Browse > Article
http://dx.doi.org/10.46670/JSST.2021.30.1.51

Printing of Polymer Dielectric via Optimal Blade Coating for Large-scale Low-Leakage Capacitors  

Seo, Kyeong-Ho (School of Electronic and Electrical Engineering, Kyungpook National University)
Bae, Jin-Hyuk (School of Electronic and Electrical Engineering, Kyungpook National University)
Publication Information
Abstract
We demonstrated a polymer dielectric with low leakage characteristics through an optimal blade coating method for low-cost and large-scale fabrication of metal-insulator-metal (MIM) capacitors. Cross-linked poly(4-vinylphenol) (C-PVP), which is a typically used polymer dielectric, was coated on a 10 × 10 cm indium-tin-oxide (ITO) deposited glass substrate by changing the deposition temperature (TD) and coating velocity (VC) in the blade coating. During the blade coating, the thickness of the thin c-PVP varied depending on TD and VC owing to the 'Landau-Levich (LL) regime'. The c-PVP-dielectric-based MIM capacitor fabricated in this study showed the lowest leakage current characteristics (10-6 A/㎠ at 1.2 MV/㎠, annealing at 200 ℃) and uniform electrical characteristics when TD was 30 ℃ and VC was 5 mm/s. In addition, at TD = 30 ℃, stable leakage characteristics were confirmed when a different electric field was applied. These results are expected to positively contribute to applications with next-generation electronic devices.
Keywords
Large-scale; Polymer dielectric; Metal-insulator-metal capacitors; Low leakage characteristics; Blade coating; Cross-linked poly(4-vinylphenol);
Citations & Related Records
연도 인용수 순위
  • Reference
1 C. Sekine, Y. Tsubata, T. Yamada, M. Kitano and S. Doi, "Recent Process of high performance polymer OLED and OPV materials for organic printed electronics", Sci. Technol. Adv. Mater., Vol. 15, No. 3, pp. 034203(1)-034203(15), 2014.   DOI
2 Y. Khan, A. Thielens, S. Muin, J. Ting, C. Baumbauer and A. C. Arias, "A New Frontier of Printed Electronics: Flexible Hybrid Electronics", Adv. Mater., Vol. 32, No. 15 pp. 1905279(1)-1905279(29), 2020.   DOI
3 W. Wu, "Inorganic nanomaterials for printed electronics: a review", Nanoscale, Vol. 9, No.22, pp. 7342-7372, 2017.   DOI
4 M. Richard, A. Al-Ajaji, S. Ren, A. Foti, J. Tran, M. Frigoli, B. Gusarov, Y. Bonnassieux, E. G. Caurel, P, Bulkin, R. Ossikovski, A. Yassar, "Large-scale patterning of π-conjugated materials by meniscus guided coating methods", Adv. Colloid Interface Sci., Vol. 275, pp. 102080(1)-102080(25), 2020.
5 R. Janneck, D. Karaginnis, P. Heremans, J. Genoe and C. Rolin, "Influence of Solute Concentration on Meniscus-Guided Coating of Highly Crystalline Organic Thin Films", Adv. Mater. Interfaces, Vol. 6, No. 19, pp. 1900614(1)-190614(11), 2019.
6 Y. Lu, R. Ganguli, C. A. Drewien, M. T. Anderson, C. J. Brinker, W. Gong, Y. Guo, H. Soyez, B. Dunn, M. H. Huang and J. I. Zink "Continuous formation of supported cubic and hexagonal mesoporous films by sol-gel dip coating", Nature, Vol. 389, No. 6649, pp. 364-386, 1997.   DOI
7 X. Gu, L. Shaw, K. Gu, M. F. Toney and Z. Bao, "The meniscus-guided deposition of semiconducting polymers", Nat. Commun., Vol. 9, No. 1, pp. 534(1)-534(16), 2018.   DOI
8 D. Khim, H. Han, K.-J. Baeg, J. Kim, S.-W. Kwak, D.-Y. Kim, Y.-Y. Noh, "Simple Bar-Coating Process for Large Area, High Performance Organic Field-Effect Transistors and Ambipolar Complementary Integrated Circuits", Adv. Mater., Vol. 25, No. 31, pp. 4302-4308, 2013.   DOI
9 Y.-H. Chang, S.-R. Tseng, C.-Y. Chen, H.-F. Meng, E. -C. Chen, S.-F. Horng, and C.-S. Hsu, "Polymer solar cell by blade coating", Org. Electron., Vol. 10, No. 5, pp. 741-746, 2009.   DOI
10 S.-R. Tseng, H.-F. Meng, K.-C. Lee and S.-F. Horng, "Multilayer polymer light-emitting diodes by blade coating method", Appl. Phys. Lett., Vol. 93, No. 15, pp. 153308(1)-153308(3), 2008.   DOI
11 A. Pierre, M. Sadeghi, M. M. Payne, A. Facchetti, J. E. Anthony and A. C. Arias, "All-Printed Flexible Organic Transistors Enabled by Surface Tension-Guided Blade Coating", Adv. Mater., Vol. 26, No. 32, pp. 5722-5727, 2014.   DOI
12 S. Chu, W. Chen, Z. Fang, X. Xiao, Y. Liu, J. Chen, J.g Huang and Z. Xiao, "Large-area and efficient perovskite light-emitting diodes via low temperature blade coating", Nat. Commun., Vol. 12, No. 1, pp. 147(1)-147(9), 2021.
13 A. Liu, H. Zhu, H. Sun, Y. Xu and Y.-Y. Noh, "Solution Processed Metal Oxide High-k Dielectrics for Emerging Transistors and Circuits", Adv. Mater., Vol. 30, No. 33, pp. 1706364(1)-1706364(39), 2018.   DOI
14 M. Hollerer, D. Luftner, P. Hurdax, T. Ules, S. Soubatch, F. S. Tautz, G. Koller, P. Puschnig, M. Sterrer and M. G. Ramsey, "Charge Transfer and Orbital Level Alignment at Inorganic/Organic Interfaces: The Role of Dielectric Interlayers", ACS Nano, Vol. 11, No. 6, pp. 6252-6260, 2017.   DOI
15 A. Liu, G. Liu, H. Zhu, B. Shin, E. Fortunato, R. Martins and F. Shan, "Eco-Friendly water induced-aluminum oxide dielectrics and their application in a hybrid metal oxide/polymer TFT", RSC Advances, Vol. 5, No. 105, pp. 86606-86613, 2015.   DOI
16 K. K. Banger, Y. Yamashita, K. Mori, R. L. Peterson, T. Leedham, J. Rickard and H. Sirringhaus, "Low-temperature, high performance solution-processed metal oxide thin-film transistors formed by a 'sol-gel on chip' process", Nature Mater., Vol. 10, No. 1, pp. 45-50, 2011.   DOI
17 B. Nketia.-Yawson, Y.-Y. Noh, "Recent Progress on High-Capacitance Polymer Gate Dielectrics for Flexible Low-Voltage Transistors, Adv. Mater., Vol. 28, No. 42, pp. 1802201(1)-1802201(27), 2018.
18 A. Azizi, M. R. Gadinski, Q. Li, M. A. AlSaud, J. Wang, Y. Wang, B. Wang, F. Liu, L. Q. Chen, N. Alem and Q. Wang, "High-Performance Polymers Sandwiched with Chemical Vapor Deposited Hexagonal Boron Nitrides as Scalable High-Temperature Dielectric Materials", Adv. Mater., Vol. 29, No. 35, pp. 1701864(1)-1701864(7), 2017.   DOI
19 Y. Zhou and Q. Wang, "Advanced polymer dielectrics for high temperature capacitive energy storage", J. Appl. Phys., Vol. 127, No. 24, pp. 240902(1)-240902(18), 2020.   DOI
20 M.-H. Lim, W.-S. Jung, J.-H. Park, "Curing temperature-and concentration-dependent dielectric properties of cross-linked poly-4-vinylphenol (PVP), Curr. Appl. Phys., Vol. 13, No. 8, pp. 1554-1557, 2013.   DOI
21 W. Xia, G. Xia, G. Tu, X. Dong, S. Wang and R. Liu, "Sol-gel processed high-k aluminum oxide dielectric films for fully solution-processed low voltage thin-film transistor", Ceram. Int., Vol. 44, No. 8, pp. 9125-9131, 2018.   DOI
22 J.-H. Kwon, J.-H. Choi, H. Lee, J.-H. Bae and J. Park, "Structural modification of poly(4-vinylphenol) insulators in pentacene transistors by using dimethyl ketone", Mol. Cryst. Liq. Cryst , Vol. 704, No. 1, pp. 145-152, 2020.   DOI
23 D.-K. Kim, P. Vincent, J. Jang, I. M. Kang, H. Kim, P. Lang, M. Choi and J.-H. Bae, "Contact line curvature-induced molecular misorientation of a surface energy patterned organic semiconductor in meniscus-guided coating", Appl. Surf. Sci., Vol. 504, pp. 144362(1)-144362(6), 2020.   DOI
24 J. Chang, C. Chi, J. Zhang and J. Wu, "Controlled Growth of Large-Area High-Performance Small-Molecule Organic Single-Crystalline Transistors by Slot-Die Coating Using A Mixed Solvent System", Adv. Mater., Vol. 25, No. 44, pp. 6442-6447, 2013.   DOI
25 F. Doumenc and B. Guerrier, "Drying of a Solution in a Meniscus: A Model Coupling the Liquid and the Gas Phase", Langmuir, Vol. 26, No. 17, pp. 13959-13967, 2010.   DOI
26 M. L. Berre, Y. Chen and D. Baigl, "From Convective Assembly to Landau-Levich Deposition of Multilayered Phospholipid Films of Controlled Thickness", Langmuir, Vol. 25, No. 5, pp. 2554-2557, 2009.   DOI