The effect of the Mo addition on the high temperature creep properties of the 9Cr-3W steel was also evaluated. Two experimental steels, (9Cr-3W and 9Cr-3W-0.5Mo), were prepared using a vacuum induction melting process, followed by hot rolling and heat treatment processes. Three types of precipitates, ($M_{23}C_6$, Nb-rich MX and V-rich MX) were observed in a typical tempered martensitic matrix. Significant effects of the Mo addition on the tensile properties were not observed. However, the creep properties at $650^{\circ}C$ under applied stresses of 140 and 150 MPa were considerably enhanced by the Mo addition. The microstructural observation after the creep test indicated that the addition of Mo could function to retain the recovery of the martensitic matrix, thus resulting in the enhanced creep properties of the 9Cr-3W-0.5Mo steel. Furthermore coarsening of the $M_{23}C_6$ carbides and formation of Laves phases were observed in both samples after the creep tests.

Although aluminum-silicon based commercial casting alloys have been used in applications that demand high electrical or thermal conductivity, new aluminum casting alloys that possess higher conductivities are currently required for advanced applications. Therefore, there is much research into the development of new high conductivity aluminum casting alloys that contain lower amounts of or no silicon. In this research, the properties and casting characteristics of Al-Zn-Fe-Si alloys with various Fe and Si contents were investigated. Two types of AlFeSi phases were formed depending on the Fe and Si contents. As the silicon content increased, the tensile strength of the Al-Zn-Fe-Si alloy increased slightly, while the electrical conductivity decreased slightly. It was also observed that both the fluidity and hot cracking susceptibility of the investigated alloys were closely related to the formation of the AlFeSi phases.

The effects of rare earth element (R.E.) and cooling rate on the eutectic reaction of flake graphite cast irons were studied by combined analysis of macro/micro-structure and cooling curve data. The correlation between eutectic reaction parameter and macro/micro-structure was systematically investigated. Two sets of chemical compositions with the different addition of R.E. were designed to cast. Three types of molds for cylindrical specimens with the different diameters were prepared to analyze cooling rate effect. The difference between undercooling temperature and cementite eutectic temperature (${\Delta}T_1=T_{U}-T_{E,C}$), which is increased by adding R.E. and decreased by increasing cooling rate, is considered to be a suitable eutectic reaction parameter for predicting graphite morphology. According to the criterion, A-type graphite is mainly suggested to form for ${\Delta}T_1$ over $20^{\circ}C$. Eutectic reaction time (${\Delta}t$), which is decreased by adding R.E. or increasing cooling rate, is a suitable eutectic reaction parameter for predicting eutectic cell size. Eutectic cell size is found to decrease in a proportion to the decrease of ${\Delta}t$.

In order to develop an aluminum alloy, that can combine high thermal conductivity and good castability and anodizability, aluminum alloys with low Si content, such as Al-(0.5~1.5)Mg-1Fe-0.5Si and Al-(1.0~1.5)Si-1Fe-1Zn, were designed. The developed aluminum alloys exhibited 170~190% thermal conductivity (160~180 W/mK), 60~85% fluidity, and equal or higher ultimate tensile strength compared with those of the ADC12 alloy. In each developed alloy system, the thermal conductivity decreased and the strength increased with the increment of Mg and Si, which are the significant alloying elements. The fluidity was in reverse proportion to the Mg content and in proportion to the Si content. The Al-(0.5~1.5)Mg-1Fe-0.5Si alloys exhibited better fluidity in thick-wall castings, while the Al-(1.0~1.5)Si-1Fe-1Zn alloys were better in thin-wall castability due to their lower surface energies. The fluidity behavior was complexly affected by the heat release for the solidification, viscosity, solidification range, and the type, quantity, and formation juncture of the main secondary phase.