Recently, as to destruction and renovation of aged building, waste concretes have been reclaimed near foreshore and filled up underground. Recycling demolished concrete as aggregate helps to settle economic and environmental problems of obtaining superior aggregates from natural sources and to dispose waste concretes. An experimental study was carried out to investigate the strength characteristics of no-fine concrete containing recycled aggregates. The cement-aggregate weight ratios of 1: 5, 1: 6, 1: 7 and water-cement ratios of 30, 35, 40, 45% were chosen for the mix design of no-fine concretes. The compressive and splitting tensile strength at 7 and 28 days were measured for 12 different mixes. On the basis of test results, the optimum mix proportion of no-fine concrete containing recycled aggregates was determined and applied to the production of retaining wall block.

The waste sludge is by-produced about 20-30% of total production and arised to the severe problems of this mine's surrounding environmnet. This study was invested the composition of component, particle of size of the waste sludge by Chemical Analysis, X, R, D, Particle Size Analyzer and the physical properties (air content, slump, strength, etc) of concrete when the waste sludge is added into concrete. so, It's recomended the proper content of the waste sludge to be added into concrete. and then, is verified to be applied at batch plant in field. Above the results, the recomeded content of the waste sludge is about 2-4% (about 4-8% in cement) in aggregates and when it's added the recomended content, they are detected to be more or less changed the physical properties of concrete, ( equally strength and durability, little less air con tent, little increased shinkage, etc). but the application of the recomended content don't arise the problem of the basic quality control of concrete and physical properties.

This experiments carried out in order to investigate decreasing of the hydration heat and physical characteristics of the low blaine OPC. The experiments results indicated hydration heat was reduced by about 15% in th low blaine OPC(2300$\textrm{cm}^2$/g). The Mini-slump value of the cement paste was significantly increased and viscosity of one was decreased as blaine value in OPC decrease.

In this study, blended cement with low blaine(2000, 3000$\textrm{cm}^2$/g) blast-furnace slag power by 10-70wt.% was investigated through the measurement hydration heat, physical properties. The experiment results indicated compressive strength was decreased as low blaine slag blended, but hydration heat was reduced significantly and flow of the cement paste was increased.

일반적으로 동일한 배합에서 콘크리트의 강도를 증진시키는 방법중에서 혼화재를 넣는 방법이 일반적이다. 이는 첨가된 혼화재의 양만큼 생산비용이 증가하며, 본 실험에서 콘크리트 강도를 증진시키기 위해 사용한 자화수는 자석을 통과시켜 만든 물이며 제작방법 이 매우 간편하고 자석이라는 비소모성 및 무동력의 장치를 사용하여, 또한 화학물질을 사 용하지 않고 얻을 수 있다. 이때의 자화수는 외관상으로는 보통물과 아무런 차이가 없으며 무색무취이다. 즉 강력한 자장속에 보통 물을 통과시켜서 이온화된 자화수를 얻을 수 있을 것이다. 실례로 러시아 "샤프스쿠스크" 철근 콘크리트 제품공장에서는 자화수를 사용해서 매년 약 15%의 시멘트절약에 성공하고 있고, 모스크바의 철근콘크리트연구소에서 자주 자 화수의 전문회의가 열리며, 매번 좋은 결과를 서로 보고하고 있다고 한다. 본 실험에서는 자 화수에 의한 강도증진효과를 보기 위해서 동일배합에서 보통물과 자화수를 배합수로 하여 각각의 콘크리트 공시체를 제작해 압축강도를 비교하였다. 그 결과 보통물을 사용해 제작한 공시체 보다 4~13% 가량 강도증진효과를 보았다. 따라서 다른 혼화재를 사용하지 않고 오 직 자화수를 배합수로 하여 제작된 콘크리트 강도를 높임으로써, 동일한 배합강도를 얻기 위해서 보통물을 배합수로 제작된 콘크리트에 비해 시멘트 사용량을 줄일 수 있어 이에 따 른 경제적 효과를 얻을 수 있다고 본다. 이에 따라 본 연구는 여러 가지변수에 따라 자화수 가 콘크리트 강도증진에 어떠한 영향을 주는지를 알아보았다.는지를 알아보았다.

This study was carried out to investigate quantitatively the relationship between the water binder ratio and the concrete strength using finely ground granulated furnace blast slag. In the experiment, the compressive strength and elastic modulus of concrete which slag contents are 0%, 10%, 20% and 30% at 7days and 28days age. As a result, the compressive strength have a high correlation with slag contents and water binder ratio. Thus, it is possible to calculate the water binder ratio using compressive strength of concrete contented with slag.

Recently, it has been reported that recycling of wasted glasses should be a hot issue in related business field. Thus, the purpose of this experimental research is to recycle wasted glasses by substituting for the cement in mortar and concrete. As a pilot test, workability and the strength of mortar with recycled glass have been tested and analyzed according to replacement ratio of recycled glass with grain size of them. As a result, considering the workability and the strength of mortar containing recycled glass, the existence of the optimum replacement ratio and grain size of them have been obtained.

Experimental investigation was undertaken to determine early-age strength development and the relationships between the mechanical properties of type I, V and V/fly ash cement concrete with different curing temperature. The tests for mechanical properties, i.e., compressive strength, splitting tensile strength and modulus of elasticity were carried out for type, I, V and V with 15% replacement with fly ash cement concrete. For this purpose 480 concrete cylinders cured at isothermal conditions of 10, 23, 35 and 5$0^{\circ}C$ were tested at ages of 1, 3, 7 and 28days. According to the experiments, the concrete subjected to high temperature at early age got greater strength at early age, however eventually lower strength at late age. The derived relationships between compressive strength and splitting tensile strength and elastic modulus of elasticity appeared to be identical for all types of cement.

The purpose of this study to fine the mixture of concrete for Top-Down method. As a result, In fresh concrete, slump value and slump-flow value were increased as fly ash concrete(10% ratio). When plasticizer was added 1.5% by weigh of binder in concrete, no fly ash concrete and fly ash concrete(10% ratio) all occurred segregation. And, no fly ash concrete and fly concrete(10% ratio) all showed compressive strength development close plain concrete as increasing plasticizer quantity. Especially, in case of 1.5% plasticizer of binder showed high compressive strength development.

This experimental Study presents the flow properties of mortar Using the Blast-furnace Slag Sand. It gives following result. The substitution rate is inversely proportional to flow. But W/C ratio is directly proportional to flow. Consequently Flow characteristics of the Blast-furnace mortar is simillar to the river sand mortar.

This experimental Study presents the strength properties of mortar Using the Blast-furnace Slag Sand. It gives following result. The 3-days and 7-days compression strength is increase as substitution rate is higher. As W/C ratio increase, the strength is decrease. The flexural strength is increase as substitution rate is higher specially. As flexural strength ratio for compression strength is each 16.7%, 21.1%, 25.4% on 3-days, 7-days, 28-days, long age flexural strength is higher than short age.

Recently, it has been increased to construct massive concrete structures, like under-ground structure, offshore structure etc., ie. concrete construction have become larger and higher and are demanding lower heat concrete to prevent thermal cracking. It has been progressed to replace cements with fly-ash and slag to lower heat of hydration, but it is hard to control quality of the mineral admixtures in stage of adjusting of real construction. Application of low heat portland(Belite Rich) cement for the mass concrete is the best solution to satisfied those requirements. Here are explained the basic properties of fresh concrete as well as hardened concrete of using low heat portland cement(LHPC). Also, we compare the results of adiabatic temperature rise test using LHPC and OPC.

In this study, we investigate the difference of concrete between natural aggregate and electric are furnace(EAF) slag one in oder to use EAF slag aggregate as coarse aggregate in concrete. We find the physical and chemical properties of EAF slag aggregate for the aging process. We consider the properties od the concrete made with EAF slag aggregate which are compressive strength, splitting tensile strength and modulus of elasticity.

The physical properties of cement sludge treated with hydrofluosilicic acid were investigated. The compressive strength of cement mortar substituted cement sludge was decreased than that of OPC(ordinary portland cement) mortar. Cement sludge, for improving its physical properties, was treated with hydrofluosilicic acid. And compressive strength of cement mortar substituted TCS was greatly improved than that of OPC mortar. Particularly, cement mortar substituted TCS had the higher value in water-proofness than of OPC.

Recently, underwater concrete constructions are increasing. Therefore it is considered important to control the quality of underwater concrete. In this paper, we have an intention of evaluating fundamental properties of underwater concrete using the Ground Granulated Blast Furnace Slag (GGBF Slag). Thus, it has been investigated that the slump flow of the concrete, pH value and suspended solids in solution, compressive strength on both of specimens made above and below water. Also the percentage of GGBF Slag was found to alter the filling-up in underwater concrete.

The purpose of this study is to use paper sludge ash as a material in manufacturing high strength admixture. The reactivity of paper sludge ash as iteself is low for the crystallized non-reactive $SiO_2$, but when the $SiO_2$ was removed, the phase component is mainly composed of glass phase which could react with cement hydrates. In this study, we manufactured high strength admixture using separated paper sludge ash, and examined the strength of mortar, spun concrete with and without this high strength admixture in steam curing. The strength of spun concrete with high strength admixture including paper sludge ash was more higher than that of spun concrete without admixture. As a result, it was found that paper sludge ash could be used to a pozzolanic material in manufacturing high strength admixture.

Fluidity retention of concrete used high range water reducing AE agent(HWAE) is varied according to type, dosage amount and dosing method of HWAE. The type and substitution ratio of mineral admixture also have influence on the fluidity retention of concrete using HWAE. For the purpose of improving the fluidity retention in concrete used HWAE, 3 types of HWAE and ground granulated blast furnace slag(SG) are applied in cement-based composites such as cement paste, mortar and concrete respectively. According to using the HWAE of naphthalene sulfonates and SG, the fluidity retention of mortar and concerete is improving the fluidity retention and strength of concrete regardless of type of HWAE.

A study is carried out to investigate the characteristics of concrete various level(0~60%) of fly ash. These results indicate that compressive strength of fly ash concrete seems to be slightly higher than that of ordinary concrete between 7 and 28 days, thereafter the strength of fly ash concrete is significantly higher. In fresh properties of the fly ash concrete, the loss of slump and air content with time up to 120 minutes is lower, but the setting time is increased with increasing fly ash content.

The purpose of this was to examine the used of fly ash as a type of construction material. In this paper the results from a recent study on development of a cement composite utilizing relatively large amount of fly ash are presented. The flowable fly ash-cement sand composite was investigated for strength and flowability characteristics. The independent variable considered were: fly-ash content, sand content, and ratio of water to cementitious materials. Results of this study show that high volume fly-ash composite can be proportioned to obtain 10~15kg/$\textrm{cm}^2$ compressive strength at 28 days. For applications requiring strength between 10kg/$\textrm{cm}^2$ and 15kg/$\textrm{cm}^2$, the mixture with fly ash-cement ratio of 5.6 and sand-cement ratio of 28 with relatively high water content may be used. Slump was held at 25$\pm$1cm for all mixtures produced compressive strength at 28 days were found to range from 5kg/$\textrm{cm}^2$ to 13.7kg/$\textrm{cm}^2$.

Most previous wave tests for concrete have been done to evaluate static material properties, and thus there are less works to investigate dynamic material characteristics of concrete, which should be few in Korea. The objective of this experimental work is to investigate dynamic material characteristics of concrete, such as dynamic elastic modulus, dynamic shear modulus, first resonant frequency, dynamic poisson's ratio and etc. A dynamic Signal Analyzer has been used to perform the wave analysis for various dynamic material properties of test specimen. First Fourier transform technique has been carried out on various wave data acquired by the Resonant Column method, which is a kind of nondestructive tests. Wave analysis has been performed based on KS F2437, which is similar to ASTM C607-71 and is identical to JIS A 1127-1976.

The objective of this study is to investigate the possibility for application of E.P-dust as both admixture and fillers for aggregates under various mixproportion, replacing method and the ratios of replacement. According to the experimental results, improvement of viscosity and reducing of segregation at fresh state and gain in strength at hardened state can be achieved by applying E.P-dust. It can be considered from the results that application of E.P-dust will be more efficient as fillers for aggregates than as binder

Increased costs for cement have favoured the use of supplementary cementing materials in concrete. The use of fly ash in concrete has increased in the past few years. Concrete have been selected for use as a construction material in aggressive environment. The use of fly ash as concrete material has a role, and an understanding of its effect on concrete durability is essential to its correct and economical application. In this study, durability tests including permeability, freezing thawing resistance for Korean fly ash concrete are conducted. The durability characteristics of fly ash concrete are discussed.

The purpose of this study is to find mechanical properties of fly ash ratio in mortar as flowing, setting time, compressive strength, suction ratio of water, length change ratio. As a result, it was shown that proper fly ash ratio replaced by cement weight in mortar was generally positive effect to flowing, compressive strength suction ratio of water, length change ratio. So if fly ash is well done quality control is considered as good replacement of cement.

The purpose of this study is to offer basic information of fly ash concrete for field application. Through before study and fly ash in mortar, various properties as fly ash ratio in concrete were checked according to the experimental result, slump was increased and entrained air quantity was decreased as fly ash ratio is increased in fresh concrete. In hardened concrete, strength development of plain concrete(W/B 50%) was slower than water-reduced concrete(W/B 40%) at early age. Especially water-reduced concrete was remarkabily faster than no fly ash in concrete. Moduls of stastic elasticity and stress-strain relationship of fly ash in concrete nearly were effect on no fly ash concrete.

This study is intended to devolop the self waterproof agents for high performance concrete by analyzing the properties of fresh and hardened mortar with various addition ratios of the inorganic admixture and zinc stearate. As the results of the test, the flow and air content increase with the addition of expansive additives. When the replacement rate of silica fume increases, the flow decreases for the increased viscidity. And the flow and sir content decrease with the addition of zinc stearate. At hardened state, the compressive strength, tensile strength and flexual strength decrease with the addition of expansive additives and zinc stearate. With the increase of silica fume's replacement, they show a little decrease at early age and then increase gradually. Also, absorption and permeability show a steep decrease when zinc stearate is added, and a slack decrease with the replacement of silica fume.

This study deals with the effect on performance of epoxy resign mortar mixed special cement for surface control and maintenance of aging concrete construction. The test of main property of epoxy resign in this study are the evaluation on the adhesive strength between substrate and epoxy resign mortar under the environment of wet or concrete substrate surface. We gained the test results of good adhesive strength over 15 kgf/$\textrm{cm}^2$ under the wet and dry condition of concrete surface.

Concrete structures is appeared the shrinkage after being harden of the hydration effect of cement. To overcome this disadvantage, expansive additives are used. In our country, the most popular expansive additives are hauyne(CSA) or free lime(free-CaO) systems. These expansive additives are used to expansive cement mortar or concrete materials. In this study, we analyzed the expansive property mechanism about the hydration reaction of the free lime systems and in particular we convinced size distributions of the free lime size affect the expansion ratio with expansion ratio with experiments. We carried out the experiment for the expansive properties by using the soundness molds and with various the humidity and dry setting conditions. The hydration reactions of the free lime affect the reaction properties according to the relative humidity by laboratory experiments.

KS F 4419, which is dealt with the Inter-Locking block, states that water to cement ratio for manufacturing inter-locking block should be less than 25% and in KS F4419, the use of admixture is shown to be reluctant to recommend. In this paper, reinvestigation of some regulations in KS F 4419 are carried out. According to the experimental results, as W/C increases, flexural strength and compressive strength are tended to decrease, whereas they increases within certain range, Flexural strength and compressive strength have higher values in 1:2(W/C=35%), 1:4(W/C=45%) and 1:6(W/C=55%) of mix proportions. Moreover they have rather higher values with the containment of high range AE water-reducing agent. The absorption ratios decrease with the increase of W/C and the containment of high range AE water-reducing agent. Therefore, the regulations on the W/C and admixture in KS F 4419 reguire revision.

The concrete structures designed and constructed by conventional design concept based on structural performance consideration show sometimes serious durability problem when the structures are exposed to aggressive environment. Because present design system focuses on the structure safety and considers durability indirectly by the concrete mix design and cover depth, the durability of concrete structure cannot be ensured. As the first step to develope the durability design for concrete structure, durability index which represents internal concrete resistance and environment index which represents external environmental exposure are derived quantitatively. In the next step, the durability design system is developed by checking durability limit state with computed two indexes under service life condition by considering of the reliability of structure. Finally, the proposed system is verified with a model problem.

The purpose of this study is recycling of ready mixed concrete sludge as artificial aggregate by product technique of artificial aggregate in the normal temerature. For the qulity test of artificial aggregate using ready mixed concrete sludge, it is tested in the various aspect. Therefor, Quality of artificil aggregate is suitable as coarse aggregate except absoption, abrasion. For the application of aggregate in cement concrete, Coarse aggregate are replaced with artificial aggregate using ready mixed concrete sludge 100% of volume. The results of test shown that the artificial aggregate using ready mixed concrete sludge could be used replacement of coarse aggregate in cement concrete.

This study is described the experimental result of the development of artificial aggregate using paper sludge ash and the application of it in concrete. Artificial aggregates are prepared with crushed stone in the variety aspect. Therefore, Quality properties of artificial aggregate using paper sludge ash are fairly corresponded with it of crushed stone. For the application of artificial aggregate using paper sludge ash in concrete, Coarse aggregates are replaced with artificial aggregate using paper sludge ash in the constant of volume(0%, 30%, 70%, 100%). It is conclued from the test results that the artificial aggregate using paper sludge ash could be used replacement of coarse aggregate in concrete. Continuous study should be planned for improvement of it's quality.

The permeability of concrete influences the durability of concrete remarkably. This paper describes a programme of permeability tests carried out to determine the differences between permeability coefficients derived using water, oxygen and chloride ions. Tests have been carried out on three concretes having water/cement ratios of 0.45, 0.55, 0.65 to measure their water, chloride-ion and gas permeability coefficients. The test results indicate that the permeability of concrete increase with the increase water cement ratios. The water and gas permeability coefficients is presented from $1.43$\times$10^{-10} to 19.01$\times$10^{-10}m/s$ and from $0.88$\times$10^{-10}$ to $1.59$\times$10^{-10}$m$^2$for concrete of different water cement ratios. The current intensity passing through the concrete is presented from 4504 to 4920 C.

Corrosion of steel reinforcement is the most significant factor of deterioration in reinforced concrete structures. Chloride ion is considered one of the most common culprits on the corrosion of steels in concrete. The main objective of this study is understanding behavior of chloride ion in hardened cement pastes at different stages of curing. Cement pastes with water-cement ratio of 0.5 are allowed to hydrate in sealed containers for 28, 70, 180 days. And than pore solution is expressed. It was found that the $Cl^-$ concentrations in pore solution is decreased with increasing curing time in all Nacl addition level, the $OH^-$ concentrations is increased to 70 days but decrease at 180 days in all Nacl addition level. The $Cl^-$/$OH^-$ in pore solution is increased with increasing curing time in all Nacl addition level, however $Cl^-$/$OH^-$ of maximum Nacl addition level(Nacl 0.54% by weight of cement) is under the onset of depassivation level 0.3.

Under concentrational paste and dilute suspension systems, we have been tested the effects in the dosage of two superplasticizers [naphtalenic(NSF) and polycarboxylic(NT-2)] which has been varied from 0 to 2.0 wt%, in both one case of cement Ⅱ-anhydrite and fly ash itself and the other case that cement has been substituted 10wt% to Ⅱ-anhydrite and fly ash. The result of tested zeta potential tells that zeta potential values increase in addition to increasing of the NSF dosage. And it's effect was high in case of fly ash. We has confirmed the 10wt% substitution of Ⅱ -anhydrite and fly ash would be more effective than the cement itself in initial fluidity and stable fluidity. And in case of NT-2 and NSF, addition of 1.0wt% NT-2 improved the fluidity of paste cement more than that for NSF.

The corrosion of steel reinforcements in concrete is of much concern in recent years. The mechanism of corrosion, however, is not clear yet. This study is focused on the corrosion of steel induced by internal chlorides in concrete at early ages. To examine the critical concentration of steel, half-cell potential, chemical composition of expressed pore solutions of mortars and rate of corrosion area were observed with respect to additions of chlorides, types of binders, water-binders ratio.

In reinforced concrete carbonation of concrete leads to depassivation of the reinforcement, and hence to initiation of corrosion. As a result of carbonation accelerating experiment with using effect of wet-dry cycle and 15% concentration of CO ₂, the carbonation rate shows very distinct difference according to W/C ratio. OPC-40 estimated no carbonation depth, whereas OPC-60 estimated rapidly the carbonation rate. The comparative analysis of the carbonation rate accelerating depends on different kinds of cement shows fastest FAC-20. Also, highly W/C ratio's concrete shows low half-cell potential value and fast corrosion rate. During period for 14 weeks. corrosion rate was not severe. So, it can be concluded that only carbonation attack on concrete doesn't severly deteriorated except very poor qualitified concrete.

Recently it has become general to use the inhibitor with a view to protecting corrosion of rebars in concrete. So, it needs to study effect of protection and reasonable dosage of inhibitor to reduce corrosion of rebar in concrete containing chlorides. In this study, we estimate the corrosion rate of rebar in mortar by Tafel extrapolation method, one of electrochemical techniques, and the reasonable dosage of inhibitor for different chlorides environments.

Recently the shortage of good aggregate has encouraged the use of sea sand in construction field, and the corrosion damage of the reinforced steel in concrete structures has been increased due to chlorides from sea sand and deicing salt. Therefore, a number of researchs are proceeding to prevent the corrosion of the reinforced steel in concrete, especially in marine environments. This study focused on the effect of corrosion inhibitors to evaluate protection characteristics for mortar specimens containing clorides. Corrosion behaviors have been investigated by half-cell potential measurement, linear polarization method, AC impedance method, and cyclic polarization test after immersing in sea water for 7 years. A possitive effect of a corrosion inhibitor has been obtained.

In these days, mostof marine structures are constructed by reinforcement concrete due to economic reason. Theoretically, it is widely recognized that rebar in sound concrete is safe against corrosion because of the high alkalinity of concrete. However, corrosion for reinforcement concrete made by marine aggregate and exposed to ocean enviroments has become serious social problem. Especially in Korea, with the rapid economic growth construction activities have been accelerated and needed more natural aggregate. Therefore, inevitably marine aggregate had to be used due to limitation of good quality aggregate. In this study, as a part of efforts to establish the fundamental counterplan on corrosion problems related to marine aggregate, concrete specimens with chloride containing material and inhibitor have been studied. And, in order to analyze corrosion characteristics several electrochemical techniques including half-cell potential survery, linear and cyclic polarization tests were carried out.

This study is to investigate on the remaining life of reinforced concrete apartment by using the probability of a reinforcing-steel corrosion and the carbonation tendency of domestic reinforced concrete apartments by using the statistic method. The results are as follow. ·To compare with the carbonation velocity of Kishitani's formula (x=3.727{{{{ SQRT { t} }}) when water-cement ratio is w=0.6, R=1, it is founded out that the carbonation velocity is slow a little in all area investigated and inland area, and fast a bit in coastal area. ·In the influencing factors in regard to the probability of reinforcing-steel corrosion, It seems that the influence of elapsed time is more effective than that of region. Therefore, it is necessary that it makes sure of the cover depth under apartment construction in recent so far as the durability is considered.