Bulletin of the Korean Chemical Society

  • 제28권6호
  • /
  • Pages.1015-1020
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  • 2007
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Au/Titania Composite Nanoparticle Arrays with Controlled Size and Spacing by Organic-Inorganic Nanohybridization in Thin Film Block Copolymer Templates

  • Li, Xue (Max Planck Institute for Polymer Research) ;
  • Fu, Jun (Max Planck Institute for Polymer Research) ;
  • Steinhart, Martin (Max Planck Institute of Microstructure Physics) ;
  • Kim, Dong-Ha (Max Planck Institute for Polymer Research) ;
  • Knoll, Wolfgang (Max Planck Institute for Polymer Research)
  • 발행 : 2007.06.20
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초록

A simple approach to prepare arrays of Au/TiO2 composite nanoparticles by using Au-loaded block copolymers as templates combined with a sol-gel process is described. The organic-inorganic hybrid films with closely packed inorganic nanodomains in organic matrix are produced by spin coating the mixtures of polystyrene-block-poly(ethylene oxide) (PS-b-PEO)/HAuCl4 solution and sol-gel precursor solution. After removal of the organic matrix with deep UV irradiation, arrays of Au/TiO2 composite nanoparticles with different compositions or particle sizes can be easily produced. Different photoluminescence (PL) emission spectra from an organic-inorganic hybrid film and arrays of Au/TiO2 composite nanoparticles indicate that TiO2 and Au components exist as separate state in the initial hybrid film and form composite nanoparticles after the removal of the block copolymer matrix.

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