• Title/Summary/Keyword: Metal oxide addition

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Effects of Doping Concentration of Polycrystalline Silicon Gate Layer on Reliability Characteristics in MOSFET's (MOSFET에서 다결정 실리콘 게이트 막의 도핑 농도가 신뢰성에 미치는 영향)

  • Park, Keun-Hyung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.2
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    • pp.74-79
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    • 2018
  • In this report, the results of a systematic study on the effects of polycrystalline silicon gate depletion on the reliability characteristics of metal-oxide semiconductor field-effect transistor (MOSFET) devices were discussed. The devices were fabricated using standard complimentary metal-oxide semiconductor (CMOS) processes, wherein phosphorus ion implantation with implant doses varying from $10^{13}$ to $5{\times}10^{15}cm^{-2}$ was performed to dope the polycrystalline silicon gate layer. For implant doses of $10^{14}/cm^2$ or less, the threshold voltage was increased with the formation of a depletion layer in the polycrystalline silicon gate layer. The gate-depletion effect was more pronounced for shorter channel lengths, like the narrow-width effect, which indicated that the gate-depletion effect could be used to solve the short-channel effect. In addition, the hot-carrier effects were significantly reduced for implant doses of $10^{14}/cm^2$ or less, which was attributed to the decreased gate current under the gate-depletion effects.

Photocatalytic and Adsorption Properties of WO3 Nanorods Prepared by Hydrothermal Synthesis (수열합성법으로 제조된 나노막대 구조 WO3의 광촉매 효과 및 염료 흡착 반응)

  • Yu, Su-Yeol;Nam, Chunghee
    • Journal of Powder Materials
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    • v.24 no.6
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    • pp.483-488
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    • 2017
  • Transition-metal oxide semiconductors have various band gaps. Therefore, many studies have been conducted in various application fields. Among these, methods for the adsorption of organic dyes and utilization of photocatalytic properties have been developed using various metal oxides. In this study, the adsorption and photocatalytic effects of $WO_3$ nanomaterials prepared by hydrothermal synthesis are investigated, with citric acid added in the hydrothermal process as a structure-directing agent. The nanostructures of $WO_3$ are studied using transmission electron microscopy and scanning electron microscopy images. The crystal structure is investigated using X-ray diffraction patterns, and the changes in the dye concentrations adsorbed on $WO_3$ nanorods are measured with a UV-visible absorption spectrophotometer based on Beer-Lambert's law. The methylene blue (MB) dye solution is subjected to acid or base conditions to monitor the change in the maximum adsorption amount in relation to the pH. The maximum adsorption capacity is observed at pH 3. In addition to the dye adsorption, UV irradiation is carried out to investigate the decomposition of the MB dye as a result of photocatalytic effects. Significant photocatalytic properties are observed and compared with the adsorption effects for dye removal.

A Study on the Design of Voltage Mode PWM DC/DC Power Converter (전압모드 PWM DC/DC 전력 컨버터 설계연구)

  • Lho, Young-Hwan
    • Journal of the Korean Society for Railway
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    • v.14 no.5
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    • pp.411-415
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    • 2011
  • DC/DC switching power converters are commonly used to generate a regulated DC output voltages with high efficiencies from different DC input sources. The voltage mode DC/DC converter utilizes MOSFET (metal-oxide semiconductor field effect transistor), inductor, and a PWM (pulse-width modulation) controller with oscillator, amplifier, and comparator, etc. to efficiently transfer energy from the input to the output at periodic intervals. The fundamental boost converter and a buck converter containing a switched-mode power supply are studied. In this paper, the electrical characteristics of DC/DC power converters are simulated by program of SPICE, and the PWM controller is implemented to check the operation. In addition, power efficiency is analyzed based on the specification of each component.

Synthesis and application of Pt and hybrid Pt-$SiO_2$ nanoparticles and control of particles layer thickness (Pt 나노입자와 Hybrid Pt-$SiO_2$ 나노입자의 합성과 활용 및 입자박막 제어)

  • Choi, Byung-Sang
    • The Journal of the Korea institute of electronic communication sciences
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    • v.4 no.4
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    • pp.301-305
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    • 2009
  • Pt nanoparticles with a narrow size distribution (dia. ~4 nm) were synthesized via an alcohol reduction method and used for the fabrication of hybrid Pt-$SiO_2$ nanoparticles. Also, the self-assembled monolayer of Pt nanoparticles (NPs) was studied as a charge trapping layer for non-volatile memory (NVM) applications. A metal-oxide-semiconductor (MOS) type memory device with Pt NPs exhibits a relatively large memory window. These results indicate that the self-assembled Pt NPs can be utilized for NVM devices. In addition, it was tried to show the control of thin-film thickness of hybrid Pt-$SiO_2$ nanoparticles indicating the possibility of much applications for the MOS type memory devices.

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Chemiresistive Gas Sensors for Detection of Chemical Warfare Agent Simulants

  • Lee, Jun Ho;Lee, Hyun-Sook;Kim, Wonkyung;Lee, Wooyoung
    • Journal of Sensor Science and Technology
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    • v.28 no.3
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    • pp.139-145
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    • 2019
  • Precautionary detection of chemical warfare agents (CWAs) has been an important global issue mainly owing to their toxicity. To achieve proper detection, many studies have been conducted to develop sensitive gas sensors for CWAs. In particular, metal-oxide semi-conductors (MOS) have been investigated as promising sensing materials owing to their abundance in nature and excellent sensitivity. In this review, we mainly focus on various MOS-based gas sensors that have been fabricated for the detection of two specific CWA simulants, 2-chloroethyl ethyl sulfide (2-CEES) and dimethyl methyl phosphonate (DMMP), which are simulants of sulfur mustard and sarin, respectively. In the case of 2-CEES, we mainly discuss $CdSnO_3-$ and ZnO-based sensors and their reaction mechanisms. In addition, a method to improve the selectivity of ZnO-based sensors is mentioned. Various sensors and their sensing mechanisms have been introduced for the detection of DMMP. As the reaction with DMMP may directly affect the sensing properties of MOS, this paper includes previous studies on its poisoning effect. Finally, promising sensing materials for both gases are proposed.

Synthesis of CoO/Co(OH)2 Nanosheets Depending on Reaction Temperatures (반응 온도에 따른 CoO/Co(OH)2 나노시트의 합성)

  • Minjeong Lee;Gayoung Yoon;Gyeong Hee Ryu
    • Korean Journal of Materials Research
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    • v.33 no.5
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    • pp.222-228
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    • 2023
  • Transition metal oxides formed by a single or heterogeneous combination of transition metal ions and oxygen ions have various types of crystal structures, which can be classified as layered structures and non-layered structures. With non-layered structures, it is difficult to realize a two-dimensional structure using conventional synthesis methods. In this study, we report the synthesis of cobalt oxide into wafer-scale nanosheets using a surfactant-assisted method. A monolayer of ionized surfactant at the water-air interface acts as a flexible template for direct cobalt oxide crystallization below. The nanosheets synthesized on the water surface can be easily transferred to an arbitrary substrate. In addition, the synthesizing morphological and crystal structures of the nanosheets were analyzed according to the reaction temperatures. The electrochemical properties of the synthesized nanosheets were also measured at each temperature. The nanosheets synthesized at 70 ℃ exhibited higher catalytic properties for the oxygen evolution reaction than those synthesized at other temperatures. This work suggests the possibility of changing material performance by adjusting synthesis temperature when synthesizing 2D nanomaterials using a wide range of functional oxides, resulting in improved physical properties.

Effect of Water Addition on Activity of Gold Catalysts Supported on Metal Oxide at Low Temperature CO Oxidation (일산화탄소 저온 산화에서 금속산화물에 담지된 금촉매의 활성에 미치는 수분첨가의 영향)

  • Ahn, Ho-Geun;Kim, Ki-Joong;Chung, Min-Chul
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.720-725
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    • 2011
  • Gold catalysts supported on metal-oxides were prepared by co-precipitation using the various metal nitrates and chloroauric acid as precursors, and effect of water addition on the catalytic activity in CO oxidation was investigated. Among the various supported gold catalysts, Au/$Co_{3}O_{4}$ and Au/ZnO catalysts showed the excellent activity for CO oxidation. Water in the reactant gas had a negative effect on the oxidation activity over Au/$Co_{3}O_{4}$ catalysts and a positive effect on that over Au/ZnO, which means the activity depends strongly on the nature of support. It was also confirmed that no significant change in the particle size of gold was observed after reaction both in dry and wet conditions. This fact suggested that the deactivated catalyst due to a carbonate species could be regenerated by water addition in the reactant gas.

Printing of Polymer Dielectric via Optimal Blade Coating for Large-scale Low-Leakage Capacitors (대면적 저누설 커패시터를 위한 최적화 블레이드 코팅 기반 고분자 유전체 프린팅)

  • Seo, Kyeong-Ho;Bae, Jin-Hyuk
    • Journal of Sensor Science and Technology
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    • v.30 no.1
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    • pp.51-55
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    • 2021
  • We demonstrated a polymer dielectric with low leakage characteristics through an optimal blade coating method for low-cost and large-scale fabrication of metal-insulator-metal (MIM) capacitors. Cross-linked poly(4-vinylphenol) (C-PVP), which is a typically used polymer dielectric, was coated on a 10 × 10 cm indium-tin-oxide (ITO) deposited glass substrate by changing the deposition temperature (TD) and coating velocity (VC) in the blade coating. During the blade coating, the thickness of the thin c-PVP varied depending on TD and VC owing to the 'Landau-Levich (LL) regime'. The c-PVP-dielectric-based MIM capacitor fabricated in this study showed the lowest leakage current characteristics (10-6 A/㎠ at 1.2 MV/㎠, annealing at 200 ℃) and uniform electrical characteristics when TD was 30 ℃ and VC was 5 mm/s. In addition, at TD = 30 ℃, stable leakage characteristics were confirmed when a different electric field was applied. These results are expected to positively contribute to applications with next-generation electronic devices.

EAF Dust Treatment at Miike Smelting CO., LTD.

  • Noda, Shinji;Tatehana, Yoshikazu
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.375-380
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    • 2001
  • MF is a half shaft blast furnace which has been developed at Mitsui Miike Smelter in the 1960’s to treat vertical retort residue. The MF has also been tested for treatment of various recycling materials and wastes. Now various secondaries and wastes (EAF dust, zinc leaching residue, Cu sludge, etc ) are mainly treated. Powder materials are briquetted with reductant before being fed to the furnace. Products are crude zinc oxide, matte, non-hazardous slag and steam. Zinc and lead are recovered in oxide dust, and copper and silver are recovered in matte. The MF can be widely applied to many kinds of materials which contain such non-ferrous metal-valuables. In addition, the improvement in operation and technology has effectively made the unit capacity much larger. The MF now has many advantages for these treatment processes.

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Characterization of Low Temperature Selective Catalytic Reduction over Ti Added Mn-Cu Metal Oxides (Ti가 첨가된 Mn-Cu 혼합산화물을 이용한 저온 SCR 반응 특성)

  • Lee, Hyun Hee;Park, Kwang Hee;Cha, Wang Seog
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.599-604
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    • 2013
  • In this study, Ti added Mn-Cu mixed oxide catalysts were prepared by a co-precipitation method and used for the low temperature (< $200^{\circ}C$) selective catalytic reduction (SCR) of NOx with $NH_3$. Physicochemical properties of these catalysts were characterized by BET, XRD, XPS, and TPD. Mn-Cu mixed oxide catalysts were found to be amorphous with a large surface and they showed high SCR activity. Experimental results showed that the addition of $TiO_2$ to Mn-Cu oxide enhanced the SCR activity and $N_2$ selectivity. Ti addition led to the chemically adsorbed oxygen species that promoted the oxidation of NO to $NO_2$ and increased the number of $NH_3$ adsorbed-sites such as $Mn^{3+}$.