• Korean Journal of Metals and Materials
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• v.50 no.4
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• pp.280-284
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• 2012

In this study, we prepared a sample of AISI 409L weld metals using automotive exhaust manifolds and evaluated their corrosion properties by conducting an anodic polarization test after 10 minute of heat treatment at $900^{\circ}C$. The specimens of AISI 409L transformed fully ferrite. Weld metal was refined more than base metal. Specimen of heat treatment at $900^{\circ}C$ and as weld specimen was formed precipitation. However heat treatment specimen was bulkly formed and coarser than the as weld specimen. The strength measured by 10 Hv highly at heat treatment specimens in comparison with as weld. The increase in strength is attributed to the precipitation of Ti. The result of heat treatment suggest that there was a decrease of current density and high corrosion potential. Following heat treatment process produced Ti precipitation and for this reason, it can restrain Cr-carbide so that steel will have more corrosion resistance.

• Corrosion Science and Technology
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• v.23 no.1
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• pp.33-40
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• 2024

The concentration and diffusion coefficient of oxide ion vacancies in the oxide scale formed on Fe-22Cr-0.5Mn ferritic stainless steel with and without molybdenum (Mo) was measured at 800℃ by the electrochemical polarization method. After pre-oxidation for 100 h in ambient air at 800 ℃, the oxide scale on one side was completely removed with sandpaper. A YSZ plate was placed on the side where the oxide scale remained. Platinum (Pt) meshes were attached on the top of the YSZ plate and the side where the oxide scale was removed. Changes in electrical current were measured after applying an electrical potential through Pt wires welded to the Pt meshes. The results were interpreted by solving the diffusion equation. The diffusion coefficient and concentration of oxide ion vacancy decreased by 30% and 70% in the specimen with Mo, respectively, compared to the specimen without Mo. The oxide ion vacancy concentration of chromia decreased due to the addition of Mo.

• Journal of Powder Materials
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• v.27 no.4
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• pp.311-317
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• 2020

In this study, the effects of Co content on the microstructure and Charpy impact properties of Fe-Cr-W ferritic/martensitic oxide dispersion strengthened (F/M ODS) steels are investigated. F/M ODS steels with 0-5 wt% Co are fabricated by mechanical alloying, followed by hot isostatic pressing, hot-rolling, and normalizing/tempering heat treatment. All the steels commonly exhibit two-phase microstructures consisting of ferrite and tempered martensite. The volume fraction of ferrite increases with the increase in the Co content, since the Co element considerably lowers the hardenability of the F/M ODS steel. Despite the lowest volume fraction of tempered martensite, the F/M ODS steel with 5 wt% Co shows the highest micro-Vickers hardness, owing to the solid solution-hardening effect of the alloyed Co. The high hardness of the steel improves the resistance to fracture initiation, thereby resulting in the enhanced fracture initiation energy in a Charpy impact test at - 40℃. Furthermore, the addition of Co suppresses the formation of coarse oxide inclusions in the F/M ODS steel, while simultaneously providing a high resistance to fracture propagation. Owing to these combined effects of Co, the Charpy impact energy of the F/M ODS steel increases gradually with the increase in the Co content.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.144-145
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• 2006

A developed molybdenum hybrid-alloyed steel powder is based on a molybdenum prealloyed steel powder to which molybdenum powder particles are diffusion bonded. The sintered compact made of this powder has a finer pore structure than that of the conventional molybdenum prealloyed steel powder, because the ferritic iron phase $({\alpha}-phase)$ with a high diffusion coefficient is formed in the sintering necks where molybdenum is concentrated resulting in enhanced sintering. The rolling contact fatigue strength of the sintered and carburized compacts made of this powder improved by a factor of 3.6 compared with that of the conventional powder due to the fine pore structures.

• Journal of Korean Society of Steel Construction
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• v.25 no.5
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• pp.463-474
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• 2013

Many experimental and numerical researches for thin-walled carbon steel and austenitic stainless steel single shear bolted connections have been conducted and the modified design equations of ultimate strength were proposed. In this study, the tests of double shear bolted connections with bolt arrangements ($2{\times}1$, $2{\times}2$) and end distance parallel to the loading direction as main variables were performed. Specimens were planed with a constant dimension of edge distance perpendicular to the loading direction, bolt diameter, pitch and gauge like single shear bolted connections. The test results such as ultimate strength and fracture mode were compared with those of current design standards. Furthermore, modified block shear equations for double shear bolted connections were suggested.

• Journal of the Korean Society for Heat Treatment
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• v.30 no.2
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• pp.53-60
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• 2017

The aim of this study is to examine a feasibility to substitute Ti for Ta in reduced activation ferritic/martensitic (RAFM) steel by comparing a Ti-added RAFM steel with a conventional Ta-added RAFM steel. The microstructures and mechanical properties of Ta-, and Ti-added RAFM steels were investigated and a relationship between microstructures and mechanical properties was considered based on quantitative analysis of precipitates in two RAFM steels. Ta-, and Ti-added RAFM steels were normalized at $1000{\sim}1040^{\circ}C$ for 30 min and tempered at $750^{\circ}C$ for 2 hr. Both RAFM steels had very similar microstructures, that is, typical tempered martensite with relatively coarse $M_{23}C_6$ carbides at boundaries of grain and lath, and fine MX precipitates inside laths. The MX precipitates were identified as TaC in Ta-added RAFM steel and TiC or (Ti, W)C in Ti-added RAFM steel, respectively. It is believed that these RAFM steels show similar tensile and Charpy impact properties due to similar microstructures. Precipitate hardening and brittle fracture strength calculated with quantitative analysis of precipitates elucidated well the similar behaviors on the tensile and Charpy impact properties of Ta-, and Ti-added RAFM steels.

• Nuclear Engineering and Technology
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• v.49 no.1
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• pp.178-188
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• 2017

To study the effects of zirconium (Zr) addition on the microstructure, hardness and the tensile properties of oxide dispersion strengthened (ODS) ferritic-martensitic steels, two kinds of 9Cr-ODS ferritic-martensitic steels with nominal compositions (wt.%) of $Fe-9Cr-2W-0.3Y_2O_3$ and $Fe-9Cr-2W-0.3Zr-0.3Y_2O_3$ were fabricated by the mechanical alloying (MA) of premixed powders and then consolidated by hot isostatic pressing (HIP) techniques. The experimental results showed that the average grain size decreases with Zr addition. The trigonal ${\delta}$-phase $Y_4Zr_3O_{12}$ oxides and body-centered cubic $Y_2O_3$ oxides are formed in the 9Cr-Zr-ODS steel and 9Cr non-Zr ODS steel, respectively, and the average size of $Y_4Zr_3O_{12}$ particles is much smaller than that of $Y_2O_3$. The dispersion morphology of the oxide particles in 9Cr-Zr-ODS steel is significantly improved and the number density is $1.1{\times}10^{23}/m^3$ with Zr addition. The 9Cr-Zr-ODS steel shows much higher tensile ductility, ultimate tensile strength and Vickers hardness at the same time.

• Journal of the Korean Society for Nondestructive Testing
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• v.28 no.5
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• pp.407-415
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• 2008

The tubes in heat exchanger are typically made from copper alloy, stainless steel, carbon steel, titanium alloy material. type-439 ferritic stainless steel is ferromagnetic material, and furnish higher heat transfer rates than austenitic stainless steels and higher resistance to corrosion-induced flaws. Ferritic stainless steel can typically be found in low-pressure(LP) feedwater heaters and moisture separator reheaters(MSRs). LP feedwater heaters generally utilize thin wall type-439 stainless steel tubing, whereas MSRs typically employ a heavier wall tubing with integral fins. Service-induced damage can occur on the OD(outside diameter) surface of type-439 ferritic stainless steel tubing which is employed for MSRs tubing, and the most typical damage mechanism is vibration-induced tube-to-TSP(tube support plate) wear and fatigue cracking. The wear has been reported that occurs mainly on the OD surface. Accordingly, in this study, we have evaluated the flaw sizing capability of magnetic saturation eddy current technique using magnetic saturation probe and flawed specimen.

• Journal of Powder Materials
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• v.24 no.2
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• pp.133-140
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• 2017

This study investigates the oxidation properties of Fe-14Cr ferritic oxide-dispersion-strengthened (ODS) steel at various high temperatures (900, 1000, and $1100^{\circ}C$ for 24 h). The initial microstructure shows that no clear structural change occurs even under high-temperature heat treatment, and the average measured grain size is 0.4 and $1.1{\mu}m$ for the as-fabricated and heat-treated specimens, respectively. Y-Ti-O nanoclusters 10-50 nm in size are observed. High-temperature oxidation results show that the weight increases by 0.27 and $0.29mg/cm^2$ for the as-fabricated and heat-treated ($900^{\circ}C$) specimens, and by 0.47 and $0.50mg/cm^2$ for the as-fabricated and heat-treated ($1000^{\circ}C$) specimens, respectively. Further, after 24 h oxidation tests, the weight increases by 56.50 and $100.60mg/cm^2$ for the as-fabricated and heat-treated ($1100^{\circ}C$) specimens, respectively; the latter increase is approximately 100 times higher than that at $1000^{\circ}C$. Observation of the surface after the oxidation test shows that $Cr_2O_3$ is the main oxide on a specimen tested at $1000^{\circ}C$, whereas $Fe_2O_3$ and $Fe_3O_4$ phases also form on a specimen tested at $1100^{\circ}C$, where the weight increases rapidly. The high-temperature oxidation behavior of Fe-14Cr ODS steel is confirmed to be dominated by changes in the $Cr_2O_3$ layer and generation of Fe-based oxides through evaporation.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2001.10a
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• pp.293-296
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• 2001

The dynamic softening mechanisms of AISI 316, AISI 304 and AISI 430 stainless steels were studied with torsion test in the temperature range of $900 - 1200^{\circ}C$ and the strain rate range of $5.0x10^{-2}-5.0x10^0/sec$. The austenitic stainless steels, such as AISI 316 and AISI 304 were softened by dynamic recrystallization (DRX) during hot deformation. Also, the evolutions of flow stress and microstructure of AISI 430 ferritic stainless steel show the characteristics of continuous dynamic recrystallization (CDRX). To establish the quantitative equations for DRX of AISI 316 stainless steel, the evolution of flow stress curve with strain was analyzed. The critical strain (${\varepsilon}_c$) and strain for maximum softening rate (${\varepsilon}^{*}$) could be confirmed by the analysis of work hardening rate ($d{\sigma}/d{\varepsilon}={\theta}$). The volume fraction of dynamic recrystallization ($X_{DRX}$) as a function of processing variables, such as strain rate ( $\varepsilon$ ), temperature (T), and strain ( $\varepsilon$ ) were established using the ${\epsilon}_c$ and ${\varepsilon}^{*}$. For the exact prediction the ${\varepsilon}_c,\;{\varepsilon}^{*}$ and Avrami' exponent (m') were quantitatively expressed by dimensionless parameter, Z/A, respectively. It was found that the calculated results were agreed with the experimental data for the steels at my deformation conditions. Also, we can reasonably conclude that the DRX, CDRX and grain refinement of stainless steels can be achieved by large strain deformation at high Z parameter condition.