• Title/Summary/Keyword: particle physics

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Au/Titania Composite Nanoparticle Arrays with Controlled Size and Spacing by Organic-Inorganic Nanohybridization in Thin Film Block Copolymer Templates

  • Li, Xue;Fu, Jun;Steinhart, Martin;Kim, Dong-Ha;Knoll, Wolfgang
    • Bulletin of the Korean Chemical Society
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    • v.28 no.6
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    • pp.1015-1020
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    • 2007
  • A simple approach to prepare arrays of Au/TiO2 composite nanoparticles by using Au-loaded block copolymers as templates combined with a sol-gel process is described. The organic-inorganic hybrid films with closely packed inorganic nanodomains in organic matrix are produced by spin coating the mixtures of polystyrene-block-poly(ethylene oxide) (PS-b-PEO)/HAuCl4 solution and sol-gel precursor solution. After removal of the organic matrix with deep UV irradiation, arrays of Au/TiO2 composite nanoparticles with different compositions or particle sizes can be easily produced. Different photoluminescence (PL) emission spectra from an organic-inorganic hybrid film and arrays of Au/TiO2 composite nanoparticles indicate that TiO2 and Au components exist as separate state in the initial hybrid film and form composite nanoparticles after the removal of the block copolymer matrix.

The Measurement of the LIDAR Ratio by Using the Rotational Raman LIDAR

  • Choi, Sung-Chul;Baik, Sung-Hoon;Park, Seung-Kyu;Cha, Hyung-Ki;Song, Im-Kang;Kim, Duk-Hyeon
    • Journal of the Optical Society of Korea
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    • v.14 no.3
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    • pp.174-177
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    • 2010
  • The rotational Raman LIDAR technique has been used to accurately measure aerosol optical properties such as backscatter coefficient, extinction coefficient, and LIDAR ratio. In the case of the vibrational Raman technique, the ${\AA}$ngstr$\ddot{o}$om exponent, which has wavelength dependence on the particle properties, is assumed to obtain the extinction coefficient. However, this assumed ${\AA}$ngstr$\ddot{o}$m exponent can cause systematic errors in retrieving aerosol optical properties. In the case of the rotational Raman technique, the aerosol optical properties can be measured without any assumptions about the ${\AA}$ngstr$\ddot{o}$m exponent. In this paper, the LIDAR ratio was measured by using the rotational Raman LIDAR and vibrational Raman LIDAR in the troposphere. And, the LIDAR ratios measured by these two methods were compared.

Implementation of Underwater Simulation of a Net using OpenMP (OpenMP 병렬프로그램을 이용한 그물의 수중형상 시뮬레이션 구현)

  • Park, Myeong-Chul;Park, Seok-Gyu
    • Journal of the Korea Society of Computer and Information
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    • v.13 no.2
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    • pp.11-17
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    • 2008
  • The net shape effects by the various vectors in underwater. Each particle of the net calculating the effect of all vectors augments an accuracy and reality. But, the time complexity becomes larger because of huge calculation. The previous techniques reduced a physics reality. And embodied the underwater virtual reality which augments visual reality with simulation. In this paper, parallel processing the particles, it embodied the simulation which is satisfied a physical reality and time reality. The parallel processing used the OpenMP, and the reality graphic expression used the OpenGL. The simulation which this paper Proposes will be the possibility becoming the fundamental data for a model analysis or a specialist system from game and marine field.

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Preparation and Characterization of Surface Capped CdSe Nanoparticles from an Aqueous Solution (수용액으로부터 표면 수식된 CdSe 나노 입자의 제조 및 특성)

  • Kim, Shin-Ho;Lee, Yoon-Bok;Kim, Yong-Jin;Kim, Yang-Do;Kim, In-Bae
    • Korean Journal of Materials Research
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    • v.16 no.11
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    • pp.663-667
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    • 2006
  • CTAB(cetyltrimethylammonium bromide)-capped CdSe nanoparticles were prepared by using a 4 : 1(v/v) distilled water-isopropyl alcohol mixture. The cadmium chloride and sodium selenosulfate were used as the cadmium and selenium source. By the analysis of XRD and XPS, the resultant particle was confirmed to be cubic CdSe phase. TEM image showed CdSe nanoparticles with empty core. The CTAB-capped sample showed an maximum absorption at 418nm, blue-shifting compared with bulk CdSe, which indicated stronger quantum confinement effect compared with uncapped sample. From FT-IR analysis, it was found that the presence of the new peaks in the $850{\sim}1250cm^{-1}$ range indicated the existence of chemical bonding between CTAB and surface of CdSe nanoparticles. Also TG analysis indicated that there were two weight-loss steps for the CTAB-capped CdSe nanoparticles. It was suggested that CTAB played a significant role in protecting CdSe nanoparticles.

Enhancement of high temperature cycling stability in high-nickel cathode materials with titanium doping

  • Song, Jun-Ho;Bae, Joongho;Lee, Ko-woon;Lee, Ilbok;Hwang, Keebum;Cho, Woosuk;Hahn, Sang June;Yoon, Songhun
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.124-128
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    • 2018
  • Titanium doping is employed to enhance the structural strength of a high-Ni layered cathode material in lithium ion batteries during high temperature cycling. After Ti-doping, the external morphology remains similar, but the lattice parameters of the layered structure are slightly shifted toward larger values. With application of the prepared materials as cathodes in lithium-ion batteries, the initial capacities are similar but the cycling performance at $25^{\circ}C$ is enhanced by Ti-doping. During high temperature cycling at $60^{\circ}C$, furthermore, highly improved capacity retention is achieved with the Ti-doped material (95% of initial capacity at 50th cycles), while cycle fading is accelerated with the bare electrode. This enhancement is attributed to better retention of the compressive strength of the particles and retarded crack formation within the particles. In addition, impedance increase is reduced in the Ti-doped electrode, which is attributed to an improvement in the structural strength of the high-Ni cathode material with Ti-doping.

Method for Analysis on Optimization of Averaging Interval of Rainfall Rate Measured by Tipping-Bucket Rain Gauges

  • Nam, Kyung-Yeub;Chang, Ki-Ho;Kim, Kyung-Eak;Oh, Sung-Nam;Choi, Young-Jean;Kim, Kyung-Sik;Lee, Dong-In;Kim, Kum-Lan
    • Korean Journal of Remote Sensing
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    • v.24 no.1
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    • pp.17-24
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    • 2008
  • Rainfall data from three different types of rain gauge system have been collected for the summertime rain event at Mokpo in the Korean peninsula. The rain gauge system considered in this paper is composed of three tipping-bucket rain gauges with 0.1, 0.2, and 0.5 mm measuring resolutions, the Optical Rain Gauge (ORG), and the PARSIVEL (PARticle SIze and VELocity). The PARSIVEL rainfall rate has been considered as the reference for comparison since it gave good resolution and performance on this event. Comparison with the PARSIVEL rainfall rate gives the results that the error and temporal variation of rainfall rate are simultaneously reduced with increasing the averaging interval of rainfall rate or decreasing the size of tipping bucket. This suggests that the estimated rainfall rate must be optimized, differently for the type of tipping-bucket rain gages, by minimizing the averaging interval of rainfall rate under the condition satisfying the given performance of rainfall rate.

Separate and integral effect tests of aerosol retention in steam generator during tube rupture accident

  • Lee, Byeonghee;Kim, Sung-Il;Ha, Kwang Soon
    • Nuclear Engineering and Technology
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    • v.54 no.7
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    • pp.2702-2713
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    • 2022
  • A steam generator tube rupture accompanying a core damage may cause the fission product to be released to environment bypassing the containment. In such an accident, the steam generator is the major path of the radioactive aerosol release. AEOLUS facility, the scaled-down model of Korean type steam generator, was built to examine the aerosol removal in the steam generator during the steam generator tube rupture accident. Integral and separate effect tests were performed with the facility for the dry and flooded conditions, and the decontamination factors were presented for different tube configurations and submergences. The dry test results were compared with the existing test results and with the analyses to investigate the aerosol retention physics by the tube bundle, with respect to the particle size and the bundle geometry. In the flooded tests, the effect of submergence were shown and the retention in the jet injection region were presented with respect to the Stokes number. The test results are planned to be used to constitute the aerosol retention model, specifically applicable for the analysis of the steam generator tube rupture accident in Korean nuclear power plants to evaluate realistic fission product behavior.

Control of a pressurized light-water nuclear reactor two-point kinetics model with the performance index-oriented PSO

  • Mousakazemi, Seyed Mohammad Hossein
    • Nuclear Engineering and Technology
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    • v.53 no.8
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    • pp.2556-2563
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    • 2021
  • Metaheuristic algorithms can work well in solving or optimizing problems, especially those that require approximation or do not have a good analytical solution. Particle swarm optimization (PSO) is one of these algorithms. The response quality of these algorithms depends on the objective function and its regulated parameters. The nonlinear nature of the pressurized light-water nuclear reactor (PWR) dynamics is a significant target for PSO. The two-point kinetics model of this type of reactor is used because of fission products properties. The proportional-integral-derivative (PID) controller is intended to control the power level of the PWR at a short-time transient. The absolute error (IAE), integral of square error (ISE), integral of time-absolute error (ITAE), and integral of time-square error (ITSE) objective functions have been used as performance indexes to tune the PID gains with PSO. The optimization results with each of them are evaluated with the number of function evaluations (NFE). All performance indexes achieve good results with differences in the rate of over/under-shoot or convergence rate of the cost function, in the desired time domain.

α-Synuclein Disrupts Vesicle Fusion by Two Mutant-Specific Mechanisms

  • Yoo, Gyeongji;An, Hyeong Jeon;Yeou, Sanghun;Lee, Nam Ki
    • Molecules and Cells
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    • v.45 no.11
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    • pp.806-819
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    • 2022
  • Synaptic accumulation of α-synuclein (α-Syn) oligomers and their interactions with VAMP2 have been reported to be the basis of synaptic dysfunction in Parkinson's disease (PD). α-Syn mutants associated with familial PD have also been known to be capable of interacting with VAMP2, but the exact mechanisms resulting from those interactions to eventual synaptic dysfunction are still unclear. Here, we investigate the effect of α-Syn mutant oligomers comprising A30P, E46K, and A53T on VAMP2-embedded vesicles. Specifically, A30P and A53T oligomers cluster vesicles in the presence of VAMP2, which is a shared mechanism with wild type α-Syn oligomers induced by dopamine. On the other hand, E46K oligomers reduce the membrane mobility of the planar bilayers, as revealed by single-particle tracking, and permeabilize the membranes in the presence of VAMP2. In the absence of VAMP2 interactions, E46K oligomers enlarge vesicles by fusing with one another. Our results clearly demonstrate that α-Syn mutant oligomers have aberrant effects on VAMP2-embedded vesicles and the disruption types are distinct depending on the mutant types. This work may provide one of the possible clues to explain the α-Syn mutant-type dependent pathological heterogeneity of familial PD.

Determination of dosimetric dependence for effective atomic number of LDR brachytherapy seed capsule by Monte Carlo simulation

  • Berkay Camgoz;Dilara Tarim
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.2734-2741
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    • 2023
  • Brachytherapy is a special case of radiotherapy. It should be arranged according to some principles in medical radiation applications and radiation physics. The primary principle is to use as low as reasonably achievable dose in all ionizing radiation applications for diagnostic and therapeutic treatments. Dosimetric distributions are dependent on radioactive source properties and radiation-matter interactions in an absorber medium such as phantom or tissue. In this consideration, the geometrical structure and material of the seed capsule, which surrounds a radioactive material, are directly responsible for isodose profiles and dosimetric functions. In this study, the radiometric properties of capsule material were investigated on dose distribution in a water phantom by changing its nuclear properties using the EGSnrc Monte Carlo (MC) simulation code. Effective atomic numbers of hypothetic mixtures were calculated by using different elements with several fractions for capsule material. Model 6711 brachytherapy seed was modeled by EGSnrc/Dosrcnrc Code and dosimetric functions were calculated. As a result, dosimetric parameters of hypothetic sources have been acquired in large-scale atomic number. Dosimetric deviations between the data of hypothetic seeds and the original one were analyzed. Unit dose (Gy/Particle) distributions belonging to different types of material in seed capsule have remarkably differed from the original capsule's data. Capsule type is major variable to manage the expected dose profile and isodose distribution around a seed. This study shows us systematically varied scale of material type (cross section or effective atomic number dependent) offers selective material usage in production of seed capsules for the expected isodose profile of a specific source.