• Title/Summary/Keyword: Stability Agent

Search Result 621, Processing Time 0.028 seconds

Synthesis and Flame Retardant Characteristics of Melamine Cyanurate Treated with Silane Agent (실란이 처리된 멜라민 시아누레이트의 합성과 난연특성)

  • Park, Tae-Hun;Kang, Kuk-Hyoun;Lee, Jin-Hwa;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
    • /
    • v.27 no.3
    • /
    • pp.300-309
    • /
    • 2010
  • Melamincyanurate(MC), as an non halogen flame retardant are used as the polymer and plastic materials. In this study, melamine and cyanuric acid were used for the synthesis of MC. The optimum condition of synthetic MC were controlled by different molar ratio of melamine to cyanuric acid. MC was modified by coupling reaction with four different agents. The influences of modified MC were based on the coupling agent types. Preparation methods are available to offer the prospect of improved morphology control deposit stability in polyol. The results reveal that glycidoxypropyltrimethoxysilane(GDS) has the best storage stability. The best properties were obtained with melamine and cyanuric acid from 1:1 molar ratio. Modification of MC through coupling agent can efficiently enhanced the deposit stability in polyol up to 30 %.

Preparation of Porous Inorganic Materials by Foaming Slurry (슬러리 발포에 의한 연속성 무기질 다공체의 제조)

  • 박재구;이정식
    • Journal of the Korean Ceramic Society
    • /
    • v.35 no.12
    • /
    • pp.1280-1285
    • /
    • 1998
  • Foaming method is presented the preparation of porous materials from high-concentrated kaolin silica and flyash slurries. The slurries were foamed dried and sintered respectively. The porosity of sintered ma-terials was about 70-75% Mean pore-size was the range of 70-150$\mu\textrm{m}$ and pore structure was continuous Sodium lauryl sulfate anionic surfactant was used as a foaming agent. The foaming ability and the froth sta-bility were increased with increasing the concentration of the foaming agent. But the size of the constituent bubble of froth after foaming process was not affected by the concentration of the foaming agent. These results showed that the mean pore-size of sintered materials was closely related to the froth stability which is related to the change of bubble-size during the drying process.

  • PDF

Stability of H2O2 as an Oxidizer for Cu CMP

  • Lee, Do-Won;Kim, Tae-Gun;Kim, Nam-Hoon;Kim, Sang-Yong;Chang, Eui-Goo
    • Transactions on Electrical and Electronic Materials
    • /
    • v.6 no.1
    • /
    • pp.29-32
    • /
    • 2005
  • Chemical mechanical polishing is an essential process in the production of copper-based chips. On this work, the stability of hydrogen peroxide ($H_{2}O_{2}$) as an oxidizer of copper CMP slurry has been investigated. $H_{2}O_{2}$ is known as the most common oxidizer in copper CMP slurry. But $H_{2}O_{2}$ is so unstable that its stabilization is needed using as an oxidizer. As adding KOH as a pH buffering agent, stability of $H_{2}O_{2}$ decreased. However, $H_{2}O_{2}$ stability in slurry went up with putting in small amount of BTA as a film forming agent. There was no difference of $H_{2}O_{2}$ stability between pH buffering agents KOH and TMAH at similar pH value. Addition of $H_{2}O_{2}$ in slurry in advance of bead milling led to better stability than adding after bead milling. Adding phosphoric acid resulted in the higher stability. Using alumina C as an abrasive was good at stabilizing for $H_{2}O_{2}$.

Study on the characteristic of liner and cover material by accelerating agent type (급결제 종류에 따른 광산 차수재의 특성 연구)

  • Cho, Yong-Kwang;Nam, Seong-Young;Lee, Yong-Mu;Kim, Chun-Sik;Seo, Shin-Seok;Jo, Sung-Hyun;Lee, Hyoung-Woo;Ahn, Ji-Whan
    • Journal of Environmental Science International
    • /
    • v.27 no.2
    • /
    • pp.75-81
    • /
    • 2018
  • At present research on mining backfill materials is being carried out to prevent ground subsidence and breaking by underground cavern of exhausted mines. However, backfill materials can cause secondary environmental issues such as ground pollution. To solve these issues, liner and cover materials are constructed before backfill materials constructed, to inhibit toxic substances form moving to the surroundings. Liner and cover materials, however, should have an accelerating performance after construction and when the accelerating performance is degraded, the work efficiency can be lowered, and the construction cost can be increased, by many rebound content. Therefore, this study develops mining liner and cover materials, and evaluates their accelerating performance and physical properties of liner and cover materials by types and content of accelerating agent. In case of aluminate accelerating agent, it is mixed with more than 5% of liner and cover materials(binder/ratio); thus an accelerating performance satisfying Korean Industrial Standards(KS) occurs, and in case of alkali-free accelerating agent, when it is mixed with more than 7%(binder/ratio), accelerating performance satisfying KS occurs. The more the accelerating agent capacity increases, the more compressive strength decreases. In addition, it is confirmed that compressive strength of aluminate accelerating agent is more degraded than compressive strength of the alkali-free accelerating agent. It is also confirmed that drying shrinkage stability of the alkali-free accelerating agent is better than the drying shrinkage stability of the aluminate accelerating agent.

Roles of Phosphoric Acid in Slurry for Cu and TaN CMP

  • Kim, Sang-Yong;Lim, Jong-Heun;Yu, Chong-Hee;Kim, Nam-Hoon;Chang, Eui-Goo
    • Transactions on Electrical and Electronic Materials
    • /
    • v.4 no.2
    • /
    • pp.1-4
    • /
    • 2003
  • The purpose of this study was to investigate the characteristics of slurry including phosphoric acid for chemical-mechanical planarization of copper and tantalum nitride. In general, the slurry for copper CMP consists of alumina or colloidal silica as an abrasive, organic acid as a complexing agent, an oxidizing agent, a film forming agent, a pH control agent and additives. Hydrogen peroxide (H$_2$O$_2$) is the material that is used as an oxidizing agent in copper CMP. But, the hydrogen peroxide needs some stabilizers to prevent decomposition. We evaluated phosphoric acid (H$_3$PO$_4$) as a stabilizer of the hydrogen peroxide as well as an accelerator of the tantalum nitride CMP process. We also estimated dispersion stability and zeta potential of the abrasive with the contents of phosphoric acid. An acceleration of the tantalum nitride CMP was verified through the electrochemical test. This approach may be useful for the development of the 2$\^$nd/ step copper CMP slurry and hydrogen peroxide stability.

Studies on the Stabilities of Insectcides Combined with some Stabilizers (살충제제(殺蟲製劑)의 안정성(安定性)에 관(關)한 연구(硏究))

  • Woo, Chong-Hak;Kim, Jae-Wan
    • Journal of Pharmaceutical Investigation
    • /
    • v.1 no.1
    • /
    • pp.101-108
    • /
    • 1971
  • The stability and toxicity test for p.p'-DDT, DDVP and dipterex that put to used sample in this study effects is follows A. about p.p'-DDT (1) In elevating the stability of p.p'-DDT, best stabilizing solvent was benzene. (2) The stability-agent has no difficulty as long as it not contain metal ion for instance $Z_n^{2+}$,$C_r^{3+}$,$Al^{3+}$,and $Fe^{2+or3+}$ but in case of contain $F_e^{3+}$, the combination of salicylaminoguanidine is best effective. (3) Using this product for water-suspension, We must use span 40 for stability agent and adding it at the same time. (4) We must use container which does not week alkali and metal ion but it is to preserved in tight light-resistant container. (5) The stopper of container is adapted with above-mentioned condition of container, but it is better not to use metal material. (6) This product needs opening ventilation more than 30 minutes after diffusion or spray and in the room we remove cause of remained poison by cleaning the bottom. B. about DDVP and Dipterex (1) Benzene or toluene in best solvent to preserve stability of DDVP and Dipterex. (2) Span 40 is superior for stability agent of this product and second is span 80. (3) The pH of solution is very stable in pH 5-6 and comparative stable in alkali more than p,p'-DDT. (4) Container is to preserved in tight, lightresistant container and especially be careful of outflow and inflow of water. (5) Because this product is centeral stimulant poison, we must pay attention to prevent cause of contact diadermic toxicity after use.

  • PDF

STUDY ON THE INFLUENCE OF POLYOL ON MICROEMULSION GEL SYSTEM (Microemulsion gel system에 있어서 Polyol의 효과에 관한 연구)

  • Youn, J.;Jin, P.K.
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.18 no.1
    • /
    • pp.132-149
    • /
    • 1992
  • This study relates to a microemulsion gel which is applied in various cosmetic preparations because of good appearance, superior stability and a thin, uniform, non-greasy fi Am on the skin. Main object of this study is to elucidate the influence of polyol(clarifying agent and/or coupling agent in microemulsion) on microemulsion and to establish the optimum conditions for microemulsion gel formation in the view of superior consistency, stability, clarity and pick-up from a container. The constituents of the system are composed of water, polar ester oi1, nonionic surfactant and polyol. Using the three-component phase diagram and the tetrahedral-phase diagram, we have investigated the changes of transparence regions, consistency and resonance effect by an impact in microemulsion gel varying in polyol ratio. The results of this study showed that the variation in the content of water and couple ins agent has major influence on the microemulsion gel and the optimum formation region of microemulsion gel is the widest when the ratio of glycerine(coupling agent) to water is 63-75% It is believed that optimum use of polyol seems to be helpful to obtain the microemulsion gel containing maximum amount of oil phase with minimum amount of surfactant which is recently one of the major problems of cosmetic chemists.

  • PDF

LQ Inverse Optimal Consensus Protocol for Continuous-Time Multi-Agent Systems and Its Application to Formation Control (연속시간 다개체 시스템에 대한 LQ-역최적 상태일치 프로토콜 및 군집제어 응용)

  • Lee, Jae Young;Choi, Yoon Ho
    • Journal of Institute of Control, Robotics and Systems
    • /
    • v.20 no.5
    • /
    • pp.526-532
    • /
    • 2014
  • In this paper, we present and analyze a LQ (Linear Quadratic) inverse optimal state-consensus protocol for continuous-time multi-agent systems with undirected graph topology. By Lyapunov analysis of the state-consensus error dynamics, we show the sufficient conditions on the algebraic connectivity of the graph to guarantee LQ inverse optimality and closed-loop stability. A more relaxed stability condition is also provided in terms of the algebraic connectivity. Finally, a formation control protocol for multiple mobile robots is proposed based on the target LQ inverse optimal consensus protocol, and the simulation results are provided to verify the performance of the proposed LQ inverse formation control method.

Study of Dyeing Properties by Swelling Agent on meta-aramid Fiber with Cationic Dyes (Swelling agent에 따른 메타계 아라미드 섬유의 Cationic dye 염색특성)

  • Kim, Eun-Mi;Park, Chung-Won;Choi, Jae-Hong
    • Textile Coloration and Finishing
    • /
    • v.24 no.1
    • /
    • pp.1-7
    • /
    • 2012
  • Dyeing and fastness characteristics of 100% meta-aramid fiber were investigated with cationic dyes and swelling agents under various dyeing conditions such as dyeing temperature and pH of dye bath. Dye exhaustion started at around $80^{\circ}C$ and settled down at $130^{\circ}C$. Among swelling agents used, N-methyl formanilide showed comparatively higher K/S values comparing to 1-phenoxypropan-2-ol. Under weak acidic conditions in the range pH 5 to 7, the exhaustion of cationic dyes could be enhanced leading to higher adsorption and stability of colorimetric property. Wash and rubbing fastness were generally good but low light fastness found can be attributable to the poor photo-stability of the cationic dyes.

Mechanical properties of stabilized saline soil as road embankment filling material

  • Li Wei;Shouxi Chai;Pei Wang
    • Geomechanics and Engineering
    • /
    • v.37 no.5
    • /
    • pp.499-510
    • /
    • 2024
  • In northern China, abundant summer rainfall and a higher water table can weaken the soil due to salt heave, collapsibility, and increased moisture absorption, thus the chlorine saline soil (silty clay) needs to be stabilized prior to use in road embankments. To optimize chlorine saline soil stabilizing programs, unconfined compressive strength tests were conducted on soil treated with five different stabilizers before and after soaking, followed by field compaction test and unconfined compressive strength test on a trial road embankment. In situ testing were performed with the stabilized soils in an expressway embankment, and the results demonstrated that the stabilized soil with lime and SH agent (an organic stabilizer composed of modified polyvinyl alcohol and water) is suitable for road embankments. The appropriate addition ratio of stabilized soil is 10% lime and 0.9% SH agent. SH agent wrapped soil particles, filled soil pores, and generated a silk-like web to improve the moisture stability, strength, and stress-strain performance of stabilized soil.