• 제목/요약/키워드: latex stability

검색결과 31건 처리시간 0.025초

라텍스 모르타르를 이용한 콘크리트 교면 방수층 보호 공법 개발 및 적용에 관한 연구 (Application and Development of Protect Technique for waterproofing Reinforced Concrete Bridge Decks by Latex-Modified Mortar)

  • 한상일;이원영;김재원;강승희;차동화;김진만
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2009년도 추계 학술논문 발표대회
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    • pp.175-178
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    • 2009
  • This study is thing for construction properties that protect about damage of waterproofing course that is problem in asphalt pavement and latex modification concrete pavement. It is thing about new method of construction and develop protecting material of waterproofing. Did performance test item first at, as a result, drew by suitable thing in all KS items, This is considered to have more effective spot construction work because if means that have stability by material as well as method construction.

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Fabrication of Multi-Layered Graphenes/P(S-co-BA) Nanocomposite via Sudden Heating Heterocoagulation Process

  • Choi, JinKyu;Lee, Eun-Kyoung;Shim, Sang Eun
    • Elastomers and Composites
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    • 제52권4호
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    • pp.272-279
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    • 2017
  • The heterocoagulation of latex is a simple and useful method to fabricate various polymer nanocomposites in which a precise control of the colloid stability is essential. In this work, a multi-layered graphenes (MLGs)/poly(styrene-co-butyl acrylate) (P(S-co-BA)) nanocomposite having an excellent dispersion of MLGs was prepared via the sudden heating heterocoagulation process. The P(S-co-BA) component was obtained by emulsion polymerization. This process can effectively shorten the process and particles growth steps. The colloid stability of these dispersions was controlled by factors such as ionic charge, temperature, and reaction times. The influence of these factors on heterocoagulation was evaluated and the properties of the nanocomposites were investigated. The conductivity of the MLGs/P(S-co-BA) nanocomposites increased from -11.53 to -5.70 S/cm for an increase in MLG content from 0.01 to 5 wt%. Moreover, percolation threshold was observed in the case of 0.01 wt% MLGs.

Modified Silica with Cellulose/Starch by Gel-Adsorption Method as Reinforcing Materials for SBR Latex

  • Li, Xiang Xu;Cho, Ur Ryong
    • Elastomers and Composites
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    • 제53권1호
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    • pp.6-12
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    • 2018
  • Styrene-butadiene Rubber (SBR) Latex composites, incorporated with cellulose/starch-silica hybrids synthesized by gel-adsorption method, were filled into rubber by the latex compounding method. The structure morphology, mechanical properties, and thermodynamic properties of gel-silica hybrids were characterized. The states of hybrids which used as fillers were also characterized by SEM. As the fillers ratio increased, the difference for storage modulus of samples had been morphology by rubber process analyzer (RPA). Then, as more fillers ratio was filled into the matrix, the best tensile strength result, and the largest modulus value were also proved by UTM and RPA. As for thermal stability, increase in the ratio of fillers led to higher initial decomposition temperature, which was also proved by TGA. The swelling ratio of samples has also been characterized. From the results of all the tests, cellulose-silica hybrid showed the best results as a filler, and the best filling ratio of this hybrid is about 10 phr, which has the best storage modulus and great tensile strength.

Phase Inversion Emulsification and Enhancement of Physical Properties for Cationic Emulsified Asphalt

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • 제50권4호
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    • pp.265-273
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    • 2015
  • In this work, the emulsified asphalt with high phase stability and storage stability was prepared by using phase inversion emulsification and the surfactant mixed with cationic and nonionic surfactants. It was found that the asphalt together with Span 20, nonionic surfactant and DDA (Dimethyl Dodecyl Amine), cationic surfactant showed the most stable phase. The phase stability of the emulsified asphalt, therefore, was investigated through the particle size with mixed surfactant content, rheology behavior and Zeta potential value; the particle size decreased with the increase of the mixed surfactant content but the viscosity increased. The shear thinning behaviors and the Zeta potential value with 50 mV~60 mV were shown, which was found to be considered stable. In addition, SBR latex(Styrene-butadiene-rubber) and water dispersed Epoxy (EPD) were used to enhance the physical properties of the emulsified asphalt. The swelling and adhesion features of the emulsified asphalt were also studied with $CaCO_3$, Silica, and Montmorillonite (MMT). It was shown that the addition of SBR latex and MMT can be another way to improve the physical properties of the emulsified asphalt in that the lowest swelling feature was found.

옥내외 광고용 디지털 인쇄의 색 관리 방안에 관한 연구 (A Study on the Color Management Plan of Digital Printing for Indoor and Outdoor Advertisement)

  • 김주정;오성상;조가람;이재수
    • 한국인쇄학회지
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    • 제31권1호
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    • pp.15-37
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    • 2013
  • Split digital printing into interior and outdoors on present advertisement. When is printing machine for interior mainly, use ink of water-based type. Equipment of this type embodies high resolution, but ink special quality light stability is weak. Also, when is printing machine for outdoors, printing machines of solvent or UV type are used because of water resistance and light stability. This printing machines hard to embody ink special quality high resolution mainly. And because outside is far visibility range, is uncommon in case high resolution requires embodiment. Therefore, high resolution of inside is water-based type considering this item and outside printing machine of low resolution solvent type mainly announce. Also, divide into eco-friendly latex ink type that is announced to water-based, solvent, UV according to ink type and the latest market using in occasion of digital printing machine used as advertisement industry. Color management that is been consistent of original image has a lot of difficulties by using substrate that is also various to digital printing machine for such various advertisement. But, consumers is rising realization about color or desire about quality improvement of color gradually in interior outside advertisement market. So, require solution method. Therefore, in this paper, eco-friendly ink use applied device calibration through linearization in done latex digital printing machine to basis. And studied right color management plan of digital printing for interior outside advertisement through three steps such as G7 calibration application and ICC profile application.

기능성 복합 라텍스의 합성과 열분해 특성에 관한 연구 (A Study on Synthesis of Functional Composite Latex and Characteristics of Thermal Decomposition)

  • 권재범;김남석;이내우;설수덕
    • 한국안전학회지
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    • 제19권2호
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    • pp.47-53
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    • 2004
  • Emulsion polymerization ws carried out using Alkyl methacrylate(RMA) like MMA, EMA, BMA and Styrene Monomer(SM) for core-shell latex preparation. It was synthesized at $80^{\circ}C$ in the presence of anionic surfactant SLS(Sodium Lauryl Sulfate). FT-IR and DSC analysis are used to confirm the synthesized core-shell emulsion latexes. Moreover DSC and TGA were used to investigate the thermal characterisitcs of them. The differences of the decomposition rate and the activation energy from TGA and DSC analysis are not so big. It considers that the pendent group is not affect of the thermal characteristics and stability on core-shell latexes, which is synthesized with RMA and Styrene. For investigating combustion products, LC50 values were calculated by FED(Fractional Effective Dose)from the Pyrolyzer-Mass sepctrometer.

그래핀 옥사이드/카르복실화한 스티렌-부타디엔 고무 나노 복합체에 관한 연구 (A Study on Graphene Oxide and Carboxylated Styrene-Butadiene Rubber(XSBR) Nanocomposites)

  • 장선호;리시앙수;조을룡
    • 반도체디스플레이기술학회지
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    • 제16권1호
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    • pp.52-58
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    • 2017
  • Graphene oxide (GO)/carboxylated styrene-butadiene rubber (XSBR) nanocomposites with various contents of GO were prepared by a latex compounding method. It has been confirmed that the functional groups of GO and the hydrogen bonds between GO and XSBR are existed. It can be seen that the scorch time ($t_{s2}$), which is the measurement of incipient vulcanization of rubber, showed a delay after the addition of GO. Field emission scanning electron microscopy was employed to confirm the uniform dispersion of filler in the matrix. Indeed, with increasing fillers loading, the torque, tensile strength, thermal stability and crosslink density of obtained nanocomposites were improved. These results were correlated to the better dispersion of fillers through the rubber matrix.

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Latex Modified Concrete를 이용한 철도교량의 PCL층 적용에 관한 실험적 연구 (An Experimental Study on the Application of P.C.L-layer on the Railroad Bridge used to Latex Modified Concrete)

  • 이선규;최성민;성상경;박성기;오상근
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.757-760
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    • 2008
  • 대표적 진동구조물인 도로교량 바닥판에는 진동구조물의 특성에 따른 문제점을 해결하기 위해2000년 이후부터 LMC(Latex Modified Concrete)가 널리 적용되고 있다. 그러나 철도교량 바닥판은 날로 증대되는 철도교통수요를 해결하기 위해 건설물량은 늘어나고 있지만 철도교량 특성상 시공 후 설계변경 및 유지보수 관리가 어렵기 때문에 콘크리트 내구수명과 같은 내구성을 확보할 수 있는 관점에서 적용가능한 보호공법을 검토할 필요성이 있다. 따라서 본 연구에서는 LMC의 특성 및 장점을 이용하여 철도교량 바닥판의 PCL층을 대신할 수 있으면서 교면방수 기능을 동시에 발휘할 수 있는 콘크리트 바닥판 일체형 불투수성 PCL층을 적용하고자 하며, 재료의 성능 및 방수 적합성에 대한 시험평가를 통해 그 적정성 여부를 평가하고자 한다. 6가지 항목에 대한 성능평가 결과, LMC가 철도교량 바닥판의 PCL층을 대체하여 교면방수로서 성능발현 및 적용에 이상이 없는 것으로 확인되었다.

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저품질의 순환골재를 혼입한 초속경 시멘트 모르타르의 기초물성 및 부피안정성 (Basic Properties and Dimension Stability of Ultra Rapid Setting Cement Mortar Containing Low-Quality Recycled Aggregate)

  • 전상민;김형기
    • 한국건설순환자원학회논문집
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    • 제9권3호
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    • pp.246-252
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    • 2021
  • 초속경 시멘트 모르타르에 KS 기준보다 흡수율이 높고 비중이 낮은 저품질의 순환골재가 혼입되었을 때 모르타르의 기초물성과 부피안정성을 실험적으로 확인하였다. 순환골재를 사용하지 않는 배합은 관련 업체에서 사용하고 있는 일반 보수 모르타르의 것을 따랐다. 라텍스 혼입 및 미혼입 배합에 대해 잔골재에 대해 부피비로 15%, 30% 치환하였으며, 모르타르의 슬럼프, 응결시간, 압축/휨강도, 그리고 밀봉/노출 양생에 따른 길이변화량을 확인해 보았다. 실험 결과 저품질의 순환골재가 사용될 때, 사용하지 않은 경우에 비해 24시간 이내 극초기 강도가 최대 50%까지 감소하거나, 건조수축이 최대 2배 까지 증가할 위험이 있는 것을 확인하였다.

Preparation and Characterization of Anionic Emulsified Asphalt with Enhanced Adhesion Properties

  • Lee, Eun-Kyoung
    • Elastomers and Composites
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    • 제50권4호
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    • pp.304-313
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    • 2015
  • In this study, the anionic emulsified asphalt was prepared by dispersing asphalt particles evenly into water with combination of anionic and nonionic surfactants. Effects of NaOH and $CaCl_2$ on the phase stability of the emulsified asphalt were also investigated through zeta potential value and rheology behavior; the emulsified asphalt added with NaOH and $CaCl_2$ showed higher zeta potential value than that the asphalt with addition of only anionic and nonionic surfactants. In addition, with regard to shear thinning behaviors, it was found that pH of the emulsified anionic asphalt and $Ca^{2+}$, counter ion, affected the phase stability. SBR (styrene-butadiene-rubber) latex, EPD (water dispersed Epoxy), PU (polyurethane) and RI-10S, SBS (styrene-butadiene-styrene)-based property improvement additive, were used and studied to enhance the adhesion properties with the aggregates. RI-10S, however, was found to be only compatible with the anionic emulsified asphalt; the coating rate, adhesion and compression strength were increased with the RI-10S content.