• Corrosion Science and Technology
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• v.20 no.5
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• pp.295-307
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• 2021

Effects of ε-carbide (Fe_2.4C) on corrosion and hydrogen diffusion behaviors of ultra-strong steel sheets for automotive application were investigated using a number of experimental and analytical methods. Results of this study showed that the type of iron carbide precipitated during tempering treatments conducted at below A₁ temperatures had a significant influence on corrosion kinetics. Compared to a steel sample with cementite (Fe₃C), a steel sample with ε-carbide (Fe_2.4C) showed higher corrosion resistance during a long-term exposure to a neutral aqueous solution. In addition, the diffusion kinetics of hydrogen atoms formed by electrochemical corrosion reactions in the steel matrix with ε-carbide were slower than the steel matrix with cementite because of a comparatively higher binding energy of hydrogen with ε-carbide. These results suggest that designing steels with fine ε-carbide distributed uniformly throughout the matrix can be an effective technical strategy to ensure high resistance to hydrogen embrittlement induced by aqueous corrosion.

• Steel and Composite Structures
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• v.31 no.4
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• pp.361-372
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• 2019

In recent years, considerable attention has been paid to the research and development of high-strength steel plates, with particular emphasis on the enhancement of the seismic resistance of buildings and bridges. Many efforts have also been undertaken to improve the properties of high-strength bolts and weld materials. However, there are still different opinions on steel joints that combine high-strength bolts and fillet welds. Therefore, it is necessary to verify the design specifications and guidelines, especially for newly developed 1,400-MPa high-strength bolts, 570-MPa steel plates, and weld materials. This paper presents the results of literature reviews and experimental investigations. Test parameters include bolt strengths, weld orientations, and their combinations. The results show that advances in steel materials have increased the plastic deformation capacities of steel welds. That allows combination joints to gain their maximum strength before the welds have fracture failures. When in combination with longitudinal welds, high-strength bolts slip, come in contact with cover plates, and develop greater bearing strength before the joints reach their maximum strength. However, in the case of combinations with transverse welds, changes in crack angles cause the welds to provide additional strength. The combination joints can therefore develop strength greater than estimated by adding the strength of bolted joints in proportion to those of welded joints. Consequently, using the slip resistance as the available strength of high-strength bolts is recommended. That ensures a margin of safety in the strength design of combination joints.

• Journal of the Society of Naval Architects of Korea
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• v.51 no.3
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• pp.246-253
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• 2014

Liquid natural gas is stored and transported inside cargo tank which is made of specially designed cryogenic materials such as 9% Ni steel, Al5083-O alloy and SUS304 and so on. The materials have to keep excellent ductile characteristics under the cryogenic environment, down to -163oC, in order to avoid the catastrophic sudden brittle fracture during the operation condition. High manganese steel is considered to be the promising alternative material that can replace the commonly used materials mentioned above owing to its cost effectiveness. In line with this industrial need, the mechanical properties of the high manganese steel under both room and cryogenic environment were investigated in this study focused on its tensile and fatigue behavior. In terms of the tensile strength, the ultimate tensile strength of the base material of the high manganese steel was comparable to the existing cryogenic materials, but it turned out to be undermatched one when welding is involved in. The fatigue strength of the high manganese steel under room temperature was as good as other cryogenic materials, but under cryogenic environment, slightly less than others though better than Al 5083-O alloy.

• Corrosion Science and Technology
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• v.16 no.6
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• pp.317-327
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• 2017

The change in the oxidation behavior of three types of B-added ultrahigh strength martensitic steels containing Ti and Nb induced by applying constant cathodic current was investigated. In a 3% NaCl+0.3% $NH_4SCN$ solution, the overall polarization behavior of the three alloys was similar, and degradation of the oxide film was observed in the three alloys after applying constant cathodic current. A significant increase in the anodic current density was observed in the Nb-added alloy, while it was diminished in the Ti-added alloy. Both Ti and Nb alloying decreased the hydrogen overpotential by forming NbC and TiC particles. In addition, the thickest oxide film was formed on the Ti-added alloy, but the addition of Nb decreased the film thickness. Therefore, it was concluded that the remarkable increase in the anodic current density of Nb-added alloy induced by applying constant cathodic current density was attributed to the formation of the thinnest oxide film less protective to hydrogen absorption, and the addition of Ti effectively blocked the hydrogen absorption by forming TiC particles and a relatively thick oxide film.

• Metals and materials international
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• v.24 no.6
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• pp.1241-1248
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• 2018

The reactive wetting behaviors of molten Zn-Al-Mg alloys on MnO- and amorphous (a-) $SiO_2$-covered steel sheets were investigated by the sessile drop method, as a function of the Al and Mg contents in the alloys. The sessile drop tests were carried out at $460^{\circ}C$ and the variation in the contact angles (${\theta}_c$) of alloys containing 0.2-2.5 wt% Al and 0-3.0 wt% Mg was monitored for 20 s. For all the alloys, the MnO-covered steel substrate exhibited reactive wetting whereas the $a-SiO_2$-covered steel exhibited nonreactive, nonwetting (${\theta}_c>90^{\circ}$) behavior. The MnO layer was rapidly removed by Al and Mg contained in the alloys. The wetting of the MnO-covered steel sheet significantly improved upon increasing the Mg content but decreased upon increasing the Al content, indicating that the surface tension of the alloy droplet is the main factor controlling its wettability. Although the reactions of Al and Mg in molten alloys with the $a-SiO_2$ layer were found to be sluggish, the wettability of Zn-Al-Mg alloys on the $a-SiO_2$ layer improved upon increasing the Al and Mg contents. These results suggest that the wetting of advanced high-strength steel sheets, the surface oxide layer of which consists of a mixture of MnO and $SiO_2$, with Zn-Al-Mg alloys could be most effectively improved by increasing the Mg content of the alloys.

• Steel and Composite Structures
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• v.33 no.6
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• pp.823-836
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• 2019

Spiral welded tubes (SWTs) are fabricated by helically bending a steel plate and welding the resulting abutting edges. The cost-effectiveness of concrete-filled steel tube (CFST) columns can be enhanced by utilising such SWTs rather than the more conventional longitudinal seam welded tubes. Even though the steel-concrete interface bond strength of such concrete-filled spiral-welded steel tubes (CF-SWSTs) is an important consideration in relation to ensuring composite behaviour of such elements, especially at connections, it has not been investigated in detail to date. CF-SWSTs warrant separate consideration of their bond behaviour to CFSTs of other tube types due to the distinct weld seam geometry and fabrication induced surface imperfection patterns of SWTs. To address this research gap, axial push-out tests on forty CF-SWSTs were carried out where the effects of tube material, outside diameter (D), outside diameter to wall thickness (D/t), length of the steel-concrete interface (L) and concrete strength grade (f'_c) were investigated. D, D/t and L/D values in the range 102-305 mm, 51-152.5 and 1.8-5.9 were considered while two nominal concrete grades, 20 MPa and 50 MPa, were used for the tests. The test results showed that the push-out bond strengths of CF-SWSTs of both mild-steel and stainless-steel were either similar to or greater than those of comparable CFSTs of other tube types. The bond strengths obtained experimentally for the tested CF-SWSTs, irrespective of the tube material type, were found to be well predicted by the guidelines contained in AISC-360.

• Corrosion Science and Technology
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• v.21 no.3
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• pp.209-220
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• 2022

Erosion-corrosion behaviors of Hadfield steel under a neutral aqueous environment with fine SiO₂ particles were examined and compared with those of conventional carbon steel. A range of electrochemical experiments (potentiodynamic polarization, linear polarization, and impedance), immersion test, and slurry pot test (i.e., erosion-corrosion test) were performed. Results showed that the Hadfield steel composed of austenitic matrix with (Fe,Mn)-based carbide had lower corrosion potential and higher corrosion current density than carbon steel with a typical ferrite/pearlite structure. In addition, pipe forming increased total corrosion rates (i.e., pure corrosion and erosion-enhanced corrosion rates). Nevertheless, the erosion-corrosion rate of Hadfield steel was much smaller. Morphological observation showed that local damage in the form of a crater by erosion-corrosion was more noticeable in carbon steel. The higher resistance of Hadfield steel to erosion-corrosion was attributed to its lower total erosion rates (i.e., pure erosion and corrosion-enhanced erosion rates) highly depending on surface hardness. This study suggests that Hadfield steel with higher resistances to flowing erosion-corrosion in an aqueous environment can be applied widely to various industrial fields.

• Transactions of Materials Processing
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• v.20 no.2
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• pp.99-103
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• 2011

Many parameters influence the frictional behavior of steel sheet during stamping. The contact pressure between a die and a sheet during stamping is one of them. Thus, this parameter is investigated for high strength steel (HSS) sheets, which are widely used for auto body panels due to their potential for weight reduction. Since HSS extend the limits of contact pressure for mild steel, the effect of this parameter on friction cannot be ignored. To investigate the influence of contact pressure on the frictional behavior of steel sheets, a flat type of friction test was conducted on three different steel sheets under various contact pressures. For bare steel sheets, the curve representing the relationship between contact pressure and friction coefficient exhibits a U shape. Coated steel sheets show a similar tendency except at low contact pressure. For these materials, when the contact pressure is very low, the friction coefficient slightly increases with pressure before it starts to decrease. The test results show that the effect of contact pressure on frictional behavior of steel sheet is not negligible even for contact pressures that are lower than the strength of HSS sheet.

• Transactions of Materials Processing
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• v.12 no.4
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• pp.364-369
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• 2003

Non-heat treated steels are attractive in the steel-wire industry since the spheroidization and quenching-tempering treatment are not involved during the processing. However, non-heat treated steels should satisfy high strength and good formability without performing heat treatment. Therefore, it is important to investigate optimum materials showing a good combination of strength and formability after the drawing process. In this study, three different steels such as dual phase steel, low-Si steel, and ultra low carbon bainitic steel were used to study their mechanical properties and the cold formability. The cold formability of three steels was investigated by estimating the deformation resistance and the forming limit. The deformation resistance was estimated by calculating the deformation energy, and the forming limit was evaluated by measuring the critical strain revealing crack initiation at the notch tip of the specimens. The results showed that deformation resistance was the lowest in the low-Si steel, and the forming limit strains of ultra low carbon bainitic steel and low-Si steel were higher than that of commercial SWRCH45F steel.

• Journal of the Korean Society for Heat Treatment
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• v.30 no.2
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• pp.53-60
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• 2017

The aim of this study is to examine a feasibility to substitute Ti for Ta in reduced activation ferritic/martensitic (RAFM) steel by comparing a Ti-added RAFM steel with a conventional Ta-added RAFM steel. The microstructures and mechanical properties of Ta-, and Ti-added RAFM steels were investigated and a relationship between microstructures and mechanical properties was considered based on quantitative analysis of precipitates in two RAFM steels. Ta-, and Ti-added RAFM steels were normalized at $1000{\sim}1040^{\circ}C$ for 30 min and tempered at $750^{\circ}C$ for 2 hr. Both RAFM steels had very similar microstructures, that is, typical tempered martensite with relatively coarse $M_{23}C_6$ carbides at boundaries of grain and lath, and fine MX precipitates inside laths. The MX precipitates were identified as TaC in Ta-added RAFM steel and TiC or (Ti, W)C in Ti-added RAFM steel, respectively. It is believed that these RAFM steels show similar tensile and Charpy impact properties due to similar microstructures. Precipitate hardening and brittle fracture strength calculated with quantitative analysis of precipitates elucidated well the similar behaviors on the tensile and Charpy impact properties of Ta-, and Ti-added RAFM steels.