• Polymer(Korea)
• /
• v.33 no.6
• /
• pp.525-529
• /
• 2009

In order to manufacture 2-layer flexible copper clad laminate (FCCL) s having the excellent performance high adhesion properties between copper foil and polyimide film are required. Silane coupling agents with specific functional groups as an adhesion promoter are generally used to enhance the adhesion. In our study, we synthesized a novel silane coupling agent for increasing the adhesive property between copper layer and polyimide layer. The surface morphology of rolled copper foil, as a function of the concentrations of the coated silane coupling agent, was fully characterized. As fabricated 2-layer FCCL, we observed that adhesive properties were changed by the surface morphology and we confirmed that the novel silane coupling agent affects adhesive properties in FCCL with two types of poly (amic acid)s.

• Journal of Adhesion and Interface
• /
• v.3 no.4
• /
• pp.10-18
• /
• 2002

Modern plastics are of great importance in many practical applications and their performance can be enhanced by surface modification to improve their hardness, wear and chemical resistance. The object of this study is invention of functional hardening coating materials which are applied to plastic, such as polycarbonate, polymethylmethacylate and acrylonitrilebutadienestyrene. In order to invention of hardening coating materials, we synthesized new silicone acrylate oligomer and prepared coating films containing silicone acrylate oligomer (SAOE) on PC substrate. The curing of coatings is performed by UV-radiation. As results of experiments, The properties of coating films which are contained SAOE is greatly improved in comparison with coating films non-contained SAOE. Especially, when 1 wt% SAOE was introduced into the coating formulation, the UV hardening coatings obtained showed the best surface hardness and gloss.

• Journal of the Korean Vacuum Society
• /
• v.19 no.2
• /
• pp.148-154
• /
• 2010

We have fabricated $SiO_2$ oxidation thin films by TCP-CVD (transformer coupled plasma chemical vapor deposition) method for passivation layer of OLED (organic light emitting diode). The purpose of this paper is to control and estimate the deposition rate and refracive index characteristics with process parameters. They are power, gas condition, distance of source and substrate and process temperature. The results show that transmittance of thin films is over 90%, rapid deposition rate and stable reflective index from 1.4 to 1.5 at controled process conditions. They are $SiH_4$ : $O_2$ = 30 : 60 [sccm] gas condition, 70 [mm] distance of source and substrate, no-biased substrate and under 80 [$^{\circ}C$] process temperature.

• Journal of the Korean institute of surface engineering
• /
• v.42 no.4
• /
• pp.179-185
• /
• 2009

Diamond-like carbon(DLC) films were deposited by linear ion source(LIS)-physical vapor deposition method changing the anode voltages from 800 V to 1800 V, and characteristics of the films were investigated using residual stress tester, nano-indentation, micro raman spectroscopy, scratch tester and Field Emission Scanning Electron Microscope(FE-SEM). The results showed that the residual stress and hardness increased with increasing the ion energy up to anode voltage of 1400 V. It was also found that the content of $SP^3$ carbon increased with increasing the anode voltage $SP^3/SP^2$ ratio through investigation of $SP^3/SP^2$ ratio by the micro-raman analysis. From these results, it can be concluded that the physical properties of DLC films such as residual stress and hardness are increased with increasing the anode voltage. These results can be explained that 3-dimensional cross-links between carbon atoms and Dangling bond are enhanced and the internal compressive stress also increased with increasing the anode voltage. The optimal anode voltage is considered to be around 1400 V in these experimental conditions.

• Journal of Sensor Science and Technology
• /
• v.29 no.6
• /
• pp.388-393
• /
• 2020

In this study, a PbS quantum dots (QDs)-based H₂ gas sensor with a Pd electrode was proposed. QDs have a size of several nanometers, and they can exhibit a high surface area when forming a thin film. In particular, the NH₂ present in the ligand of PbS QDs and H₂ gas are combined to form NH₃⁺, subsequently the electrical characteristics of the QDs change. In addition to the resistance change owing to the reaction between Pd and H₂ gas, the resistance change owing to the reaction between the NH₂ of PbS QDs and H₂ gas increases the current signal at the sensor output, which can produce a high output signal for the same concentration of H₂ gas. Using the XRD and absorbance properties, the synthesis and particle size of the synthesized PbS QDs were analyzed. Using PbS QDs, the sensitivity was significantly improved by 44%. In addition, the proposed H₂ gas sensor has high selectivity because it has low reactivity with heterogeneous gases such as C₂H₂, CO₂, and CH₄.

• Textile Coloration and Finishing
• /
• v.29 no.2
• /
• pp.86-96
• /
• 2017

To make uniform pressure distributed over the contact surface was necessary to cold pad batch dyeing machine. In this study, to confirm characteristic of flexibility and the contact pressure distribution through experimental analysis of padder roll were controlled by hydraulic cell. When there were no load pressure only inner pressure, the value of displacement in the center of padder were greater than the end of the padder. The results of this study showed that the padder had the optimum value of inner pressure for uniform contact pressure distribution. Measuring the contact pressure in a padder system were driven by using a pre-scale film. Uniform contact pressure distribution of cell padder were a linearly with load pressure and inner pressure. When the load pressure was less than 8 tons, the inner pressure for the uniform contact pressure was 1~4 bar. The padder roll performance curves proposed in this study were available for practical production environments and various roll designs.

• Journal of Korea Foundry Society
• /
• v.34 no.5
• /
• pp.170-178
• /
• 2014

Using the Gleeble test, the effects of [Mn/S] ratios and the presence of sulfides on the high-temperature fracture morphology of heavy-section steel castings were analysed via the observations of the microstructures. The specimens for which the [Mn/S] ratio was in the range of 60~80 showed a ductile fracture morphology with an area reduction of more than 60%, while some specimens with similar [Mn/S] ratios showed a brittle fracture morphology with an area reduction of 0.0% due to the liquidation of sulfides at the grain boundary. The fracture morphology was classified into three types in the Gleeble high-temperature tensile test specimens. The first type showed dimple formation at the grain boundary, the formation of globular MnS sulfides, and plastic deformation of sulfides at an elevated temperature, indicating a needle-point type of ductile fracture with area reductions of 96.0~97.8%. The second type was a knife-edge type brittle fracture with an area reduction of 0.0% due to the film-type liquidation of sulfides at the grain boundary, band-type liquidation, and the liquidation of a terraced nipple pattern. The third type was the typical ductile fracture with an area reduction of 31.3~81.0%, in accordance with the mixture of dimples with in the grains and terraced nipple pattern at the grain boundary.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2007.11a
• /
• pp.281-281
• /
• 2007

Low Temperature Co-fired Ceramic (LTCC) technology has been used in electronic device for various functions. LTCC technology is to fire dielectric ceramic and a conductive electrode such as Ag or Cu thick film below the temperature of $900^{\circ}C$ simultaneously. The glass-ceramic has been widely used for LTCC materials due to its low sintering temperature, high mechanical properties and low dielectric constants. To obtain the high strength, addition of filler, the microstructure should have various crystals and low pores in a composite. In this study, two glass frits were mixed with different alumina size(0.5, 2, 3.7um) and sintered at the range of $850{\sim}950^{\circ}C$. The microstructure, crystal phases, thermal and mechanical properties of the composites were investigated using FE-SEM, XRD, TG-DTA, Dilatomer. When the particle size of $Al_2O_3$ filler increased, the starting temperatures for the densification of the sintered bodies, onset point of crystallization, peak crystallization temperature in the glass-ceramic composites decreased gradually. After sintered at $900^{\circ}C$, the glass frits were crystallized as $CaAl_2Si_2O_8\;and\;CaMgSi_2O_6$. The purpose of our study is to understand the relationship between the $Al_2O_3$ particle size and thermal properties in composites.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.26 no.7
• /
• pp.503-509
• /
• 2013

In this study, $Cu(In_{1-x},Ga_x)Se_2$ (CIGS) thin films were prepared on the Mo coated soda-lime glass by the DC magnetron sputtering and a subsequent selenization process. For the selenization process, selenization rapid thermal process(RTP) with cracker cell, which was helpful to smaller an atomic of Se, was adopted. To make CIGS layer, they were then annealed with the cracked Se. Based on this selenization method, we made several CIGS thin film and investigated the effects of In deposition time, and selenization time. Through x-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and atomic force microscopy (AFM), it is found that the Mo/In/CuGa structure and the high sputtering power shows the dominant chalcopyrite structure and have a uniform distribution of the grain size. The CIGS films with the In deposition time of 5 min has the best structure due to the smooth surface. And CIGS films with the selenization time of 50 min show good crystalline growth without any voids.

• Korean Journal of Applied Biomechanics
• /
• v.26 no.4
• /
• pp.333-341
• /
• 2016

Objective: The purpose of this study was to assess the consistency of the gliding and push-off motion for single leg skating from the first to fourteenth steps. We hypothesized that: 1) there would be no difference in stroke trajectory, step rate, and cycle rate between the left and right steps of gliding; and 2) there would be a difference in the resultant velocity of toe push-off and the horizontal velocity of the center of mass after six step push-offs. Method: The study included five male 500-m speed skaters (mean height, $1.80{\pm}0.02m$; mean weight, $76.8{\pm}3.96kg$; record, $35.83{\pm}0.30sec$; 100-m record, <9.97 sec). Data were collected from the first to fourteenth steps (40 m) and recorded using five digital JVC GR-HD1KR video cameras (Victor Co., Japan) operating at a sampling frequency of 60 fields/sec and shutter speed of 1/500 sec. For each film frame, the joint positions were digitized using the KWON3D motion analyzer. Position data were filtered with low-pass Butterworth $4^{th}$ order at the cut-off frequency of 7.4 Hz. Results: The right toe of the skating trajectories at $2^{nd}$, $5^{th}$, and $7^{th}$ strokes differed from those of the left toe. The angles of the right and left knee demonstrated unbalanced patterns from the flexion and extension legs. The step and cycle rates of the right and left leg differed from the start until 20 m. The resultant velocities of the toe at the push-off phase and of the body mass center diverged before the six push-offs. Conclusion: This study's findings indicate that the toe of skating trajectory on left and right sliding after push-off should maintain a symmetrical trajectory. The resultant velocity of toe push-off and horizontal velocity from the center of body need to be separated after about six step push-offs.