• Title/Summary/Keyword: interface-controlled mechanism

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Nucleation, Growth and Properties of $sp^3$ Carbon Films Prepared by Direct $C^-$ Ion Beam Deposition

  • Kim, Seong I.
    • The Korean Journal of Ceramics
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    • v.3 no.3
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    • pp.173-176
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    • 1997
  • Direct metal ion beam deposition is considered to be a whole new thin film deposition technique. Unlike other conventional thin film deposition processes, the individual deposition particles carry its own ion beam energies which are directly coupled for the formation of this films. Due to the nature of ion beams, the energies can be controlled precisely and eventually can be tuned for optimizing the process. SKION's negative C- ion beam source is used to investigate the initial nucleation mechanism and growth. Strong C- ion beam energy dependence has been observed. Complete phase control of sp3 and sp3, control of the C/SiC/Si interface layer, control of crystalline and amorphous mode growth, and optimization of the physical properties for corresponding applications can be achieved.

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Ddsign of a backcap system for remote control of hydraulic valves (유압밸브의 원격제어를 위한 Backcap 시스템 설계 연구)

  • Lee, Jae-Gyu;Myung, Jae-Sik;Kim, Kyung-Jin;Kim, Ock-Hyun
    • Journal of the Korean Society for Precision Engineering
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    • v.11 no.2
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    • pp.65-74
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    • 1994
  • Backcap is an electric remote control system for the operation of directional flow control valves. This paper presents a new type of basckcap system which is characterized by its simple construction. The backcap is essentially a hydraulic cylinder of which the piston is connected to a spool of hydraulic valve and controlled by input current. An inherent feedback is imposed on its mechanism so that no artificial noe is needed. Characteristics of the backcap is verified by stability analysis, transient motion and steady state positioning for step inputs. Design parameter analyses have been executer by some analytical approaches and computer simulations, which lead to their optimal valves. These results contributed to an effective new backcap system and its design strategy.

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Comparative investigation of endurance and bias temperature instability characteristics in metal-Al2O3-nitride-oxide-semiconductor (MANOS) and semiconductor-oxide-nitride-oxide-semiconductor (SONOS) charge trap flash memory

  • Kim, Dae Hwan;Park, Sungwook;Seo, Yujeong;Kim, Tae Geun;Kim, Dong Myong;Cho, Il Hwan
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.12 no.4
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    • pp.449-457
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    • 2012
  • The program/erase (P/E) cyclic endurances including bias temperature instability (BTI) behaviors of Metal-$Al_2O_3$-Nitride-Oxide-Semiconductor (MANOS) memories are investigated in comparison with those of Semiconductor-Oxide-Nitride-Oxide-Semiconductor (SONOS) memories. In terms of BTI behaviors, the SONOS power-law exponent n is ~0.3 independent of the P/E cycle and the temperature in the case of programmed cell, and 0.36~0.66 sensitive to the temperature in case of erased cell. Physical mechanisms are observed with thermally activated $h^*$ diffusion-induced Si/$SiO_2$ interface trap ($N_{IT}$) curing and Poole-Frenkel emission of holes trapped in border trap in the bottom oxide ($N_{OT}$). In terms of the BTI behavior in MANOS memory cells, the power-law exponent is n=0.4~0.9 in the programmed cell and n=0.65~1.2 in the erased cell, which means that the power law is strong function of the number of P/E cycles, not of the temperature. Related mechanism is can be explained by the competition between the cycle-induced degradation of P/E efficiency and the temperature-controlled $h^*$ diffusion followed by $N_{IT}$ passivation.

Superhydrophobic/Superoleophobic Spray Coatings based on Photocurable Polyurethane Acrylate and Silica Nanoparticles (UV경화형 폴리우레탄 아크릴레이트와 실리카 나노입자를 이용한 초발수 및 초발유 스프레이 코팅)

  • Kim, Su Hyun;Lee, Seung Goo
    • Journal of Adhesion and Interface
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    • v.21 no.2
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    • pp.58-64
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    • 2020
  • This paper describes a simple approach for preparing a superhydrophobic and superoleophobic coating via spraying the mixture of UV-curable polyurethane acrylate and silica nanoparticles dispersed in a solvent. The prepared surface structures can be controlled by changing the types of solvents, the concentration of the polymer, and the amount of spraying. Superhydrophobicity and superoleophobicity are quantified by measuring the contact angle of water and oil, respectively. We also demonstrate the mechanism of spray coating with maximized superhydrophobicity and superoleophobicity through the analysis of re-entrant surface structures. At the appropriate amount and the composition of mixed solutions, the contact angle hysteresis of water and oil on the prepared surface is less than 2° and 30°, respectively. In addition, it shows excellent water-repellent and oil-repellent properties such that the oil droplet bounces off the surface.

Electrical characteristics of 4H-SiC MIS Capacitors With Ni/CNT/SiO2 Structure (Ni/CNT/SiO2 구조의 4H-SiC MIS 캐패시터의 전기적 특성)

  • Lee, Taeseop;Koo, Sang-Mo
    • Journal of IKEEE
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    • v.18 no.4
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    • pp.620-624
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    • 2014
  • In this study, the electrical characteristics of Ni/CNT/$SiO_2$ structures were investigated in order to analyze the mechanism of carbon nanotubes in 4H-SiC MIS device structures. We fabricated 4H-SiC MIS capacitors with or without carbon nanotubes. Carbon nanotubes were dispersed by isopropyl alcohol. The capacitance-voltage (C-V) is characterized at 300 to 500K. The experimental flat-band voltage ($V_{FB}$) shift was positive. Near-interface trapped charge density and oxide trapped charge density values of Ni/CNT/$SiO_2$ structure were less than values of reference samples. With increasing temperature, the flat-band voltage was negative. It has been found that its oxide quality is related to charge carriers or defect states in the interface of 4H-SiC MIS capacitors. Gate characteristics of 4H-SiC MIS capacitors can be controlled by carbon nanotubes between Ni and $SiO_2$.

Effect of Intermetallic Compounds Growth Characteristics on the Shear Strength of Cu pillar/Sn-3.5Ag Microbump for a 3-D Stacked IC Package (3차원 칩 적층을 위한 Cu pillar/Sn-3.5Ag 미세범프 접합부의 금속간화합물 성장거동에 따른 전단강도 평가)

  • Kwak, Byung-Hyun;Jeong, Myeong-Hyeok;Park, Young-Bae
    • Korean Journal of Metals and Materials
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    • v.50 no.10
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    • pp.775-783
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    • 2012
  • The effect of thermal annealing on the in-situ growth characteristics of intermetallics (IMCs) and the mechanical strength of Cu pillar/Sn-3.5Ag microbumps are systematically investigated. The $Cu_6Sn_5$ phase formed at the Cu/solder interface right after bonding and grew with increased annealing time, while the $Cu_3Sn$ phase formed at the $Cu/Cu_6Sn_5$ interface and grew with increased annealing time. IMC growth followed a linear relationship with the square root of the annealing time due to a diffusion-controlled mechanism. The shear strength measured by the die shear test monotonically increased with annealing time. It then changed the slope with further annealing, which correlated with the change in fracture modes from ductile to brittle at a critical transition time. This is ascribed not only to the increasing thickness of brittle IMCs but also to the decreasing thickness of the solder, as there exists a critical annealing time for a fracture mode transition in our thin solder-capped Cu pillar microbump structures.

Control of Glass Infiltration at the Al2O3/Glass/Al2O3 Interface

  • Jo, Tae-Jin;Yeo, Dong-Hun;Shin, Hyo-Soon;Hong, Youn-Woo;Cho, Yong-Soo
    • Transactions on Electrical and Electronic Materials
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    • v.12 no.1
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    • pp.32-34
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    • 2011
  • A zero-shrinkage sintering process in which the shrinkage of the x-y axis is controlled to be zero is in great demand due to the high integration trend in ceramic modules. Among the zero-shrinkage sintering processes available, the glass infiltration method proposed in the preliminary study with an $Al_2O_3/Glass/Al_2O_3$ structure is one promising method. However, problems exist in regard to the glass infiltration method, including partially incomplete joining between $Al_2O_3$ and glass layers due to the precipitate of Ti-Pb rich phase during the sintering process. Therefore, we wish to solve the de-lamination problems and suggest a mechanism for delamination and the solutions in the zero-shrinkage low temperature co-fired ceramic (LTCC) layers. The de-lamination problems diminished using the Pb-BSi-O glass without $TiO_2$ in Pb-B-Ti-Si-O glass and produced a very dense zero-shrinkage LTCC.

Numerical simulations of fracture shear test in anisotropy rocks with bedding layers

  • Haeri, Hadi;Sarfarazi, Vahab;Zhu, Zheming;Nejati, Hamid Reza
    • Advances in concrete construction
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    • v.7 no.4
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    • pp.241-247
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    • 2019
  • In this paper the effect of bedding layer on the failure mechanism of rock in direct shear test has been investigated using particle flow code, PFC. For this purpose, firstly calibration of pfc2d was performed using Brazilian tensile strength. Secondly direct shear test consisting bedding layer was simulated numerically. Thickness of layers was 10 mm and rock bridge length was 10 mm, 40 mm and 60 mm. In each rock bridge length, bedding layer angles changes from $0^{\circ}$ to $90^{\circ}$ with increment of $15^{\circ}$. Totally 21 models were simulated and tested. The results show that two types of cracks develop within the model. Shear cracks and tensile cracks. Also failure pattern is affected by bridge length while shear strength is controlled by failure pattern. It's to be noted that bedding layer has not any effect on the failure pattern because the layer interface strength is too high.

Kinetic Studies on Cooking of Naked and Covered Barley (쌀 보리 및 겉 보리 취반에 대한 역학적 연구)

  • Kim, Hae-Ran;Kim, Sung-Kon;Cheigh, Hong-Sik
    • Korean Journal of Food Science and Technology
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    • v.12 no.2
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    • pp.122-125
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    • 1980
  • The mechanism of cooking barlay (naked and covered barley) was investigated. Cooking properties of both naked and covered barley were similar. At higher cooking temperature of above $110^{\circ}C$, a browning reaction occurred and no terminal point of cooking was observed. The cooking rate followed the equation of a first-order reaction. The activation energies of cooking temperatures below $100^{\circ}C$ and above $100^{\circ}C$ were about 19,500 and 9,500 cal/mole, respectively. The cooking process of barley comprised two mechanisms: At temperatures below $100^{\circ}C$ the cooking rate is controlled by the reaction rate of barley constituents with water, and at temperatures above $100^{\circ}C$, it is controlled by the rate of diffusion of water through the cooked portion toward the interface of uncooked core in which the reaction is occurring.

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Effect of the Addition of Fluorinated Surfactant on the Solubilization of n-Hexane by Hydrocarbon Surfactant (불소계 계면활성제 첨가가 탄화수소계 계면활성제에 의한 n-헥산의 가용화에 미치는 영향에 관한 연구)

  • Hee Dong Shin;Ki Ho Park;Jong Choo Lim
    • Applied Chemistry for Engineering
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    • v.34 no.4
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    • pp.397-403
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    • 2023
  • In this study, the effect of the addition of fluorinated surfactant FS-606 on the solubilization of n-hexane by hydrocarbon surfactant CDP-W was investigated. Oil drop contacting experiments revealed that solubilization rate is independent of initial oil drop size and proportional to the initial surfactant concentration, suggesting that solubilization of n-hexane oil by the surfactant mixture of FS-606 and CDP-W is controlled by an interface-controlled mechanism. In addition, the solubilization rate has been shown to increase with an increase in FS-606 composition, reach a maximum, and then decrease with a further increase in FS-606 composition. On the other hand, the interfacial tension between micellar solution and n-hexane oil has been found to decrease with an increase in FS-606 composition, reach a minimum, and then increase with a further increase in FS-606 composition.