• Title/Summary/Keyword: Ozone Process

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Decolorization System of Effluent of Activated Sludge Process Using Ozone (오존에 의한 활성오니처리 방류수의 탈색처리 연구)

  • 최희철;곽정훈;최동윤;권두중;김형호;이덕수;강희설;최영수;천상석
    • Journal of Animal Environmental Science
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    • v.8 no.3
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    • pp.153-158
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    • 2002
  • Decolorization system using ozone was developed to reduce the pollutants and dark brown color remained in effluent of activated sludge process for pig wastewater. The results are as follows. 1. Wastewater temperature was increased during the ozone treatment from 31$^{\circ}C$ to 41.9$^{\circ}C$. 2. Oxidation reduction potential(ORP) at the beginning time was 148㎷, but it was increased to 330㎷ according to the ozone treatment. 3. 11mg/l of BO $D_{5}$ in effluent of activated sludge process was decreased to 1mg/l by ozone treatment, CO $D_{MN}$ also decreased from 83mg/l to 1.0mg/l. 4. 442 unit(dark brown color) of color in effluent of activated sludge process was changed to 6 units(colorless), and color removal efficiency was 98.6%.

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Study on the Removal of Fluorescent Whitening Agent for Paper-mill Wastewater Reuse using the Submerged Membrane Bioreactor(SMBR) with Ozone Oxidation Process (제지폐수 재이용을 위한 침지형 생물막 여과와 오존산화공정(SMBR-Ozone Oxidation Process)에 의한 형광증백제 제거에 관한 연구)

  • Choi, Jang-Seung;Shin, Dong-Hun;Ryu, Seung-Han;Lee, Jae-Hun;Ryu, Jae-Young;Shin, Won-Sik;Lee, Seul-Ki;Park, Min-Soo;Lee, Sang Oh
    • Textile Coloration and Finishing
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    • v.30 no.1
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    • pp.51-61
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    • 2018
  • In this study, effluent water was produced through Submerged Membrane Bio-Reactor(SMBR) process, which is a simple system and decomposes organic matter contained in wastewater with biological treatment process and performs solid-liquid separation, Especially, ozone oxidation treatment process is applied to effluent water containing fluorescent whitening agent, which is a trace pollutant which is not removed by biological treatment, and influences the quality of reused water. The concentration of $COD_{Cr}$ in the SMBR was $449.3mg/{\ell}-COD_{Cr}$, and the concentration of permeate water was $100.3mg/{\ell}-COD_{Cr}$. The removal efficiency was about 70.1%. The amount of ozone required for the removal of the fluorescent whitening agent in the permeated water in SMBR was $6.67g-O_3/min$, and the amount of ozone required to remove $COD_{Mn}$ relative to the permeate water was calculated to remove $0.997mg-COD_{Mn}$ for 1mg of $O_3$.

Treatment Study of Textile Wastewater by Fenton's Oxidation (펜톤 산화반응에 의한 염색폐수처리 연구)

  • 박영규
    • Journal of environmental and Sanitary engineering
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    • v.15 no.4
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    • pp.20-25
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    • 2000
  • The wastewater treatment for the purpose of water-recycling was performed using Fenton's & ozone's methods. These methods were used to increase the treatment efficiency of textile wastewater and to search for the optimal operating conditions. The optimal conditions by Fenton process were determined so that input amounts of $FeSO_4{\cdot}7H_2O$ and $H_2O_2$ were $7.2mM/{\;}{\ell}$ and $49.0m/{\;}{\ell}$ respectively, treatment by ozone process had 92% removal efficiency at ozone concentration of 9.73g/min and $130mM/{\;}{\ell}$ of $H_2O_2$.

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A Study on Removal of Phenol and Its By-Product by Ozone, Ozone/Hydrogen Peroxide and Ozone/Granular Activated Carbon (오존, 오존/과산화수소와 오존/활성탄 처리에 의한 페놀 및 그 부산물의 제거에 관한 연구)

  • 배현주;김영규;정문호
    • Journal of Environmental Health Sciences
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    • v.23 no.3
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    • pp.121-129
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    • 1997
  • This study was performed to delineate the removal phenol in solutions using of ozone, ozone/$H_2O_2$ and ozone/GAC. The disinfection by-product of phenol by ozonation, hydroquinone, was analyzed and it's control process was investigated. The followings are the conclusions that were derived from this study. 1. The removal efficiency of phenol by ozonation was 58.37%, 48.34%, 42.15%, and 35.41% which the initial concentration of phenol was 5 mg/l, 10 mg/l, 15 mg/l, and 20 mg/l, respectively. 2. The removal efficiency of phenol by ozonation was 42.95% at pH 4.0 and 69.39% at pH 10, respectively. The removal efficiencies were gradually increased, as pH values were increased. 3. With the ozone/$H_2O_2$ combined system, the removal efficiency of phenol was 72.87%. It showed a more complete degradation of phenol with ozone/$H_2O_2$ compared with ozone alone. 4. When ozonation was followed by filtration on GAC, phenol was completely removed. 5. Oxidation, if carried to completion, truly destroys the organic compounds, converting them to carbon dioxide. Unless reaction completely processed, disinfection by-products would be produced. To remove them, ozone/GAC treatment was used. The results showed that disinfection by-product of phenol by ozonation, hydroquinone, was completely removed. These results suggested that ozone/GAC should also be an appropriate way to remove phenol and its by-product.

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Post Sliced Cleaning of Silicon Wafers using Ozone and Ultrasound (오존과 초음파를 이용한 실리콘 웨이퍼의 Post Sliced Cleaning)

  • Choi, Eun-Suck;Bae, So-Ik
    • Korean Journal of Materials Research
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    • v.16 no.2
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    • pp.75-79
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    • 2006
  • The effect of ozone and/or ultrasound treatments on the efficiency of slurry removal in post sliced cleaning (PSC) of silicon ingot was studied. Efficiency of slurry removal was evaluated as functions of time, temperature and surfactant with DOE (Design of Experiment) method. Residual slurries were observed on the wafer surface in case of cleaning by ozone or ultrasound separately. However, a clean wafer surface was appeared when cleaned with ozone and ultrasound simultaneously. It has found that cleaning time was the main effect among temperature, time and surfactant. Elevated temperature, addition of surfactant and high ozone concentration helped to accelerate efficient removal of slurry. The improvement of removal efficiency seems to be related to the formation of more active OH radicals. The highly cleaned surface was achieved at 10 wt% ozone, 1 min and 10 vol% surfactant with ultrasound. Application of ozone and ultrasound might be a useful method for PSC process in wafer cleaning.

A Study on the Effect of Cumulus Parameterization and Microphysics on Ozone Simulations during Long-range Transport Process over Northeast Asia (동북아 장거리 수송 과정에서 적운 모수화 및 미세물리과정이 오존 모사농도에 미치는 영향 연구)

  • Kang, Jeong-Eon;Kim, Cheol-Hee
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.2
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    • pp.135-151
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    • 2013
  • This study has been carried out to analyze the sensitivity of ozone concentrations by employing different options of cumulus parameterization schemes (CPSs) and microphysics schemes in MM5 models. These sensitivity tests were applied to long-range transport case of higher ozone over Northeast Asia. Employed CPS schemes are Betts-Miller (BM), Grell (GR), Kain-Fritsch2 (KF2), Anthes-Kuo (AK), None scheme (grid scale physics only), and four microphysics used here are Simple ice, Reisner1, Reisner2, Schultz scheme in MM5. We chose two cases of high ozone long range transport case by employing both concentrations ozone level and backward trajectory model. The results showed that modeled ozone concentrations indicated about 10% differences among CPSs. Of the all options, GR and KF2 (for CPS), and Rersiner-1 and Resiner-2 (for microphysics) showed relatively good and stable variations against ensemble mean values. For both CPS and microphysics schemes, the difference of precipitation arising from different parameterization schemes was significant by itself, but the resultant ozone variations showed only marginal. But the cloud fraction differences arising from different parameterization schemes showed better correlation with ozone variations than precipitation differences, indicating that the photochemical ozone generation variations is more dominant by cloud fraction than wet removal process for high and long-ranged transported ozone cases over Northeast Asia.

Evaluation Method for Graphene Grain Boundary by UV/ozone-oxidation Chemical-etching Process (UV/ozone 산화처리 및 화학적 식각공정을 적용한 그래핀 Grain Boundary 평가 방법)

  • Kang, Jaewoon;Park, Hongsik
    • Journal of Sensor Science and Technology
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    • v.25 no.4
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    • pp.275-279
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    • 2016
  • Chemical vapor deposited (CVD) polycrystalline graphene is widely used for various sensor application because of its extremely large surface-to-volume ratio. The electrical properties of CVD-graphene is significantly affected by the grain size and boundaries (GGBs), but evaluation of GGB of continuous monolayer graphene is difficult. Although several evaluation methods such as tunneling electron microscopy, confocal Raman, UV/ozone-oxidation are typically used, they still have issues in evaluation efficiency and accuracy. In this paper, we suggest an improved evaluation method for precise and simple GGB evaluation which is based on UV/ozone-oxidation and chemical etching process. Using this method, we could observe clear GGBs of CVD-graphene layers grown by different process conditions and statistically evaluate average grain sizes varying from $1.69{\sim}4.43{\mu}m$. This evaluation method can be used for analyzing the correlation between the electrical properties and grain size of CVD-graphene, which is essential for the development of graphene-based sensor devices.

A Study on the Optimal Use of Silent Discharge Type Ozonizer in Purification Plant (정수장의 무성방전형 오존발생기 최적활용방안에 관한 연구)

  • Shin, Hong-Sub;Park, Hyun-Mi;Kwon, Young-Hak;Song, Hyun-Gig;Park, Won-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.3
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    • pp.54-60
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    • 2015
  • There are 5 purification plants with the adopted advanced water purification treatment process in Korea. Annual operating costs were 8,990 million won including purchase cost of oxygen and power usage charges. We need research to optimize, in the future, when considering the direction of domestic water treatment continues to adopt advanced water treatment process. In this paper, calculate the optimal operating costs by injected the oxygen gas, used power cost. approximately 25% of the operating costs can be reduced when injected the ozone gas is 1.0ppm than 2.0ppm, the necessary amount of oxygen is increased then power is lower. so operating costs are decided according to oxygen costs. On the other hand, high ozone concentration 2.0ppm, the necessary power is increased then amount of oxygen is lower. Therefore, in the case of G purification plant, the controlling factor of the input ozone concentration 2ppm, PID control operation by setting the concentration of over 10Wt% is efficient. The installed capacity is the more little the more better when considering on Ozone injection rate in the process of water treatment.

Development of the Dielectric Barrier Discharge Plasma Generator for the Eco-friendly Cleaning Process of the Electronic Components (전자부품의 친환경 세정공정 적용을 위한 유전체장벽 방전 플라즈마 생성 장치 개발)

  • Son, Young-Su;Ham, Sang-Yong;Kim, Byung-In
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.10
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    • pp.1217-1223
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    • 2011
  • In this paper, the dielectric barrier discharge plasma generator has been studied for producing of the high concentration ozone gas. Proposed plasma generator has the structure of extremely narrow discharge air gap(0.15mm) in order to realize the high electric field discharge. We investigate the performance of the dielectric barrier discharge plasma generator experimentally and the results show that the generator has very high ozone concentration characteristics of 13.7[wt%/$O_2$] at the oxygen flow rate of 1[${\ell}$/min] of each discharge cell. So, we confirmed that the proposed plasma generator is suitable for the high concentration ozone production facility of the eco-friendly ozone functional water cleaning system in the electronic components cleaning process.

An Ozone-based Advanced Oxidation Process for an Integrated Air Pollution Control System (복합대기오염 저감 시스템을 위한 오존 고속산화 기반 고도산화공정)

  • Uhm, Sunghyun;Hong, Gi Hoon;Hwang, Sangyeon
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.237-242
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    • 2021
  • Simultaneous removal technologies of multi-pollutants such as particulate matters (PMs), NOx, SOx, VOCs and ammonia have received consistent attention due to the enhancement of pollutant abatement efficiency in addition to the stringent environmental regulation and emission standard. Pretreatment of insoluble NO by an ozone oxidation can be considered to be more effective route for saving space occupation as well as operation cost in comparison with that of traditional selective catalytic reduction (SCR) process. Moreover the primary advantage of ozone oxidation process is that the simultaneous removal with acidic gas including SOx is also available. Herein, we highlight recent studies of multi-pollutant abatement via ozone oxidation process and the promising research topics for better application in industrial sectors.