• 제목/요약/키워드: Particle Transition

검색결과 279건 처리시간 0.028초

알킬 아크릴레이트계의 다중 Core-shell 복합입자의 제조 (Manufacture of Alkyl Acrylate Multi Core-shell Composite Particle)

  • 조대훈;최성일;고현미;설수덕
    • 접착 및 계면
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    • 제12권1호
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    • pp.16-25
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    • 2011
  • Core 입자로 methyl methacrylate (MMA), n-butyl methacrylate (BMA)를 하고 shell 입자로 MMA, BMA, stylene (St), 2-hydroxylethylmethacrylate (2-HEMA), acrylic acid (AA)를 각각 사용하여 개시제 aommonium persulfate (APS), 유화제로 sodium dodecyl benzene sulfonate (SDBS)의 농도(0.01~0.03 wt%), 단량체의 종류와 조성을 변화시켜 수용성 유화중합으로 다중 core-shell 복합입자를 제조하여 전화율, 입자경 및 입도 분포, 평균 분자량, 분자구조, 유리전이온도, 입자의 형태 및 인장강도와 신율을 각각 측정하여 다음과 같은 결론을 얻었다. SDBS 농도 0.02 wt%에서 MMA core-(BMA/St/AA) shell 복합인자가 전화율이 98%로 우수하였고, 입자 직경은 SDBS 농도 0.03 wt%에서 BMA core-(MMA/St/AA) shell의 복합입자가 $0.47{\mu}m$로 높게 나왔다. 유리전이온도 측정은 단일 core-shell 복합입자의 2군데에 비하여 다중 core-shell 복합입자는 3군데가 존재하여 shell단량체 내의 단량체의 종류와 조성에 따라 유리전이온도 조절도 가능하고 동시에 접착력이 향상된 접착소재로서 부직포 섬유 결속제로 사용될 수 있었다.

잡음 모델을 이용한 파티클 필터 측위 (Particle Filter Localization Using Noisy Models)

  • 김인철;김승연;김혜숙
    • 정보처리학회논문지B
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    • 제19B권1호
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    • pp.27-30
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    • 2012
  • 지능형 에이전트에게 요구되는 가장 기초적인 기능 중의 하나가 불확실한 센서 데이터에 의존하여 자신의 현재 위치가 어디인지를 파악하는 일이다. 본 논문에서는 가장 효과적인 확률 기반의 측위 기법인 파티클 필터를 실제 로봇 측위에 적용한 로봇 측위 시스템의 구현에 대해 설명하고, 성능 평가를 위한 실험의 결과를 소개한다. 특히 비-잡음 상태 전이 모델과 로봇 동작의 오차를 고려한 잡음 모델간의 비교 실험을 통해, 실제 로봇 동작의 불확실성에 근사한 상태 전이 모델이 파티클 필터 측위의 성능 개선에 도움이 될 수 있음을 보인다.

Mechanism of Formation of Three Dimensional Structures of Particles in a Liquid Crystal

  • West, John L.;Zhang, Ke;Liao, Guangxun;Reznikov, Yuri;Andrienko, Denis;Glushchenko, Anatoliy V.
    • Journal of Information Display
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    • 제3권3호
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    • pp.17-23
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    • 2002
  • In this work we report methods of formation of three-dimensional structures of particles in a liquid crystal host. We found that, under the appropriate conditions, the particles are captured and dragged by the moving isotropic/nematic front during the phase transition process. This movement of the particles can be enhanced significantly or suppressed drastically with the influence of an electric field and/or with changing the conditions of the phase transition, such as the rate of cooling. As a result, a wide variety of particle structures can be obtained ranging from a fine-grained cellular structure to stripes of varying periods to a course-grained "root" structures. Changing the properties of the materials, such as the size and density of the particles and the surface anchoring of the liquid crystal at the particle surface, can also be used to control the morphology of the three-dimensional particle network and adjust the physical properties of the resulting dispersions. These particle structures may be used to affect the performance of LCD's much as polymers have been used in the past.

DETAILED EXAMINATION OF INVERSE-ANALYSIS PARAMETERS FOR PARTICLE TRAPPING IN SINGLE CHANNEL DIESEL PARTICULATE FILTER

  • Jung, S.C.;Park, J.S.;Yoon, W.S.
    • International Journal of Automotive Technology
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    • 제8권2호
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    • pp.165-177
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    • 2007
  • Predictions of diesel particulate filtration are typically made by modeling of a particle collection, and providing particle trapping levels in terms of a pressure drop. In the present study, a series of single channel diesel particulate filter (DPF) experiments are conducted, the pressure traces are inversely analyzed and essential filtration parameters are deducted for model closure. A DPF filtration model is formulated with a non-linear description of soot cake regression. Dependence of soot cake porosity, packing density, permeability, and soot density in filter walls on convective-diffusive particle transportation is examined. Sensitivity analysis was conducted on model parameters, relevant to the mode of transition. Soot cake porosity and soot packing density show low degrees of dispersion with respect to the Peclet number and have asymptotes at 0.97 and $70\;kg/m^3$, respectively, at high Peclet number. Soot density in the filter wall, which is inversely proportional to filter wall Peclet number, controls the filtration mode transition but exerts no influence on termination pressure drop. The percolation constant greatly alters the extent of pressure drop, but is insensitive to volumetric flow rate or temperature of exhaust gas at fixed operation mode.

PIV 기법을 이용한 초음속 평판 경계층의 속도 분포 측정 (Velocity profile measurement of supersonic boundary layer over a flat plate using the PIV technique)

  • 이혁;김영주;변영환;박수형
    • 한국항공우주학회지
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    • 제44권6호
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    • pp.477-483
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    • 2016
  • 본 연구는 Particle Image Velocimetry(PIV) 기법을 이용하여 마하수 2.96의 평판에 대해 층류, 천이, 난류 경계층의 속도 분포를 측정하였다. Schlieren 가시화 기법과 PIV 기법을 이용하여 앞전에서 발생한 경사 충격파가 평판 위의 유동장에 영향을 주는지 확인하였다. 층류 경계층의 경우, 실험에서 측정한 속도 분포가 압축성 Blasius 속도 분포를 만족하였다. 천이 경계층의 속도 분포는 벽면 부근부터 이론적인 난류 속도 분포로 변했으며, Re = $1.41{\times}10^6$에서 천이가 시작되었다. 난류 경계층 영역에서는 압축성 효과를 고려한 Van Driest 변환 속도가 비압축성 로그 법칙을 만족하였다. 또한 로그 구간이 끝나는 위치($y/{\delta}{\approx}0.28$)가 비압축성 난류 경계층($y/{\delta}{\approx}0.2$)에 비해 벽면에서 더 멀어진 것을 확인하였다.

Kinetic Properties of Plasmas at Earth's Bow Shock

  • Lee, En-sang;Parks, George;Wilber, Mark;Lin, Naiguo
    • 한국우주과학회:학술대회논문집(한국우주과학회보)
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    • 한국우주과학회 2011년도 한국우주과학회보 제20권1호
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    • pp.29.2-29.2
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    • 2011
  • Earth's bow shock is a transition layer across which properties of plasmas change irreversibly. Although some features of the bow shock are well described by continuities of fluxes of various macroscopic quantities, particle dynamics across the transition layer is very complicated. Observed phase space distributions show multiple ion beams and partially thermalized ions around the transition layer. In some cases, both hot magnetosheath ions and cold solar wind ions simultaneously exist in the magnetosheath. Electrons around the transition layer usually have flat-top distributions with temperature anisotropy. From the observed properties of the phase space distributions we will discuss thermalization processes that occur across the shock transition.

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STOCHASTIC FRAGMENTATION AND SOME SUFFICIENT CONDITIONS FOR SHATTERING TRANSITION

  • Jeon, In-Tae
    • 대한수학회지
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    • 제39권4호
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    • pp.543-558
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    • 2002
  • We investigate the fragmentation process developed by Kolmogorov and Filippov, which has been studied extensively by many physicists (independently for some time). One of the most interesting phenomena is the shattering (or disintegration of mass) transition which is considered a counterpart of the well known gelation phenomenon in the coagulation process. Though no masses are subtracted from the system during the break-up process, the total mass decreases in finite time. The occurrence of shattering transition is explained as due to the decomposition of the mass into an infinite number of particles of zero mass. It is known only that shattering phenomena occur for some special types of break-up rates. In this paper, by considering the n-particle system of stochastic fragmentation processes, we find general conditions of the rates which guarantee the occurrence of the shattering transition.

Oxygen reduction reaction and electrochemical properties of transition metal doped (Pr,Ba)Co2O5+𝛿

  • Kanghee Jo;Heesoo Lee
    • 한국결정성장학회지
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    • 제33권1호
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    • pp.37-44
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    • 2023
  • Transition metal (Me = Cu, Fe, Ni) doped (Pr, Ba)Co2O5+𝛿 (PBCO) material were investigated in terms of electronic structure change and electrochemical properties. It was confirmed that (Pr, Ba)(Co, Cu)O5+𝛿 (PBCCu) and (Pr, Ba)(Co, Fe)O5+𝛿 (PBCFe) showed cubic and orthorhombic structures, respectively, but (Pr, Ba)(Co, Ni)O5+𝛿 (PBCNi) showed secondary phases. PBCCu has an average particle diameter of 1093 nm, and PBCO and PBCFe have an average particle diameter of 495.1 nm and 728 nm, respectively. The average oxidation values of B site ions in PBCMe were calculated to be 3.26 (PBCO), 2.48 (PBCCu), 3.32 (PBCFe), and valence band maximum (VBM) was -0.42 eV (PBCO), -0.58 eV (PBCCu), -0.11 eV (PBCFe). It is expected that PBCCu easily interacts with adsorbed oxygen due to the lowest oxidation value and the highest VBM. The polarization resistance was 0.91 Ω cm2 (PBCO), 0.77 Ω cm2 (PBCCu), 1.06 Ω cm2 (PBCFe) at 600℃, showing the lowest polarization resistance of PBCCu.

Application of the H Infinity Control Principle to the Sodium Ion Selective Gating Channel on Biological Excitable Membranes

  • Hirayama, Hirohumi
    • International Journal of Control, Automation, and Systems
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    • 제2권1호
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    • pp.23-38
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    • 2004
  • We proposed the infinity control principle to evaluate the Biological function. The H infinity control was applied to the Sodium (Na) ion selective gating channel on the excitable cellular membrane of the neural system. The channel opening, closing and inactivation processes were expressed by movements of three gates and one inactivation blocking particle in the channel pore. The rate constants of the channel state transition were set to be voltage dependent. The temporal changes in amounts per unit membrane area of the channel states were expressed by means of eight differential equations. The biochemical mimetic used to complete the Na ion selective channel was regarded as noise. The control inputs for ejecting the blocking particle with plugging in the channel pore were set for the active transition from inactivated states to a closed or open state. By applying the H infinity control, we computed temporal changes in the channel states, observers, control inputs and the worst case noises. The present paper will be available for evaluating the noise filtering function of the biological signal transmission system.