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http://dx.doi.org/10.12925/jkocs.2008.25.1.9

Preparation of Quaternary Ammonium Salt Derivatives Supported on Silica gel and Its Ion Exchange Characteristics  

Ahn, Beom-Shu (Department of Chemistry, Dae Jin University)
Publication Information
Journal of the Korean Applied Science and Technology / v.25, no.1, 2008 , pp. 65-72 More about this Journal
Abstract
The ion exchangers supported on silica gel containing primary, secondary, or tertiary amine groups show a behaviour that is weakly acidic, while the quaternary salts are strongly acidic. These properties change according to the hydrophilicities of the modifier functional groups. Ammonium salt derivatives supported on silica gel were prepared from silica modified with 3-Aminopropyltriethoxysiliane and N-3-(Trimethoxysilyl)propylehtylene diamine. The preparation and the ion exchange properties of two systems were discussed. Two systems have different hydrophilicities and contain ammonium chloride derivatives of 3-amminopropyltriethoxysilane and N-3-(triehtoxysilyl)propyl ethylene diamine supported on silica gel, $SA^+/Cl^-$ and $SA^+/Cl^-$, respectively. The high affinity to perchlorate ion presented by the $SA^+/Cl^-$ through the equilibrium studies of ion exchange led us to its application as an ion selective electrode for the perchlorate ion. The determination of the perchlorate ion in the presence of other anions and in complexes is very difficult. Few analytical methods are available and most of them are indirect. Both materials showed potential use as an ion exchanger; they are thermically stable, achieve equilibrium rapidly in the presence of suitable exchanger ions, and are easily recovered.
Keywords
quaternary salts; hydrophilicities; ion exchange; affinity coefficient; counterion; selectivity;
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Times Cited By KSCI : 3  (Citation Analysis)
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1 E. Fisher, M. Shen, and R. Siriwardine, Adsorption and Desorption on Solid Sorbents, US Department of Energy, 348 (2001)
2 F. Santos, G. Oskam, and C. Searson, Influence of the Reactant Concentrations on the Synthesis of Nanoparticles, J. Colloid Interf. Sci., 288, 313 (2005)   DOI   ScienceOn
3 Y. Moroli and J. Lee, Solubilization Study for Aggregatesof Sodium dodecyl sulfate and a Cationic Polymer of High Charge Density, J. Collid Inter. Sci., 273, 645 (2004)   DOI   ScienceOn
4 C. H. Ju and K. H. Park, A Study on the Valve regulated Battery using Phosphoric Acid Gel Electrolyte, J. Kor. Oil Chem. Soc., 20, 296 (2003)   과학기술학회마을
5 T. R. Burke, B. S. Bajwa, K. C. Rice, and W. A. Klee, Probes for Narcotic Receptor Mediated Phenomena, J. Med. Chem., 27, 1570 (1984)   DOI
6 H. S. Kim and N. H. Jeong, Light Emitting Properties of Organic Luminescent Devices using Zinc Complexes. J. Kor. Oil Chem Soc., 20, 316 (2003)   과학기술학회마을
7 D. Peiffer, S. Jochusch, and N. Turro, Interactions between Hydrophobically Modfied Polymers and Surfactants, Langmuir, 18, 3860 (2002)   DOI   ScienceOn
8 J. Lee and Y. Moroi, Binding of Sodium dodecyl sulfate to a Cationic Polymer of High Charge Density, Bull. Chem. Soc. Jpn, 76, 2099 (2003)   DOI   ScienceOn
9 S. Grylewicz, Rapeseed Oil MethylEsters Preparing Using Heterogenous Catalysts, Biores. Technol., 70, 249 (1999)   DOI   ScienceOn
10 S. M. Haile and D. W. Johnson, Aqueous Precipitation of Spherical oxide powders for varistor Applications, J. Am. Ceram. Soc., 72, 2004 (1989)   DOI
11 B. W. Barry, Dermatological Formulations, pp. 75-124, Marcel Dekker, New York (1998)
12 J. T. Lutz and R. F. Grossman, Polymer Modifiers and Additives, pp 85 - 92, Marcel Dekker Inc., New York (2001)
13 P. Hanson and B. Lindman, Mixed Solution of Surfactant and Hydrophilycally Modfied Polymer, J. Phys. Chem. B., 102, 7099 (1998)   DOI   ScienceOn
14 M. Sivaci, F. S. Kilic, and K. Erol, Synthesis of Some Triazolylantipyrine Derivatives and Investigation of analgestic Activity, Eur. J. Med. Chem., 36, 685 (2001)   DOI   ScienceOn
15 A. M. Kuhn, C. H. Senayake, D. W. Kesser, and S. A.Wald, Effective Synthesis of Hydroxytriconazole, Tetrahedron Lett., 39, 6845 (1998)   DOI   ScienceOn
16 M. Lergenmueller, J. Schultz, and R. Daniels, Investigation of Stability in Emulsions Stabilized with Differebt Surface, Colloid Surfaces A, 232, 261 (2004)   DOI   ScienceOn
17 T. Sugimoto, Preparation of Monodispersed Colloidal Particles, Adv. Colloid Interf. Sci., 28, 65 (1987)   DOI   ScienceOn
18 S. B. Kim, E. S. Park, H. S. Park, and H. S. Hahm, Activity Changes of Supported Nickel Catalysts with Respect to Ni Loading, J. Kor. Oil. Chem. Soc., 20, 230 (2003)