• Title/Summary/Keyword: Oxidation Resistance

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Antioxidant Effect of Vitamin-C/alginate Gel-entrapped Liposome for Resistance of DHA Autoxidation (DHA의 산화방지를 위한 Vitamin C/alginate Gel-entrapped Liposome의 항산화 효과)

  • 한성철;허은정;김연주;이기영;김진철
    • KSBB Journal
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    • v.18 no.3
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    • pp.229-233
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    • 2003
  • Antioxidant effect of reconstituted liposome was studied for application to food and cosmetic industry. Vitamin-C/alginate alginate gel-entrapped DHA-PC liposome (AVDL) was prepared and studied with respect to morphology (TEM), loading efficiency (TLC) and antioxidant effect (TBARS assay). AVDL has spherical structure and 80 ∼ 250 ㎚ size. As DHA content increased, DHA and PC loading efficiency and antioxidant effect was increased. At addition of 0.2 % vitamin C in AVDL, DHA auto-oxidation was minimized and sustained about 3 days.

The Optical Properties of Si3N4/SnZnO/AZO/Ag/Ti/ITO Multi-layer Thin Films with Laminating Times (Si3N4/SnZnO/AZO/Ag/Ti/ITO 다층 박막의 적층 횟수에 따른 광학적 특성)

  • Lee, Sang-Yun;Jang, Gun-Eik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.1
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    • pp.7-11
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    • 2015
  • In this study, $Si_3N_4$/SnZnO/AZO/Ag/Ti/ITO multi-layer film were prepared on glass substrate by DC/RF magnetron sputtering method. To prevent interfacial reaction between Ag and ITO layer, Ti buffer layer was inserted. Optical properties and sheet resistance were studied depending on laminating times of each multi-layered film especially in visible ray. The simulation program, EMP (essential macleod program), was adopted and compared with experimental data to expect the experimental result. It was found out that the transmittance of the first stacked $Si_3N_4$/SnZnO/AZO/Ag/Ti/ITO multi-layer film was more than 90%. However, with increasing stacking times, the optical properties of $Si_3N_4$/SnZnO/AZO/Ag/Ti/ITO multi-layer film get worse. Consequently, Ti layer is good for oxidation barrier, but too many uses of this layer may have an adverse effect to optical properties of TCO film.

Operating Characteristics of Direct Methanol Fuel Cell Based on Pt-Ru/C Anode Catalyst (Pt-Ru/C 촉매를 이용한 직접메탄을 연료전지 운전 특성)

  • Jung, D.H.;Lee, C.H.;Kim, C.S.;Chun, Y.G.;Shin, D.R.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1252-1254
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    • 1997
  • Direct methanol fuel cell based on a proton-exchange membrane electrolyte was investigated. 60% Pt-Ru/C and 60%Pt/C catalysts were employed for methanol oxidation and oxygen reduction, respectively. Morphologies of the catalysts were investigated by x-ray power diffraction, energy dispersive x-ray spectroscopy, and transmission microscopy. Electrochemical characteristics of the catalysts were tested by using cyclic voltametry technique. I-V characteristics of the fuel cell were tested by changing methanol concentration, temperature, and Nafion type as a proton-exchange membrane electrolyte. AC impedance technique was used to investigate the electrochemical performance of the fuel cell. The performance of single cell was enhance with increasing cell temperature. High operation temperature attributed to the combined effects of the reduction of ohmic resistance and polarization. High cell voltage was obtained from the concentration of 205M methanol. With Nafion 112, a current density of $230mA/cm^2$ at 0.55V was obtained from the concentration of 2.5M methanol.

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Biofouling and Microbial Induced Corrosion -A Case Study

  • Mohammed, R.A.;Helal, A.M.;Sabah, N.
    • Corrosion Science and Technology
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    • v.7 no.1
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    • pp.27-34
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    • 2008
  • In industrial and fluid handling systems, frequently the protective film forming materials suffer from severe corrosion due to microbial effects. As an example, various micro-organisms, including bacteria, exist in seawater normally fed to power and desalination plants. Unless seawater intakes are properly disinfected to control these microbial organisms, biological fouling and microbial induced corrosion (MIC) will be developed. This problem could destroy metallic alloys used for plant construction. Seawater intakes of cogeneration plants are usually disinfected by chlorine gas or sodium hypochlorite solution. The dose of disinfectant is designed according to the level of contamination of the open seawater in the vicinity of the plant intake. Higher temperature levels, lower pH, reduced flow velocity and oxidation potential play an important role in the enhancement of microbial induced corrosion and bio-fouling. This paper describes, in brief, the different types of bacteria, mechanisms of microbiological induced corrosion, susceptibility of different metal alloys to MIC and possible solutions for mitigating this problem in industry. A case study is presented for the power plant steam condenser at Al-Taweelah B-station in Abu Dhabi. The study demonstrates resistance of Titanium tubes to MIC.

A Study on the Metallization Properties of Cu-Sn Alloy Layers Deposited by the Electroplating Method (전해도금법으로 증착한 Cu-Sn 합금막의 배선특성에 관한 연구)

  • Kim, Ju-Yeon;Bae, Gyu-Sik
    • Korean Journal of Materials Research
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    • v.12 no.3
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    • pp.225-230
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    • 2002
  • Sn was selected as an alloying element of Cu. The Cu-Sn thin layers were deposited on the Si substrates by the electroplating method and their properties were studied. By rapidly thermal annealing(RTA) up to 40$0^{\circ}C$ after electroplating, sheet resistance decreased and adhesion strength increased, but that trend was reversed at the 50$0^{\circ}C$ RTA. Cu-Sn particles grew dense and the surface was uniform up to 40$0^{\circ}C$, but at 50$0^{\circ}C$, empty area was introduced and the surface became rough owing to oxidation and particle coarsening and agglomeration. Deposited layer contained significant amount of Si, while pure Cu-Sn layer with the composition ratio of 90:10 was present only on the top surface. However, no significant change in the Cu composition within alloy layers occured by the RTA regardless of its temperature. This indicates that the Cu diffusion into the Si was suppressed by the presence of Sn.

Corrosion Behavior of Ni 200 and Ni-base Alloys in Hot Lithium Molten salt (고온 리튬용융염에서 Ni 200 및 Ni-base 합금의 부식거동)

  • Cho Soo-Hang;Lim Jong-Ho;Yun Ki-Seok;Park Seung-Won
    • Korean Journal of Materials Research
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    • v.14 no.4
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    • pp.251-259
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    • 2004
  • In the development of the advanced spent fuel management process based on the molten salt technology, it is essential to choose the optimum material for the process equipment handling molten salt. Corrosion behavior of Ni 200 and Ni-base alloys in molten salt of LiCl-$Li_2$O under oxidation atmosphere was investigated in the temperature range of $650~800^{\circ}C$ for 24~312 hrs. The order of corrosion rate was Ni 200 > Inconel 690 > Inconel 601 > Inconel 600. Inconel 600 alloy showed the highest corrosion resistance among the examined alloys, but Ni 200 exhibited the highest corrosion rate. Corrosion products of Inconel 600 and Inconel 601 were $Cr_2$$O_3$ and $NiFe_2$$O_4$. In case of Inconel 690, a single layer of $CrO_2$$O_3$ was formed in the early stage of corrosion and an outer layer of $NiFe_2$O$_4$ and inner layer of $Cr_2$$O_3$ were formed with increase of corrosion time. Inconel 600 showed local corrosion behavior and Inconel 601, 690 showed uniform corrosion behavior.

Low Temperature Processed Transparent Conductive Thin Films Based on Sol-Gel ZnO / Ag Nanowire (저온 형성 가능한 "졸겔 ZnO / 은 나노선" 복합 투명전도막)

  • Shin, Won-Jung;Kim, Bo Seok;Moon, Chan-Su;Cho, Won-Ki;Baik, Seung Jae
    • Current Photovoltaic Research
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    • v.2 no.3
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    • pp.110-114
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    • 2014
  • We propose a low temperature sol-gel ZnO/Ag nanowire composite thin film to fulfill low temperature and low cost requirements, which are essential criteria in future flexible electronic devices. In this proposed thin film, Ag nanowire plays the role of electrical conduction, and sol-gel ZnO provides a structural medium with a high visible transmittance. Low temperature restriction in the sol-gel fabrication process prevents sufficient oxidation of Zn acetate precursors, which were solved by a post-coating treatment with ultraviolet light irradiation. Composite thin film formation was performed by spin coating methods with a mixed precursor solution or in a sequential manner. We obtained an average visible transmittance larger than 85% and a sheet resistance smaller than $50{\Omega}/sq$. After optimization in a fabricated composite transparent conductive thin film with the thickness around 100 nm. Similar experimental demonstration in a flexible substrate (polyethyleneterephthalate) was successful, which implies a promising application opportunity of this technology.

Study of Hydrogen Evolution Reaction by Molybdenum Oxide Doped TiO2 Nanotubes (몰리브덴 산화물이 도핑된 티타늄 나노튜브전극의 수소 발생 반응 연구)

  • Oh, Kiseok;Yoo, Hyeonseok;Lee, Gibaek;Choi, Jinsub
    • Journal of the Korean institute of surface engineering
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    • v.49 no.6
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    • pp.521-529
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    • 2016
  • In this study, titanium nanotubes, prepared by anodization method, showing high surface and strong chemical stability in acidic and basic media, have been employed for the application to the electrodes for water splitting in KOH solution. Due to its high polarization resistance of $TiO_2$ itself, proper catalysts are essentially required to reduce overpotentials for water oxidation and reduction. Most of academic literature showed noble metal catalysts for foreign dopants in $TiO_2$ electrodes. From commercialization point of view, screening of low-cost catalyst is important. Herein, we propose molybdenum oxide as low-cost catalysts among various catalysts tested in the experiments, which exhibits the highest performance for hydrogen evolution reaction in highly alkaline solution. We showed that molybdenum oxide doped electrode can be operated in extreme acidic and basic conditions as well.

Effect of Room Temperature Prestrain on Creep Life of Austenitic 25Cr-20Ni Stainless Steels (오스테나이트계 25Cr-20Ni 스테인리스강의 실온예변형이 크리프 수명에 미치는 영향)

  • Park, In-Duck;Ahn, Seok-Hwan;Nam, Ki-Woo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.4
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    • pp.453-459
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    • 2004
  • 25Cr-20Ni series strainless steels have an excellent high temperature strength high oxidation and high corrosion resistance. However, further improvement can be expected of creep strength by work hardening prior creep. In the present study, the effect of prestraining at room temperature on the creep behavior of a Class M(STS310S) and a Class A(STS310J1TB) alloy containing precipitates have been examined. Prestaining was carried out at room temperature and range of prestrain was 0.5-2.5 % at STS310J1TB and 2.0-7.0% at STS310S. Creep behavior and creep rate of pre-strained specimens were compared with that of virgin specimens. Room temperature prestraining produced the creep life that is longer than that of a virgin specimen both for STS310J1TB and STS310S when creep test was carried out at the temperature lower than recrystallization temperature. The reason for this improvement of creep life was ascribable to the interaction between dislocations and precipitates in addition to the dislocation-dislocation interaction in STS310J1TB and the dislocation-dislocation interaction in STS310S. The beneficial effect of prestraining in STS310J1TB was larger than that of STS310S.

Self-Aligned $n^+$ -pPolysilicon-Silicon Junction Structure Using the Recess Oxidation (Recess 산화를 이용한 자기정렬 $n^+$ -p 폴리실리콘-실리콘 접합구조)

  • 이종호;박영준;이종덕;허창수
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.6
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    • pp.38-48
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    • 1993
  • A recessed n-p Juction diode with the self-aligned sturcture is proposed and fabricated by using the polysilicon as an n$^{+}$ diffusion source. The diode structure can be applicable to the emitter-base formation of high performance bipolar divice and the n$^{+}$ polysilicone mitter has an important effect on the device characteristics. The considered parameters for the polysilicon formation are the deposition condition. As$^{+}$ dose for the doping of the polysilicon and the annealing condition using RTP system. The vertical depth profiles of the fabricated diode are obtained by SIMS and the electrical characteristics are analyzed in terms of the ideality factor of diode (n), contact resistance and reverse leakage current. In addition, n$^{+}$-p junction diodes are formed by using the amorphous silicon (of combination of amorphous and polysiliocn) instead of polysilicon and their characteristics are compared with those of the standard sample. The As$^{+}$ dose for the formation of good junction is about 1~2${\times}10^{16}cm^{2}$ at given RTA conditions (1100.deg. C, 10sec).

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