• Title/Summary/Keyword: Nuclear Reaction

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Residual Stress Variation by Isothermal and Isochronal Annealing in Cold Rolled Alloy 600 (냉간 압연된 Alloy 600에서 등온 및 등시 소둔에 의한 잔류응력의 변화)

  • Kim, Sung Soo;Park, Duck Geun;Cheong, Young Moo
    • Korean Journal of Metals and Materials
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    • v.49 no.6
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    • pp.462-467
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    • 2011
  • In order to understand why annealing at $480^{\circ}C$ for several hour prevents the initiation of PWSCC, the residual stress variation with isothermal annealing at $480^{\circ}C$ and isochronal annealing between 480 and $800^{\circ}C$ in cold rolled Alloy 600 was investigated by the XRD method. The isothermal annealing decreased residual stress slightly in the rolling direction but not in the transverse direction, whereas the isochronal annealing for two hours increased residual stress. It seemed that the decrease in residual stress by isothermal annealing was due to lattice contraction by an ordering reaction because the isothermal annealing increased hardness. The effects of the isochronal annealing could be interpreted as the influence of thermal expansion and a disordering reaction.

Effects of the Ordering Reaction on High Temperature Mechanical Behavior in Alloy 600 (Alloy 600에서 고온 기계적 거동에 미치는 규칙 반응의 영향)

  • Kim, Sung Soo;Kim, Dae Whan;Kim, Young Suk
    • Korean Journal of Metals and Materials
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    • v.50 no.10
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    • pp.703-710
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    • 2012
  • The effects of the ordering reaction on high temperature mechanical behavior is investigated by tensile tests at $2{\times}10^{-2}/s-3.3{\times}10^{-5}/s$ up to $745^{\circ}C$. The tensile deformed region is examined by differential scanning calorimeter (DSC), TEM, and high resolution neutron diffraction (HRPD). The results showed that a plateau of tensile strength appeared at $150-500^{\circ}C$ whereas the elongation minimum occurred at about $600^{\circ}C$. This suggests that the occurrence of a plateau does not cause the elongation minimum. The temperature of the elongation minimum decreases with the strain rate. HRPD results show a lattice contraction in the tensile deformed specimen at the temperature of the plateau occurring region. The plateau of tensile strength, the lattice contraction, and the occurrence of serration appeared in the same temperature region.

Study on the Characteristics of Catalyst Reaction for Hydrogen Recovery from Nuclear Fusion Exhaust Gas (핵융합 배가스 중 수소 회수를 위한 촉매반응 특성 연구)

  • JUNG, WOOCHAN;JUNG, PILKAP;KIM, JOUNGWON;MOON, HUNGMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.5
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    • pp.402-408
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    • 2015
  • In D-T fusion reaction, $D_2$ (duterium) and $T_2$(tritium) are used as fuel gas. The exhaust gas of nuclear fusion includes hydrogen isotopes $Q_2$ (Q means H, D or T), tritiated components ($CQ_4$ and $Q_2O$), CO, $CO_2$, etc. All of hydrogen isotopes should be recovered before released to the atmosphere. This study focused on the recovery of hydrogen isotopes from $CQ_4$ and $Q_2O$. Two kinds of experiments were conducted to investigate the catalytic reaction characteristics of SMR (Steam Methane Reforming) and WGS (Water Gas Shift) reactions using Pt catalyst. First test was performed to convert $CH_4$ into $H_2$ using 6% $CH_4$, 6% CO/Ar feed gas. In the other test, 100% CO gas was used to convert $H_2O$ into $H_2$ at various reaction conditions (reaction temperature, S/C ratio, GHSV). As a result of the first test, $CH_4$ and CO conversion were 41.6%, 57.8% respectively at $600^{\circ}C$, S/C ratio 3, GHSV $2000hr^{-1}$. And CO conversion was 72% at $400^{\circ}C$, S/C ratio 0.95, GHSV $333hr^{-1}$ in the second test.

Development of a Mechanistic Model for Hydrogen Generation in Fuel-Coolant Interactions

  • Lee, Byung-Chul;Park, Goon-Cherl;Chung, Chang-Hyun
    • Nuclear Engineering and Technology
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    • v.29 no.2
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    • pp.99-109
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    • 1997
  • A dynamic model for hydrogen generation by Fuel-Coolant Interactions(FCI) is developed with separate models for each FCI stage, coarse mixing and stratification. The model includes the physical concept of FCI, semi-empirical heat and mass transfer correlation and the concentration diffusion equation with the general non-zero boundary condition. The calculated amount of hydrogen, which is mainly generated in stratification, is compared with the FITS experiments. The model developed in this study shows a good agreement within a range of 10 % fuel oxidation rate and predicts the controlled mechanism of the chemical reaction very well. And this model predicts more accurately than the previous works. It is shown from the sensitivity study that the higher initial temperature of fuel particle is, the larger the reaction rate is. Up to 2700 K of temperature of the particle, the reaction rate increases rapid, which can lead to metal ignition.

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Conceptual Safety Design Analyses of Korea Advanced Liquid Metal Reactor

  • Suk, S.D.;Park, C.K.
    • Nuclear Engineering and Technology
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    • v.31 no.6
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    • pp.66-82
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    • 1999
  • The national long-term R&D program, updated in 1997, requires Korea Atomic Energy Research Institute(KAERI) to complete by the year 2006 the basic design of Korea Advanced Liquid Metal Reactor(KALIMER), along with supporting R&D work, with the capability of resolving the issue of spent fuel storage as well as with significantly enhanced safety. KALIMER is a 150 MWe pool-type sodium cooled prototype reactor that uses metallic fuel. The conceptual design is currently under way to establish a self-consistent design meeting a set of major safety design requirements for accident prevention. Some of the current emphasis includes those for inherent and passive means of negative reactivity insertion and decay heat removal, high shutdown reliability, prevention of and protection from sodium chemical reaction, and high seismic margin, among others. All of these requirements affect the reactor design significantly and involve extensive supporting R&D programs. This paper summarizes some of the results of conceptual engineering and design analyses performed for the safety of HAMMER in the area of inherent safety, passive decay heat removal, sodium water reaction, and seismic isolation.

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Measurement of Branching Ratio for broad 27-keV Resonance of $^{19}F(n,g)^{20}F$ Reaction by using Time-of-flight Method with Anti-Compton NaI(Tl) Spectrometer

  • Lee, Sam-Yol
    • Journal of the Korean Society of Radiology
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    • v.2 no.1
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    • pp.31-34
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    • 2008
  • The neutron capture spectrum for the light nuclide was very useful to study the nuclear structure. In the present study, the capture gamma-ray from the 27-keV resonance of $^{19}F(n,g)^{20}F$ reaction were measured with an anti-Compton NaI(Tl) spectrometer and the 3-MV Pelletron accelerator of the Research Laboratory for Nuclear Reactors at the Tokyo institute of technology. A neutron Time-of-Flight method was adopted with a 1.5 ns pulsed neutron source by the $^7Li(p,n)^7Be$ reaction. In the present experiment, a Teflon(($CF_2$)n) sample was used The sample was disk with a diameter of 90mm. The thickness of sample was determined so that reasonable counting rates could be obtained and the correction was not so large for the self-shielding and multiple scattering of neutrons in the sample, and was 5mm. The primary gamma-ray transitions were compared with previous measurement of Kenny.

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Studies on Setting up of Radioimmunoassay System of Thyroid Stimulating Hormone (갑상선자극(甲狀腺刺戟)호르몬의 방사면역측정법(放射免疫測定法) 확립(確立)에 관한 연구(硏究))

  • Kim, Jae-Rok;Park, Kyung-Bae;Awh, Ok-Doo
    • The Korean Journal of Nuclear Medicine
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    • v.20 no.1
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    • pp.75-83
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    • 1986
  • Various TSH RIA kit components were prepared. Conditions for $^{125}I$ labelling of h-TSH were optimized by diminishing the amount of chloramine-T, ertending reaction time and lowering reaction temperature. Yield, specific activity, and immunological activity could be maintained moderately under such mild reaction conditions. The mixture of polyethyleneglycol(PEG) and second antibody worked effectively as a B/F separation agent. Even though the mixture was made with more diluted PEG and second antibody than those of using the sole component separately, the tine required for the B/F separation was shorter in case of using the mixture. The sequential saturation technique was efficient than those of applying ordinary equilibrium saturation technique in assay sensitivity and assay precision points of view.

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Pressure Effects on Zircaloy-4 Steamside Corrosion and Hydrogen Pick-up

  • Ok, Young-kil;Kim, Yong-soo
    • Nuclear Engineering and Technology
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    • v.30 no.5
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    • pp.396-402
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    • 1998
  • Experiments on the steamside corrosion and hydrogen pick-up of Zircaloy-4 under high pressure up to 10.3MPa are carried out to estimate the pressure effects on the kinetics. Temperature and reaction time are determined to be 37$0^{\circ}C$ and 72hours for the pre-transition test and $700^{\circ}C$ and 210minutes for the post-transition test, respectively. Results show that under 10.3MPa pressure the oxidation reaction is 50% and 100% enhanced in the pre-and the post-transition regime, respectively. Total amount of hydrogen uptake in the reaction is proportionally increased as corrosion weight gain is elevated. However, pick-up fraction is not affected by the high pressure. The fraction is almost twice greater than that in the waterside corrosion. Edges in the specimens play a certain role in the enhancement, especially in the post-transition regime. To identify physical property changes of oxide film such as micro-cracks or micro-pores, careful and thorough examination must be needed with some special techniques.

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Effect of a chemical reaction on magnetohydrodynamic (MHD) stagnation point flow of Walters-B nanofluid with newtonian heat and mass conditions

  • Qayyum, Sajid;Hayat, Tasawar;Shehzad, Sabir A.;Alsaedi, Ahmed
    • Nuclear Engineering and Technology
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    • v.49 no.8
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    • pp.1636-1644
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    • 2017
  • The main purpose of this article is to describe the magnetohydrodynamic stagnation point flow of Walter-B nanofluid over a stretching sheet. The phenomena of heat and mass transfer are based on the involvement of thermal radiation and chemical reaction. Characteristics of Newtonian heating are given special attention. The Brownian motion and thermophoresis models are introduced in the temperature and concentration expressions. Appropriate variables are implemented for the transformation of partial differential frameworks into sets of ordinary differential equations. Plots for velocity, temperature, and nanoparticle concentration are displayed and analyzed for governing parameters. The skin friction coefficient and local Nusselt and Sherwood numbers are studied using numerical values. The temperature and heat transfer rate are enhanced within the frame of the thermal conjugate parameter.

Residual salt separation technique using centrifugal force for pyroprocessing

  • Kim, Sung-Wook;Lee, Jong Kwang;Ryu, Dongseok;Jeon, Min Ku;Hong, Sun-Seok;Heo, Dong Hyun;Choi, Eun-Young
    • Nuclear Engineering and Technology
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    • v.50 no.7
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    • pp.1184-1189
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    • 2018
  • Pyroprocessing uses various molten salts during electrochemical unit processes. Reaction products after the electrochemical processes must contain a significant amount of residual salts to be separated. Vacuum distillation is a common method to separate the residual salts; however, its high operation temperature may cause side reactions. In this study, a simple rotation technique using centrifugal force was suggested to separate the residual salts from the reaction products at relatively low temperature compared to the distillation technique. When a reaction product container with porous wall rotates inside a vessel heated above the melting point of the residual salt, the residual salt in the liquid phase is separated through centrifugal force. It was shown that the $LiNO_3-Al_2O_3$ mixture can be separated by this technique to leave solid $Al_2O_3$ inside the container, with a separation efficiency of 99.4%.