In this study, the measurement system was developed for the measurement of pollutants from building materials, and specimens were made with concrete, gypsum board, mortar and wall paper. Characteristics of VOCs and TVOC concentration and Emission Factor as a function of time were assessed, and the conclusion was drawn as follows. (1) From predicting TVOC concentration decrease of specimen 7 with the wall paper attached to the concrete, the graph may become linear by converting the value of y-axis into the log function, and the prediction equation can be expressed as $y=34906{\ast}e^{-0.0093{\ast}time}$. Moreover, chi-square value was 0.83 which is relatively high value, indicating that TVOC concentration can be properly predicted if the same materials are used indoors. (2) From predicting VOCs Emission Factor decrease of specimen 7, the prediction equation can be expressed as $EF=15111{\ast}e^{-0.0093{\ast}time}$, and chi-square value was 0.83. (3) From predicting TVOC concentration decrease of specimen 7, prediction equation can be considered to be $y=254323{\ast}(1-e^{-0.1046{\ast}time})$, and chi-square was 0.994 which is significantly high value, indicating that indoor TVOC concentration can be properly predicted if the same materials are used indoors. Furthermore, the prediction of concentration decrease using cumulative value of hourly measured concentration is considered to be more accurate than that using just hourly measured value directly. (4) From predicting Emission Factor decrease with cumulative hourly data of Emission Factor, chi-square appeared to be higher than that by just using hourly data of Emission Factor directly. Therefore, the prediction of Emission Factor with cumulative hourly data can provide more reliable prediction equation than the case by using just hourly concentration directly.