• Proceedings of the KIEE Conference
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• 2003.07b
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• pp.723-725
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• 2003

The result of design and Partial fabrication of a 1 MVA single phase high temperature superconducting(HTS) transformer for power distributions are presented in this paper. The HTS windings are wound as double pancake windings which have advantages of uniform distribution of high voltage over the windings. the rated primary and secondary voltages are 22.9 kV and 6.6 kV respectively. Four HTS tapes are wound in parallel for secondary windings considering the rated currents of the transformer. The HTS windings will be cooled down to 65 K by natural convection of sub-cooled liquid nitrogen using a single-staged GM-cryocooler in order to make the stability of the HTS windings better. The iron core is designed as shell type and isolated from the liquid nitrogen by an FRP cryostat which have a room temperature bore. After the complete fabrication of the total HTS transformer system, performance test of the transformer will be carried out.

• Macromolecular Research
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• v.16 no.6
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• pp.549-554
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• 2008

Proton conducting crosslinked membranes were prepared using polymer blends of polystyrene-b-poly(hydroxyethyl acrylate)-b-poly(styrene sulfonic acid) (PS-b-PHEA-b-PSSA) and poly(vinyl alcohol) (PVA). PS-b-PHEA-b-PSSA triblock copolymer at 28:21:51 wt% was synthesized sequentially using atom transfer radical polymerization (ATRP). FT-IR spectroscopy showed that after thermal ($120^{\circ}C$, 2 h) and chemical (sulfosuccinic acid, SA) treatments of the membranes, the middle PHEA block of the triblock copolymer was crosslinked with PVA through an esterification reaction between the -OH group of the membrane and the -COOH group of SA. The ion exchange capacity (IEC) decreased from 1.56 to 0.61 meq/g with increasing amount of PVA. Therefore, the proton conductivity at room temperature decreased from 0.044 to 0.018 S/cm. However, the introduction of PVA resulted in a decrease in water uptake from 87.0 to 44.3%, providing good mechanical properties applicable to the membrane electrode assembly (MEA) of fuel cells. Transmission electron microscopy (TEM) showed that the membrane was microphase-separated with a nanometer range with good connectivity of the $SO_3H$ ionic aggregates. The power density of a single $H_2/O_2$ fuel cell system using the membrane with 50 wt% PVA was $230\;mW/cm^2$ at $70^{\circ}C$ with a relative humidity of 100%. Thermogravimetric analysis (TGA) also showed a decrease in the thermal stability of the membranes with increasing PVA concentration.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.77.2-77.2
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• 2013

In this talk, I will briefly review recent results of my group related to application of atomic layer deposition (ALD) for fabricating environmental catalysts and organic solar cells. ALD was used for preparing thin films of TiO2 and NiO on mesporous silica with a mean pore size of 15 nm. Upon depositing TiO2 thin films of TiO2 using ALD, the mesoporous structure of the silica substrate was preserved to some extent. We show that efficiency for removing toluene by adsorption and catalytic oxidation is dependent of mean thickness of TiO2 deposited on silica, i.e., fine tuning of the thickness of thin film using ALD can be beneficial for preparing high-performing adsorbents and oxidation catalysts of volatile organic compound. NiO/silica system prepared by ALD was used for catalysts of chemical conversion of CO2. Here, NiO nanoparticles are well dispersed on silica and confiend in the pore, showing high catalytic activity and stability at 800oC for CO2 reforming of methane reaction. We also used ALD for surface modulation of buffer layers of organic solar cell. TiO2 and ZnO thin films were deposited on wet-chemically prepared ZnO ripple structures, and thin films with mean thickness of ~2 nm showed highest power conversion efficiency of organic solar cell. Moreover, performance of ALD-prepared organic solar cells were shown to be more stable than those without ALD. Thin films of oxides deposited on ZnO ripple buffer layer could heal defect sites of ZnO, which can act as recombination center of electrons and holes.

• Korean Journal of Materials Research
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• v.25 no.3
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• pp.138-143
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• 2015

Aluminum nitride, a compound semiconductor, has a Wurtzite structure; good material properties such as high thermal conductivity, great electric conductivity, high dielectric breakdown strength, a wide energy band gap (6.2eV), a fast elastic wave speed; and excellent in thermal and chemical stability. Furthermore, the thermal expansion coefficient of the aluminum nitride is similar to those of Si and GaAs. Due to these characteristics, aluminum nitride can be applied to electric packaging components, dielectric materials, SAW (surface acoustic wave) devices, and photoelectric devices. In this study, we surveyed the crystallization and preferred orientation of AlN thin films with an X-ray diffractometer. To fabricate the AlN thin film, we used the magnetron sputtering method with $N_2$, NH3 and Ar. According to an increase in the partial pressures of $N_2$ and $NH_3$, Al was nitrified and deposited onto a substrate in a molecular form. When AlN was fabricated with $N_2$, it showed a c-axis orientation and tended toward a high orientation with an increase in the temperature. On the other hand, when AlN was fabricated with $NH_3$, it showed a-axis orientation. This result is coincident with the proposed mechanism. We fabricated AlN thin films with an a-axis orientation by controlling the sputtering electric power, $NH_3$ pressure, deposition speed, and substrate temperature. According to the proposed mechanism, we also fabricated AlN thin films which demonstrated high a-axis and c-axis orientations.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.3
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• pp.47-57
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• 2011

All solid rocket propellants are divided in two basic classes according to chemical state: homogeneous(double base) and heterogeneous (composite). Today, composite propellants are extensively used as power sources covering the range from gas generators and small rocket systems to large launch vehicles in space programs. The development of composite rocket propellants in the past was mainly directed to thermoset polymers. But, the thermoset composite propellants have the complication in formulation and fabricating process to adapt to rocket system requirements. In contrast to the thermoset propellant, the PVC plastisols composite propellants have the advantages in the view of loss in manufacturing process, low cost of raw material, and stability of the handling process even though moderate ballistic and mechanical properties. It is predicted that the application field of this class will be used more widely than any other classes.

• Korean Journal of Materials Research
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• v.31 no.9
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• pp.502-510
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• 2021

Hierarchically porous carbon materials with high nitrogen functionalities are extensively studied as high-performance supercapacitor electrode materials. In this study, nitrogen-doped porous carbon textile (N-PCT) with hierarchical pore structures is prepared as an electrode material for supercapacitors from a waste cotton T-shirt (WCT). Porous carbon textile (PCT) is first prepared from WCT by two-step heat treatment of stabilization and carbonization. The PCT is then nitrogen-doped with urea at various concentrations. The obtained N-PCT is found to have multi-modal pore structures with a high specific surface area of 1,299 m² g^-1 and large total pore volume of 1.01 cm³ g^-1. The N-PCT-based electrode shows excellent electrochemical performance in a 3-electrode system, such as a specific capacitance of 235 F g^-1 at 1 A g^-1, excellent cycling stability of 100 % at 5 A g^-1 after 1,000 cycles, and a power density of 2,500 W kg^-1 at an energy density of 3.593 Wh kg^-1. Thus, the prepared N-PCT can be used as an electrode material for supercapacitors.

• Applied Chemistry for Engineering
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• v.32 no.6
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• pp.659-663
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• 2021

10 m³/min (CMM) multi-pollutants abatement system was successfully developed by effectively integrating ozone oxidation, wet scrubbing, and wet electrostatic precipitation for the simultaneous removal of particulate matters (PMs) and NOx in a semiconductor fabrication process. The sophisticated control and optimization of operating parameters were conducted to maximize the destruction and removal efficiency of NOx. In particular, the stability test of a wet electrostatic precipitator was carried out in parallel for 30 days to validate the reliability of core parts including a power supply. An O₃/NO ratio, which is the most important operating parameter, was optimized to be about 1.5 and the optimization of wet scrubbing with a reducing agent made it possible to analyze the contribution of neutralization reaction.

• Korean Journal of Materials Research
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• v.32 no.9
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• pp.369-378
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• 2022

The recycling of solid waste materials to fabricate carbon-based electrode materials is of great interest for low-cost green supercapacitors. In this study, porous carbon foam (PCF) was prepared from waste floral foam (WFF) as an electrode material for supercapacitors. WFF was directly carbonized at various temperatures of 600, 800, and 1,000 ℃ under an inert atmosphere. The WFF-derived PCF (C-WFF) was found to have a specific surface area of 458.99 m²/g with multi-modal pore structures. The supercapacitive behavior of the prepared C-WFF was evaluated using a three-electrode system in a 6 M KOH aqueous electrolyte. As a result, the prepared C-WFF as an active material showed a high specific capacitance of 206 F/g at 1 A/g, a rate capability of 36.4 % at 20 A/g, a specific power density of 2,500 W/kg at an energy density of 2.68 Wh/kg, and a cycle stability of 99.96 % at 20 A/g after 10,000 cycles. These results indicate that the C-WFF prepared from WFF could be a promising candidate as an electrode material for high-performance green supercapacitors.

• Journal of Drive and Control
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• v.18 no.4
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• pp.1-8
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• 2021

An electro proportional pressure control valve is mainly used to control the clutch of an agricultural tractor's automatic transmission. During transmission, the operating, hydraulic oil is mix with many kinds of contaminants. The contaminants can be trapped between the valve body and spool of the proportional pressure control valve leading to abnormal operating conditions and finally critical damage to the transmission hydraulic system. The present study aimed to verify the valve control algorithm as a basic study of developing control logic that removes contaminants between the spool and the body of the proportional pressure control valve. To develop the algorithm, MATLAB/SIMULINK was used. PWM method was used to control the applied solenoid coil current. The effectiveness of the algorithm was verified by comparing the actual pressure of the normal valve with the actual pressure of the abnormal valve. Based on the present study findings, when the algorithm was applied, the response of the valve pressure according to the current became stable and oil contaminated particles were removed. In the future study, the control algorithm will be optimized for the stability of the proportional pressure reducing valve, and it will be verified in consideration with the driving of the clutch.

• Tribology and Lubricants
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• v.39 no.4
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• pp.139-147
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• 2023

Cavitation phenomena observed during the operation of a submerged plain journal bearing (PJB) can affect bearing performance parameters such as dynamic coefficients, whirl frequency ratio, and critical mass. This study presents numerical solutions of the Reynolds equation for steadily and dynamically loaded submerged PJBs with half-Sommerfeld (HS), Reynolds, and Jakobsson-Floberg-Olsson (JFO) cavitation models when the supply pressure is larger or equal to the cavitation pressure. The loads at various eccentricity ratios are identical; however, the attitude angle is approximately 6% smaller when the eccentricity ratio is between 0.2 and 0.7 and the JFO model is used, compared to that when the Reynolds model is used. Dynamic coefficients obtained with the HS and Reynolds model show good agreement with each other, except for k_xz, which is sensitive to changes in the force normal to the rotor weight, and is attributed to the difference in the attitude angle obtained with each cavitation model. Stiffness coefficients are determined using the pressure distribution in the film, and therefore, when the JFO model is used, the direct stiffness coefficients are affected and show opposite signs for most eccentricity ratios. The mass-conservative JFO model can predict at least a 30% smaller critical mass compared to that using the HS and Reynolds models. Thus, the instability analysis results can change based on the cavitation model used in a submerged PJB. The results of this research indicate that the JFO model should be used when designing a rotor system supported by submerged PJBs.