• 제목/요약/키워드: core property

검색결과 533건 처리시간 0.027초

One-Dimensional Core/Shell Structured TiO2/ZnO Heterojunction for Improved Photoelectrochemical Performance

  • Ji, In-Ae;Park, Min-Joon;Jung, Jin-Young;Choi, Mi-Jin;Lee, Yong-Woo;Lee, Jung-Ho;Bang, Jin-Ho
    • Bulletin of the Korean Chemical Society
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    • 제33권7호
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    • pp.2200-2206
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    • 2012
  • One-dimensional $TiO_2$ array grown on optically transparent electrode holds a promise as a photoelectrode for photoelectrochemical water splitting; however, its crystal structure is rutile, imposing constraints on the potent use of this nanostructure. To address this issue, a heterojunction with type-II band alignment was fabricated using atomic layer deposition (ALD) technique. One-dimensional core/shell structured $TiO_2$/ZnO heterojunction was superior to $TiO_2$ in the photoelectrochemical water splitting because of better charge separation and more favorable Fermi level. The heterojunction also possesses better light scattering property, which turned out to be beneficial even for improving the photoelectrochemical performance of semiconductor-sensitized solar cell.

Thermal and Solid State Assembly Behavior of Amphiphilic Aliphatic Polyether Dendrons with Octadecyl Peripheries

  • Chung, Yeon-Wook;Lee, Byung-Ill;Cho, Byoung-Ki
    • Macromolecular Research
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    • 제16권2호
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    • pp.113-119
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    • 2008
  • A series of amphiphilic dendrons n-18 (n: generation number, 18: octadecyl chain) based on an aliphatic polyether denderitic core and octadecyl peripheries were synthesized using a convergent dendron synthesis consisting of a Williamson etherification and hydroboration/oxidation reactions. This study investigated their thermal and self-assembling behavior in the solid state using differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) absorption spectroscopy, and small angle X-ray scattering (SAXS). DSC indicated that the melting transition and the corresponding heat of the fusion of the octadecyl chain decreased with each generation. FT-IR showed that the hydroxyl focal groups were hydrogen-bonded with one another in the solid state. DSC and FT-IR indicated microphase-separation between the hydrophilic dendritic cores and hydrophobic octadecyl peripheries. SAXS data analysis in the solid state suggested that the lower-generation dendrons 1-18 and 2-18 self-assemble into lamellar structures based upon a bilayered packing of octadecyl peripheries. In contrast, the analyzed data of higher-generation dendron 3-18 is consistent with 2-D oblique columnar structures, which presumably consist of elliptical cross sections. The data obtained could be rationalized by microphase-separation between the hydrophilic dendritic core and hydrophobic octadecyl peripheries, and the degree of interfacial curvature associated with dendron generation.

국내 손해 보험사의 e-Business 기업 혁신 사례 연구 (A Case Study of Process Innovation for e-Business Transformation: Lessons Learned from a Korea-Based Leading P&C Insurance Company)

  • 김승언;박주석;김재경
    • 한국IT서비스학회지
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    • 제5권1호
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    • pp.17-34
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    • 2006
  • As insurers have undergone changing customer expectations, increased cross-industry competition and restructured distribution channels, they need to enhance customer relationships, cut costs, increase agility and streamline operations while differentiating the core competency. As such, the importance of e-business transformation has increased where organizational core processes are restructured around customers and interned-based technology is adopted for flexible and adaptive information systems. This paper presents a case study of process innovation for e-business transformation in a Korea-based leading property & casualty insurance company. The company initiated three years-long e-business transformation program to remain competitive and to keep sustainable growth under risky and down economy. The program, which covered enterprise-wide business processes such as product, marketing & sales, customer, claim, investment & loan, accountings, etc., included redesigning processes from customers' viewpoint and then implementing process-aligned information systems. Leadership, sponsorship, change management, performance measurement, business and IT alignment, empowerment, and customized methodology, were emphasized throughout the program. As a result, the company could expect not only improvements in customer-centricity, sales productivity, and operational excellence but also increased revenues and profits in the next three years. The presented case addresses a feasible approach for enterprise-wide e-business transformation. Although the strategies, actions, and business and IT models are not described in detail due to confidentiality, the methodology and the success factors would be applicable to other insurers and possibly organizations in different industries.

HDL 코딩 방법에 따른 FPGA에서의 성능 실험 및 평가 (FPGA Performance Evaluation According to HDL Coding Style)

  • 이상욱;이보선;이승은;서태원
    • 한국정보처리학회:학술대회논문집
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    • 한국정보처리학회 2011년도 추계학술발표대회
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    • pp.62-65
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    • 2011
  • FPGA는 대용량의 게이트를 지원하는 하드웨어를 프로그램 할 수 있는 디바이스이다. ASIC을 위해 설계된 로직은 칩으로 제조되기 전에 검증 과정을 거친다. 이 검증 과정에서 시뮬레이션의 한계를 극복하기 위해 FPGA를 사용한 에뮬레이션 방법을 많이 채택한다. 에뮬레이션 과정에서 ASIC의 동작 속도로 검증하는 것이 바람직하지만 FPGA의 특성상 ASIC과 같은 속도로 동작하기는 쉽지 않은 것이 현실이다. 본 논문에서는 HDL 코딩 방법에 따른 FPGA의 성능 민감도를 실험하였다. 실험 및 평가를 위해 다양한 알고리즘을 가진 가산기를 이용하였고 각 가산기 종류와 비트수에 따라 Verilog-HDL을 이용하여 코딩하였으며 대표적인 FPGA 제조사(Altera와 Xilinx)별, 디바이스별로 동작 속도와 자원 사용량을 측정하였다. 실험 결과 FPGA 제조사별로 다른 경향을 보임을 확인하였다. 성능 면에서는 비트별로 다소 차이는 있지만 Altera 디바이스에서는 Ripple Carry, Carry Lookahead 가산기보다 Prefix 가산기의 성능이 우수하게 나왔다. Xilinx 디바이스에서는 예상과 달리 가산기들 사이의 성능 차이가 크게 나지 않았으며 Ripple Carry, Carry Lookahead 가산기가 Prefix 가산기보다 높은 성능을 보이는 경우도 있었다. 비용 면에서는 디바이스별로 큰 차이가 나지 않았으며 ASIC과 비슷한 성능 민감도를 보였다. 그리고 각 제조사에서 제공하는 IP(Intellectual Property) Core를 사용했을 경우는 대부분의 디바이스에서 우수한 성능을 보여 주었다. TSMC 90nm 공정 기술로 제작한 ASIC과 IP Core를 비교했을 때는 ASIC의 성능이 4배 정도 우수한 것으로 나타났다.

논체질여병증(论体质与病证) (Study on Body Constitution and Disease Symptoms and Signs)

  • 최정식;최명화
    • 대한한의학원전학회지
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    • 제22권4호
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    • pp.241-247
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    • 2009
  • Body constitution research in Korean traditional medicine adopt the diagnosis and treatment theory of "image-differentiation[body constitution differentiation, disease differentiation] in combination with syndrome differentiation diagnostic model and symptoms and signs of herbal property belong to image" as its core, which is key national medical science research project of State Administration of Traditional Chinese Medicine, the project brought up 4 key scientific problem ? body constitution differentiation theory, correlation theory of body constitution and disease, body constitution adjustable theory and symptoms and signs of herbal property belong to image theory. In body constitution pathology, it brought up "correlation between body constitution and symptoms", "differentiation between body constitution and symptoms" which increase the diagnostic level and diagnostic accuracy rate. In the condition of pathology, it obviously has low reliability according to body constitution differentiation, sometimes happen the description not comply with body constitution and disease symptoms, which lead to decrease the clinic diagnostic and treatment level, treatment effect not satisfying too. Now taking 4 key scientific achievement as criterion to illustrate the body constitution and disease symptoms.

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초고속튜브열차 추진/부상용 LSM의 설계 기법 및 특성 분석 연구 (A study on a design method and characteristic analysis of a LSM for a propulsion/levitation of the high-speed tube train)

  • 박찬배;이형우;이병송;김남포;박현준
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2010년도 춘계학술대회 논문집
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    • pp.830-837
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    • 2010
  • Since it started the researches on a maglev train on 1960, Germany and Japan arrived to putting to practical use level and accomplished most tests from their test-line. Korea is in progress the preparation for a practical use of low-speed maglev train in 110 [km/h] class and Korea Railroad Research Institute(KRRI) is in progress of a research about core technology of maglev system for high-speed tube train of 700 [km/h] class. In this paper, authors suggest an effective design method of Linear Synchronous Motor(LSM) for high-speed tube train of 700 [km/h] class which has a wound type electro-magnet. Then, authors calculate a variety of properties by changing speed of the LSM model which is designed by a method based on some theoretical equations. Then, authors verify the validity of the method based on some theoretical equations through a verification of property values by Finite Element Method(FEM) analysis method. Finally, in order to design a shape of pole-shoe part of LSM electro-magnet which is hard to design with a basic design method, authors analyze a transition of property values by changing a pole-shoe width and current of the electro-magnet through an analytical method by FEM.

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PTT/Wool/Modal Air vortex사 편성물의 의류 착용성능과 쾌적물성 (Wearing Performance and Comfort Property of PTT/Wool/Modal Air Vortex Yarn Knitted Fabrics)

  • 김현아
    • 한국의류학회지
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    • 제40권2호
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    • pp.305-314
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    • 2016
  • This paper investigated the applicable possibility of PTT and wool staple fibers to the air vortex system as high quality yarns for a high emotional and comfort garment. It was found that the tactile hand of vortex yarn knitted fabrics was harsher than ring and compact yarns knitted fabrics. It was observed that formability and sewability of air vortex yarn knitted fabrics seemed worse than ring and compact yarns due to low tensile and compressional resilience and high bending and shear hysteresis of air vortex yarn knitted fabrics. It revealed that wicking and drying rates of air vortex yarn knitted fabric were better than ring and compact yarns; in addition, the heat keepability of vortex yarn knitted fabric was higher than ring and compact yarns due to low thermal conductivity and max heat flow rate ($Q_{max}$). Any difference of thermal shrinkage between air vortex and ring yarn knitted fabrics was not shown, but pilling characteristic of air vortex yarn knitted fabric was superior. However, it was shown that wicking, drying, thermal property and pilling characteristics of air vortex yarn knitted fabric were superior due to air vortex yarn structure with parallel fibers in the core part and periodical and fasciated twists in the sheath part of the yarns.

BaTiO3 세라믹 내 희토류(Dy, Y, Ho) 첨가 효과 (The Doping Effects of Intermediate Rare-earth Ions (Dy, Y and Ho) on BaTiO3 Ceramics)

  • 박금진;김창훈;김영태;허강헌
    • 한국세라믹학회지
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    • 제46권2호
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    • pp.181-188
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    • 2009
  • The electrical property and microstructure in $BaTiO_3$ ceramics doped rare-earth ions with intermediate ionic size ($Dy^{3+},Ho^{3+},Y^{3+}$) were investigated. Microstructures have been characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). Incorporation of rare-earth ions to $BaTiO_3$ ceramics depended on their ionic radius sensitively. Compared to Ho and Y ions, Dy ions provide $BaTiO_3$ ceramics with the high rate of densification and well-developed shell formation, due to their high solubility in the $BaTiO_3$ lattice, but the microstructure of Dy doped $BaTiO_3$ ceramics is unstable at high temperature, because Dy ions could not play a role of grain growth inhibition, leading to diffuse into $BaTiO_3$ lattice continuously after completion of densification during sintering. Comparing electrical property and microstructure, it is shown that the reliability of capacitor improved by high shell ratio.

Li 도핑된 ZnSnO 박막 트랜지스터의 전기 및 광학적 특성에 대한 고속 중성자 조사의 영향 (Influence of Fast Neutron Irradiation on the Electrical and Optical Properties of Li Doped ZnSnO Thin Film Transistor)

  • 조인환;김찬중;전병혁
    • 한국재료학회지
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    • 제30권3호
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    • pp.117-122
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    • 2020
  • The effects of fast neutron irradiation on the electrical and optical properties of Li (3 at%) doped ZnSnO (ZTO) thin films fabricated using a sol-gel process are investigated. From the results of Li-ZTO TFT characteristics according to change of neutron irradiation time, the saturation mobility is found to increase and threshold voltage values shift to a negative direction from 1,000 s neutron irradiation time. X-ray photoelectron spectroscopy analysis of the O 1s core level shows that the relative area of oxygen vacancies is almost unchanged with different irradiation times. From the results of band alignment, it is confirmed that, due to the increase of electron carrier concentration, the Fermi level (EF) of the sample irradiated for 1,000 s is located at the position closest to the conduction band minimum. The increase in electron concentration is considered by looking at the shallow band edge state under the conduction band edge formed by fast neutron irradiation of more than 1,000 s.

Cruciform Thiophene-based Molecules as Organic Semiconductors for Field Effect Transistor Applications

  • Choi, Dong-Hoon;Kim, Dae-Chul;Kim, Kyung-Hwan;Cho, Min-Ju;Jin, Jung-Il
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.170-173
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    • 2007
  • Cruciform conjugated molecule, 4(DP3T)-benzene bearing terthiophene moieties has been synthesized through Horner-Emmons Reaction using 5-dodecyl-5"-aldehyde-[2,2';5',2"] terthiophene as dendrons and octaethyl benzene- 1,2,4,5-tetrayltetrakis(methylene)tetraphosphonate as the core unit; this molecule has been fully characterized. The terthiophene-based molecule exhibits good solubility in common organic solvents and good self-film forming property. They are intrinsically crystalline as they exhibit well-defined X-ray diffraction patterns from uniform orientations of molecules. Thus, intermolecular interaction can be enhanced to affect the carrier transport phenomena after annealing at $148^{\circ}C$. The semiconducting property of 4(DP3T)-benzene have been evaluated in organic field-effect transistors. 4(DP3T)-benzene exhibit carrier mobility as high as $(6.6{\pm}0.5)$ ${\times}$ $10^{-6}cm^2V^{-1}s^{-1}$.

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