• Title/Summary/Keyword: 반응 조건 최적화

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Study on the Insulation Properties of Silicone Rubber (ATH 고충진 실리콘 고무의 절연특성 연구)

  • Kang, Dong-Pil;Park, Hoy-Yul;Ahn, Myeong-Sang;Kim, Dae-Whan;Myung, In-Hae;Lee, Hoo-Bum;Oh, Se-Ho
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1442-1444
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    • 2003
  • 폴리머 애자용 shed 재료의 전기방전에 대한 열화내성과 표면이 오염된 조건하에서도 우수한 발수성 유지는 제품의 장기성능에 있어서 가장 중요한 인자들이다. 내트래킹성 확보를 위한 보강재로는 ATH가 주로 사용되고 있으며 ATH의 첨가량이 많을 수록 내트래킹성은 대체로 향상되는 것으로 되어 있다. 그러나 애자 제조시 무결점 성형성의 만족이 대단히 중요하기 때문에 ATH를 고충진하는 경우 사용하는 process oil들의 종류 및 첨가량을 고려한 ATH 첨가량의 최적화는 필요하다. 본 논문에서는 ATH를 170 part로 다량으로 첨가하면서 화학적 구조와 점도가 다른 몇 가지 실리콘 fliud들을 사용하여 무결점 성형에 적합한 가소도를 갖는 컴파운드를 제조하여 기본물성과 초고압 옥외절연물의 shed 재료로서 장기성능에 영향을 주는 방전열화내성과 표면발수성의 회복특성을 평가하였다. 컴파운드의 성형작업성과 관련이 큰 가소도는 fluid 점도에 따라 상당한 차이를 보이므로 실리콘 fluid 종류의 선택과 첨가량의 최적화에는 성형작업성, 발수성 회복특성, 열화내성 등의 고려가 필요하다. 무결점 애자성형을 위한 진공 사출에서 고무 컴파운드의 가소도가 중요한데 동일한 ATH첨가조건에서 일정한 가소도를 갖게 하는데 필요한 양은 fluid들의 종류에 따라서 상당한 차이가 있었다. 코로나 처리후 발수성 회복특성은 fluid들의 분자크기와 반응기의 종류에 따라 상당히 영향을 받았으며 분자가 클수록 초기회복속도는 다소 느렸지만 평상시에 늘 유지되는 상시발수성은 다소 높게 유지되었다. 아크와 트래킹 방전에 의한 무게 감소는 ATH가 과량으로 첨가되어 상당히 적었으며 fluid의 분자가 크면서 페닐기를 가진 fluid들이 첨가된 고무가 우수한 특성을 보였다.

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Optimization of Fermentation Process for Acetic Acid Production (초산 생성을 위한 발효공정의 최적화)

  • Shin, Jin-A;Oh, Nam-Soon
    • Food Engineering Progress
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    • v.14 no.3
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    • pp.217-221
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    • 2010
  • Various conditions of acetic acid fermentation by Acetobacter aceti B20 strain were investigated and evaluated to optimize the fermentative production of acetic acid. The effects of the initial ethanol concentration on growth and acid productivity in a flask and fermentor were also studied. The growth of A. aceti B20 strain was inhibited as the concentration of ethanol increased. However, the highest total acidity and fermentation yield were 5.34% and 56.1%, respectively when the initial concentration of ethanol was 7% in the batch fermentation. Although the concentration of initial glucose influenced the growth rate of B20 strain, it did not influence the total acidity in the flask culture. When the agitation speed increased, the growth, total acidity and fermentation yield were all improved. In fed-batch fermentation, total acidities and fermentation yields were 7.14-8.76% and 39.1-53.0%, respectively, and their values mostly depended on the feeding methods.

Optimization of Hot-Water Extraction Condition of Garlic Using a Response Surface Methodology (반응표면분석법을 이용한 마늘 열수추출조건의 최적화)

  • Lee, Jin-Man;Cha, Tae-Yang;Kim, Seong-Ho;Kwon, Taeg-Kyu;Kwon, Joong-Ho;Lee, Sang-Han
    • Food Science and Preservation
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    • v.14 no.4
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    • pp.385-393
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    • 2007
  • Much research is conducted on the biological activities of medicinal herbs, traditional plants, and agricultural products, cultivated in Korea. This study focused on optimization of hot-water extraction methods for such products, by analyzing and monitoring extraction characteristics using a response surface methodology. We found that the total phenolics contents, electron-donating abilities, and nitrite-scavenging abilities of extracts were significantly affected both by the solvent used for extraction, and by the nature of the particular herb or plant under study. The extraction efficiencies of valuable ingredients such as alliin, allicin, and total thiosulfinate, were greatly affected by extraction temperature, but not by extraction time or the solvent used. We elicited a regression formula for each variable. We first entered the optimal values of all extraction conditions giving active ingredients into the model. Next, we entered the optimal values of all extraction conditions favoring the retention of valuable antioxidant characteristics. Finally, we entered processing factors into the model. Overall, the optimal extraction was at $80^{\circ}C$ for 3.5 hr with 8.5 ml of solvent/g of sample. The predicted values of each variable were similar to the actual values.

Optimizing the Hot-water Extraction Conditions for Acanthopanacis cortex Using Response Surface Methodology (반응표면분석법을 이용한 오가피의 열수 추출조건 최적화)

  • Kim, In-Ho;Kim, Seong-Ho;Kwon, Joong-Ho
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.37 no.4
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    • pp.512-520
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    • 2008
  • In order to examine the effective components and antioxidative characteristics of Acanthopanacis cortex, response surface methodology was used to optimize the hot water extraction process by analyzing and monitoring the extraction condition characteristics. The total extraction yield was optimized using the extraction temperature of $84.28^{\circ}C$, extraction time of 3.59 hr and 18.37 mL/g as the amount of solvent per sample. For the effective component of eleutheroside E, the optimal extraction temperature, time and amount of solvent per sample were $81.16^{\circ}C$, 3.56 hr, and 19.06 mL/g, respectively; also, for total phenolics, the optimal conditions were $88.45^{\circ}C$, 4.33 hr, and 21.12 mL/g, respectively. Regression equations were deduced for each variable and then eleutheroside E, chlorogenic acid, and antioxidative characteristics were superimposed with the optimal conditions to obtain values for each extraction process factor. The predicted results were $81{\sim}88^{\circ}C$, $3.5{\sim}4.3hr$, and $18{\sim}21mL/g$, respectively. The estimated values for the optimal extraction conditions of Acanthopanacis cortex's effective components and antioxidative characteristics were similar to the experimental results.

Dermal Papilla Cells Proliferation Constituent of Schisandra chinensis Fruits and Optimization Using Response Surface Methodology (오미자의 모유두세포 증식 활성성분과 반응표면분석을 이용한 추출조건의 최적화)

  • Cho, Hyun Dae;Jeong, JiYeon;Ryu, Hwa Sun;Lee, JungNo;Park, Sung-Min
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.46 no.4
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    • pp.415-424
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    • 2020
  • In the present study, we have refined gomisin N, which represents activity in the proliferation of dermal papilla cells (HFDPCs) from the fruit of Schisandra chinensis (S. chinensis), and have identified optimal extraction conditions for obtaining extracts with high content of gomisin N. The activity of the extracts and fractions was evaluated, and the results indicated approximately 29% proliferation activity in the group treated with 1 ㎍/mL of n-hexane fraction. Column chromatography was used to assess the active ingredient in the n-hexane fraction, and two compounds, namely gomisin N(1) and schisandrin(2), were isolated and identified. When the HFDPCs proliferation activity was tested for the isolated compounds, gomisin N exhibited ≥ 20% proliferation activity. Thus, via response surface methodology (RSM), the optimum extraction conditions to obtain the maximum level of gomisin N from the fruit of S. chinensis were determined, where ethanol proportion, extraction time, and extraction temperature were used as the independent variables. The results revealed coefficient of determination ≥ 0.95 and p-value ≤ 0.05, which confirmed the fit of the model. The optimum extraction conditions to achieve the maximum content of gomisin N were as follows: ethanol proportion 83.8%, extraction temperature 80 ℃, and extraction time 8.7 h. The content of gomisin N using these conditions was predicted as 378,300 ppm, and a mean value close to the predicted value (376,884 ppm) was obtained while validating the aforementioned conditions.

Optimization of Fermentation Conditions for the Ethanol Production from Sweet Sorghum Juice by Saccharomyces cerevisiae using Response Surface Methodolgy (단수수 착즙액으로부터 에탄올 생산을 위한 반응표면분석법을 이용한 효모 발효조건 최적화)

  • Cha, Young-Lok;Park, Yu-Ri;Kim, Jung-Kon;Choi, Yong-Hwan;Moon, Youn-Ho;Bark, Surn-Teh;An, Gi-Hong;Koo, Bon-Cheol;Park, Kwang-Geun
    • New & Renewable Energy
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    • v.7 no.4
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    • pp.3-9
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    • 2011
  • Optimization of initial total sugar concentration of sweet sorghum juice, aeration time and aeration rate on ethanol production was performed by response surface methodology (RSM). The optimum conditions for ethanol production from concentrated sweet sorghum juice were determined as follows: initial total sugar concentration, 21.2 Brix; aeration time, 7.66h; aeration rate, 1.22 vvm. At the optimum conditions, the maximum ethanol yield was predicted to be 91.65% by model prediction. Similarly, 92.98% of ethanol yield was obtained by verification experiment using optimum conditions after 48 h of fermentation. This result was in agreement with the model prediction.

Optimal Material and Conditions for the Immobilization of Rhizopus nigricans in the $11{\alpha}-Hydroxylation$ Reaction of Progesterone (Rhizopus nigricans를 이용한 Progesterone의 $11{\alpha}-Hydroxylation$ 반응에서의 고정화 재료와 조건의 최적화)

  • Kim, Myung-Hee;Lee, Jung-Jin;Kim, Mal-Nam;Min, Byung-Re
    • The Korean Journal of Mycology
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    • v.18 no.2
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    • pp.84-88
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    • 1990
  • Hydroxylation in the $11{\alpha}$-position of progesterone molecules was carried out using Rhizopus nigricans spores immobilized within various gel matrices, among which polyacrylamide and agar gel were proved to be the most effective. Reactions with the immobilized cells and in­tact free cells showed almost identical conversion rate of progesterone, optimal pH and reaction time for attaining maximal yield, from which were confirmed absence of any decay and modification of enzyme activities.

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Structural Optimization of an Outer Tie Rod Using RSM and Kriging (반응표면법 및 크리깅을 이용한 아우터 타이로드의 구조 최적화)

  • Kim, Young-Jun;An, Kyo-Jin;Lee, Kwon-Hee;Park, Young-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.1
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    • pp.27-34
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    • 2015
  • It is known that the severest loading condition is the buckling case in the structural design of an outer tie rod. The optimum design of the OTR was suggested considering the buckling performance. The aluminum alloy was investigated as a steel substitute. Then, the structural optimization based on the response surface method and the kriging interpolation method were performed.

A Study on the Effects of Temperature and Flow Rate for DMFC Performance (DMFC에서 온도 및 유량이 성능에 미치는 영향에 관한 연구)

  • Kim, Hong-Gun;Kwac, Lee-Ku;Kang, Young-Woo;Kim, Tae-Jin;Kwak, Sang-Hee;An, Kay-Hyeok;Park, Gyung-Se
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.656-659
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    • 2009
  • 직접메탄올형 연료전지(Direct Methanol Fuel Cell)는 휴대용으로 사용할 수 있는 소형 전원용으로 주로 개발되고 있으며, 다양한 용도로 사용이 가능하다. 하지만 직접메탄올연료전지에서 전해질로 많이 쓰이는 Nafion막은 이를 통한 메탄올 크로스오버(Crossover) 때문에 연료전지의 성능을 제한시키고 있다. 본 연구에서는 Nafion 117를 사용하여 전극 면적 100cm2 의 DFMC용 MEA를 제작하고, 공기 유량을 3ml/mim으로 고정하고, 메탄올 유량을 2,3 ml/min로 각각 공기극와 연료극에 공급하여 온도변화(50, 60, 70, $80^{\circ}C$)에 따른 성능을 확인하였다. DMFC의 적당 반응 온도는 $70^{\circ}C$로 생각되고, 유량은 메탄올 2ml/min, 공기 3ml/min유량 공급시가 성능이 높게 나오는 결과를 얻으나 일정시간 지나면 성능이 메탄올 3ml/min, 공기 3ml/min유량 공급시 보다 성능이 떨어지는 현상이 일어나기 때문에 $70^{\circ}C$ 반응온도에 메탄올 3ml/min, 공기 3ml/min의 유량 공급이 본 논문에서 최적화된 성능을 내는 조건으로 사료된다.

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Optimization of Fluidized Bed Granulating Conditions for Powdered Milk by Response Surface Methodology (반응표면분석에 의한 분유의 유동층 과립공정 최적화)

  • 강현아;신명곤
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.1
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    • pp.225-228
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    • 2004
  • Optimization of fluidized bed granulating conditions for yield, bulk density, and tapped density of powdered milk was determined using response surface methodology. Yield of powdered milk was greatly affected by feeding rate of water, and bulk density and tapped density could be reduced by decreasing of atomization pressure. The optimum conditions for fluidized bed granulating of powdered milk were predicted with 6$0^{\circ}C$ of inlet air temperature, 16 mL/min of feeding rate, and 2.1 bar of atomization pressure. Also 94% of yield 0.350 g/㎤ of bulk density, and 0.446 g/㎤ of tapped density of powdered milk could be obtained by the optimum granulating conditions.