• Title/Summary/Keyword: Grain refinement

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Effects of Ti Addition and Homogenizing Heat Treatment on the Mechanical Properties of Centrifugal Cast Cu-Zn-Al Alloy (원심주조한 Cu-Zn-Al계 합금의 기계적 성질에 미치는 Ti 첨가와 균질화 처리의 영향)

  • Kwon, Young-Hwan;Jea, Chang-Wooing;Yoon, Jae-Hong;Kang, Chang-Yong;Kim, Chang-Gyu
    • Journal of Korea Foundry Society
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    • v.17 no.5
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    • pp.450-457
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    • 1997
  • Effects of Ti addition and homogenizing heat treatment on the mechanical properties in Cu-Zn-Al alloy (high strength yellow brass) were investigated. Grain refinement was successfully achieved by Ti addition. The microstructure, which was composed of island or fine feather-like branched Ti compounds was changed to feather-like eutectic microstructure as the content of Ti increased. The highest hardness value was obtained for 0.5 wt.% Ti specimen and the second was Ti non-added specimen in as-cast condition. The highest tensile strength was obtained for 0.5 wt.% Ti specimen. Because of the presence of cast defects and worse castability, tensile strength decreased as the content of Ti increased. Elongation increased with increasing homogenizing time and temperature; remarkable increase was obtained for $400^{\circ}C$ homogenizing temperature in the 0.5 wt.% Ti specimen. For $500^{\circ}C$ and $600^{\circ}C$ homhgenizing, temperature, high elongation was obtained in 2 and 4 wt.% Ti specimen.

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Modification Behavior of Eutectic Si with Varying Heat Treatment Conditions in A356 Alloy with Al2Ca (Al2Ca를 함유한 A356 합금에서의 다양한 열처리 조건에 따른 공정 Si 개량화 거동)

  • Kim, Se-Jun;Hyun, Soong-Keun;Kim, Shae K.;Yoon, Young-Ok
    • Journal of Korea Foundry Society
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    • v.34 no.5
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    • pp.156-161
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    • 2014
  • This study is focused on the effect of $Al_2Ca$ as a modifier on eutectic Si modification of A356 alloy. Microstructural observation was carried out for as-cast, as-solution treated and as-aged samples. Solution treatment and aging were performed for 2, 4, 6 and 10 hrs at $540^{\circ}C$ and $170^{\circ}C$, respectively. Although A356 alloy, which $Al_2Ca$ was added, has no significant difference in as-cast phases with normal A356 alloys, it shows much more modified eutectic Si, grain refinement and improved tensile property both in as-cast and as-heat treated conditions. TGA result shows that $Al_2Ca$ added A356 alloy has a certain improvement in oxidation resistance.

Texture Evolution of Extruded AZ80 Mg Alloy under Various Compressive Forming Conditions (AZ80 마그네슘 합금 압출재의 압축 성형조건에 따른 방위특성 분석)

  • Yoon, J.H.;Lee, S.I.;Lee, J.H.;Park, S.H.;Cho, J.H.
    • Transactions of Materials Processing
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    • v.21 no.4
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    • pp.240-245
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    • 2012
  • With the increasing demand for light-weight materials to reduce fuel consumption, the automobile industry has extensively studied magnesium alloys which are light weight metals. The intrinsic poor formability and poor ductility at ambient temperature due to the hexagonal close-packed (HCP) crystal structure and the associated insufficient number of independent slip systems restricts the practical usage of these alloys. Hot working of magnesium alloys using a forging or extrusion enables net-shape manufacturing with enhanced formability and ductility since there are several operative non-basal slip systems in addition to basal slip plane, which increases the workability. In this research, the thermomechanical properties of AZ80 Mg alloy were obtained by compression testing at the various temperatures and strain rates. Optical microscopy and EBSD were used to study the microstructural behavior such as misorientation distribution and dynamic recrystallization. The results were correlated to the hardening and the softening of the alloy. The experimental data in conjunction with a physical explanation provide the optimal conditions for net-shape forging under hot or warm temperatures through control of the grain refinement and the working conditions.

Palladium-Nickel Alloy Electrodeposition Using Ethylenediamine as Complexing Agent (에틸렌디아민을 착화제로 사용하는 팔라듐-니켈 합금도금)

  • Choi, Byungha;Sohn, Ho-Sang;Kim, Kyung Tae;Son, Injoon
    • Journal of Surface Science and Engineering
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    • v.47 no.5
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    • pp.215-220
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    • 2014
  • Electrodeposition behaviors of Pd-Ni alloys were investigated from the polarization curves in a solution containing ethylenediamine as complexing agent. The microstructure and hardness of electrodeposited Pd-Ni alloys were also characterized. Codeposition of Pd-Ni alloys was successfully performed in the wide current density ranging from 2 to $5000A{\cdot}m^{-2}$ because the deposition potential of Pd became close to that of Ni in the ethylenediamine-contained solution. It was also found from X-ray diffraction patterns that the solid solution between Pd and Ni was formed with variation of the composition of alloys. The measured hardness of Pd-Ni alloys increased with increasing the contents of Ni due to solid solution strengthening and grain refinement. The electrodeposited Pd-Ni alloys also exhibited a crack free smooth surface morphology from the SEM observation.

Microstructure and Tensile Property of In-Situ (TiB+TiC) Particulate Reinforced Titanium Matrix Composites (반응생성 합성에 의한 (TiB+TiC) 입자강화 Ti기 복합재료의 미세조직 및 인장특성 평가)

  • Choi, Bong-Jae;Kim, Young-Jig
    • Korean Journal of Metals and Materials
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    • v.48 no.8
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    • pp.780-789
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    • 2010
  • The aim of this study is to evaluate the microstructure and tensile property of in-situ (TiB+TiC) particulate reinforced titanium matrix composites (TMCs) synthesized by the investment casting process. Boron carbide ($1,500{\mu}m$ and $150{\mu}m$) was added to the titanium matrix during vacuum induction melting, which can provide the in-situ reaction of $5Ti+B_4C{\rightarrow}4TiB+TiC$. 0.94, 1.88 and 3.76 wt% of $B_4C$ were added to the melt. The phases identification of the in-situ synthesized TMCs was examined using scanning electron microscopy, an X-ray diffractometer, an electron probe micro-analyzer and transmission electron microscopy. Tensile properties of TMCs were investigated in accordance with the reinforcement size and volume fraction. The improvement of tensile property of titanium matrix composites was caused by load transfer from the titanium matrix to the reinforcement and by grain refinement of titanium matrix and reinforcements.

Effect of C, Mn and Al Additions on Tensile and Charpy Impact Properties of Austenitic High-manganese Steels for Cryogenic Applications (극저온용 오스테나이트계 고망간강의 인장 및 충격 특성에 미치는 C, Mn, Al 첨가의 영향)

  • Lee, Seung-Wan;Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.189-195
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    • 2019
  • The effect of C, Mn, and Al additions on the tensile and Charpy impact properties of austenitic high-manganese steels for cryogenic applications is investigated in terms of the deformation mechanism dependent on stacking fault energy and austenite stability. The addition of the alloying elements usually increases the stacking fault energy, which is calculated using a modified thermodynamic model. Although the yield strength of austenitic high-manganese steels is increased by the addition of the alloying elements, the tensile strength is significantly affected by the deformation mechanism associated with stacking fault energy because of grain size refinement caused by deformation twinning and mobile dislocations generated during deformation-induced martensite transformation. None of the austenitic high-manganese steels exhibit clear ductile-brittle transition behavior, but their absorbed energy gradually decreases with lowering test temperature, regardless of the alloying elements. However, the combined addition of Mn and Al to the austenitic high-manganese steels suppresses the decrease in absorbed energy with a decreasing temperature by enhancing austenite stability.

Analysis on Milling Behavior of Oxide Dispersion Strengthened Ni-based Atomizing Powder with Ni5Y Intermetallic Phase (Ni5Y 합금상이 형성된 Ni계 산화물 분산강화 아토마이징 분말의 밀링 거동 분석)

  • Park, Chun Woong;Byun, Jong Min;Choi, Won June;Kim, Young Do
    • Journal of Powder Materials
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    • v.26 no.2
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    • pp.101-106
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    • 2019
  • Ni-based oxide dispersion strengthened (ODS) alloys have a higher usable temperature and better high-temperature mechanical properties than conventional superalloys. They are therefore being explored for applications in various fields such as those of aerospace and gas turbines. In general, ODS alloys are manufactured from alloy powders by mechanical alloying of element powders. However, our research team produces alloy powders in which the $Ni_5Y$ intermetallic phase is formed by an atomizing process. In this study, mechanical alloying was performed using a planetary mill to analyze the milling behavior of Ni-based oxide dispersions strengthened alloy powder in which the $Ni_5Y$ is the intermetallic phase. As the milling time increased, the $Ni_5Y$ intermetallic phase was refined. These results are confirmed by SEM and EPMA analysis on microstructure. In addition, it is confirmed that as the milling increased, the mechanical properties of Ni-based ODS alloy powder improve due to grain refinement by plastic deformation.

Development of a micro-scale Y-Zr-O oxide-dispersion-strengthened steel fabricated via vacuum induction melting and electro-slag remelting

  • Qiu, Guoxing;Zhan, Dongping;Li, Changsheng;Qi, Min;Jiang, Zhouhua;Zhang, Huishu
    • Nuclear Engineering and Technology
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    • v.51 no.6
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    • pp.1589-1595
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    • 2019
  • In this paper, the CLAM steel strengthened by micro-scale Y-Zr-O was prepared by vacuum induction melting followed by electroslag remelting (VIM-ESR). Yttrium (Y) and zirconium (Zr) were easy to aggregates into massive yttrium-zirconium-rich inclusions in the steel melted by vacuum induction melting (VIM), which would interrupt the continuity of the matrix and reduce the mechanical properties of steel. Micron-sized Y-Zr-O inclusions would be produced with the removal of original blocky Y-Zr-rich inclusions and the submicron-sized inclusions smaller than $0.2{\mu}m$ could be retained in the steel. The small grain size and the better refinement and distribution uniformity of Y-Zr-O inclusions after remelting would be responsible for the better yield strength and toughness. For VIM-ESR alloy, the ultimate tensile strength is 749 MPa and the yield strength is 642 MPa at room temperature, meanwhile they are 391 MPa and 367 MPa at $600^{\circ}C$, respectively. Meanwhile, the ductile-brittle transition temperature (DBTT) reduced from $-43^{\circ}C$ (VIM) to $-76^{\circ}C$ (VIM-ESR).

Effect of the Amplitude in Ultrasonic Nano-crystalline Surface Modification on the Corrosion Properties of Alloy 600

  • Kim, Ki Tae;Kim, Young Sik
    • Corrosion Science and Technology
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    • v.18 no.5
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    • pp.196-205
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    • 2019
  • Surface modification techniques are known to improve SCC by adding large compressive residual stresses to metal surfaces. This surface modification technology is attracting attention because it is an economical and practical technology compared to the maintenance method of existing nuclear power plants. Surface modification techniques include laser, water jet and ultrasonic peening, pinning and ultrasonic Nano-crystal surface modification (UNSM). The focus of this study was on the effect of ultrasonic amplitude in UNSM treatment on the corrosion properties of Alloy 600. A microstructure analysis was conducted using an optical microscope (OM), scanning electron microscope (SEM) and electron backscattering diffraction (EBSD). A cyclic polarization test and AC-impedance measurement were both used to analyze the corrosion properties. UNSM treatment influences the corrosion resistance of Alloy 600 depending on its amplitude. Below the critical amplitude value, the pitting corrosion properties are improved by grain refinement and compressive residual stress, but above the critical amplitude value, crevices are formed by the formation of overlapped waves. These crevices act as corrosion initiators, reducing pitting corrosion resistance.

Analysis for Deformation and Fracture Behavior of Magnesium during Equal Channel Angular Pressing by the Finite Element Method (마그네슘의 등통로각압축 공정 시 변형 및 파괴 거동에 대한 유한요소해석)

  • Yoon, Seung Chae;Pham, Quang;Kim, Hyoung Seop
    • Korean Journal of Metals and Materials
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    • v.46 no.3
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    • pp.144-149
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    • 2008
  • Equal channel angular pressing (ECAP) has been studied intensively over the decade as a typical top-down process to produce ultrafine/nano structured materials. ECAP has successfully been applied for a processing method of severe plastic deformation to achieve grain refinement of magnesium and to enhance its low ductility. However, difficult-to-work materials such as magnesium and titanium alloys were susceptible to shear localization during ECAP, leading to surface cracking. The front pressure, developed by Australian researchers, can impose hydrostatic pressure and increase the strain level in the material, preventing the surface defect on workpiece. In the present study, we investigated the deformation and fracture behavior of pure magnesium using experimental and numerical methods. The finite element method with different ductile fracture models was employed to simulate plastic deformation and fracture behavior of the workpiece.