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Studies on the Surface Properties of PMMA after Accelerated Weathering

  • Kwon, Young Bum;Ha, Jin Uk;Hwang, Ye Jin;Oh, Jeong Seok
    • Elastomers and Composites
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    • v.51 no.4
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    • pp.350-354
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    • 2016
  • The surface properties of poly(methyl methacrylate) (PMMA) were investigated after accelerated weathering. Glossinesses, contact angles, surface free energies, thermal stability, and mechanical properties were investigated. The glossiness of the weathered PMMA was decreased with increasing exposure time. Contact angles and surface free energies were not overtly changed because the amount of oxygen on the surface was remained. PMMA was compounded with anti-block and antistatic agents using a co-rotating twin screw extruder to improve the durability. The PMMA composites showed better glossinesses after accelerated weathering while maintaining the contact angles, surface energy, thermal stability, and mechanical properties without significant changes.

Development of apparatus for Single-sided Wet Etching and its applications in Corrugated Membrane Fabrication

  • Kim, Junsoo;Moon, Wonkyu
    • Journal of Sensor Science and Technology
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    • v.30 no.1
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    • pp.10-14
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    • 2021
  • Wet etching is more economical than dry etching and provides a uniform etching depth regardless of wafer sizes. Typically, potassium hydroxide (KOH) and tetra-methyl-ammonium hydroxide (TMAH) solutions are widely used for the wet etching of silicon. However, there is a limit to the wet etching process when a material deposited on an unetched surface reacts with an etching solution. To solve this problem, in this study, an apparatus was designed and manufactured to physically block the inflow of etchants on the surface using a rubber O-ring. The proposed apparatus includes a heater and a temperature controller to maintain a constant temperature during etching, and the hydrostatic pressure of the etchant is considered for the thin film structure. A corrugation membrane with a diameter of 800 ㎛, thickness of 600 nm, and corrugation depth of 3 ㎛ with two corrugations was successfully fabricated using the prepared device.

An Implementation of Integrated System for Topographic and Cadastral Data (지형 및 지적자료의 통합체계 구축)

  • 유복모;김갑진
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.18 no.2
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    • pp.143-155
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    • 2000
  • With the increasing needs for the integrated use of topographic and cadastral data in order to build an efficient geo-spatial information system. it is urgently necessary to research into its solution. The intention of this study is to detect error types of data and to propose adjustment methods for solving the problems caused by integrating topographic and cadastral data. For this purpose a primary integrated data model is created to link attribute data(land management system) and graphic data within cadastral information in the first step. In next, a secondary integrated data model based on the improved method is formed to coincide the graphic data of cadastral map with that of topographic map. At the first, because a numerous error types md sources caused by separate management of graphic and attribute data are easily checked, it is possible to suggest an improved method to correct these errors using the primary integrated data model. In addition, the accuracy in position and area with coordinate transformation method based on multi-block adjustment is more efficient than rubber-sheeting method. As a result, the secondary integrated data model could be built by harmonizing cadastral map with topographic map using the improved solution.

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Present and Future of Thermoplastic Elastomers As Environmentally Friendly Organic Materials (친환경 유기 소재로서 열가소성 탄성체의 오늘과 내일)

  • Choi, Eun-Ji;Yoon, Ji-Hwan;Jo, Jung-Kyu;Shim, Sang-Eun;Yun, Ju-Ho;Kim, Il
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.170-187
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    • 2010
  • Much interest on the thermoplastic elastomers (TPEs) has recently been attracted in commercial fields as well as scientific and applied researches. The TPEs have their own characteristic area especially in relation with block copolymers as well as many other polymeric materials, since they show interesting features displayed by the conventional vulcanized rubber, and at the same time, by the thermoplastics. In addition, they are characterized by a set of interesting properties inherent to block and graft copolymers, variety of blends and vulcanized materials. The importance of TPE as organic materials can be evaluated by the number of published reports (papers, patents, technical reports, etc). The input of the concept 'thermoplastic elastomer' to SciFinderScholar yields 18,508 results between 1939 and July 10, 2010, and the number increased exponentially after the mid of 1990. For the suitable introduction of the TPE, historic, scientific, technical and commercial considerations should be taken into account. This review article starts with a brief discussion on historical considerations, followed by a introduction of the main preparations and analytical techniques utilized in chemical, structural, and morphological studies. The properties, processing tools, the position among organic materials, and applications of TPEs are also briefly reviewed. Finally, the most probable trends of their future development are discussed in a short final remarks.

Comparison of Marginal Fitness of Zirconia Copings According to Impression Techniques and Zirconia Blocks (구강인기방법과 블록 종류에 따른 지르코니아 코핑의 변연적합도 비교)

  • Chung, In-Sung;Jeon, Byung-Wook;Kim, Won-Young
    • The Journal of the Korea Contents Association
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    • v.16 no.1
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    • pp.151-157
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    • 2016
  • The purpose of this study was to compare of marginal fitness of zirconia copings according to impression techniques and zirconia blocks. For the conventional impression, two types of rubber impression materials were used and digital impression was made by using an intraoral scanner. Zirconia copings were manufactured from three types of blocks. With each of ten zirconia copings was determined by surface roughness and marginal fitness. For surface roughness, LUXEN Smile($2.3{\pm}0.9{\mu}m$) block was superior. And the lowest mean values and standard deviations of marginal gap for the HL specimens were $26.5{\pm}2.1{\mu}m$ for buccal, $27.2{\pm}2.1{\mu}m$ for lingual, and that of the HJ specimens $29.6{\pm}4.0{\mu}m$ for mesial, $29.0{\pm}3.0{\mu}m$ for distal. One-way ANOVA showed statistically significant difference between groups for marginal fitness(p<0.05). From the above results, the impression techniques and zirconia blocks had influence on marginal fit of the zirconia copings. Also the marginal fitness of all groups showed clinically acceptable range.

Comparison of marginal fit of metal copings according to wax blocks and oral scanning methods (구강인기법과 왁스블록의 종류에 따른 금속 코핑의 변연적합도 비교)

  • Chung, In-Sung;Kim, Won-Young;Jeon, Byung-Wook
    • Journal of Technologic Dentistry
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    • v.42 no.3
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    • pp.234-239
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    • 2020
  • Purpose: We investigated the marginal fit between abutment and metal copings according to impression technique, wax block types, and metal types. Methods: We selected the traditional impression method of using rubber impression materials and the digital impression method of using oral scanners, three types of wax blocks, and two types of metal, both of which were domestically and commercially available, were selected to produce metal copings, and the marginal fit was determined through the use of silicon replication. Results: The measurements of axial wall fit revealed that the IYV specimens had the best fit, with a mean gap of 24.11±5.95 ㎛, followed by CEV, CHV, CSS, CSV, CES, CHS, and IYS specimens (mean: 33.44±8.41 ㎛). The differences were not statistically significant. The marginal gap measurements showed that the CEV specimen had the smallest gap, 17.25±4.13 ㎛, followed by the CSV, CHV, CSS, CES, CHS, IYV, and IYS specimen (mean: 43.47±15.63 ㎛). The differences were statistically significant. Conclusion: The axial wall fit of the metal coping (VeraBond2V; Aalba Dent, Inc., Fairfield, CA, USA) produced by the lost wax technique with the traditional impression method was excellent. The marginal fit of the metal coping (VeraBond 2V) produced by wax milling with the use of an oral scanner was also excellent. The marginal fit of the metal coping was within the clinically acceptable limits in all groups.

Effect of Carbon-based Nanofillers on the Toughening Behavior of Epoxy Resin

  • Lee, Gi-Bbeum;Kim, Haeran;Shin, Wonjae;Jeon, Jinseok;Park, In-Seok;Nah, Changwoon
    • Elastomers and Composites
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    • v.56 no.3
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    • pp.179-186
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    • 2021
  • Carbon-based nanofillers, including nanodiamond (ND) and carbon nanotubes (CNTs), have been employed in epoxy matrixes for improving the toughness, using the tow prepreg method, of epoxy compounds for high pressure tanks. The reinforcing performance was compared with those of commercially available toughening fillers, including carboxyl-terminated butadiene acrylonitrile (CTBN) and block copolymers, such as poly(methyl methacrylate)-b-poly(butyl acrylate)-b-poly(methyl methacrylate) (BA-b-MMA). CTNB improved the mechanical performance at a relatively high filler loading of ~5 phr. Nanosized BA-b-MMA showed improved performance at a lower filler loading of ~2 phr. However, the mechanical properties deteriorated at a higher loading of ~5 phr because of the formation of larger aggregates. ND showed no significant improvement in mechanical properties because of aggregate formation. In contrast, surface-treated ND with epoxidized hydroxyl-terminated polybutadiene considerably improved the mechanical properties, notably the impact strength, because of more uniform dispersion of particles in the epoxy matrix. CNTs noticeably improved the flexural strength and impact strength at a filler loading of 0.5 phr. However, the improvements were lost with further addition of fillers because of CNT aggregation.

Reduction Gear Stability Estimation due to Torque Variation on the Marine Propulsion System with High-speed Four Stroke Diesel Engine (고속 4행정 디젤엔진을 갖는 선박 추진시스템에서 토크변동에 의한 감속기어 안정성 평가)

  • Kim, InSeob;Yoon, Hyunwoo;Kim, Junseong;Vuong, QuangDao;Lee, Donchool
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.25 no.12
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    • pp.815-821
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    • 2015
  • Maritime safety has been more critical recently due to the occurrence of shipboard accidents involving prime movers. As such, the propulsion shafting design and construction plays a vital role in the safe operation of the vessel other than focusing on being cost-efficient. Smaller vessels propulsion shafting system normally install high speed four-stroke diesel engine with reduction gear for propulsion efficiency. Due to higher cylinder combustion pressures, flexible couplings are employed to reduce the increased vibratory torque. In this paper, an actual vibration measurement and theoretical analysis was carried out on a propulsion shafting with V18.3L engine installed on small car-ferry and revealed higher torsional vibration. Hence, a rubber-block type flexible coupling was installed to attenuate the transmitted vibratory torque. Considering the flexible coupling application factor, reduction gear stability due to torque variation was analyzed in accordance with IACS(International Association of Classification Societies) M56 and the results are presented herein.

A Study on the Core Noise Reduction Techniques of Power Transformers (전력용 변압기 철심소음 저감기술에 관한 연구)

  • Kweon, Dong-Jin;Koo, Kyo-Sun;Cho, Ik-Choon;Kim, Yoo-Hyun;Kim, Yung-Sig
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.11
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    • pp.1962-1969
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    • 2008
  • According to the increase of power demand and expansion of downtown, it is necessary to install transformers additionally in operating substations and construct substations in residential area. But the public complaint is increased due to the transformer noise of the substation. KEPCO has used a vibration preventing pad, various soundproof walls and an encloser to transformers in outdoor substations, and a soundproof door, shutter and wind-path soundproof equipment in indoor substations to block the sound propagation of the transformers. But these noise reduction methods are not satisfied. It should be considered to reduce transformer noise itself. In this paper, we investigated core noise reduction techniques to develope a low noise transformer. The techniques to reduce core noise of the transformer are application of high permeability grain oriented silicon sheets, decrease of magnetic flux density of core, application of 6step-lap core stacking method, improvement of core binding method(binding addition, band fixing) and application of rubber damper in oder to reduce transmission of core vibration, etc.

Application of Composites Composed of Phosphoric Acid-Doped Silica Gel and Styrene-Ethylene-Butylene-Styrene Elastomer to Electric Double-Layer Capacitors

  • Matsuda, Atsunori;Honjo, Hiroshi;Hirata, Kazuki;Tatsumisago, Masahiro;Minami, Tsutomu
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.353-356
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    • 1999
  • Highly proten-conductive elastic composites have been successfully prepared from $H_3PO_4$-doped silica gel and styrene-ethylene-butylene-styrene block elastic copolymer. In addition solid state electric double-layer capacitors have been fabricated using the composite as an electrolyte and activated carbon powders(ACP) hybridized with the composite as a polrizable electrode. The cyclic voltammogram of the electric double-layer capacitor fabricated demonstrated that electric charge was stored in the elecric double-layer at the interface between the polarizable electrode and the electrolyte. The value of capacitance of the capacitor was 10 F/(gram of total ACP), which was comparable to that of the capacitors using conventional liquid electrolytes.

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