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Reaction Properties of Dinuclear Metallocenes

  • Noh Seok-Kyun;Jeong Eung-Yeong;Qei Duang Huang Dan;Lyoo Won-Seok
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.224-225
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    • 2006
  • The Ethylene polymerization behavior of a series of polymethylene bridged dinuclear CGC $[Zr({\eta}^{5}:{\eta}^{1}-C_{9}H_{5}SiMe_{2}NCMe_{3})Me_{2}]_{2}[(CH_{2})_{n}]\;[_{n}=6(1),\;9(2),\;12(3)]$ in the cocatalytic activation with $Ph_{3}C^{+}B^{-}(C_{6}F_{5})_{4}\;(B_{1})\;or\;Ph_{3}C^{+}(C_{6}F_{5})_{3}B^{-}C_{6}F_{4}B^{-}(C_{6}F_{5})_{3}Ph_{3}C^{+}\;(B_{2})\;or\;B(C_{6}F_{5})_{3}\;(B_{3})$ were investigated to study the nuclearity effects as well as the counteranion effects. The ethylene polymerization and ethylene/1-hexene copolymerization were conducted at $30^{\circ}C$ It was found that both in ethylene polymerization and ethylene/1-hexene copolymerization, activities increased in the order of 1 < 2 < 3, which indicates the presence of longer bridge between two active sites contributes more efficiently to facilitate the polymerization activity.

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ON A CLASS OF UNIVALENT FUNCTIONS

  • NOOR, KHALIDA INAYAT;RAMADAN, FATMA H.
    • Honam Mathematical Journal
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    • v.15 no.1
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    • pp.75-85
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    • 1993
  • For A and B, $-1{\leq}B<A{\leq}1$, let P[A, B] be the class of functions p analytic in the unit disk E with P(0) = 1 and subordinate to $\frac{1+Az}{1+Bz}$. We introduce the class $T_{\alpha}[A,B]$ of functions $f:f(z)=z+\sum\limits_{n=2}^{{\infty}}a_nz^n$ which are analytic in E and for $z{\in}E$, ${\alpha}{\geq}0$, $[(1-{\alpha}){\frac{f(z)}{z}}+{\alpha}f^{\prime}(z)]{\in}P[A,B]$. It is shown that, for ${\alpha}{\geq}1$, $T_{\alpha}[A,B]$ consists entirely of univalent functions and the radius of univalence for $f{\in}T_{\alpha}[A,B]$, $0<{\alpha}<1$ is obtained. Coefficient bounds and some other properties of this class are studied. Some radii problems are also solved.

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A Generalization of Formal Local Cohomology Modules

  • Rezaei, Shahram
    • Kyungpook Mathematical Journal
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    • v.56 no.3
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    • pp.737-743
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    • 2016
  • Let a and b be two ideals of a commutative Noetherian ring R, M a finitely generated R-module and i an integer. In this paper we study formal local cohomology modules with respect to a pair of ideals. We denote the i-th a-formal local cohomology module M with respect to b by ${\mathfrak{F}}^i_{a,b}(M)$. We show that if ${\mathfrak{F}}^i_{a,b}(M)$ is artinian, then $a{\subseteq}{\sqrt{(0:{\mathfrak{F}}^i_{a,b}(M))$. Also, we show that ${\mathfrak{F}}^{\text{dim }M}_{a,b}(M)$ is artinian and we determine the set $Att_R\;{\mathfrak{F}}^{\text{dim }M}_{a,b}(M)$.

Functional Analysis of the marB gene of Escherichia coli K-12

  • Lee, Chang-Mi;Park, Byung-Tae
    • Biomedical Science Letters
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    • v.10 no.2
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    • pp.153-161
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    • 2004
  • Antibiotic resistance is often associated with the production of inner membrane proteins (for example, AcrAB/TolC efflux pump) that are capable to extrude antibiotics, detergents, dyes and organic solvents. In order to evaluate the unknown MarB function of Escherichia coli, especially focused on the function of OmpF porin, several mutants were construted by T4GT7 transduction. MarA plays a major roles in mar (multiple antibiotic resistance) phenotype with AcrAB/TolC efflux pump in E. coli K-12. Futhermore, MarA decreases OmpF porin expression via micF antisense RNA. Expression of acrAB is increased in strains containing mutation in marR, and in those carrying multicopy plasmid expressing marA. MarB protein of E. coli K-12 showed its activity at OmpF porin & TolC protein as target molecule. Some paper reported MarB positively regulates OmpF function. MarA shows mar phenotype, and MarB along with MarA show decreased MIC through OmpF function. By this experiment, MarB could decrease MIC through the OmpF porin & TolC protein as target.

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A NOTE ON CONTINUED FRACTIONS WITH SEQUENCES OF PARTIAL QUOTIENTS OVER THE FIELD OF FORMAL POWER SERIES

  • Hu, Xuehai;Shen, Luming
    • Bulletin of the Korean Mathematical Society
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    • v.49 no.4
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    • pp.875-883
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    • 2012
  • Let $\mathbb{F}_q$ be a finite field with q elements and $\mathbb{F}_q((X^{-1}))$ be the field of all formal Laurent series with coefficients lying in $\mathbb{F}_q$. This paper concerns with the size of the set of points $x{\in}\mathbb{F}_q((X^{-1}))$ with their partial quotients $A_n(x)$ both lying in a given subset $\mathbb{B}$ of polynomials in $\mathbb{F}_q[X]$ ($\mathbb{F}_q[X]$ denotes the ring of polynomials with coefficients in $\mathbb{F}_q$) and deg $A_n(x)$ tends to infinity at least with some given speed. Write $E_{\mathbb{B}}=\{x:A_n(x){\in}\mathbb{B},\;deg\;A_n(x){\rightarrow}{\infty}\;as\;n{\rightarrow}{\infty}\}$. It was shown in [8] that the Hausdorff dimension of $E_{\mathbb{B}}$ is inf{$s:{\sum}_{b{\in}\mathbb{B}}(q^{-2\;deg\;b})^s$ < ${\infty}$}. In this note, we will show that the above result is sharp. Moreover, we also attempt to give conditions under which the above dimensional formula still valid if we require the given speed of deg $A_n(x)$ tends to infinity.

The Effects of Diallyl Disulfide on Antimetastatic Potential of B16-F10 Murine Melanoma Cells (B16-F10 Murine Melanoma 세포의 암전이 억제에 미치는 Diallyl Disulfide의 효과)

  • Kang, Mi-Kyung;Jun, Hye-Seung;Yum, Yung-Na;Hwang, Myung-Sil;Park, Mi-Sun;Kim, Ok-Hee
    • Toxicological Research
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    • v.22 no.4
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    • pp.349-356
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    • 2006
  • Diallyl disulfide (DADS), an oil-soluble organosulfur compound in garlic has been reported to suppress tumor growth and to induce apoptosis in cancer. In the present study, we investigated the effects of DADS on pulmonary metastasis of B16-F10 murine melanoma cells. DADS (i.p. 40 mg/kg) significantly (p<0.05) reduced the number of pulmonary metastatic nodules (48%) in experimental pulmonary metastasis assay. We also found that DADS inhibited adhesion, invasion and migration of B16-F10 melanoma cells in a dose-dependent manner. To study the antimetastatic potential of DADS, we performed the effects of DADS on matrix metalloproteinase activity. DADS significantly inhibited the expression of matrix metalloproteinase-2 activity in B16-F10 cells by gelatin zymography. These results suggest that DADS prevent metastasis in part through suppression of migration of B16-F10 melanoma cells by Inhibiting matrix metalloproteirase-2 responsible for degradation of extracellar matrix.

Whitening Effects of Anthricin on B16F10 Cells (B16F10 세포에서 Anthricin의 미백 효능)

  • Shim, Joong Hyun
    • Korean Journal of Pharmacognosy
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    • v.52 no.1
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    • pp.13-18
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    • 2021
  • This study was performed to clarify the whitening effects of anthricin on the B16F10 cell line. In order to elucidate the whitening effects of anthricin on the B16F10 cell line, cell viability, messenger ribonucleic acid (mRNA) expressions, tyrosinase activity assay, and melanin production assay were measured. The effects of anthricin on tyrosinase-related protein 1(TYRP1)/TYRP2/tyrosinase (TYR)/microphthalmia-associated transcription factor (MITF) mRNA expressions and melanin content were determined. Quantitative real-time RT-PCR showed that anthricin decreased the mRNA expression level of TYRP1/TYRP2/TYR/MITF genes and melanin production contents than α-MSH-treated B16F10 cells. The tyrosinase activity assay revealed that anthricin decreased the melanin production on the B16F10 cells. These data show that anthricin increases the whitening effects on the B16F10 cells; thus, anthricin is a potent ingredient for skin whitening. Thus, further research on the mechanism of action of anthricin for the development of not only cosmetics, but also healthy food and medicine should be investigated.

Stability of a Generalized Quadratic Type Functional Equation (일반화된 2차형 범함수 방정식의 안정성)

  • Kim, Mi-Hye;Hwang, In-Sung
    • The Journal of the Korea Contents Association
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    • v.2 no.4
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    • pp.93-98
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    • 2002
  • Functional equations are useful in the experimental science because they play very important role for researchers to formulate mathematical models in general terms, through some not very restrictive equations that only stipulate basic properties of functions showing in these equations, without postulating the exact forms of such functions. Of lots of such functional equations, in this paper we adopt and solve some generalized quadratic functional equation a$^2$f((x+y/a))+b$^2$f((x-y/b)) = 2f(x)+2f(y)

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Copolymerization of Ethylene and 1-Hexene via Polymethylene Bridged Cationic Dinuclear Constrained Geometry Catalysts (폴리메틸렌 다리로 연결된 양이온 이핵 CGC를 이용한 에틸렌과 1-헥센의 공중합)

  • Bian, Feng Ling;Que, Dang Hoang Dan;Lyoo, Won-Seok;Lee, Dong-Ho;Noh, Seok-Kyun;Kim, Yong-Man
    • Polymer(Korea)
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    • v.31 no.6
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    • pp.497-504
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    • 2007
  • We have prepared the dinuclear half-sandwich CGC(constrained geometry catalyst) with polymethylene bridge $[Zr(({\eta}^5\;:\;{\eta}^1-C_9H_5SiMe_2NCMe_3)Me_2)_2\;[(CH_2)_n]$ [n=6(4), 9(5), 12(6)] by treating 2 equivalents of MeLi with the corresponding dichlorides compounds. To study the catalytic behavior of the dinuclear catalysts we conducted copolymerization of ethylene and 1-hexene in the presence of three kinds of boron cocatalysts, $Ph_3C^+[B(C_6F_5)_4]^-\;(B_1),\;B(C_6F_5)_3\;(B_3)$, and $Ph_3C^+[(C_6F_5)_3B-C_6F_4-B(C_6F_5)_3]^{2-}\;(B_2)$. It turned out that all active species formed by the combination of three dinuclear CGCs with three cocatalyst were very efficient catalysts for the polymerization of olefins. The activities increase as the bridge length of the dinuclear CGCs increases. At the same time the dinuclear cocatalyst exhibited the lowest activity among three cocatalysts. The prime observation is that the dinuclear cocatalyst gave rise to the formation of the copolymers with the least branches on the polyethylene backbone.

Physicochemical Properties of Indoor Particulate Matter Collected on Subway Platforms in Japan

  • Ma, Chang-Jin;Matuyama, Sigeo;Sera, Koichiro;Kim, Shin-Do
    • Asian Journal of Atmospheric Environment
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    • v.6 no.2
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    • pp.73-82
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    • 2012
  • This study was aimed to thoroughly estimate the characteristics of indoor particulate matter (PM) collected on subway platforms by the cooperative approach of semi-bulk and single particle analyses. The size-resolved PM and its number concentration were measured on the platform in a heavily traveled subway station in Fukuoka, Japan. Particle Induced X-ray Emission (PIXE) and micro-PIXE techniques were applied to the chemical analyses of semi-bulk and single particle, respectively. There was the close resemblance of timely fluctuation between PM number concentration and train service on the third basement floor (B3F) platform compared to the second basement floor (B2F) and its maximum level was marked in rush hour. Higher number counts in large particles ($>1{\mu}m$) and lower number counts in fine particles ($<1{\mu}m$) were shown on the platform compared to an above ground. PM2.5 accounted for 58.2% and 38.2 % of TSP on B3F and on B2F, respectively. The elements that were ranked at high concentration in size-resolved semi-bulk PM were Fe, Si, Ca, S, and Na. The major elements tending to have more elevated levels on B3F than B2F were Fe (4.4 times), Ca (17.3 times), and Si (46.4 times). Although concentrations were very low, Cr ($11.9ng\;m^{-3}$ on B3F, $2.4ng\;m^{-3}$ on B2F), Mn ($3.4ng\;m^{-3}$ on B3F, $0.9ng\;m^{-3}$ on B2F), and Pb ($0.6ng\;m^{-3}$ on B3F, $1.6ng\;m^{-3}$ on B2F) were detected from PM2.5. Individual PM was nearly all enriched in Fe with Si and Ca. Classifying and source profiling of the individual particles by elemental maps and particle morphology were tried and particles were presumably divided into four groups (i.e., train/rail friction, train-rail sparking, ballast/abrasive, and cement).