• Title/Summary/Keyword: sulfur oxidation

Search Result 230, Processing Time 0.024 seconds

Characterization of Plant Growth-Promoting Traits of Free-Living Diazotrophic Bacteria and Their Inoculation Effects on Growth and Nitrogen Uptake of Crop Plants

  • Islam, Md. Rashedu;Madhaiyan, M.;Boruah, Hari P.Deka;Yim, Woo-Jong;Lee, Gill-Seung;Saravanan, V.S.;Fu, Qingling;Hu, Hongqing;Sa, Tongmin
    • Journal of Microbiology and Biotechnology
    • /
    • v.19 no.10
    • /
    • pp.1213-1222
    • /
    • 2009
  • The search for diverse plant growth-promoting (PGP) diazotrophic bacteria is gaining momentum as efforts are made to exploit them as biofertilizers for various economically important crops. In the present study, 17 diazotrophic strains belonging to eight different genera isolated from rice paddy fields were screened for multiple PGP traits and evaluated for their inoculation effects on canola and rice plants. All of the strains tested positive for 1-aminocyclopropane-1-carboxylate (ACC) deaminase activity and production of indole 3-acetic acid (IAA) and ammonia ($NH_3$). Additionally, four of the strains were able to solubilize phosphorus (P), five tested positive for zinc (Zn) solubilization and sulfur (S) oxidation, and eight strains produced siderophores. Based on the presence of multiple PGP traits, 10 strains were selected for inoculation studies. Treatment with Herbaspirillum sp. RFNB26 resulted in maximum root length (54.3%), seedling vigor, and dry biomass in canola, whereas Paenibacillus sp. RFNB4 exhibited the lowest activity under gnotobiotic conditions. However, under pot culture conditions, Paenibacillus sp. RFNB4 significantly increased plant height and dry biomass production by 42.3% and 29.5%, respectively. Canola plants and rhizosphere soils inoculated with Bacillus sp. RFNB6 exhibited significantly higher nitrogenase activity. In greenhouse experiments, Serratia sp. RFNB18 increased rice plant height by 35.1%, Xanthomonas sp. RFNB24 enhanced biomass production by 84.6%, and rice rhizosphere soils inoculated with Herbaspirillum sp. RFNB26 exhibited the highest nitrogenase activity. Our findings indicate that most of the selected strains possess multiple PGP properties that significantly improve the growth parameters of the two plants when tested under controlled conditions.

Occurrence and Influence of acid Leachate by Pyrite in Underground Rocks of Road Construction Field in the Miryang Area (밀양지역 도로건설 현장 지반암석내 분포하는 황철석에 의한 산성침출수 발생과 영향)

  • Chae, Sun Hee;Jeong, Chan Ho;Lee, Yu Jin;Lee, Yong Cheon;Shin, Sang Sik;Park, Jun Sik;Ou, Song Min
    • The Journal of Engineering Geology
    • /
    • v.28 no.3
    • /
    • pp.501-512
    • /
    • 2018
  • The acid leachate derived from the sulfide mineral such as pyrite can cause problems such as aging of infrastructure and environment contamination around the civil construction site. The purpose of this study is to assess the environmental effect of an acid leachate derived from pyrite in the Miryang area under road construction. In this study, 13 samples of situ core were used for the net acid generation (NAG) experiment. The chemical composition including pH, oxidation and reduction potential (ORP) and electrical conductance of water samples produced from the NAG test was analyzed. In additional, five polished thin sections of rock cores were made for electro microprobe analyses. In the results of the NAG tests, 7 samples showed lower values than pH 3.5. It strongly indicated that these areas are under the environmental and infrastructure damage by the acid leachate. The chemical type of the 7 samples was classified as the $Fe(Ca)-SO_4$ type, which is totally a different type compared to general groundwater. The concentration of total sulfur ranges from 0.004% to 12.5%. 6 rock samples are plotted on a potentially acid forming zone in the relation diagram between the total sulfide and NAG-pH. In conclusion, it is suggested that a protection method against an environmental demage and an infrastructure corrosions by the acid leachate should be prepared in all of areas under a road construction.

Simultaneous Removal of $SO_2$ and NOx Using Ozone Generator and Absorption- Reduction Technique (오존발생장치와 흡수환원법을 이용한 배기가스 동시 탈황 탈질 공정)

  • Mok, Young-Sun;Lee, Joo-Hyuck;Shin, Dong-Nam;Koh, Dong-Jun;Kim, Kyong-Tae
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.28 no.2
    • /
    • pp.191-196
    • /
    • 2006
  • The injection of ozone, produced by dielectric barrier discharge, into the exhaust gas gives rise to a rapid oxidation of NO that is the main component of nitrogen oxides($NO_x$) in most practical exhaust gases. Once NO is converted into $NO_2$, it on readily be reduced to $N_2$ in the next step by a reducing agent such as sodium sulfide and sodium sulfite. The reducing agents used ca also remove $SO_2$ effectively, which makes it possible to treat $NO_x\;and\;SO_2$ simultaneously. The present two-step process made up of an ozonizing chamber and an absorber containing a reducing agent solution was able to remove about 95% of the $NO_x$ and 100% of the $SO_2$, initially contained in the simulated exhaust gas. The formation of $H_2S$ from sodium sulfide was prevented by using a strong basic reagent(NaOH) together with the reducing agent. The removal of $NO_x$\;and\;SO_2$ was more effective for $Na_2S$ than $Na_2SO_3$.

Chemical Characteristics of Water Soluble Components in Fine Particulate Matter at a Gwangju area (광주지역 PM2.5 입자 수용성 성분의 화학적 특성조사)

  • Park, Seung Shik;Cho, Sung Yong;Kim, Seung Jai
    • Korean Chemical Engineering Research
    • /
    • v.48 no.1
    • /
    • pp.20-26
    • /
    • 2010
  • Water soluble organic and inorganic species are important components in atmospheric aerosol particles and may act as cloud condensation nuclei to indirectly affect the climate. To characterize organic and elemental carbon(OC and EC), water-soluble organic carbon(WSOC) and inorganic ionic species contents, daily $PM_{2.5}$ measurements were made during the wintertime at an urban site of Gwangju. Average concentrations of WSOC, $NO_3^-$, $SO_4^{2-}$ and $NH_4^+$, which are major components in the water-soluble fraction in PM2.5, are 2.11, 5.73, 3.51 and $3.31{\mu}g/m^3$, respectively, representing 12.0(2.9~23.9%), 21.0(12.9~37.6%), 11.6(2.5~25.9%) and 11.7%(3.8~18.6%) of the $PM_{2.5}$, respectively. Abundance of water soluble organic compounds ranged from 5.4 to 35.9% of total water soluble organic and inorganic components with a mean of 17.6%. Even though the sampling was performed during the winter, the average contributions of secondary OC and WSOC, as deduced from primary OC/EC(or WSOC/EC) ratio, were relatively high, accounting for 17.9%(0~44.4%) of the total OC and 11.2%(0.0~51.4%) of the total WSOC, respectively. During the sampling period, low $SO_4^{2-}/(SO_4^{2-}+SO_2$) ratio of 0.14(0.03~0.32) and relative humidity condition in the winter time suggest an possibility of impact of long-range transport and/or aqueous transformation processes such as metal catalyzed oxidation of sulfur, in-cloud processes, etc.

Characteristics and Improvement of Potential Acid Sulfate Soil Derived from Continental Materials on Alluvial Fan (선상지(扇床地) 육성(陸成) 잠재특이산성토(潛在特異酸性土)의 특성과 개량)

  • Jung, Yeun-Tae;Yun, Eul-Soo;Son, Il-Soo
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.25 no.3
    • /
    • pp.195-201
    • /
    • 1992
  • A Potential acid sulfate soil derived from continental Holocene deposits on the fan-base was found and it was characterized with improvement practices. Artesian wells were scattered in the area, and the imperfectly drained soils were featured by having fine loamy with 7~30% of gravels. The potential acid sulfate soil layers were typified by having darkness in color with around 3.3~3.8% of O.M. and 0.34~0.41% of total sulfur. Soil pH ranged from 3.4 to 3.8 but it was decreased to 1.9~2.5 after oxidation with $H_2O_2$. Ground water sprang out from an artesian well contained a high amount of minerals such as Na, Ca, Mg, K, etc. and about 80ppm of sulfate which seemed to be responsible for pyrite formation. The soil was classified to member of "Fine loamy, mixed, acid, mesic, sulfic Haplaquepts" in taxonomically, and "weak potential acid sulfate soils" in interpretatively. The installation of tile drains with adding fine earth and liming were effective. However, the pH goes down to 4.8 again after 3 years of improvement practices.

  • PDF

Study on the Sediment Quality in Bottom Water (I) (수 저층의 저질 조사 (I) - 저질 조사의 중요성과 분석에 관하여 -)

  • Kim, Do-Hee
    • Journal of the Korean Society of Marine Environment & Safety
    • /
    • v.13 no.1 s.28
    • /
    • pp.93-102
    • /
    • 2007
  • Particle materials sink in bottom and dissolved inorganic substances release from sediment and many kinds of materials continuously exchange in sediment and water column as well as transfer and transformation in sediment. The study of sediment quality means the state of sediment pollution relation of the water quality, sediment biota, materials fluxes between sediment and water column, transformation of materials in sediment is being important in recent. The state of sediment quality imply that the history of water pollution for long time, because the sediment quality does not change temporally. The sediment quality of bottom water can be used as a good indicator of pollution at present and in future. The major index of sediment qualities are the content of nutrients and hazard materials such as metals, Ignition Loss (IL), Total Sulfur (TS), Oxidation Reduction Potential (ORP), sediment COD, color, odor and the release of nutrients from sediment. However, there are some arguments between researchers about compare to estimation of sediment quality and sampling and analysis of sediment. In this study, I will introduce the method of sediment sampling, analyzing and estimating of the sediment pollution.

  • PDF

Reaction Characteristics of SOx/NOx Removal Using CuO/γ-Al2O3 Sorbent/Catalyst (CuO/γ-Al2O3 흡수제/촉매를 이용한 SOx/NOx 제거 반응특성)

  • Yoo, Kyung Seun;Kim, Sang Done
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.22 no.4
    • /
    • pp.671-678
    • /
    • 2000
  • Reaction characteristics of simultaneous removal of SOx and NOx have been investigated in a thermogravimetric analyzer and tubular fixed bed reactor using the $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst. Sulfur removal capacity of $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst is largely enhanced above both the temperature of $450^{\circ}C$ and the loading of 6wt% due to the participation of alumina support in a sulfation reaction. The NO reduction efficiency of 8wt% $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst shows the maximum value at $370^{\circ}C$ and then decreases with the increase of reaction temperature due to the oxidation of $NH_3$ gas. The presence of sulfate on the surface of sorbent/catalyst enhances the optimum reaction temperature showing the maximum deNOx efficiency. In the simultaneous removal of SOx and NOx at $250^{\circ}C$. deNOx activity of $CuO/{\gamma}-Al_2O_3$ sorbent/catalyst is rapidly decreased due to the formation of ammonium salts such as $NH_4HSO_4$. In the simultaneous removal reaction of SOx and NOx, the optimum temperature showing the maximum deNOx efficiency increases to $400^{\circ}C$ due to the presence of $SO_2$ gas.

  • PDF

Isolation and Characterization of Acetic Acid Bacteria for Producing "Makgeolli Seed-Vinegar" (막걸리 종초 제조에 적합한 초산균의 분리 및 발효특성)

  • Lee, Hye-Bin;Oh, Hyeonhwa;Jeong, Do-Youn;Jun, Hyun-Il;Song, Geun-Seoup;Kim, Young-Soo
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.46 no.10
    • /
    • pp.1216-1224
    • /
    • 2017
  • Acetic acid bacteria strains were isolated from commercial natural vinegar. Ten isolated strains were identified using 16S rRNA gene sequencing data after evaluating the ethanol- and sulfur-tolerance. Eight of the strains isolated were identified as Acetobacter pasteurianus. A. pasteurianus JAC002, JAC005, and JAC008 strains, which showed a high ethanol tolerance, were selected for making "Makgeolli seed-vinegar". Rice wine vinegars were manufactured with the selected strains through fermentation, and their physicochemical properties and antimicrobial activities were evaluated. A. pasteurianus JAC002 strain showed the highest oxidation ability to acetic acid from ethanol on the twentieth day of fermentation, resulting in 4.21% total acidity, 3,791.77 mg% acetic acid content, and 2,931.78 mg% ethanol consumption content. Rice wine vinegar manufactured with the A. pasteurianus JAC002 strain showed increased antimicrobial activities against Staphylococcus aureus (KACC1927) and Escherichia coli (KACC10115). As a result, A. pasteurianus JAC002 strain was found to be the most suitable strain for "Makgeolli seed-vinegar".

Effect of Sludge Digestion on Removal Efficiency of Heavy Metals from Sewage Sludge Using Thiobacillus thiooxidans MET (Thiobacillus thiooxidans MET를 이용한 중금속 제거 효율에 미치는 슬러지 성상의 영향)

  • 임설희;이소은;이인숙;조경숙;류희욱
    • KSBB Journal
    • /
    • v.16 no.4
    • /
    • pp.389-397
    • /
    • 2001
  • The effect of sludge digestion on the leaching efficiency of heavy metals from sludge by bioleaching with Thiobacillus thiooxidans MET was investigated. The used sludges were a non- and anaerobically digested. The leaching efficiency of heavy metals was strongly dependent on the pH of the sludge solution rather than the sludge condition and stolid concentration. The lower the pH the more heavy metal was leached from 3.0 of pH. The sequent orders of leaching heavy metals were Zn, Cu, and Cr. Although the buffering capacity of non-digested sludge was similar to anaerobically digested sludge, the pH decrease rate of the anaerobically digested sludge solution was faster than that of the non-digested sludge solution due to the higher sulfur oxidation rate of T. thiooxidans MET in the anaerobically digested sludge. The amount of leached heavy metals from the anaerobically digested sludge showed higher than that of non-digested sludge at the same pH value. This result might be caused by the difference of the insoluble metal types, which were contained in the sludge. An increase in sludge solids concentration decreased the leaching efficiency of heavy metals in the range of solids concentration 10 g/L to 70 g/L. The optimum ratio of S° to sludge stolid was 0.1 in both the sludge. The bioleaching process of heavy metals with T. thiooxidans MET showed the disinfecting effect over 90% as well as the reduction effect in sludge weight of 20%.

  • PDF

Predictive Exploration of the Cretaceous Major Mineral Deposits in Korea : Focusing on W-Mo Mineralization (한국 백악기 주요 금속광상의 예측 탐사 : W-Mo 광화작용을 중심으로)

  • Choi, Seon-Gyu;Kang, Jeonggeuk;Lee, Jong Hyun
    • Economic and Environmental Geology
    • /
    • v.52 no.5
    • /
    • pp.323-336
    • /
    • 2019
  • The Mesozoic activity on the Korean Peninsula is mainly represented by the Triassic post-collisional, Jurassic orogenic, and Cretaceous post-orogenic igneous activities. The diversity of mineralization by each geological period came from various geothermal systems derived from the geochemical characteristics of magma with different emplacement depth. The Cretaceous metallic mineralization has been carried out over a wide range of time periods from ca. 115 to 45 Ma (main stage; ca. 100 to 60 Ma) related to post-orogenic igneous activity, and spatial distribution patterns of most metal deposits are concentrated along small granitic stocks. The late Cretaceous metal deposits in the Gyeonggi and Yeongnam massifs are generally distributed along the boundary among the Gongju-Eumseong fault system and the Yeongdong-Gwangju fault system and the Gyeongsang Basin, most of them are in the form of a distal epithermal~mesothermal Au-Ag vein or a transitional mesothermal Zn-Pb-Cu vein. On the other hand, diverse metal commodities in the Taebaeg Basin, the Okcheon metamorphic belt and the Gyeongsang Basin are produced from various deposit types such as skarn, carbonate-replacement, vein, porphyry, breccia pipe, and Carlin type. In the late Cretaceous metallic mineralization, various mineral deposits and commodities were induced not only by the pathway of the hydrothermal solution, but also by the diversity of precipitation environment in the proximity difference of the granitic rocks. The diversity of these types of Cretaceous deposits is fundamentally dependent on the geochemical characteristics such as degree of differentiation and oxidation state of related igneous rocks, and ore-forming fluids generally exhibit the evolutionary characteristics of intermediate- to low-sulfur hydrothermal fluids.