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Hardness and Oxidation Resistance of Ti0.33Al0.67N/CrN Nano-multilayered Superlattice Coatings

  • Ahn, Seung-Su;Oh, Kyung-Sik;Chung, Tai-Joo;Park, Jong-Keuk
    • 한국세라믹학회지
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    • 제56권1호
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    • pp.49-55
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    • 2019
  • $Ti_{0.33}Al_{0.67}N/CrN$ nano-multilayers, which are known to have excellent wear resistance, were prepared using an unbalanced magnetron sputter to have various periods of 2-5 nm. $Ti_{0.33}Al_{0.67}N$ had a hexagonal structure in a single layer, but converted to a cubic structure by forming a multilayer with CrN, which has a cubic structure. Thus, $Ti_{0.33}Al_{0.67}N$ formed a superlattice in the multilayer. The $Ti_{0.33}Al_{0.67}/CrN$ multilayer with a period of 2.5 nm greatly exceeded the hardness of the $Ti_{0.33}Al_{0.67}N$ and the CrN single layer, reaching 39 GPa. According to the low angle X-ray diffraction results, the $Ti_{0.33}Al_{0.67}N/CrN$ multilayer maintained its as-coated structure to a temperature as high as $700^{\circ}C$ and exhibited hardness of 30 GPa. The thickness of the oxide layer of the $Ti_{0.33}Al_{0.67}N/CrN$ multilayered coating was less than one-tenth of those of the single layers. Thus, $Ti_{0.33}Al_{0.67}N/CrN$ multilayered coating had hardness and oxidation resistance far superior to those of its constituent single layers.

마이크로 금형 부품을 위한 마이크로 절삭가공 기술 (Micro cutting process technology for micro molds parts)

  • 하석재;박정연;김건희;윤길상
    • Design & Manufacturing
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    • 제13권1호
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    • pp.5-12
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    • 2019
  • In this paper, we studied the micro tool deflection, micro cutting with low temperature, and deformation of micro ribs caused by cutting forces. First, we performed an integrated machining error compensation method based on captured images of tool deflection shapes in micro cutting process. In micro cutting process, micro tool deflection generates very serious problems in contrast to macro tool deflection. To get the real images of micro tool deflection, it is possible to estimate tool deflection in cutting conditions modeled and to compensate for machining errors using an iterative algorithm correcting tool path. Second, in macro cutting fields, the cryogenic cutting process has been applied to cut the refractory metal but, the serious problem may be generated in micro cutting fields by the cryogenic environment. However, if the proper low temperature is applied to micro cutting area, the cooling effect of cutting heat is expected. Such effect can make the reduction of tool wear and burr formation. For verifying this passibility, the micro cutting experiment at low temperature was performed and SEM images were analyzed. Third, the micro pattern was deformed by the cutting forces and the shape error occurred in the sidewall multi-step cutting process were minimized. As the results, the relationship between the cutting conditions and the deformation of micro-structure during micro cutting process was investigated.

Ti0.5Al0.5N/CrN 나노 다층 박막의 기계적 성질과 열적 안정성 (Mechanical Properties and Thermal Stability of Ti0.5Al0.5N/CrN Nano-multilayered Coatings)

  • 안승수;박종극;오경식;정태주
    • 한국분말재료학회지
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    • 제27권5호
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    • pp.406-413
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    • 2020
  • Ti0.5Al0.5N/CrN nano-multilayers, which are known to exhibit excellent wear resistances, were prepared using the unbalanced magnetron sputter for various periods of 2-7 nm. Ti0.5Al0.5N and CrN comprised a cubic structure in a single layer with different lattice parameters; however, Ti0.5Al0.5N/CrN exhibited a cubic structure with the same lattice parameters that formed the superlattice in the nano-multilayers. The Ti0.5Al0.5/CrN multilayer with a period of 5.0 nm exceeded the hardness of the Ti0.5Al0.5N/CrN single layer, attaining a value of 36 GPa. According to the low-angle X-ray diffraction, the Ti0.5Al0.5N/CrN multilayer maintained its as-coated structure up to 700℃ and exhibited a hardness of 32 GPa. The thickness of the oxidation layer of the Ti0.5Al0.5N/CrN multilayered coating was less than 25% of that of the single layers. Thus, the Ti0.5Al0.5N/CrN multilayered coating was superior in terms of hardness and oxidation resistance as compared to its constituent single layers.

교육 및 자격의 동등성 확보를 위한 영향변수 결정을 위한 실증 연구 (A Empirical study to determine the influential variables for equivalence of the Korea Education and qualifications)

  • 이원박;김세한;정희택;정병한;강경식
    • 대한안전경영과학회지
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    • 제15권2호
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    • pp.233-242
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    • 2013
  • Korea have been efforts to revitalize the national economy by concentrating for the industrialization about 60 years after the Korean war. A result of these efforts, We will enter to the advanced country as the current economic power. But, Our social structure under the Korean Confucianism cannot ecdysis, because we recognise to the academic ability rather than the competency ability. So, the current government is trying to build social skills by presenting the slogan for the ability to implement social policy. This research utilized by the Human Resources Development Service of Korea and the Ministry of Education statistics for the variables to determine the equivalence of the Korea Education and qualifications in order to achieve the government's efforts to meet the need to improve equivalency is to empirically.

모바일-매니퓰레이터 구조 로봇시스템의 안정한 모션제어에 관한연구 (A Study on Stable Motion Control of Mobile-Manipulators Robot System)

  • 박문열;황원준;박인만;강언욱
    • 한국산업융합학회 논문집
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    • 제17권4호
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    • pp.217-226
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    • 2014
  • Since the world has changed to a society of 21st century high-tech industries, the modern people have become reluctant to work in a difficult and dirty environment. Therefore, unmanned technologies through robots are being demanded. Now days, effects such as voice, control, obstacle avoidance are being suggested, and especially, voice recognition technique that enables convenient interaction between human and machines is very important. In this study, in order to conduct study on the stable motion control of the robot system that has mobile-manipulator structure and is voice command-based, kinetic interpretation and dynamic modeling of two-armed manipulator and three-wheel mobile robot were conducted. In addition, autonomous driving of three-wheel mobile robot and motion control system of two-armed manipulator were designed, and combined robot control through voice command was conducted. For the performance experiment method, driving control and simulation mock experiment of manipulator that has two-armed structure was conducted, and for experiment of combined robot motion control which is voice command-based, through driving control, motion control of two-armed manipulator, and combined control based on voice command, experiment on stable motion control of voice command-based robot system that has mobile-manipulator structure was verified.

SK텔레콤 가치네트워크의 역동적 진화에 관한 장기사례분석 (The Longitudinal Case Study on the Dynamically Evolving Value Network of SK Telecom)

  • 장용호;박종구
    • 한국산학기술학회논문지
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    • 제14권5호
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    • pp.2150-2156
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    • 2013
  • 새로운 가치를 창출하기 위한 자원 확보는 기술과 시장의 불확실성이 높은 융합시장에서 기업이 살아남기 위한 필수조건이다. 이 연구는 융합환경에 직면한 이동통신사가 새로운 가치창출을 위해 필요한 자원들의 연결체인 가치네트워크를 어떻게 재구성해왔는지를 밝혀내고자 했다. 이를 위해 SK텔레콤을 분석 사례로 선정하여 1999년부터 2008년까지 SK텔레콤의 출자구조에 대한 측정을 통해 자원구성관점에서 SK텔레콤의 가치네트워크가 융합환경에 어떻게 적응해왔는지를 실증적으로 분석하였다. 연구결과 이동통신망의 고도화에 기반한 융합서비스 제공은 SK텔레콤의 수입원천에 구조적인 변화를 가져왔으며, 사업영역의 확장을 통해 SK텔레콤이 미디어기업으로 자리매김할 수 있는 원동력으로 작동하였다. 이 과정에서 출자구조로 측정된 SK텔레콤의 가치네트워크는 새로운 가치창출을 위해 동종 산업뿐만 아니라 이종 산업에 존재하는 보완적 자산을 역동적으로 재구성해가며 가치 지향적으로 진화했다.

고분자 / 액정 복합막의 Guest-Host효과 (The Guest-Host Effect of the Polymer / Liquid Crystal Composite Films)

  • 박관선;최성부;정노희;남기대;카지야마
    • 한국응용과학기술학회지
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    • 제13권2호
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    • pp.29-37
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    • 1996
  • The phase separated structure and the electo-optical properties of the polymer /liquid crystal(LC) composite films including a dye were investigated. The phase separated structure of the polymer /LC / dye composite film(GH composite film) including below 2wt% dye against LC was almost same with the composite film which does not include dye. But the electro-optical properties of the GH composite film strongly depended on weight fraction of the dye against the LC. The response time of the GH composite film increased with the increase of the dissolved dye in LC because the dye acts as a registivity for the orientation of LC molecules by the electric filed.

장시간 안정성을 위한 CdSe/ZnS 양자점의 표면처리 기술 (Surface Treatment Method for Long-term Stability of CdSe/ZnS Quantum Dots)

  • 박현수;정다운;김범성;주소영;이찬기;김우병
    • 한국분말재료학회지
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    • 제24권1호
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    • pp.1-5
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    • 2017
  • We have investigated the washing method of as-synthesized CdSe/ZnS core/shell structure quantum dots (QDs) and the effective surface passivation method of the washed QDs using PMMA. The quantum yield (QY%) of as-synthesized QDs decreases with time, from 79.3% to 21.1%, owing to surface reaction with residual organics. The decreased QY% is restored to the QY% of as-synthesized QDs by washing. However, the QY% of washed QDs also decreases with time, owing to the absence of surface passivation layer. On the other hand, the PMMA-treated QDs maintained a relatively higher QY% after washing than that of the washed QDs that were kept in toluene solution for 30 days. Formation of the PMMA coating layer on CdSe/ZnS QD surface is confirmed by HR-TEM and FT-IR. It is found that the PMMA surface coating, when combined with washing, is useful to be applied in the storage of QDs, owing to its long-term stability.

습식화학공정에 의한 광촉매용 TiO2 3차원 나노구조체 제조 연구 (Study on the Preparation of TiO2 3D Nanostructure for Photocatalyst by Wet Chemical Process)

  • 이덕희;박재량;이찬기;박경태;박경수
    • 한국분말재료학회지
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    • 제27권5호
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    • pp.381-387
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    • 2020
  • In this work, TiO2 3D nanostructures (TF30) were prepared via a facile wet chemical process using ammonium hexafluorotitanate. The synthesized 3D TiO2 nanostructures exhibited well-defined crystalline and hierarchical structures assembled from TiO2 nanorods with different thicknesses and diameters, which comprised numerous small beads. Moreover, the maximum specific surface area of TiO2 3D nanostructures was observed to be 191 ㎡g-1, with concentration of F ions on the surface being 2 at%. The TiO2 3D nanostructures were tested as photocatalysts under UV irradiation using Rhodamine B solution in order to determine their photocatalytic performance. The TiO2 3D nanostructures showed a higher photocatalytic activity than that of the other TiO2 samples, which was likely associated with the combined effects of a high crystallinity, unique features of the hierarchical structure, a high specific surface area, and the advantage of adsorbing F ions.