• Journal of the Korean Chemical Society
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• v.22 no.2
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• pp.67-77
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• 1978

MO's of a complex are expanded in terms of the set of Shull-Lowdin functions based on a single point, the nucleus of central metal ion, and the result was interpreted from the viewpoint of perturbation theory. We find that even in the case of $[NiF_6]^{4-}$, which has relatively small covalency, excited configurations with high orbital angular momentum are considerably mixed into $e_g$ and $t_{2g}$, orbitals of central metal ion, and that the distortions in these orbitals differ from each other. Therefore it is concluded that the energy difference between $e^*_g$ and $t^*_{2g}$, orbitals evaluated in the MO scheme has little meaning of the unique parameter 10Dq in the crystal field theory, and that such a unique parameter cannot be defined in a rigorous sense in the MO scheme.

• Journal of the Korean Chemical Society
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• v.21 no.1
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• pp.23-31
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• 1977

For the metal complex of $d^1$ configuration with the octahedrally coordinated ligands, the crystal field parameter, 10Dq, is calculated from first principles within the framework of the crystal field theory. With the point charge model, the configuration interaction is introduced by use of the Shull-L$\"{o}$wdin functions. Through the Integral Hellmann-Feynman Theorem, the higher order effect is visualized. It is found that the higher order effect on 10Dq is about $50{\%}$ of the first order effect. Since 3d function is angularly undistorted and radially equally distorted in $E_g\;and\;T_{2g}$ states, due to the octahedral potential, the calculated 10Dq is still the unique parameter for the splitting.

• The Journal of the Korea institute of electronic communication sciences
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• v.1 no.1
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• pp.49-55
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• 2006

Applied by periodic Stimulating Currents in Bonhoeffer -Van der Pol(BVP) model, chaotic and periodic phenomena occured at specific conditions. The conditions of the chaotic motion in BVP comprised 0.7182< $A_1$ <0.792 and 1.09< $A_1$ <1.302 proved by the analysis of phase plane, bifurcation diagram, and lyapunov exponent. To control the chaotic motion, two methods were suggested by the first used the amplitude parameter A1, $A1={\varepsilon}((x-x_s)-(y-y_s))$ and the second used the temperature parameterc, $c=c(1+{\eta}cos{\Omega}t)$ which the values of ${\eta},{\Omega}$ varied respectlvly, and $x_s$, $y_s$ are the periodic signal. As a result of simulating these methods, the chaotic phenomena was controlled with the periodic motion of periodisity. The feasibilities of the chaotic and the periodic phenomena were analysed by phase plane Poincare map and lyapunov exponent.

• Proceedings of the KIEE Conference
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• 1995.11a
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• pp.154-156
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• 1995

The effect of a periodic and a chaotic' behaviour in the Bonhoeffer-Van der Pol(BVP) oscillation of the nerve membrane driven by a periodic stimulating current $A_1=cos\;{\omega}\;t$ are investigated by numeric analysis and hardware Implementation. To control the chaotic motion, we are suggested by temperature parameter c, $c=c(1+\eta\;cos\;{\Omega}\;t)$ which the values of $\eta,\;Omega$ varied respectively. The feasibilities of chaotic and periodic phenomena were analysed by phase plane and time series.

• The Transactions of the Korean Institute of Electrical Engineers
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• v.32 no.2
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• pp.43-49
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• 1983

In this study, model simplification problem using singular perturbation technique is considered. The correctness and errors of simplified model which is obtained by the use of this technique, depends upon the order and the time scaling factor of the simplified model But, unfortunately, there is no explicit criteria for selections of these parameters. In this paper, error equations are derived and expanded by using the useful properties of $L_2$-norm. Then, new criteria for selecting the order of the simplified model and time scaling factor with respect to error bound are suggested. Since these criteria, newly proposed in this study, have strong concern about error bound, it can be used to choose the minimum order of the simplified model and time scaling factor with respect to given error bound. Conversely, if the order of the simplified model and time scaling factor are given, the error induced by the simplification can also be computed easily.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.1
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• pp.92-101
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• 2010

Recently, the magnetic bearings which have many advantages such as no noise, less mechanical friction are widely applied to the suspension of rotors on the rotary machineries. However, the magnetic bearing system is inherently unstable, nonlinear and MIMO(multi-input-multi-output) system as well. In this paper, we design a state feedback controller using linear matrix inequality(LMI) to the multi-objective synthesis, for the magnetic bearing system with integral type servo system. The design objectives include $H_{\infty}$ performance, asymptotic disturbance rejection, and time-domain constraints on the closed-loop pole location. The results of computer simulation show the validity of the designed controller.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.47 no.6
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• pp.64-72
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• 2010

In general, due to the interactions among subsystems, it is difficult to design an decentralized controller for nonlinear interconnected systems. In this study, the model of nonlinear interconnected systems is studied via decentralized fuzzy control method with time delay and polytopic uncertainty. First, the nonlinear interconnected system is represented by an equivalent Takagi-Sugeno type fuzzy model. And the represented model can be rewritten as Parameterized Linear Matrix Inequalities(PLMIs), that is, LMIs whose coefficients are functions of a parameter confined to a compact set. We show that the resulting fuzzy controller guarantees the asymptotic stability and disturbance attenuation of the closed-loop system in spite of controller gain variations within a resulted polytopic region by example and simulations.

• Journal of the Korean Chemical Society
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• v.20 no.3
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• pp.198-205
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• 1976

The integral Hellmann-Feynman Theorem of Parr is generalized to give a full significance to the off-diagonal form, and certain aspects of it are discussed. By use of the generalized form of the theorem, effects of configuration interaction to the crystal field theory are examined, taking perturbation energies of all order collectively into account. Thus, it is shown that there do not exist, especially when the field is strong, the radial integral which is common to all states characterized by ${\Gamma}$, S and m, and could be parametrized. If, however, one restricts the perturbing excited states only to those angularly undistorted and radially equally distorted, there results simple scaling of the crystal field parameter 10 Dq and Condon-Slater parameter $F^n$ defined within the framework of the classical crystal field theory.

• Proceedings of the KIEE Conference
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• 1995.07b
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• pp.817-819
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• 1995

Applied by periodic Stimulating Currents in Bonhoeffer-Van der Pol(BVP) model, chaotic and periodic phenomena occured at specific conditions. The conditions of the chaotic motion in BVP comprised 0.7182< $A_{1}$ <0.792 and 1.09< $A_{1}$ <1.302 proved by the analysis of phase plane, bifurcation diagram, and lyapunov exponent. To control the chaotic motion, two methods were suggested by the first used the amplitude parameter $A_{1}$,$A_{1}={\varepsilon}((x-x_{s})-(y-y_{s}))$ and the second used the temperature parameter c, c=c$(1+ {\eta}cos{\Omega}t)$ which the values of $\eta$, ${\Omega}$ varied respectlvly, and $x_{s}$, $y_{s}$ are the periodic signal. As a result of simulating these methods, the chaotic phenomena was controlled with the periodic motion of periodisity. The feasibilities of the chaotic and the periodic phenomena were analysed by phase plane and lyapunov exponent.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.13 no.1
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• pp.119-127
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• 1999

In this paper, a robust direct adaptive contrdler is presented in a linear time-invariant. Continuous systems with unmodeded dynamics and bounded disturbance using a rmdified control law and the adaptive law to Compensate for the drawback of ${\sigma}$-modification algorithm. The proposed algorithm is awlied to a plant with unrmdeled dynamics represented as a singular perturbation. Boundness of all signals in overall system is guaranteed with mathematical analysis. simulation results are presented the effectiveness foc the first-order plant even in the presence of unmodelled dynamics or bounded disturbance simulatneousIy.eousIy.