalization of small hydropower development, we hope to waken the people's interest in the small hydropower

Bioenergy emerges as a promising option for achieving the sustainable growth. However, bioenergy has poor cost competitiveness to the fossil fuels such as oil and coal. So many countries either developed or developing actively works for the implementation of various bioenergies. In this paper, the various supporting policies for the activation of the bioenergy business in the developed countries have been analyzed. Through the work, the desirable strategy for the promotion of bioenergy in our country have been suggested.

The present paper describes the scale effect correction method for wind turbine by using CFD(computational fluid dynamics). For the correct ions of wind turbine scale effect, various researches on the helicopter rotor scale effect were Investigated and feasibility study of methods was performed to correct wind turbine scale effect The present paper also introduces new scale effect correction method based on two dimensional lift slope modification. In order to test the Present method, performance analyses of NREL Phase VI wind turbines under various scale conditions were carried out by using CFD. The present method showed reasonable results when applied to NREL Phase VI wind turbine.

풍력터빈 풍동시험의 경우 모델 축소에 의한 레이놀즈 수 감소가 ?V력터빈 성능에 미치는 영향이 적절히 고려되어야 한다. 본 연구를 통해 수치해석과 축소모델 풍동시험을 통해 모델 축소효과를 파악하여 이를 적절히 보상하는 기법을 개발하고자 한다. 이를 위해 풍력터빈 형상 및 실물모델 시험데이터가 공개되어 있는 NREL Phase VI 모델을 표준모델로 선정하여 수치해석 및 풍동시험을 수행하였다. 풍동시험은 KARI LSWT에서 2006. 10에 수행되었으며, 블레이드 끝단 속도를 실물 모델과 일치시켰으며 시험부 유속은 $0{\sim}25m/s$, 블레이드 설치각은 3도 조건을 기준조건으로 사용하였다. 축소모델 시험결과 최대토크는 약 10% 정도 감소현상을 보이고 있다.

Recently, the interest for renewable energy producing system is increasing rapidly. Among these, the wind turbine is most highlighted. It is installed at severe environment and generate electricity for a long time to exceed in 20. Components of wind turbine are required high reliability. Therefore, structural strength analysis for wind turbine is needed an accurate FE model. This paper is to provide reliable fine element modeling method of yaw bearing for wind turbine.

BEMT나 wake method와 같이 2-D 에어포일의 데이터를 성능과 하중 해석에 이용하는 기법의 경우 에어포일 데이터의 정확도는 전체 결과에 큰 영향을 미친다. 풍력 블레이드와 같은 회정익에서는 2-D 에어포일 데이터를 실험 등을 통하여 정확히 얻어서 적용 시키더라도 예측 결과는 실제값과 큰 차이를 보이는 경우가 많다. 이는 회전익의 유동 특성에 의해 발생하는 실속 지연의 효과로 인한 것이며 이것은 입력에 사용되는 에어포일 데이터에는 반영되지 않으므로 자체적인 보정이 필요하다. 본 연구에서는 이러한 문제를 해결하기 위해 현재 제시되어 있는 실속 지연 모델을 살펴보고 이를 불레이드의 성능과 하중 해석에 저용시켜 보아 그 유효성에 대하여 살펴보았다.

This paper presents a design approach for wind power generator. Among several different generator systems, doubly-fed induction generator(DFIG) is selected for Hyosung 2MW wind turbine system from the view of cost and weight. The time step finite element method is applied to analyze the performance of DFIG, and design of experiment(DOE) is used as an optimization method.

This paper describes the effects to wind turbine blade aerodynamics due to interaction between blade and tower on upwind type HAWT. In order to analyze effects of blade-tower interact ion, the analyst s program WINFAS which is based on VLM(Vortex Lattice Method), Free wake and FVE model is used. In this study, the changes of wind turbine blade aerodynamics caused by blade-tower interact ion are Investigated with various parameters windshear, yaw error, TSR and tower diameter.

Performed fatigue strength analysis for Hub to get the targeted service life of 20 years. ANSYS is used to analysis. The major structure of bearing which connect the hub and blades is modeled using the element of LINK10. To represent the stiffness of LINK10 element, initial strain and diameter of LINK10 element is applied. Prior to calculating the fatigue damages, the influence matrix is extracted from the unit loads. The target service life of 20 years is achieved from the Analysis results.

Load analysis software enables to design wind turbines effectively and exactly. In this paper, Bladed software developed by Garrad Hassan and Partners is used for load analysis. When using Bladed software, many time is requested to input data which is called by pre-processing. So in this paper, pre-processing Is automated by in-house software(BX) With this BX software, we can reduce the total time for pre-processing about 90%.

신재생에너지의 효율 향상을 위한 시스템 개발과 병행하여 검토되어야 할 부문이 경제성 분석이다. 본 논문은 제주도 전력계통에 연계하여 운영중인 풍력발전의 자원과 발전량을 모의하기 위하여 제주도의 전력수요와 발전설비 특성, HDVC 수전 데이터, 풍속 등의 자료를 기반으로 가격예측을 위한 범용 소프트웨어들을 사용하여 에너지 시장 측면에서 풍력발전이 갖는 경제적 가치를 분석하였다.

This paper deals with the possibility on the hybrid power system concerning wind energy at a really existing island, Sunyoo-do in the west sea near Seamangeum. In the present stage, Diesel system produces all the electrical power of the Island. However, in the new proposed system of Diesel and wind energy, an optimized guideline for drive from the economic analysis on this hybrid system is given by a mathematical and statistical modelling with a share software HOMER (hybrid optimization model for electric renewables). After a series of analysis it has been shown that the hybrid system can reduce the total expenses as well as air pollution.

As the needs of wind energy increase, the more sites for the wind farm are required. As a part of searching for the prominent wind farm site, specially for offshore wind farm, we chose 4 sites along the southern part seashore of JeonNam province based on the analysis of the data gathered by meteorological observatory ud have gathered wind data for more than a year by use of 40m Met masts installed in the representative locations, ie. small islands of 4 different bay area. The siting for the Met masts were very limited by the geographical circumstances The wind data of those areas show a little lower annual average wind speeds, for the wind farm development, of 4m/s to 5.5m/s at the height of 40m above the ground level of the respective islands. The detail figures of one year wind data of those area are presented in this report.

To get the better efficiency in Korean type wind characteristics, a new wind turbine blade was developed with some structural, vibrational, and aero-elastic analysis for the design of the full-scale blade. A series of full domestic technology from design to manufacturing was created and used in the middle of the development of nelv wind blade. And it was equipped and measured at the wind test side in the Jeju island. After test, it is verified that the blade has the regular capacity of 10kW at the air velocity of 10m/s. And it shows better capacity in the low air-velocity compared to the imported blade. therefore it can be made by only domestic technology, and used for the domestic wind distribution with the better power generation.

Control algorithms and implementation issues for a wind turbine simulator are presented for realistic emulation of variable wind characteristics using a lab-scale motor and generator set. When the average wind speed nd turbulence level is given, the torque reference of prime mover is decided through various blocks, such as random wind speed generator, blade characteristic curves, and tower effect compensation. The variable nature of wind can be implemented and tested by not only the computer simulation but also the hardware-in-loop-simulator (HILS). Some application examples of HILS include the development and test of turbine control software for more efficient and stable operation. Feasibility of the proposed simulator has verified by computer simulations and experiment.

Recently the wind farm is constructed all over the world according to the lack of the resources. The spacing between front and rear wind turbines to construct the wind farm. The wake of front wind turbine has a bad effect on the performance of the rear wind turbine. A basic CFD study on the wake effect of HAWT for construction of wind farm was done by the FLUENT. This study shows the wake of front wind turbine and the results of this study will be used to calculate the spacing between front and rear wind turbines

Tower shell design is very important because tower takes about 20% of overall wind turbine cost. This paper contains procedure of tower analysis and optimization content. Some of requirements like eigenfreauency and buckling evaluated by numerical method, strength, are derived by analytic method. But strength and fatigue can be derived by mathematical method simply.

This paper introduces a radio-wave interference assessment of wind turbines that were planned to be installed at Homi-Cape in Pohang region where wind resource has been evaluated worthwhile developing a wind farm. In that area, AM radio station with two antennas and a harbor radar facility are located so that radio-wave coupling is inevitable if the wind farm is designed without considering radio-wave environmental impact. A low-frequency analysis using MoM (Method of Moment) is used to examine interference effect caused by wind turbines and an optimal layout minimizes coupling effect is presented.

The national goal of wind energy dissemination has to be determined rationally based on technically available wind resource potential. For a reliable and scientific estimation or wind resource potential, a wind map is requisite. This paper presents the national wind map of Korea established by numerical wind simulation. Prediction accuracy of the low-resolution wind map is Improved by nudging QuikSCAT data and is validated by comparing with marine buoy beacon and met-mast measurements. Therefore, quantification of national wind resource potential is now possible and is anticipating to be utilized as a core index for policy and strategy building of wind energy dissemination and technology development.

Proper water management is important to achieve high performance and durability of Polymer electrolyte fuel cell (PEFC). Among various stack components, gas diffusion layer (GDL) is considered as a core part to determine the gas and water transportation in a cell. To optimize the water management, the changes of properties as well as basic properties of GDLs were investigated before and after clamping of colls. Thickness, electric conductivity, porosity, hydroppobicity etc. were characterized by the same criteria. The amount of residual water after cell operation also was compared by direct measuring of weight. Based on the amount of residual water the endurance on the freeze condition was evaluated.

There is a worldwide interest in the development and commercialization of Polymer Electrolyte Membrane Fuel Cells (PEMFCs) for vehicular and stationary applications. One of the major objectives is the reduction of loaded electrode materials, which is comprise of the Pt-based noble metals. In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the deposition of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled active materials were formed on the surface of carbon-supported Au nanoparticles. The structural and electrochemical analyses indicate that the active materials were deposited on the surface of Au nanoparticles selectively and that an at toying process occurred during the successive reducing process The carbon-supported & surface-alloys showed the higher electrocatalytic activity than those of the particle-alloys and commercial one (Johnson-Matthey) for the reaction of methanol and formic acid oxidation. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

A numerical study is made of a manifold and bipolar plate in polymer electrolyte fuel cells, the aim of the present study is to describe the characteristics of flow pattern In manifold and bipolar plate. The present work shows that the flow pattern in the bipolar plate is affected by the penetration flow through GDL characterized by clamping pressure and GDL intrusion in to a channel area. Manifold geometry also affects the flow distribution. The recirculation flow by bent duct destroy even distribution In manifold, the present work shows that corner rounding can improve the manifold performance.

Nb and Ti were added to 316 stainless steel, and then heat-treatments and surface treatments were performed on the 316 stainless steel and the Nb- and Ti-added alloys. All samples indicated enhanced electrical conductivity after surface treatments, whereas they showed low electrical conductivity before surface treatments due to the existence of non-conductive passive film on the alloy surface. In particular, the Hb- and Ti-added alloys showed remarkable enhancement of electrical conductivity compared to the original alloy, 316 stainless steel. Surface characterization revealed that small carbide particles formed on the alloy surface after surface treatments, while the alloys indicated flat surface structure before surface treatments. $Cr_{23}C_6$ mainly formed on the 316 stainless steel, and NbC and TiC mainly formed on the Nb- and Ti-added alloys, respectively. We attribute the enhanced electrical conductivity after surface treatments to the formation of these carbide particles, possibly acting as a means of electro-conductive channel through the passive film. Furthermore, NbC and TiC are supposed to be more effective carbides than $Cr_{23}C_6$ as electro-conductive channels of stainless steel

고분자 전해질 연료전지의 전극을 gradient catalyst coating 방법을 이용하여 제조하였다. 촉매 잉크제조 시 나피온 이오노머의 함침 구성비를 다르게 하여 조성 비율이 다른 gradient 구조를 갖도록 하여 전극을 제조하였다. Anode Cathode의 두 전극을 각각 나피온 함량비가 다른 두 개의 gradient 층구조의 촉매층으로 9:1, 8:2, 7:3, 6:4 비율의 조성비로 성능을 측정하였으며, 전극의 전기화학적 반응 면적을 알아보기 위해 순위전위법을 그리고 분극 저항(Polarization resistance) 변화를 알아보기 위해서는 0.7V에서 임피던스 측정법의 전기화학분석법으로 전극 제조법에 따른 성능변화를 확인하였다. 특히 Gradient catalyst coating 방법을 이용하여 제조한 MEA는 종래 방식의 MEA보다 high current $density(1000mA/cm^2)$이상에서 향상된 성능을 보였다.

연료전지용으로 많이 사용되는 전불소계 고분자인 Nafion은 좋은 기계적, 화학적 안정성 및 높은 이온전도도에도 불구하고 고가의 생산단가, 높은 메탄올 투과도, 그리고 MEA 재활용 문제 등으로 인해 상업적 응용에 제한이 있다. 본 연구는 불소그룹을 함유한 술폰화된 아릴렌이서계 블록 공중합체 고분자 전해질막의 제조 및 연료전지 특성에 관한 것이다. 이러한 고분자를 제조하기 위하여 양말단에 불소계 비닐기를 가지면서, 상온에서 술폰화 가능한 biphenyl계 단량체와 술폰화가 불가능한 sulfonyl계 단량체를 각각 합성하였으며, 이들로부터 다양한 몰조성과 분자량을 갖는 올리고머를 포함한 일련의 perfluorocyclobutane기를 포함하는 블록 공중합체를 열적 고리화 부가중합을 사용하여 합성하였다. 제조된 블록 공중합체를 상온에서 술폰화제인 chlorosulfonic acid를 이용하여 선택적으로 후술폰화시켜 강산 이온기인 sulfonic acid를 블록 올리고머에 도입하였다. 합성된 고분자들의 연료전지 특성을 Nafion-115와 비교하였다. 술폰화가 되는 올리고머 블록의 비율 증가에 따라 이온교환능력이 증가하였고, 그에 따라 높은 함수율과 이온 전도도를 나타내었으며 건조 및 습윤 상태에서도 기계적 강도가 우수하였다. 최적화된 블록공중합체를 대상으로 MEA를 제조하여 연료전지 초기성능을 측정한 결과 Nafion과 유사한 전기화학적 성능을 나타내었다.

전극 전해질 복합체가 하나로 구성된 단위전지는 전기출력이 낮아 원하는 전기출력을 얻기 위하여 단위전지를 여러 장 직렬로 쌓아 스택을 구성하여야 한다. 본 연구에서는 400W급 직접메탄을 연료전지 스택을 제조하여, 운전 조건의 최적화를 위한 실험을 수행하였고, 한국형 휴머노이드 로봇인 Hubo에 적용하여 그 동특성을 평가하였다. 0.8M 메탄을 용액은 260 ml/min의 유량을, 공기는 42LPM을 스택에 주입하여 400W의 성능을 나타내었다. 연료전지 스택의 온도와 전압의 편차는 작았으며 정상 운전시스템의 온도는 약 $70^{\circ}C$를 유지하였다. 로봇의 필요 전력이 높을 경우, 배터리와 연료전지가 동시에 부하 변동에 대응하였다 방전된 배터리는 로봇의 필요 전력이 낮아질 경우, 충전되어 이후의 방전 상황에 대비하였다. 연료전지 시스템 적용 결과 로봇의 성공적인 운전을 확인할 수 있었다.

With the steady depletion off fossil fuel reserves, hydrogen based energy sources become increasingly attractive. Therefore hydrogen production or separation technologies, such as Bas separation membrane based on adsorption technology, have received enormous attention in the industrial and academic fields. In this study, the transport mechanisms of the MTES (methyltriethoxysilane) templating silica/a-alumina composite membrane were evaluated by using unary, binary and quaternary hydrogen gas mixtures permeation experiments at unsteady- and steady-states. Since the permeation flux in the MTES membrane, through the experimental and theoretical study, was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously in the membrane according to molecular properties. In order to depict the transient multi-component permeation on the templating silica membrane, the GMS (generalized Maxwell-Stefan) and DGM (dust Bas model) were adapted to unsteady-state material balance

In this paper, heat and mass transfer characteristics through experimental and numerical study are extensively investigated in steam reform ins reactor under given operating conditions. In order to get simulated data at outlet of the reformer, heterogeneous reactor model is incorporated. As the reaction also takes place in porous media, two medium approach is used to take into account thermally non-equilibrium phenomena between catalyst and bulk gas. In steam reforming reaction, heat transfer issue is so significant that geometrical configuration study is also conducted.

탄화수소 연료(LNG, LPG)를 개질하여 수소를 제조하는 연료 처리 공정 중, 탈황 기술은 촉매의 활성저하 및 전극의 피독을 방지하기 위한 필수 기술이다. 본 연구에서는 도시가스 및 액화석유 가스용 부취제로 사용되는 유기 황화합물(,DMS, THT, TBM)을 제거하기 위한 탈황제로서 Cu/ZnO계 흡착제를 개발하였다. 공침법을 이용하여 흡착제를 제조하여 각 부취제별로 상온 및 고온에서의 흡착탈황 성능을 조사하였으며 또한, 이의 특성분석을 행하였다. $Cu/ZnO/Al_2O_3$ 탈황제는 메탄으로부터 고온에서 TH, DMS, TBM+THT 등의 황화합물들을 매우 효과적으로 제거할 수 있었다. 특히, TBM+THT의 혼합가스에서 TBM에 대해 선택적인 흡착을 보였다. THT 흡착에서 흡착온도가 $300^{\circ}C$ 이상에서는, 흡착과정 동안 황의 상호작용으로 인해 금속황화물이 생성되었다.

Bipolar plate, which forms about 50% of the stack cost, is an important core part with polymer electrolyte membrane in PEMFC. Bipolar plates have been commonly fabricated from graphite meterial having high electrical conductivity and corrosion resistance. Lately, many researchers have concentrated their efforts on the development of metallic bipolar plate and stainless steel has been considered as a potential material for metallic bipolar plate because of its high strength, chemical stability, low gas permeability and applicability to mass production. However, it has been reported that its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions and an increase in contact resistance by the growth of passive film therefore, its corrosion resistance as well as contact resistance must be improved for bipolar plate application. In this work, several types of coating were applied to 316L and their electrical conductivity and corrosion resistance were evaluated In the simulated PEMFC environment. Application of coating gave rise to low interfacial contact resistances below $19m{\Omega}cm^2$ under the compress force of $150N/cm^2$. It also made the corrosion potential to shift in the posit ive direct ion by 0.3V or above and decreased the corrosion current from ca. $9{\mu}A/cm^2$ to ca. $0.5{\mu}A/cm^2$ in the mixed solution of $0.1N\;N_2SO_4$ and 2ppm HF A coat ing layer under potentiostatic control of 0.6V and $0.75V_{SCE}$ for 500 hours or longer showed some instabilities, however, no significant change in coat Ing layer were observed from Impedance data. In addition, the corrosion current maintained less than $1{\mu}A/cm^2$ for most of time for potentiostatic tests. It indicates that high electrical conductivity and corrosion resistance can be obtained by application of coatings in the present work.

As the stainless steel has good corrosion resistance, mechanical property and ease of manufacture, it has been studied as the candidate material of metallic bipolar plate for automotive PIMFC. But, metal is dissolved under fuel cell operating conditions Dissolved ions contaminate a membrane electrode assembly (MEA) and, decrease the fuel cell performance. In addition, metal oxide formation on the surface of stainless steel increases the contact resistance in the fuel cell. These problems have been acted as an obstacle in the application of stainless steel to bipolar plate. Therefore, many kinds of coating technologies have been examined in order to solve these problems. In this study, stainless steel was coated in order to achieve high conductivity and corrosion resistance by several methods. Contact resistance was measured by using a tensile tester and impedance analyzer Corrosion characteristics of coated stainless steel were examined by Tafel-extrapolation method from the polarization curves in a solution simulating the anodic and cathodic environment of PEMFC. Fuel cell performance was also evaluated by single cell test. We tested various coated metal bipolar plate and conventional and graphite were also tested as comparative samples. In the result, coated stainless steel bipolar plate exhibited better cell performance than graphite to bipolar plate.

고분자전해질 연료전지의 MEA를 CCM (Catalyst Coated Membrane) CCS(Catalyst Coated Substrate) 형태로 각각 제조하고 백금담지 비율이 서로 다른 백금 담지촉매를 각각 적응하여 MEA를 CCM형태로 제조하여 단위전지 성능평가를 수행하였다 백금담지 비율이 다른 촉매를 적용한 CCM형태 MEA의 표면을 SEM (scanning electron microscopy)으로 분석하였으며, 단위전지 성능평가를 수행하는 동시에 EIS (Electrochemical Impedance Spectroscopy)를 통하여 MEA의 저항을 분석하였다. 고분자전해질 연료전지의 성능은 MEA의 제조방법과 백금담지 촉매의 백금담지비율에 따라 크게 변함을 확인 할 수 있었다.

We synthesized $(La,\;Sr)MnO_{3+{\delta}$ as a cathode for SOFC by glycine nitrate process(GNP) and knew the different properties of $(La_{1-x}Sr_x)MnO_3$ by using nitrate solution and oxide solution as starting material. In case of using nitrate solution as a starting material, main crystal phase peak of $LaMnO_3$ increased as Sr content added up and a peak of $Sr_2MnO_4\;and\;La_2O_3$ was showed as a secondary phase. We added Mn excess to control a crystal phase. In this case, the electrical conductivity had a high value 210.3S/cm at $700^{\circ}C$ On the other side, when we used oxide solution as a starting material, we found main crystal phase of $LnMnO_3$ to increase as Sr content added up and a peak of $La_2O_3$ as a secondary phase. Similary, we added Mn excess to control a crystal phase in this case. We knew $(La,\;Sr)MnO_3$ powder to sinter well and the electrical conductivity of the sintered body at $1200^{\circ}C$ for 4hrs was 152.7s/cm at $700^{\circ}C$. The sintered $(La,\;Sr)MnO_3$ powder at $1000^{\circ}C$ for 4hrs got the deoxidization peak, depending on the temperature md in case of using nitrate solution as a start ing material the deoxidization peak was showed at $450^{\circ}C$ which is lower than used a oxide solution as a starting material. As a result, when $(La,\;Sr)MnO_3$ powder was synthesized to add Mn excess and to use nitrate solution as a starting material, we found it to have the higher deoxidization property and considered it as a cathode for m properly. And we found it to have different electrical conduct ivity the synthesized $(La,\;Sr)MnO_3$ powder by using different start ing materials like nitrate solution and oxide solution which influence a sintering density and crystal phase.

The decrease of polarization resistance in cathode is the key point for intermediate temperature SOFC(Solid Oxide Fuel Cell). In this study, the Influence of Co substitution in B-site at perovskite PSCM (Pr0.3Sr0.7CoxMn(1-x)) was investigated. The PSCM series exhibits excellent MIEC(Mixed ionic Electronic Conductor) properties. The ASR(Area Specific Resistance) of PSCM3773 was $0.174{\Omega}cm^2\;at\;700^{\circ}C$. The activation energy of PSCM3773 was also lower than other compositions of PSCM. The ASR values were increased gradually during the thermal cycling test of PSCM37773 due to the delamination between electrolyte and cathode materials.

[ $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ ] cathode as a high performance cathode on YSZ electrolyte was studied by analyzing impedance spectra. It was shown that cathode property of $La_{0.8}Sr_{0.2}Co_{1-x}Mn_xO_3$ is bet ter than that of$La_{0.8}Sr_{0.2}CoO_3$. At $700^{\circ}C$ in air environment, $La_{0.8}Sr_{0.2}Co_{0.4}Mn_{0.6}O_3$ cathode on CGO- layered YSZ electrolyte showed very low area specific resistance of $0.14{\Omega}cm^2$, which is low enough for intermediate-temperature sol id oxide fuel cells. This is because material properties of ionic conductivity and thermal expansion compatibility with electrolyte were optimized. Judging from activation energy and oxygen part i al pressure dependance of cathode property, it was noted that oxygen surface exchange kinetics is dominantly influential on cathode property in higher temperature region than $700^{\circ}C$ and oxygen self-diffusion in cathode material is more influential in lower temperature region.

SOFC is a high temperature fuelcell with many advantages, but it also have several demerits. One of the Issues is cathode poisoning of Cr coming from stainless steel interconnects. Diffusion process of Cr evaporated from the surface of interconnect steel was calculated by using CFD technique to understand factors for Cr deposition. It has been cleared that factors concerned in Cr deposition and how they affect Cr deposition. Major variables for Cr deposit ion are diffusion coefficient, air velocity and temperature If diffusion coefficient decreases, Cr concentration increases in the air but decreases on the cathode surface. Increasing in air velocity, Cr concentration decreases in the air and on the cathode surface. Increase in temperature leads to rising Cr concentration on the cathode surface because of diffusion coefficient increment.

In this paper, stack voltage monitoring module is developed which monitor cell voltage of the fuel cell stack and transfer it to the main controller for monitoring fault and stopping drive when the trouble is happened in the fuel cell stack. Especially, the circuit, for monitoring each cell voltage of several hundreds cells in stack, is designed and analyzed. The connector is also developed for making wire harness simple and low cost because wire harness is complicated when the cells are connect each monitoring circuit.

수소는 미래의 청정에너지원이다. 수소를 생산하는 효과적인 방법으로는 탄소계촉매를 이용하여 부탄을 분해하는 것이다. 촉매는 카본블랙이 사용되었으며, $500{\sim}1100^{\circ}C$의 온도 범위에서 열분해 반응과 촉매분해반응이 수행되었다. 열분해의 경우 온도가 증가함에 따라 전화율이 증가하여 $800^{\circ}C$에서 98.9%로 부탄이 거의 분해되었으며, $900^{\circ}C$ 이상의 온도에서는 전화율이 100%까지 도달하였다. 부탄 분해반응에서 기대되는 생성물은 메탄, 에틸렌, 에탄, 프로필렌, 프로판 등이다. $1000^{\circ}C$이상의 온도에서는 부탄 촉매 분해반응에서 거의 대부분 수소와 메탄만이 관찰되었다. 특히 $500-1100^{\circ}C$까지 온도가 증가하였을 때 수소의 생성율은 꾸준히 증가하는 것으로 확인되었고 촉매분해반응이 촉매를 사용하지 않은 열분해반응보다 온도가 증가함에 따라 수소의 선택도를 더욱 향상시켜 보다 많은 수소가 생성되었으며, 반응성 실험이 진행되는 동안 촉매의 비활성화는 관찰되지 않았다. 반응전후의 촉매의 특성을 분석하기 위해 TEM 및 SEM 분석을 하였다. 반응전의 촉매는 매끈한 모양이었으나 $1000-1100^{\circ}C$에서 반응후에는 표면에 돌기모양을 형성하는 것을 관찰할 수 있었다.

수소 스테이션에서 사용할 수 있는 Compact 형 수소 PSA를 연구하였다. 기존의 수소 PSA 가 수소 스테이션에서 공간적 제약이 있기 때문에 그 부피를 줄이면서, 또한 효율을 높이기 위해 Compact형 수소 PSA를 고안하였다. Compact형 수소 PSA는 하나의 bed안에 다른 하나의 bed를 넣음으로써 시스템이 차지하는 부피를 줄이는 한 건, inner bed와 outer bed 사이의 열교환 효과가 나타나기 때문에 그 효율을 높일 수 가 있다. 흡착탑의 동특성을 파악하기 위하여 4성분 (H2/CO2/CH4/CO, 69:26:3:2 vol. %)의 가스를 Feed rate 7LPM, Adsorption Pressure 9atm의 조건으로 실험을 하였다. Inner bed와 outer bed의 흡착 동특성의 차이를 알아보고, PSA 공정을 가상으로 하여 각각의 탑에서 흡착과 탈착이 동시에 일어날 때의 동특성도 알아보았다. 그리고 AD step time을 달리 하면서 PSA 공정에 알맞은 Sequence을 알아보았다.

A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2-free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor The propane decomposition rate used carbon black DCC-N330, Hi-900L as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600-800^{\circ}C$, propane gas velocity of $1.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature on the reaction rates was investigated. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

In this work, the reinforcing action of carbon blacks in rubber was investigated by SEM and UTM measurements which at low a testing of the surface and mechanical properties. In order to gain an insight into the different properties between carbon blacks before and after methane/propane decomposition, various composites were prepared with SBR synthetic rubber and different carbon blacks with four loading ratios. The results were analyzed with the aim of finding suitable conditions for decomposition reaction to cut down the net cost for hydrogen production through hydrocarbon decomposition.

PdPt/C (Pd:Pt atomic ratio of around 19:1 60wt, %) 촉매를 고분자전해질 연료전지용 전극 촉매소재의 적용하였다. PdPt/C 촉매를 산화극 촉매로, 환원극 촉매로는 Pt/C 촉매를 사용하고 반대로 산화극 촉매는 Pt/C 촉매, 환원극 촉매로는 PdPt/C 촉매를 사용했을 때, PdPt/C 촉매를 산화극과 환원극 촉매로 동시에 사용했을 때의 고분자전해질 연료전지의 단위전지 성능을 각각 비교하였다. PdPt/C촉매를 산화극에만 적용했을 때에 Pt/C 상용촉매를 산화극과 환원극에 모두 적용했을 때의 성능만큼 좋은 성능을 확인할 수 있었다. 환원극 촉매는 Pt/C를 사용하고 산화극 촉매를 PdPt/C Pt/C Pd/C를 사용하였을 매의 성능을 비교하였다. Pd/C를 산화극 촉매로 사용한 단위전지가 나머지 두 경우의 성능에 비하여 현저히 떨어짐을 확인할 수 있었다. 이는 극소량의 Pt 량을 포함한 PdPt/C 촉매가 고분자전해질 연료전지의 산화극 Pt/C 촉매의 대체촉매로 사용 가능함을 보여준다.

현재까지 연료전지 전해질 막으로는 Nafion으로 잘 알려져 있는 perfluorosulfonic acid(PFSA)막이 주를 이루고 있다. 이 막들은 $80^{\circ}C$ 이하의 낮은 온도의 연료전지에서 가장 좋은 성능을 보인다. PFSA 막들은 탄소-불소로 이루어진 사슬의 특성상 산화, 환원의 조건에서도 뛰어난 안정성을 보이며 이온 전도도가 0.1S/cm 이상으로 기존에 알려진 전해질 막들 중 가장 우수한 성능을 나타낸다. 하지만 연료전지의 작동온도가 $100^{\circ}C$ 이상의 높은 온도에서 는 막에 존재하던 수분이 제거되면서 수소이온 전도도가 떨어지며 기계적 물성도 떨어지는 문제점을나타낸다. $100^{\circ}C$ 이상의 온도에서 연료전지를 작동시키면 양쪽의 전극에서 일어나는 촉매반응의 속도가 향상되며, 물의 끓는점 이상에서 작동되므로, 전지 내에서 다양한 상을 고려하지 않고 기화된 물만을 고려하여 설계를 할 수가 있다. 따라서 최근 이러한 고온/저가습 운전을 위 한 전해질 막의 개발을 위해 기존의 Nafion 막에 전도성 무기 입자를 도입하는 연구들이 활발히 진행되고 있다. 본 연구에서는 전도성 무기 입자로서 $ZrO_2$나노입자를 합성하고, 이를 상용 10 wt.% Nafion 용액에 분산하여 solution casting 방법을 통해 $61{\mu}m$ 두께의 유기-무기 복합막을 제조하였다. 제조한 유기-무기 복합막의 성능 평가를 위하여 함수율, 이온 전도도, 당량무게 및 단위 전지를 이용한 전류-전압 곡선을 측정하여 상용 Nafion 112 막과 비교해 보았다. $ZrO_2$ 입자는 전도성이며 동시에 친수성을 나타내기 때문에 상용 막에 비하여 함수율 및 수소이온 전도도가 우수하게 나타났다. 복합막의 이러한 물성은 $100^{\circ}C$이상의 고온에서 전해질 막 내의 물 관리를 용이하게 한다. 단위 전지 운전 온도 $130^{\circ}C$, 상대습도 37%의 운전 조건에서도 상당히 우수한 전지 성능을 보임에 따라 고온/저가습 조건에서 상용 Nafion 112 막보다 우수한 막 특성을 나타냄을 확인하였다.

본 연구에서는 양극의 two-phase simulation 모델을 확립하고 GDL 물성과 작동조건이 전지성능에 미치는 영향에 대해 시행하였다. 모델로는 Multi-phase $mixture(M^2)$ 모델을 사용하였는데 이 모델은 각 상의 balance식을 하나의 mixture-phase식으로 통합하여 수학적 계산이 용이할 뿐만 아니라 실제 전지 성능에 매우 근사하여 신뢰성성도 확보할 수 있었다. 최적의 GDL 구조와 작동조건을 규명하기 위해 기체투과도, 접촉각, 기공도, 기체 공급가스 차이에 따른 전지 성능 분석을 시행하였는데 그 결과 모든 파라미터들이 증가할수록 비례적으로 전지 성능이 증가하였다. 기체 공급가스>기공도>>접촉각>기체투과도 순으로 전지에 미치는 영향이 큰 것으로 나타났다.

Selection of flow channel in the separation plate of PEMFC is very important parameter to improve its performance and reduce parasite loss. Flow patterns in the channel have great influence on the transport of hydrogen and all and water generated from electrochemical reaction in diffusion layer In this study, fluid flow in flow channel with parallel and interdigitated patterns are simulated three dimensionally on full flow domain including anode and cathode electrode together. The numerical results show that the fuel cell with interdigitated flow channel represents better performance than that with parallel flow channel due to its strong convective transport across the gas diffusion layer. But the pressure drop in parallel flow channel is much more than that in nterdigitated flow channel. The effect of temperature and stoichiometric number on performance can be calculated and analyzed as well.

PEM(proton exchange membrane) fuel cell have been receiving considerable interest as power source because of high-energy efficiency. However by using reforming hydrogen gas, CO poisoning occur in anode. To improve CO tolerance PtRu catalysts were prepared by galvanostatic pulse electrodeposition. The composition(atomic ratio) of catalysts are controllable by using different concentrations of PtRu solutions. Also, the particle sizes of PtRu on carbon are similar to about $3.5{\sim}4nm$ regardless of concentration.

PtRu catalyst is most widely used as anode catalyst for a direct methanol fuel cell(DMFC). To promote the efficiency of the catalysts, it Is important to increase the triple phase boundary. In this study, we have tried to increase the triple phase boundaries in preparing electrocatalysts of the fuel cells, based on the process of grafting a proton-conducting agent onto the catalyst This grafted proton-conducting agent can act as an ionomer like Nafion, currently widely used ionomer. First, we have prepared the 80wt% PtRu/Ketjen Black electrocatalyst by an improved colloidal method. And, we have grafted methylsulfonate groups $(-CH_2SO_3H)$ into the catalyst as proton-conducting agents. As results of cyclic voltammety and single cell test of the membrane electrode assembly (MEA), we can conclude that the activity of the grafted electrocatalysts is superior to that of conventional ones, in performance of DMFCs. For our further study, we will investigate the optimum ratio of catalyst/grafted proton conduct Ing agent with maximum performance of a DMFC.

FCEV uses electric energy generated from the reaction between Hydrogen and Oxygen in fuel cell stack as driving force. As fossil fuels are exhausted, fuel cell is regarded as a potent substitute for next generation energy source, and thus, most of car-makers make every efforts to develop fuel cell electric vehicle (FCEV). In addition, fuel cell is also beneficial in aspect of environment, because only clean water is produced during chemical reaction process instead of harmful exhausted gas. Generally, Hydrogen is supplied from high-pressured fuel tank, and air blower (or compressor) supplies Oxygen by pressurizing ambient air. Air blower which is driven by high speed motor consumes about $7{\sim}8%$ of energy generated from fuel cell stack. Therefore, the efficiency of an air blower is directly linked with the overall performance of FCEV. This study will present developing process of an air blower and its consisting parts respectively.

Nafion/Pt/Polypyrrole composite membranes were fabricated by chemical in-situ polymerization of pyrrole monomers with Pt precursors in Nafion matrix for DMFC. We demonstrated that positively charged pyrrolinum groups of polypyrrole particles were co-interacted with sulfonic groups of Nafion as verified by FT-IR results. Mutual interaction between $Nafion-SO_3^-$ (or negatively charged Pt precursors) and Polypyrrole$-NH_2^+$ influenced the physical properties of pristine Nafion. Thermal property proton conductivity, methanol permeability, and cell performance of pristine and modified Nafion were analyzed for an application of DMFC membrane. Thermal stabilities of sulfonic groups and side chains in Nafion/Pt/polypyrrole composite membranes were higher than those of Nafion due to mutual interaction between sulfonic groups of Nafion and pyrrolinum groups of polypyrrole. Methanol permeabilities of Nafion/Pt/Polypyrrole composite were reduced more proton conductivities with the increase in the content of Pt particles. As a result of that, the enhancement of cell performance by Nafion/Pt/Polypyrole O2 relative to Nafion was more pronounced under the specific experimental condition such as high temperature and more concentrated methanol solution.

Recently, Direct Methanol Fuel Cell (DMFC) for portable devices has been received much attention because DMFC has a possibility of higher energy density than electrical batteries and smaller size than other fuel cells. This paper presents the fabrication and test of a thermopneumatic microactuator with a phase change for DMFC. A microactuator consists of an inlet an outlet a chamber, a heater and a sensor of resistance temperature detector(RTD). The micoractuator is fabricated by the spin-coating process, the lithograph process, the deep RIE process and so on. The total size of microactuator is $20{\times}20{\times}0.53mm^3$. When the current is applied, the heater heats liquid in chamber. As a result the liquid vaporizes. The response of temperature in the chamber was measured using thermocouple The changed temperature is $3^{\circ}C$ for 5 sec at 0.032W.

Characteristics of heat and water transfer in gas-to-gas membrane humidifiers have been experimentally investigated for various humidity rod flow rates of gas and for different thickness of Nafion membrane. The results emphasizes the importance of flow velocity for both water and heat transfer. Also, the effect of membrane thickness has been revealed to be significant to water transfer especially for unsaturated flows, while the significance of membrane thickness is minimal to heat transfer.

Pt/Nafion self-humidifying membranes for Polymer Electrolyte Membrane Fuel Cell(PEMFC) were synthesized via supercritical-impregnation methods. The Nafion 112 membranes were impregnated with Pt(II)$(acetylacetonate)_2$ from a supercritical carbon dioxide $(scCO_2)$ solution at $80^{\circ}C$ and 30MPa. After the impregnation, the pressure decreased slowly by releasing $CO_2$. And the Pt-impregnated Nafion membrane was converted Pt deposited Nafion membrane by reducing agent, sodium borohydride $(NaBH_4)$ with various concentrations under $50^{\circ}C$ and 2 hours. The prepared Pt-impregnated Nafion (Pt/Nafion) composite membrane were investigated by Electron Prove Micro analysis (EPMA) and X-rat Diffraction analysis (XRD) which showed distribution of Pt particle and Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM) a which revealed morphology of surface of Pt/Nafion composite membrane. The performance of the Pt/Nafion 112 membranes was examined in PEMFC as aself-humidifyin membranes using purpose-built equipment.

The degradation of Nafion membrane by hydrogen peroxide was investigated in polymer electrolyte membrane fuel cell (PEMFC). Degradation tests were carried out in a solution of $10{\sim}30%$ hydrogen peroxide containing 4ppm $Fe^{2+}$ ion which is well known as Fenton's reagent at $80^{\circ}C$ for 48hr. Characterization of degraded membranes were examined through the IR, Water-uptake, Ion exchange capacity, mechanical strength and $H_2$ permeability. After degradation, C-F, S-O and C-O chemical bonds of membrane were broken by radical formed by $H_2O_2$ decomposition. Breaking of C-F bond which is the membrane backbone reduced the mechanical strength of Nafion membrane and hence induced pinholes, resulting in increase of $H_2$ crossover through the membrane. Also the decomposition of C-O and S-O, side chain and terminal bond of membrane, decreased the ion exchange capacity of the membrane.

Carbon-supported Platinum (Pt) is the potential electro-catalyst material for anodic and cathodic reactions in fuel cell. Catalytic activity of the metal strongly depends on the particle shape, size and distribution of the metal in the porous supportive network. Conventional preparation techniques based on wet impregnation and chemical reduction of the metal precursors often do not provide adequate control of particle size and shape. We have proposed a novel route for preparing nano sized Pt colloidal particles in solution by oxidation of ethylene glycol. These Pt nano particles were deposited on large surface area carbon support. The process of nano Pt colloid formation involves the oxidation of solvent ethylene glycol to mainly glycolic acid and the presence of its anion glycolate depends on the solution pH. In the process of colloidal Pt formation glycolate actsas stabilizer for the Pt colloidal particle and prevents the agglomeration of colloidal Pt particles. These mono disperse Pt particles in carbon support are found uniformly distributed in nearly spherical shape and the size distribution was narrow for both supported and unsupported metals. The average diameter of the Pt nano particle was controlled in the range off to 3 nm by optimizing reaction parameters. Transmission electron microscopy, CV and RRDE experiments were used to compliment the results.

Hydrogen separation from multi-component mixture gases by the four-bed PSA process was studied experimentally and theoretically using layered bed of activated carbon and zeolited 5A. Effects of the adsorption time, the linear velocity on the process performance were investigated. The adsorption time and linear velocity affected the purity and recovery of the product $H_2$ purity is increases according as the adsorption time and linear velocity decrease; however, $H_2$ recovery shows an opposite phenomena to the purity. PSA process simulation studied to find optimum operation condition. In the results, 50sec adsorption time, 3cm/s linear velocity might be optimal values to obtain more than 99.999% purity and 65% recovery hydrogen.

WGS reaction over Mo2C and ceria based catalysts was investigated to develop an alternative commercial Cu-Zn/Al2O3 catalyst for fuel processor and hydrogen station. The Mo2C catalysts were prepared by a temperature programmed method and the various metal supported cerium oxide catalysts were prepared by an Impregnation method. The catalysts were characterized by the N2 physisorption, Co chemisorption, XRD, TEM and TPR. It was found that Mo2C and 0.2wt% Pt-40wt%, Ni/CeO2 catalysts had higher activity and stability than the Cu-Zn/Al203 above $260^{\circ}C$. Moreover, CO conversion of more than 85% was observed at $280{\sim}300^{\circ}C$. But all catalysts were deactivated during the thermal cycling runs. The results suggest that these catalysts are an attractive candidate for the alternative Cu-Zn/Al2O3 catalyst for fuel processor and hydrogen station applications.

최근 들어 고체산화물 연료전지(SOFC) 기술이 급성장함에 따라 고온 수증기 전기분해(HTE) 기술이 물로부터 수소를 대량으로 제조할 수 있는 환경 친화적인 기술로 주목 받고 있다 고온 수증기 전기분해는 기존의 액상 전기분해보다 총 에너지 요구량이 작고 전기분해에 필요한 최소의 전기에너지가 온도가 증가할수록 감소하며 고온 수증기 전기분해에 요구되는 에너지의 일부를 전기에너지 대신 열의 형태로 공급이 가능하여 보다 높은 효율을 기대할 수 있다. 따라서 off peak시 기저부하전력을 이용하고, 공정의 열원으로 고온가스의 폐열, 천연가스의 부분산화 반응열 또는 고온 가스원자로의 폐열을 활용하면 SOFC 이용 고온 수증기 전기분해 공정은 수소경제사회에서 요구되는 수소를 대량으로 제조할 수 있는 경제적인 공정이 될 것이다.

Formic acid recently attracted attention as an alternative fuel for direct liquid fuel cells(DLFCs) due to its high theoretical open circuit voltage(1.45V). In this paper, a novel chemical strategy is described for the preparation and characterization of carbon-supported and surface-alloys, which were prepared by using a successive reduction process. After preparing Au colloid nanoparticles, the deposition of Au colloid nanoparticles occurred spontaneously in the carbon black-dispersed aqueous solution. Then nano-scaled Pt layer were formed on the surface of carbon-supported Au nanoparticles. The Au-Pt[x] showed the higher electrocatalytic activity than those of the particle-alloys and commercial one (Johnson-Matthey) for the reaction of formic acid oxidation when the mass-specific currents were compared. The increased electrocatalytic activity might be attributed to the effective surface structure of surface-alloys, which have a high utilization of active materials for the surface reaction of electrode.

직접 알콜 연료전지는 액체인 알콜을 직접 연료전지에 공급하여 연소시킴으로써 높은 효율을 갖는 휴대용전원으로 주목받는 장치이다. 직접 알콜 연료전지에 담지체로 사용되는 탄소 소재는 넓은 표면적과 우수한 전기전도도를 가지고 있다는 장점 있으나 금속 촉매와의 상호작용이 약하여 촉매 활성에 영향을 주지 못한다. 산화물을 담지체로 사용할 경우 이러한 금속-담지체 간의 상호작용으로 인한 촉매활성 증가 및 입자성장 억제의 효과를 기대할 수 있다. 본 연구에서는, 안티몬 도핑된 주석산화물 (Sb-doped SnO2 : ATO nanoparticle)을 직접 메탄올 연료전지용 담지체어 적용하였으며 합성 과정은 다음과 같다. SnC14 5H2O SbC13, NaOH, HCl 수용액 혼합물을 삼구 플라스크에 넣고 $100^{\circ}C$ 온도에서 환류(reflux) 시킨 후 세척 및 건조하여 Air 분위기에서 열처리하였다. 합성된 산화물 수용액에 폴리올 방법으로 합성된 백금 콜로이드를 담지하였으며, 세척과 건조를 통하여 산화물에 담지된 백금 촉매를 촉매를 합성하였다. 촉매의 구조분석을 위해 XRD, TEM을 사용하였으며, 전극촉매로서의 활성을 평가하기 위해 cyclic voltammetry을 평가하였다. 본 연구에서는 백금의 담지량에 따른 Costripping voltammetry특성과 메탄올 및 에탄올 산화 반응 특성에 대하여, 탄소를 담지체로 사용한 Pt/C 촉매와 비교 평가하였다. 알콜 산화반응 평가결과, 주석산화물에 담지한 촉매가 탄소를 담지체로 사용한 촉매보다 우수한 활성을 나타내었으며 활성증가는 메탄올에 비해 에탄올 산화 반응의 경우 크게 증가하였다. 막과 비교해 보았다. $ZrO_2$ 입자는 전도성이며 동시에 친수성을 나타내기 때문에 상용 막에 비하여 함수율 및 수소이온 전도도가 우수하게 나타났다. 복합막의 이러한 물성은 $100^{\circ}C$이상의 고온에서 전해질 막 내의 물 관리를 용이하게 한다. 단위 전지 운전 온도 $130^{\circ}C$, 상대습도 37%의 운전 조건에서도 상당히 우수한 전지 성능을 보임에 따라 고온/저가습 조건에서 상용 Nafion 112 막보다 우수한 막 특성을 나타냄을 확인하였다.소/배후방사능비는 각각 $2.18{\pm}0.03,\;2.56{\pm}0.11,\;3.08{\pm}0.18,\;3.77{\pm}0.17,\;4.70{\pm}0.45$ 그리고 $5.59{\pm}0.40$이었고, $^{67}Ga$-citrate의 경우 2시간, 24시간, 48시간에 $3.06{\pm}0.84,\;4.12{\pm}0.54\;4.55{\pm}0.74 $이었다. 결론 : Transferrin에 $^{99m}Tc$을 이용한 방사성표지가 성공적으로 이루어졌고, $^{99m}Tc$-transferrin의 표지효율은 8시간까지 95% 이상의 안정된 방사성표지효율을 보였다. $^{99m}Tc$-transferrin을 이용한 감염영상을 성공적으로 얻을 수 있었으며, $^{67}Ga$-citrate 영상과 비교하여 더 빠른 시간 안에 우수한 영상을 얻을 수 있었다. 그러므로 $^{99m}Tc$<

For a mobile application such as cellular phone, micro fuel cells should be extremely compact and thin. RHFC can be an alternative solution because RHFC gives higher power density than DMFC and does not need ahydrogen storage vessel In this paper, RHFC using methanol fuel is made as a novel planar design without a PROX. Both reformer and cell are made closely in a same plate to share the heater of reformer with the cell. The PBI membrane is used in the cell. The reason is that high temperature of reformer can cause a performance drop when perfluorosulfonic acid membrane such as Nafion is used such a high temperature operation also guarantees the higher CO tolerance to MEA catalyst. The cell is designed as an air-breathing type which the cathode of the cell is opened to the air. The commercial Cu/ZnO/Al2O3 steam reformer catalyst is packed in reformer channel. The active area of MEA is $11.9cm^2$ and the peak power density was $27.5mW/cm^2$.

An object of the present study is to provide a hollow fiber membrane humidifier capable of improving the humidification efficiency while lowering the pressure loss, and is suitably usable for PEMFC(Polymer Electrolyte Membrane Fuel Cell). The performance of PEMFC is decisively dependent on the humidity of the electrolyte membrane(fluorinated membrane) and a humidifier plays an important role in moisturizing electrolyte membrane. Especially this humidifier is adaptable for lower price to promote the commercialization of fuel cell vehicles and is passive type to be power free and to be volumetrically optimized. In this research, we propose the substitutes for the expensive fluorinated materials and the optimum dry-jet wet spinning conditions of hollow fiber membrane to get the fuel cell humidifier. In addition to that we established the standard method of evaluating the moisturizing performance of the humidifier of various materials.

본 연구에서는 다양한 두께, loading 및 기공 구조를 갖는 MPL을 형성하여 DMFC용 확산층을 제조하였다. 본 실험에서 제조한 확산층의 경우, 두께가 증가하면서 기공이 micro-pore에서 meso-pore 영역으로 옮겨감을 확인할 수 있었으며, 또한 기공구조에 따라 공기 투과도 특성이 변화하는 것을 확인할 수 있었다 각각의 확산층은 서로 다른 운전 조건에서 우수한 성능(흑은 안정적인 성능)을 갖는 것으로 확인되었으며, 이는 용도에 따른 확산층의 적합한 구조 설계가 요구됨을 의미한다.

In this study, we investigated operating characteristics of the LNG burner for steam methane reforming. The developed LNG burner and catalytic reactor to supply an efficient heat transfer between the combustion gas and catalyst got a good response of various operating load within 5-7 minute and high efficiency for steam methane reforming as a conversion of methane over 90%. We calculated the volume of catalyst for $1Nm^3/hr$ steam LNG reforming as $211cc/(Nm^3/hr\;H_2)$ and got the operating condition and design data of the burner and steam reforming for LNG.

본 연구에서는 소형 카트용 스택제작에 사용하기 위한 분리판에 관한 연구를 진행하였다. 분리판의 두께가 감소해야 스택의 부피를 줄이고 출력밀도를 높일 수 있기 때문에 분리판 두께 감소를 위한 채널의 깊이 최적화 실험을 진행하였다. 이를 위해 캐소드 채널 깊이에 따른 DMFC 성능의 변화를 관찰하기 위해 캐소드 채널의 깊이를 0.3mm에서부터 1.0mm로 변화시켰다. 채널깊이가 0.5mm일 때 가장 좋은 성능을 보였는데, 원인으로는 단면적 감소에 의한 선속도의 증가와 내부 압력증가를 들 수 있다. 채널깊이 변화에 따른 영향을 분석하기 위해 마노미터를 이용하여 차압을 측정하였고, 임피던스 분석법을 통해 전극의 저항을 측정하였다.

고분자전해질형 연료전지(PEMFC)는 다른 연료전지에 비해 소형전원에서부터 분산용전원에 이르기 까지 넓은 응용범위를 가지고 있다. 이러한 PEMFC의 응용범위 중 메탄올 개질반응을 통하여 발생된 수소를 이용하는 휴대용 PEMFC 시스템의 경우, 개질 시 발생하는 일산화탄소가 백금촉매를 피독시켜 연료전지의 성능을 저하시키는 주요 원인이다. 따라서 연료전지의 성능저하를 막기 위해서는 개질가스의 일산화탄소의 농도를 10ppm이하로 낮추는 것이 요구된다. 본 연구에서는 이러한 개질가스의 일산화탄소 농도를 낮추기 위한 반응기를 설계 및 제작하였으며, 상용촉매를 사용하여 CO저감 성능실험을 하였다. 또한, PROX 촉매 및 methanation 촉매를 조합하여 사용함으로써 $140^{\circ}C{\sim}190^{\circ}C$ (약 $50^{\circ}C$)의 온도범위에서 일산화탄소의 농도 10ppm이하의 결과를 나타내었다.

The results of simulation of direct methane fuel cell fed with liquid-state methanol feed are shown. This numerical process is based on mass and current conservation equations. The results showed that over low current density $(<200mA/cm^2)$ IV polarization curve was well-presented compared to experimental result. Methanol fed from anodic side moved into cathodic side through electrolyte membrane and the pressure near cathode electrode increased according to amount of methanol crossover and production of water. Besides change of overpotential on each el electrode were checked by x-axis.

For commercialization of polymer electrolytemembrane fuel cell (PEMFC), durability of membrane electrode assemblies (MEAs) has to be improved. Especially, long-term stability of MEA is one of the most important issues for frequent shut-down and start-up processes of PEMFC. The degradation of MEA could be attributed to chemical attack of hydrogen peroxide radicals that are formed at high cell voltages without any special treatment to remove residual hydrogen from anode gas channel after shut-down of the fuel cell. In this study, we investigated the long-term stability of MEA under different on/off operation conditions. Residential hydrogen gas was removed from the anode flow channel by purging air or nitrogen. Also, a dummy resistance was applied to the fuel cell to exhaust residential hydrogen at the anode. In these cases, MEA showed much more stable durability. Electrochemical characteristics of the fuel cell were measured byrepeating the on/off cycles with the hydrogen removal processes. Also, degradation of MEA components was examined by SEM, TEM and XRD analyses.

Recently, small hydropower attracts attention because of its clean renewable and abundant energy resources to develop. However, suitable turbine type is not normalized yet in the range of small hydropower and it is necessary to study for the effect ive turbine type. Moreover, relatively high manufacturing cost by the complex structure of the turbine is the highest barrier for developing the small hydropower turbine. Therefore, this study is trying not only, to classify the type of current operating turbines installed in the domestic power plants and turbines supplied in Japan by Japanese manufacturer but also, to examine the practical turbine type and installation site to extract the small hydropower energy effectively.

본 논문은 신재생에너지의 한 분야로서 청정에너지인 소수력 발전시스템 운영시 수용가 부하의 변동에 따른 발전기의 특성변화를 해석한 것이다. 모의에 사용된 동기발전기-전동기가 부하의 변동에 따라 토크, 속도, 전류 등이 어떤 영향을 받는지 전자계 과도해석 프로그램을 사용하여 나타내었다.

1. 소수력 발전시스템의 자동화 및 고장진단 알고리즘, 2. 종합 제어시스템의 성능 실험과 원격제어 시스템의 개발, 3. 소수력 발전 시스템의 무인 종합 제어시스템 개발

This paper presents the friction and wear characteristics of contact type sealing unit for a water turbine of a small hydro-power generation, which Is to stop a leakage of a circulating water from a outside of an impeller to an inside of a rolling bearing. The surface wear strongly affect to the seal life of a mechanical face seal. In this study, the hardness of a stainless steel in which is a heat-treated is 892.8 in Vickers hardness and the hardness of silicone carbide of SiC is 714.1 in Vickers hardness. The surface hardness of a heat-treated stainless steel is 25% high compared with that of a ceramic material of SiC. The contact modes of rubbing surfaces aye a dry friction a water film friction and a mixed friction that is contaminated by a dust, silt and moistures, etc. These two factors of a contact rubbing modes and a material property are very important parameters on the tribological performance such as a friction and wear between a seal ring and a seal seat. The experimental result shows that the surface hardness of a seal material is very important on the friction coefficient and a wear volume. Thus, the results recommend higher hardness of a seal material, which may reduce a friction loss and increase a wear life of primary seal components

Recently, densified pollet fuel from wood biomass is widely used at North America and Europe as a regenerable and clean carbon neutral bioenergy. High-pressure compaction of sawdust of several species of wood to form a densified fuel was studied. Calorific and elemental analysis were carried out to assess pellet fuels Hot-press process was adopted for compact ion of sawdust and compaction was performed under prescribed condition. Densified fuels were evaluated by its oven-dry density and fines after 5-minute shaking test. The target density and fines of densified fuels were over $1.2g/cm^3$ and below 0.5%, respectively. When the press-temperature is over $60^{\circ}C$ densified fuels with density over $1.2g/cm^3$ and with fines below 0.5% can be produced. And the pressure over $1000kgf/cm^2$ was effect ive for this production.

아임계 및 초임계수에 의한 목질바이오매스의 당화특성을 분석하기 위하여 분해공정 동안 압력을 23MPa(물의 임계압력)로 고정하고 물의 아임계 온도$(325^{\circ}C,\;350^{\circ}C)$와 초임계 온도$(380^{\circ}C,\;400^{\circ}C,\;425^{\circ}C)$에서 현사시나무 목분을 각각 60초 동안 처리하였다. 생성된 현사시나무의 분해산물에는 액상과 고형분의 분해산물이 섞여 있었다. 각 처리조건에 따른 목질바이오매스의 분해율은 온도가 상승함에 따라 증가하였으며 초임계 온도인 $425^{\circ}C$에서 최고 83.1%의 분해율을 나타냈다. 아임계 및 초임계수에 의해서 생성된 단당류는 고성능 음이온 교환 크로바토그래프(HPAEC)를 이용하여 분석하였다. 목질바이오매스의 초임계수 분해과정에서 처리 온도가 높아지면서 단당류 수율은 증가하는 경향을 보였으며, $425^{\circ}C$에서 가장 높은 7.3%의 단당류 수율을 나타내었다. 아임계 온도 범위에서는 현사시나무의 섬유소 성분 중에서 자일란이 우선적으로 분해되어 자일로스의 생성비율이 비교적 높았으며, 처리온도가 높아지면서 셀롤로오스의 분해에 의한 글루코오스 생성율이 급격히 상승하였다. 이렇게 생성된 단당류 성분들은 고온의 반응조건하에서 열분해 반응에 의해서 더욱 분해되어 퓨란계 화합물로 변형되었다.

Recently the production of ethanol from lignocecllulosics has received much attention due to immense potential for conversion of renewable biometerials into biofuels and chemicals. Fomitopsis palustris causes a typycal brown-rot and is unusual in that it rapidly depolymerize the cellulose in wood without removing the surrounding lignin that normally prevents microbial attack. This study demonstrated that the brown rot basidiomycete F. palustris was able to degrade crystalline cellulose. This fungus could also produce the three major cellulases (BGL, EXG and EG) when the cells were grown on 2.0% Avicel. The fungus was able to degrade both the crystalline and amorphous forms of cellulose from woody biomasses. Moreover, we found that this fungus has the processive EG like CBH which are able to degrade the crystalline region of cellulose. To establish the cellulase system in relation with degradation of woody biomass, we performed that purification, characterization and molecular cloning of a BGL, EGs and GLA from F. palustris grown on Avicel.

재생 가능한 자원인 동 식물성 기름으로부터 제조되는 수소용 연료 바이오디젤은 낮은 대기오염 배출과 $CO_2$ Neutral 특성으로 환경 친화적인 연료로 인정을 받으며 전 세계적으로 그 생산량이 급격히 증가하고 있다. 바이오디젤 생산 기술에는 직접이용법, 마이크로 에멀젼법, 열분해법, 에스테르화법, 초임계 메탄올 이용 생산법 등이 있으며 현재의 대부분의 상용 공정은 전이에스테르화법에 근거하고 있다. 이 공정은 크게 나누어 원료 유지 물질의 전처리 단계, 촉매를 사용하여 알콜과 에스테르화시키는 단계, 그리고 생성된 바이오디젤/글리세린의 분리와 정제 단계로 이루어지며 각 단계의 세부기술은 바이오디젤 생산비에 직접적인 영향을 미친다. 본 연구에서는 대두 원유의 전처리 반응, 전처리된 대두원유의 전이에스테르화 반응, 그리고 분리 및 정제 공정의 운전 변수들의 영향에 대한 연구결과와 본 연구를 통해 확립된 생산 공정으로 생산한 연료 grade의 바이오디젤 연료 물성 평가하였다.

국제 유가의 상승으로 대체 에너지개발의 필요성이 대두되고 있는 지금 수송연료인 디젤의 대체 원료로 바이오디젤이 부각되었다. 차세대 대체연료인 바이오디젤의 합성 원료의 국산화로 수급의 안정성과 농가소득향상을 위해서 국내산 유채 착유기의 개발 및 유지의 함량을 측정하고 바이디젤로서의 적용가능성을 살펴보며 유박에서의 유지 추출 Biomass활용방안을 도출한다 국내산 유채 착유기 및 착유기술 평가를 통해 중소형 유채 착유기의 제작과 기본 조건을 도출을 위해 유채 착유실험을 진행하였다. 유채유의 착유온도에 따른 물성변화와 산가, 수분, 착유율의 변화와 영향을 확인하기 위해 roaster의 온도를 고온과 저온으로 나누어 착유하여 각각의 물성 실험과 산가, 수분, 착유율을 측정 비교하였다. 유채유는 저온보다 고온에서 착유량이 높으나 많은 검질과 높은 산가로 인해 바이오디젤 합성과정에 많은 어려움을 나타내었다. 유채의 유박을 바이오디젤과 에탄올로 각각 Extraction.한 결과 바이오디젤보다는 에탄올이 적용 가능성이 높음을 확인하였다.

The feasibility of biodiesel production from soapstock by acid catalyst was tested. The water content of soapstock was more than 40%. Before the esterification of soapstock, the pre-treatment of soapstock was conducted adding potassium hydroxide and sulfuric acid. The pre-treated soapstock contained 99.6wt% of free fatty acid. When the free fatty acid was esterified with methanol, the fatty acid methyl ester content became 91.7wt% under the solid acid catalyst, Amberlyst-15. When this biodiesel was distilled the methyl ester content was 98.1wt% which satisfied the biodiesel Standard. Amberlyst-15 could be recovered easily because it was the soliid catalyst. When sulfuric acid was used as the acid catalyst, the fatty acid methyl ester content was 91.0wt%. From the results, it was possible to produce biodiesel efficiently from soapstock after pre-treatment. Because soapstock is very cheap, it will become good feedstock for biodiesel product ion.

벌크형태의 태양전지 기판을 대체할 목적으로 연성기판을 적응한 태양전지 개발이 활발하게 진행되고 있으며, 주재료는 플라스틱 기판, 금속기판 등이 있다 그러나 기존의 연성기판인 플라스틱의 경우 열과, 내구성, 화학약품에 약하다는 단점이 있으며, 금속기판은 높은 생산원가, 박막화의 어려움 등의 문제를 안고 있다 이러한 문제를 극복하기 위해 전주성형법으로 제조된 철-니켈계 연성기판을 개발하였다. 이 연성기판의 경우 고온의 공정조건에서도 열팽창율이 플라스틱 기판보다 낮으며, 기존의 금속기판 보다 저렴한 생산단가로 쉽게 극박화 할 수 있다는 것이다. 전주성형법을 적용하여 40Ni, 45Ni, 52Ni 연성기관을 제조하였으며, TMA 장비를 사용하여 각 연성기판의 열팽창 계수를 측정한 결과 6.36, 6.78, $10.93{\mu}m/m^{\circ}C$로 기존의 연성기판인 플라스틱, 금속에 비해 낮은 열팽창 계수를 가짐으로서 고온 공정 중에 안정성 요구를 충분히 충족시킬 수 있다.

The paper presents a method of assessing the adequate tapaclty of photovoltaic generation systems for public buildings based on analysis of load variation patterns of customers. When PV systems are installed for supplying power for the customer load, reverse power relay is required by the guideline to be installed at the point of common coupling with the power network. The suggested method analyzes daily, weekly and monthly load demand of the customer that Irishes PV system installation, and determines the appropriate rating of the PV system for preventing PV generation from exceeding the customer demand. This work is expected to support renewable energy dissemination projects of public organizations.

태양전지는 태양광에너지를 바로 전기에너지로 전환시키는 소자이다. 과거에 많이 연구되던 고품질의 단결정 소자는 높은 에너지 변환효율을 가지고 있으나 가격 경쟁력이 크게 뒤져 일반화되지 못하였다. 최근에는 다결정 태양전지의 응웅 가능성에 대한 연구가 활발히 진행되어 오고 있다. 이중 $CuInSe_2$는 여러 가지 좋은 물성을 가지고 있어서, 저가의 고효율 태양전지를 위한 광흡수층 재료로 가장 주목받고 있다. $CuInSe_2$ 화합물 박막을 제조하기 위해 단위원소를 spttering법 과 Evaporeation법을 사용하여 증착하고 전기로에서 열처리 공정을 사용하여 single-phase 화합물 $CuInSe_2$ 박막을 얻고자 하였다.

본 연구에서는 Cu와 In 성분을 포함하는 메탄을 용액을 닥터 블레이딩 방법으로 코팅한 후 이를 Se 분위기에서 열처리하여 CIS 광흡순층을 제조하였다 $Cu(NO_3)_2,\;InCl_3$를 출발 물질로 선정하고, 이를 메탄을 용매에 녹여 전구체 용액을 만든 후 여기에 유기물 바인더 물질을 첨가하여 닥터 블레이드 코팅에 적합한 점도를 맞춘 후. 이를 Mo/glass 기판에 코팅하였다. 코팅된 Cu, In 함유 유기물 혼합체를 공기중에서 1차 열처리 후 Se 분위기에서 열처리하면 태양전지용 CIS 광흡수층을 얻게 된다 특히 본 연구에서는 전구체 합성, 유기물 첨가, 공기중 열처리 및 Se 열처리 각 단계에서 광흡수층 막의 형상, 결정구조, 화학조성의 변화과정을 분석하여 CIS 박막의 형성 과정을 고찰하였다.