• 제목/요약/키워드: contact resistance reduction

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PEMFC 고분자막의 화학적인 열화에 의한 두께 감소 보정이 성능 및 내구성에 미치는 영향 (Effect of Compensation for Thickness Reduction by Chemical Degradation of PEMFC Membrane on Performance and Durability)

  • 오소형;김유진;이승태;유동근;박권필
    • Korean Chemical Engineering Research
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    • 제62권1호
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    • pp.1-6
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    • 2024
  • 상용차용 수소 전기 차량 수요가 증가하면서 고분자 전해질 연료전지 (PEMFC) 내구성은 승용차용보다 5배 이상 증가해야 하므로 내구성 향상 연구개발이 시급한 상황이다. PEMFC 막전극접합체 (MEA)가 화학적 열화가 진행되면 MEA 두께가 감소하고 핀홀이 발생하기도 한다. 본 연구에서는 화학적 열화 가속 실험인 개회로전압 (OCV) holding 후에 단위전지의 체결압을 상승시키면서 MEA의 성능 및 내구성의 변화를 측정하였다. 체결압이 상승하면서 고분자막의 저항과 막/전극 접촉저항이 감소하여 I-V 성능이 향상되었고, 수소투과도가 감소하였다. 수소투과도 감소에 따라 OCV는 증가하였다. 핀홀 부위를 제거하고 MEA 체결압을 증가시켰을 때 수소투과도가 급감하여 국부적인 열화가 전체 셀의 성능과 내구성에 미치는 영향이 큼을 확인하였다. 핀홀 부위 제거 후 재체결하고 OCV holding 평가를 하였을 때 막 저항과 수소투과도 감소에 따라 내구성이 향상됨을 확인하였다.

전자기 성형 시 온도에 따른 알루미늄 파이프의 전자기-구조 연동해석 (Electromagnetic-structure Co-simulation Analysis of Aluminum Pipe with Electromagnetic Forming according to Temperature)

  • 강한빈;탁승민;백인석;최진규;이석순
    • 항공우주시스템공학회지
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    • 제12권3호
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    • pp.64-69
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    • 2018
  • 고속 전자기 성형 (EMF) 과정은 로렌츠 힘과 자기장의 에너지를 기반으로 한다. EMF의 장점은 향상된 성형성, 주름 감소 및 비접촉 성형 등이 있다. 본 연구에서는 전자기 성형을 통한 알루미늄 파이프의 온도에 따른 성형성을 분석하기 위해 전자기-구조 연동해석을 수행하였으며, 온도가 증가함에 따라 전기저항이 커지므로 인해 자속 밀도는 감소하고, 응력-변형률 곡선에서 온도가 높아질수록 유동 응력이 낮아지므로 변형량은 상대적으로 증가함을 확인할 수 있었다.

소형콘관입시험(Miniature CPT)의 국내현장적용 사례분석 (Case Studies on the Field Application of Miniature CPT's in South Korea)

  • 윤성수;황대진;김준오;지완구
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2010년도 추계 학술발표회
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    • pp.269-281
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    • 2010
  • The cone penetration test(CPT) has been increasingly used for in situ site characterization. However, the use of CPT is often limited due to specific site conditions depending on the cone size, geometry, and capacity of the CPT system used. In South Korea, it has generally been considered that the CPT could be satisfactorily performed only in soft soils. Louisiana State University/ Louisiana Transportation Research Center has implemented a field-rugged continuous intrusion miniature cone penetration test (CIMCPT) system since the 1990s. The miniature cone penetrometer of the CIMCPT system has a cross-sectional cone area of $2cm^2$ allowing finer soil profiles compared to the standard $10cm^2$. The reduced cross-sectional area also enables a system capacity reduction leading to cost saving and ease in maintenance. In addition, the continuous intrusion mechanism allows fast and economic site investigations. Samsung C&T Corporation has recently implemented a similar CIMCPT system. In this study, case studies on the field application of Samsung CIMCPT system for the last 2 years are presented to illustrate its performance investigation and its usefulness and limitation. Results of the case studies show that the CIMCPT system can be applied to soils with cone tip resistance($q_c$) values up to about 30MPa and allows a reliable and useful way to characterize soft soils. The results also show that the rod buckling limits the investigation depth by the system and the large contact pressure of the CIMCPT truck prevents the use of the system at sites with soft surface soils. According to the results of the case studies, the Samsung CIMCPT system has been being upgraded with a miniature cone with a longer rod, a crawler-type transportation system, a pre-boring system, and so on.

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이중 활성층(a-Si/a-SiNx)의 XeCl 엑시머 레이저 어닐링 효과 (Excimer Laser Annealing Effects of Double Structured Poly-Si Active Layer)

  • 최홍석;박철민;전재홍;유준석;한민구
    • 전자공학회논문지D
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    • 제35D권6호
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    • pp.46-53
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    • 1998
  • 저온 공정으로 제작되는 다결정 실리콘 박막 트랜지스터의 활성층을 이중 활성층(a-Si/a-SiN/sub x/)으로 제작하는 공정을 제안하고 다결정 실리콘 박막 트랜지스터를 제작하였다. 본 논문에서는 활성층의 아래쪽 실리콘 박막에 약간의 질소기를 첨가한 후 그 위에 순수한 비정질 실리콘 박막을 증착하여 엑시머 레이저의 에너지로 비정질 실리콘 박막을 결정화하여 사용하였다. 이중 활성층 (a-Si/a-SiN/sub x/)의 경우, 하부층의 NH₃/SiH₄ 유속비가 증가함에 따라, 상부 a-Si 층의 결정 성장이 촉진됨을 알 수 있었으나, n/sup +/ poly-SiN/sub x/ 층의 전도도 특성을 고려해 볼 때, NH₃/SiH₄ 유속비는 0.11의 상한치를 가짐을 알 수 있었다. 전계 방출 전류에 영향을 미치는 광학적 밴드갭의 경우, poly-Si 박막에 비해 증가하였으며, NH₃/SiH₄ 유속비가 0.11 이하에서도 0.1eV 정도의 증가를 보여, 이로 인하여 소자 제작시 전계 방출 전류가 억제될 것을 예상할 수 있다.

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복심곡선 레일이상마모 발생 저감 사례 (The Reduction Case of Occurrence of Abnormal Wearing of Rail in Compound Curve Part)

  • 김완술
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2007년도 춘계학술대회 논문집
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    • pp.1097-1106
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    • 2007
  • Rail provides running tract for train and broadly and widely conveys the weight of the train exerted from the train wheels that the rail directly supports onto the cross tie and roadbed, and supports the cross-sectional pressure exerted by centrifugal force at curvatures. That is, stationary rail provides surface on which dynamic train runs and guarantees cross-sectional resistance to enable the vertical snake motion of the train wheels as well as to maintain lateral force at curvatures. Rail provides running surface on which train wheels can run smoothly, and secures vertical and lateral force. However, it undergoes continuous destructive reactions (wearing and damages) and abrasion of the cladding by the train wheels. It is obvious that wearing will result when two metal parts act against each other. However, occurrence of abnormal wearing such as rapid wearing of the rail side due to complex generation of various mechanisms at the contact surface between the rail and train wheel flange. It is not easy to simply examine the causes of occurrence of abnormal wearing of rail and train wheel flange. Although countless number of academicians and specialists are conducting researches on abnormal wearing of rail and vertical wearing of train wheels, I believe it is too early to argue on pros and cons due to insufficiency of officially verified information on the issue. This review will be focusing on the examples of repairs that reduced the generation of abnormal wearing of rail by reviewing and improving characteristics of wearing and slack, speed of the train and cant as well as status of lubricator by choosing the compound curves present in the section between the $Anguk{\sim}Jongno3-ga$ Stations of the Route No. 3 among the compound curve tracks of the Seoul Metro Routes No. 3 & 4 at which abnormal wearing is generated continuously.

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Deep Submicron SOI n-채널 MOSFET에서 열전자 효과들의 온도 의존성 (Dependence of Hot Electron Effects on Temperature in The Deep Submicron SOI n-Channel MOSFETs)

  • 박근형;차호일
    • 한국정보전자통신기술학회논문지
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    • 제11권2호
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    • pp.189-194
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    • 2018
  • 현재 대부분의 집적회로는 bulk CMOS 기술을 사용해서 제작되고 있으나 전력 소모를 낮추고 die 크기를 줄이기에는 한계점에 도달해있다. 이러한 어려움을 획기적으로 극복할 수 있는 초저전력 기술로서 SOI CMOS 기술이 최근에 크게 각광을 받고 있다. 본 논문에서는 100 nm Thin SOI 기판 위에 제작된 n-채널 MOSFET 소자들의 열전자 효과들의 온도 의존성에 관한 연구 결과들이 논의되었다. 소자들이 LDD 구조를 갖고 있음에도 불구하고 열전자 효과들이 예상보다 더 심각한 것으로 나타났는데, 이는 채널과 기판 접지 사이의 직렬 저항이 크기 때문인 것으로 믿어졌다. 온도가 높을수록 채널에서의 phonon scattering의 증가와 함께 열전자 효과는 감소하였는데, 이는 phonon scattering의 증가는 결과적으로 열전자의 생성을 감소시켰기 때문인 것으로 판단된다.

Improved structures of stainless steel current collector increase power generation of microbial fuel cells by decreasing cathodic charge transfer impedance

  • Nam, Taehui;Son, Sunghoon;Kim, Eojn;Tran, Huong Viet Hoa;Koo, Bonyoung;Chai, Hyungwon;Kim, Junhyuk;Pandit, Soumya;Gurung, Anup;Oh, Sang-Eun;Kim, Eun Jung;Choi, Yonghoon;Jung, Sokhee P.
    • Environmental Engineering Research
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    • 제23권4호
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    • pp.383-389
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    • 2018
  • Microbial fuel cell (MFC) is an innovative environmental and energy system that converts organic wastewater into electrical energy. For practical implementation of MFC as a wastewater treatment process, a number of limitations need to be overcome. Improving cathodic performance is one of major challenges, and introduction of a current collector can be an easy and practical solution. In this study, three types of current collectors made of stainless steel (SS) were tested in a single-chamber cubic MFC. The three current collectors had different contact areas to the cathode (P $1.0cm^2$; PC $4.3cm^2$; PM $6.5cm^2$) and increasing the contacting area enhanced the power and current generations and coulombic and energy recoveries by mainly decreasing cathodic charge transfer impedance. Application of the SS mesh to the cathode (PM) improved maximum power density, optimum current density and maximum current density by 8.8%, 3.6% and 6.7%, respectively, comparing with P of no SS mesh. The SS mesh decreased cathodic polarization resistance by up to 16%, and cathodic charge transfer impedance by up to 39%, possibly because the SS mesh enhanced electron transport and oxygen reduction reaction. However, application of the SS mesh had little effect on ohmic impedance.

Experimental Investigation of Concave and Convex Micro-Textures for Improving Anti-Adhesion Property of Cutting Tool in Dry Finish Cutting

  • Kang, Zhengyang;Fu, Yonghong;Chen, Yun;Ji, Jinghu;Fu, Hao;Wang, Shulin;Li, Rui
    • International Journal of Precision Engineering and Manufacturing-Green Technology
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    • 제5권5호
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    • pp.583-591
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    • 2018
  • Tool-chip adhesion impacts on cutting performance significantly, especially in finish cutting process. To promote cutting tools' anti-adhesion property, the concave micro-grooves texture (MGT) and convex volcano-like texture (VLT) were fabricated separately on lathe tools' rake faces by laser surface texturing (LST). Various orientations of MGT and different area densities (9% and 48%) and regions (partial and full) of VLT were considered in textured patterns designing. The following orthogonal cutting experiments, machining of aluminum alloy 5038, analyzed tools' performances including cutting force, cutting stability, chip shape, rake face adhesion and abrasion. It indicated that under dry finish cutting conditions, MGT contributed to cutting stability and low cutting forces, meanwhile friction and normal force reduced by around 15% and 10%, respectively with a weak correlation to the grooves' orientation. High density VLT tools, on the other hand, presented an obvious anti-adhesion property. A $5{\mu}m$ reduction of crater wear's depth can be observed on textured rake faces after long length cutting and textured rake faces presented half size of BUE regions comparing to the flat tool, however, once the texture morphologies were filled or worn, the anti-adhesion effect could be invalid. The bearing ratio curve was employed to analysis tool-chip contact and durability of textured surfaces contributing to a better understanding of anti-adhesion and enhanced durability of the textured tools.

Effects of water on rock fracture properties: Studies of mode I fracture toughness, crack propagation velocity, and consumed energy in calcite-cemented sandstone

  • Maruvanchery, Varun;Kim, Eunhye
    • Geomechanics and Engineering
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    • 제17권1호
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    • pp.57-67
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    • 2019
  • Water-induced strength reduction is one of the most critical causes for rock deformation and failure. Understanding the effects of water on the strength, toughness and deformability of rocks are of a great importance in rock fracture mechanics and design of structures in rock. However, only a few studies have been conducted to understand the effects of water on fracture properties such as fracture toughness, crack propagation velocity, consumed energy, and microstructural damage. Thus, in this study, we focused on the understanding of how microscale damages induced by water saturation affect mesoscale mechanical and fracture properties compared with oven dried specimens along three notch orientations-divider, arrester, and short transverse. The mechanical properties of calcite-cemented sandstone were examined using standard uniaxial compressive strength (UCS) and Brazilian tensile strength (BTS) tests. In addition, fracture properties such as fracture toughness, consumed energy and crack propagation velocity were examined with cracked chevron notched Brazilian disk (CCNBD) tests. Digital Image Correlation (DIC), a non-contact optical measurement technique, was used for both strain and crack propagation velocity measurements along the bedding plane orientations. Finally, environmental scanning electron microscope (ESEM) was employed to investigate the microstructural damages produced in calcite-cemented sandstone specimens before and after CCNBD tests. As results, both mechanical and fracture properties reduced significantly when specimens were saturated. The effects of water on fracture properties (fracture toughness and consumed energy) were predominant in divider specimens when compared with arrester and short transverse specimens. Whereas crack propagation velocity was faster in short transverse and slower in arrester, and intermediate in divider specimens. Based on ESEM data, water in the calcite-cemented sandstone induced microstructural damages (microcracks and voids) and increased the strength disparity between cement/matrix and rock forming mineral grains, which in turn reduced the crack propagation resistance of the rock, leading to lower both consumed energy and fracture toughness ($K_{IC}$).

농약(Gramoxon)중독에 의한 화상으로 발생된 구강점막염 치험 (MANAGEMENT OF ORAL MUCOSITIS OWING TO CHEMICAL BURN BY INTOXICATION OF AGRICULTURAL CHEMICALS(GRAMOXON) : REPORT OF CASES)

  • 유재하;강상훈;김현실;백성흠;유태민;이지웅;정원균;김종배
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제29권2호
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    • pp.123-127
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    • 2003
  • Chemical burns onto oral mucosa which are infrequent, may result from contact with a wide variety of chemical agents. The degree of injury depends on the chemical, its concentration, duration of contact, and the natural penetrability and resistance of the tissues involved. Chemicals do not usually "burn" in that they do not cause destruction by hyperthermic activity. Rather, they damage tissue by causing coagulation of protein by one of several processes, reduction, oxidation, desiccation, corrosion, or vesication. Paraquat(Gramoxon) is the most frequently agricultural chemicals that induce the severe toxic reactions onto the organs of human body in Korea. The toxic reaction are composed of pulmonary edema and fibrosis, formation of hyaline membrane, inflammatory reaction and bleeding tendency, owing to the cell damage by the production of superoxide radicals. The contents of essential treatment in paraquat intoxication are commonly airway and breathing maintenance, gastric lavage, much hydration and diuresis, hemoperfusion and medications for the removal of the chemicals and the prevention of various complications. The sedative oral dressings, such as, orabase ointment application, warm saline gargling, lidocaine viscous gargling and oral gargling by the mixed solutions(tetracycline, prednisolone and 10% dextrose water) are important for the improvement of chemical oral mucositis and the comfortable feeding of diet. The authors managed properly two cases of oral chemical mucositis that were occurred by the incorrect use of agricultural chemicals(paraquat) and report the cases with the review of literatures about care of the chemical intoxication and oral mucositis.