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http://dx.doi.org/10.5012/bkcs.2007.28.6.1015

Au/Titania Composite Nanoparticle Arrays with Controlled Size and Spacing by Organic-Inorganic Nanohybridization in Thin Film Block Copolymer Templates  

Li, Xue (Max Planck Institute for Polymer Research)
Fu, Jun (Max Planck Institute for Polymer Research)
Steinhart, Martin (Max Planck Institute of Microstructure Physics)
Kim, Dong-Ha (Max Planck Institute for Polymer Research)
Knoll, Wolfgang (Max Planck Institute for Polymer Research)
Publication Information
Bulletin of the Korean Chemical Society / v.28, no.6, 2007 , pp. 1015-1020 More about this Journal
Abstract
A simple approach to prepare arrays of Au/TiO2 composite nanoparticles by using Au-loaded block copolymers as templates combined with a sol-gel process is described. The organic-inorganic hybrid films with closely packed inorganic nanodomains in organic matrix are produced by spin coating the mixtures of polystyrene-block-poly(ethylene oxide) (PS-b-PEO)/HAuCl4 solution and sol-gel precursor solution. After removal of the organic matrix with deep UV irradiation, arrays of Au/TiO2 composite nanoparticles with different compositions or particle sizes can be easily produced. Different photoluminescence (PL) emission spectra from an organic-inorganic hybrid film and arrays of Au/TiO2 composite nanoparticles indicate that TiO2 and Au components exist as separate state in the initial hybrid film and form composite nanoparticles after the removal of the block copolymer matrix.
Keywords
Au/$TiO_2$ nanoparticle; Block copolymer; Sol-gel; Organic-inorganic hybrid; Photoluminescence;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By Web Of Science : 11  (Related Records In Web of Science)
Times Cited By SCOPUS : 11
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