• Title/Summary/Keyword: Particle Transition

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Manufacture of Alkyl Acrylate Multi Core-shell Composite Particle (알킬 아크릴레이트계의 다중 Core-shell 복합입자의 제조)

  • Cho, Dae-Hoon;Choi, Sung-Il;Go, Hyun-Mi;Seul, Soo-Duk
    • Journal of Adhesion and Interface
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    • v.12 no.1
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    • pp.16-25
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    • 2011
  • Multi core-shell composite particles were prepared by the water-born emulsion polymerization of various core monomer such as methyl methacrylate (MMA), n-butyl methacrylate (BMA), and shell monomer such as MMA, BMA, stylene (St), 2-hydroxyl ethyl methacrylate (2-HEMA) and acrylic acid (AA) in the presence of different concentration of sodium dodecyl benzene sulfonate (SDBS). The following conclusions are drawn from the measured conversion, particle size and distribution, average molecular weight, molecular structure, glass transition temperature with DSC, morphology, tensile strength and elongation. In the case of the concentration of 0.02 wt% SDBS, the conversion of MMA core-(BMA/St/AA) shell composite particle was excellent as 98%. In the case of the concentration of 0.03 wt% SDBS, the particle size of BMA core-(MMA/St/AA) shell composite particle was high as $0.47{\mu}m$. We confirmed that 3 points of glass transition temperatures appear for multi core-shell composite particles compared to 2 points of glass transition temperatures appear for general core-shell composite particles. We showed that it is possible to adjust glass transition temperatures according to the kind and composition of the inner shell monomer that it is can be used as a adhesive binder material with improved adhesive power.

Particle Filter Localization Using Noisy Models (잡음 모델을 이용한 파티클 필터 측위)

  • Kim, In-Cheol;Kim, Seung-Yeon;Kim, Hye-Suk
    • The KIPS Transactions:PartB
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    • v.19B no.1
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    • pp.27-30
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    • 2012
  • One of the most fundamental functions required for an intelligent agent is to estimate its current position based upon uncertain sensor data. In this paper, we explain the implementation of a robot localization system using Particle filters, which are the most effective one of the probabilistic localization methods, and then present the result of experiments for evaluating the performance of our system. Through conducting experiments to compare the effect of the noise-free model with that of the noisy state transition model considering inherent errors of robot actions, we show that it can help improve the performance of the Particle filter localization to apply a state transition model closely approximating the uncertainty of real robot actions.

Mechanism of Formation of Three Dimensional Structures of Particles in a Liquid Crystal

  • West, John L.;Zhang, Ke;Liao, Guangxun;Reznikov, Yuri;Andrienko, Denis;Glushchenko, Anatoliy V.
    • Journal of Information Display
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    • v.3 no.3
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    • pp.17-23
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    • 2002
  • In this work we report methods of formation of three-dimensional structures of particles in a liquid crystal host. We found that, under the appropriate conditions, the particles are captured and dragged by the moving isotropic/nematic front during the phase transition process. This movement of the particles can be enhanced significantly or suppressed drastically with the influence of an electric field and/or with changing the conditions of the phase transition, such as the rate of cooling. As a result, a wide variety of particle structures can be obtained ranging from a fine-grained cellular structure to stripes of varying periods to a course-grained "root" structures. Changing the properties of the materials, such as the size and density of the particles and the surface anchoring of the liquid crystal at the particle surface, can also be used to control the morphology of the three-dimensional particle network and adjust the physical properties of the resulting dispersions. These particle structures may be used to affect the performance of LCD's much as polymers have been used in the past.

DETAILED EXAMINATION OF INVERSE-ANALYSIS PARAMETERS FOR PARTICLE TRAPPING IN SINGLE CHANNEL DIESEL PARTICULATE FILTER

  • Jung, S.C.;Park, J.S.;Yoon, W.S.
    • International Journal of Automotive Technology
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    • v.8 no.2
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    • pp.165-177
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    • 2007
  • Predictions of diesel particulate filtration are typically made by modeling of a particle collection, and providing particle trapping levels in terms of a pressure drop. In the present study, a series of single channel diesel particulate filter (DPF) experiments are conducted, the pressure traces are inversely analyzed and essential filtration parameters are deducted for model closure. A DPF filtration model is formulated with a non-linear description of soot cake regression. Dependence of soot cake porosity, packing density, permeability, and soot density in filter walls on convective-diffusive particle transportation is examined. Sensitivity analysis was conducted on model parameters, relevant to the mode of transition. Soot cake porosity and soot packing density show low degrees of dispersion with respect to the Peclet number and have asymptotes at 0.97 and $70\;kg/m^3$, respectively, at high Peclet number. Soot density in the filter wall, which is inversely proportional to filter wall Peclet number, controls the filtration mode transition but exerts no influence on termination pressure drop. The percolation constant greatly alters the extent of pressure drop, but is insensitive to volumetric flow rate or temperature of exhaust gas at fixed operation mode.

Velocity profile measurement of supersonic boundary layer over a flat plate using the PIV technique (PIV 기법을 이용한 초음속 평판 경계층의 속도 분포 측정)

  • Lee, Hyuk;Kim, Young Ju;Byun, Yung Hwan;Park, Soo Hyung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.6
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    • pp.477-483
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    • 2016
  • Velocity profiles of laminar, transition and turbulent boundary layers were investigated by using Particle Image Velocimetry(PIV) measurements on the flat plate at Mach 2.96. The Schlieren visualization and PIV measurements are also used to confirm whether the oblique shock wave generated from the leading edge affects the flow field over the flat plate. The laminar velocity profile measured from the experiment was well matched with the compressible Blasius solution. The velocity profile of the transition boundary layer was well correlated with the theoretical turbulent velocity profile from near the wall and the transition began from Re = $1.41{\times}106$. For the turbulent boundary layer, considering compressibility effects, the Van Driest-transformed velocity satisfies the incompressible log-law. It is found that the log region is extended farther in the wall-normal direction compared to the log region in incompressible boundary layer.

Kinetic Properties of Plasmas at Earth's Bow Shock

  • Lee, En-sang;Parks, George;Wilber, Mark;Lin, Naiguo
    • Bulletin of the Korean Space Science Society
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    • 2011.04a
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    • pp.29.2-29.2
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    • 2011
  • Earth's bow shock is a transition layer across which properties of plasmas change irreversibly. Although some features of the bow shock are well described by continuities of fluxes of various macroscopic quantities, particle dynamics across the transition layer is very complicated. Observed phase space distributions show multiple ion beams and partially thermalized ions around the transition layer. In some cases, both hot magnetosheath ions and cold solar wind ions simultaneously exist in the magnetosheath. Electrons around the transition layer usually have flat-top distributions with temperature anisotropy. From the observed properties of the phase space distributions we will discuss thermalization processes that occur across the shock transition.

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STOCHASTIC FRAGMENTATION AND SOME SUFFICIENT CONDITIONS FOR SHATTERING TRANSITION

  • Jeon, In-Tae
    • Journal of the Korean Mathematical Society
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    • v.39 no.4
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    • pp.543-558
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    • 2002
  • We investigate the fragmentation process developed by Kolmogorov and Filippov, which has been studied extensively by many physicists (independently for some time). One of the most interesting phenomena is the shattering (or disintegration of mass) transition which is considered a counterpart of the well known gelation phenomenon in the coagulation process. Though no masses are subtracted from the system during the break-up process, the total mass decreases in finite time. The occurrence of shattering transition is explained as due to the decomposition of the mass into an infinite number of particles of zero mass. It is known only that shattering phenomena occur for some special types of break-up rates. In this paper, by considering the n-particle system of stochastic fragmentation processes, we find general conditions of the rates which guarantee the occurrence of the shattering transition.

Oxygen reduction reaction and electrochemical properties of transition metal doped (Pr,Ba)Co2O5+𝛿

  • Kanghee Jo;Heesoo Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.1
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    • pp.37-44
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    • 2023
  • Transition metal (Me = Cu, Fe, Ni) doped (Pr, Ba)Co2O5+𝛿 (PBCO) material were investigated in terms of electronic structure change and electrochemical properties. It was confirmed that (Pr, Ba)(Co, Cu)O5+𝛿 (PBCCu) and (Pr, Ba)(Co, Fe)O5+𝛿 (PBCFe) showed cubic and orthorhombic structures, respectively, but (Pr, Ba)(Co, Ni)O5+𝛿 (PBCNi) showed secondary phases. PBCCu has an average particle diameter of 1093 nm, and PBCO and PBCFe have an average particle diameter of 495.1 nm and 728 nm, respectively. The average oxidation values of B site ions in PBCMe were calculated to be 3.26 (PBCO), 2.48 (PBCCu), 3.32 (PBCFe), and valence band maximum (VBM) was -0.42 eV (PBCO), -0.58 eV (PBCCu), -0.11 eV (PBCFe). It is expected that PBCCu easily interacts with adsorbed oxygen due to the lowest oxidation value and the highest VBM. The polarization resistance was 0.91 Ω cm2 (PBCO), 0.77 Ω cm2 (PBCCu), 1.06 Ω cm2 (PBCFe) at 600℃, showing the lowest polarization resistance of PBCCu.

Application of the H Infinity Control Principle to the Sodium Ion Selective Gating Channel on Biological Excitable Membranes

  • Hirayama, Hirohumi
    • International Journal of Control, Automation, and Systems
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    • v.2 no.1
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    • pp.23-38
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    • 2004
  • We proposed the infinity control principle to evaluate the Biological function. The H infinity control was applied to the Sodium (Na) ion selective gating channel on the excitable cellular membrane of the neural system. The channel opening, closing and inactivation processes were expressed by movements of three gates and one inactivation blocking particle in the channel pore. The rate constants of the channel state transition were set to be voltage dependent. The temporal changes in amounts per unit membrane area of the channel states were expressed by means of eight differential equations. The biochemical mimetic used to complete the Na ion selective channel was regarded as noise. The control inputs for ejecting the blocking particle with plugging in the channel pore were set for the active transition from inactivated states to a closed or open state. By applying the H infinity control, we computed temporal changes in the channel states, observers, control inputs and the worst case noises. The present paper will be available for evaluating the noise filtering function of the biological signal transmission system.