• Title/Summary/Keyword:

Search Result 23,296, Processing Time 0.038 seconds

Photoluminescence Enhancement of Y2O3:Eu3+ Red Phosphor Prepared by Spray Pyrolysis using Aliovalent Cation Substitution and Organic Additives (이가 양이온 금속 친환 및 유기 첨가제를 이용하여 분무열분해법으로 제조된 Y2O3:Eu3+ 적색 형광체의 휘도 개선)

  • Min, Byeong Ho;Jung, Kyeong Youl
    • Journal of Powder Materials
    • /
    • v.27 no.2
    • /
    • pp.146-153
    • /
    • 2020
  • The co-doping effect of aliovalent metal ions such as Mg2+, Ca2+, Sr2+, Ba2+, and Zn2+ on the photoluminescence of the Y2O3:Eu3+ red phosphor, prepared by spray pyrolysis, is analyzed. Mg2+ metal doping is found to be helpful for enhancing the luminescence of Y2O3:Eu3+. When comparing the luminescence intensity at the optimum doping level of each Mg2+ ion, the emission enhancement shows the order of Zn2+ ≈ Ba2+ > Ca2+ > Sr3+ > Mg2+. The highest emission occurs when doping approximately 1.3% Zn2+, which is approximately 127% of the luminescence intensity of pure Y2O3:Eu3+. The highest emission was about 127% of the luminescence intensity of pure Y2O3:Eu3+ when doping about 1.3% Zn2+. It is determined that the reason (Y, M)2O3:Eu3+ has improved luminescence compared to that of Y2O3:Eu3+ is because the crystallinity of the matrix is improved and the non-luminous defects are reduced, even though local lattice strain is formed by the doping of aliovalent metal. Further improvement of the luminescence is achieved while reducing the particle size by using Li2CO3 as a flux with organic additives.

Analysis of Amyloid Beta 1-16 (Aβ16) Monomer and Dimer Using Electrospray Ionization Mass Spectrometry with Collision-Induced Dissociation

  • Kim, Kyoung Min;Kim, Ho-Tae
    • Mass Spectrometry Letters
    • /
    • v.13 no.4
    • /
    • pp.177-183
    • /
    • 2022
  • The monomer and dimer structures of the amyloid fragment Aβ(1-16) sequence formed in H2O were investigated using electrospray ionization mass spectrometry (MS) and tandem MS (MS/MS). Aβ16 monomers and dimers were indicated by signals representing multiple proton adduct forms, [monomer+zH]n+ (=Mz+, z = charge state) and [dimer+zH]z+ (=Dz+), in the MS spectrum. Fragment ions of monomers and dimers were observed using collision-induced dissociation MS/MS. Peptide bond dissociation was mostly observed in the D1-D7 and V11-K16 regions of the MS/MS spectra for the monomer (or dimer), regardless of the monomer (or dimer) charge state. Both covalent and non-covalent bond dissociation processes were indicated by the MS/MS results for the dimers. During the non-covalent bond dissociation process, the D3+ dimer complex was separated into two components: the M1+ and M2+ subunits. During the covalent bond dissociation of the D3+ dimer complex, the b and y fragment ions attached to the monomer, (M+b10-15)z+ and (M+y9-15)z+, were thought to originate from the dissociation of the M2+ monomer component of the (M1++M2+) complex. Two different D3+ complex geometries exist; two distinguished interaction geometries resulting from interactions between the M1+ monomer and two different regions of M2+ (the N-terminus and C-terminus) are proposed. Intricate fragmentation patterns were observed in the MS/MS spectrum of the D5+ complex. The complicated nature of the MS/MS spectrum is attributable to the coexistence of two D5+ configurations, (M1++M4+) and (M2+M3+), in the Aβ16 solution.

Extreme Points, Exposed Points and Smooth Points of the Space 𝓛s(2𝑙3)

  • Kim, Sung Guen
    • Kyungpook Mathematical Journal
    • /
    • v.60 no.3
    • /
    • pp.485-505
    • /
    • 2020
  • We present a complete description of all the extreme points of the unit ball of 𝓛s(2𝑙3) which leads to a complete formula for ║f║ for every f ∈ 𝓛s(2𝑙3). We also show that $extB_{{\mathcal{L}}_s(^2l^3_{\infty})}{\subset}extB_{{\mathcal{L}}_s(^2l^n_{\infty})}$ for every n ≥ 4. Using the formula for ║f║ for every f ∈ 𝓛s(2𝑙3), we show that every extreme point of the unit ball of 𝓛s(2𝑙3) is exposed. We also characterize all the smooth points of the unit ball of 𝓛s(2𝑙3).

MAXIMAL FUNCTIONS ALONG TWISTED SURFACES ON PRODUCT DOMAINS

  • Al-Salman, Ahmad
    • Bulletin of the Korean Mathematical Society
    • /
    • v.58 no.4
    • /
    • pp.1003-1019
    • /
    • 2021
  • In this paper, we introduce a class of maximal functions along twisted surfaces in ℝn×ℝm of the form {(𝜙(|v|)u, 𝜑(|u|)v) : (u, v) ∈ ℝn×ℝm}. We prove Lp bounds when the kernels lie in the space Lq (𝕊n-1×𝕊m-1). As a consequence, we establish the Lp boundedness for such class of operators provided that the kernels are in L log L(𝕊n-1×𝕊m-1) or in the Block spaces B0,0q (𝕊n-1×𝕊m-1) (q > 1).

SEMIPRIME RINGS WITH INVOLUTION AND CENTRALIZERS

  • ANSARI, ABU ZAID;SHUJAT, FAIZA
    • Journal of applied mathematics & informatics
    • /
    • v.40 no.3_4
    • /
    • pp.709-717
    • /
    • 2022
  • The objective of this research is to prove that an additive mapping T : R → R is a left as well as right centralizer on R if it satisfies any one of the following identities: (i) T(xnyn + ynxn) = T(xn)yn + ynT(xn) (ii) 2T(xnyn) = T(xn)yn + ynT(xn) for each x, y ∈ R, where n ≥ 1 is a fixed integer and R is any n!-torsion free semiprime ring. In addition, we talk over above identities in the setting of *-ring(ring with involution).

Rare-Earth Metal Complex-Functionalized Mesoporous Silica for a Potential UV Sensor (잠재적인 UV 센서를 위한 희토류 금속착물이 기능화된 메조다공성 실리카)

  • Sung Soo Park;Mi-Ra Kim;Weontae Oh;Yedam Kim;Yeeun Lee;Youngeon Lee;Kangbeom Ha;Dojun Jung
    • Journal of Adhesion and Interface
    • /
    • v.24 no.4
    • /
    • pp.136-142
    • /
    • 2023
  • In this study, TEOS was used as a silica source, and a triblock copolymer (P123) was used as a template to produce mesoporous silica with a well-ordered hexagonal mesopore array through a self-assembly method and hydrothermal process under acidic condition. (Surfactant-extracted SBA-15). Surfactant-extracted SBA-15 showed the particle shape of a short rod with a size of approximately 980 nm. The surface area and pore diameter were 730 m2g-1 and 70.8 Å, respectively. Meanwhile, aminosilane (3-aminopropyltriethoxysilane, APTES) was grafted into the mesopores using a post-synthesis method. Mesoporous silica (APTES-SBA-15) modified with aminosilane had a well-ordered pore structure (p6mm) and well-maintained the particle shape of short rods. The surface area and pore diameter of APTES-SBA-15 decreased to 350 m2g-1 and 60.7 Å, respectively. APTES-modified mesoporous silica was treated with a solution of rare earth metal ions (Eu3+, Tb3+) to synthesize a mesoporous silica material in which rare earth metal complexes were introduced into the mesopores. (Eu/APTES-SBA-15, Tb/APTES-SBA-15) These materials exhibited characteristic photoluminescence spectra by λex=250 nm. (5D47F5 (543.5 nm), 5D47F4 (583.5 nm), 5D47F3 (620.2 nm) transitions for Tb/APTES-SBA-15; 5D07F0 (577.7 nm), 5D07F1 (592.0 nm), 5D07F2 (614.9 nm), 5D07F3 (650.3 nm) and 5D07F4 (698.5 nm) transitions for Eu/APTES-SBA-15)

Luminescent Properties and Anti-Counterfeiting Applications of SrWO4:RE3+ (RE=Dy, Sm, Dy/Sm) Phosphors Doped with Several Activator Ions (다양한 활성제 이온이 도핑된 SrWO4:RE3+ (RE=Dy, Sm, Dy/Sm) 형광체의 특성과 위조 방지 응용)

  • Yoon, Soohwan;Cho, Shinho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.33 no.5
    • /
    • pp.393-399
    • /
    • 2020
  • A series of phosphors, SrWO4:5 mol% Dy3+, SrWO4:5 mol% Sm3+, and SrWO4:5 mol% Dy3+:x Sm3+ (x=1~15 mol%), were prepared using a facile co-precipitation. The crystal structure, morphology, photoluminescence properties, and application in anti-counterfeiting fields were investigated. The crystalline structures of the prepared phosphors were found to be tetragonal systems with the dominant peak occurring at the (112) plane. The excitation spectra of the Dy3+ singly-doped SrWO4 phosphors were composed of an intense charge-transfer band centered at 246 nm in the range of 210~270 nm and two weak peaks at 351 nm and 387 nm due to the 6H15/26P7/2 and 6H15/24I13/2 transitions of Dy3+ ions, respectively. The wavelength of 246 nm was optimum for exciting the luminescence of Dy3+ and Sm3+ co-doped SrWO4 phosphors. The emission spectra consisted of two intense blue and yellow emission bands at 480 nm and 573 nm corresponding to the 4F9/26H15/2 and 4F9/26H13/2 transitions of Dy3+, and two strong emission peaks at 599 nm and 643 nm originating from the 4G5/26H7/2 and 4G5/26H9/2 transitions of Sm3+, respectively. As the concentration of Sm3+ ions increased, the emission intensities of Dy3+ rapidly decreased, while the emission intensities of Sm3+ gradually increased. These results suggest that the color of the emission light can be tuned from yellow to white by changing the concentration of Sm3+ ions at a fixed 5 mol% Dy3+. Furthermore, the fluorescent security inks were synthesized for use in anti-counterfeiting applications.

MULTIPLICATIVE FUNCTIONS COMMUTABLE WITH BINARY QUADRATIC FORMS x2 ± xy + y2

  • Poo-Sung, Park
    • Bulletin of the Korean Mathematical Society
    • /
    • v.60 no.1
    • /
    • pp.75-81
    • /
    • 2023
  • If a multiplicative function f is commutable with a quadratic form x2 + xy + y2, i.e., f(x2 + xy + y2) = f(x)2 + f(x) f(y) + f(y)2, then f is the identity function. In other hand, if f is commutable with a quadratic form x2 - xy + y2, then f is one of three kinds of functions: the identity function, the constant function, and an indicator function for ℕ \ pℕ with a prime p.

LAPLACE-BELTRAMI MINIMALITY OF TRANSLATION HYPERSURFACES IN E4

  • Ahmet Kazan;Mustafa Altin
    • Honam Mathematical Journal
    • /
    • v.45 no.2
    • /
    • pp.359-379
    • /
    • 2023
  • In the present paper, we study translation hypersurfaces in E4. In this context, firstly we obtain first, second and third Laplace-Beltrami (LBI, LBII and LBIII) operators of the translation hypersurfaces in E4. By solving second and third order nonlinear ordinary differential equations, we prove theorems that contain LBI-minimal, LBII-minimal and LBIII-minimal translation hypersurfaces in E4.

Effect of the Elevated Carbon Dioxide on the Growth and Physiological Responses of Peach 'Mihong' (CO2 상승처리가 복숭아 '미홍'의 수체생육 및 생리반응에 미치는 영향)

  • Lee, Seul Ki;Cho, Jung Gun;Jeong, Jae Hoon;Ryu, Suhyun;Han, Jeom Hwa;Do, Gyung-Ran
    • Journal of Bio-Environment Control
    • /
    • v.30 no.4
    • /
    • pp.312-319
    • /
    • 2021
  • This study was conducted to investigate the effect of elevated carbon dioxide on the growth and physiological responses of peach 'Mihong' (Prunus persica). We simulated three different carbon dioxide conditions based on climate change scenarios RCP 8.5 in the sunlight phytotron rooms from April 22 to July 6, 2020; 400 µmol·mol-1(present condition), 700 µmol·mol-1 treatment(expecting carbon dioxide concentrations in mid-21st century), 940 µmol·mol-1 treatment (expecting carbon dioxide concentrations in late 21st century). The average of maximum photosynthesis rate at 700 µmol·mol-1(16.06 µmol·CO2·m-2·s-1) was higher than those at 400 µmol·mol-1(14.45 µmol·CO2·m-2·s-1) and 940 µmol·mol-1(15.96 µmol·CO2·m-2·s-1) from May 22 to July 2. However, stomatal conductances at 700 µmol·mol-1 and 940 µmol·mol-1 were lower than those at the control. Also, the carbon dioxide saturation point in all treatments was reduced from 1,200 µmol·mol-1 in the early stage of growth to 600-800 µmol·mol-1 in the late stage of growth. The stomatal densities were decreased as carbon dioxide increased. The shoot lengths were decreased while the carbon dioxide was increased, but the increase of trunk diameter and leaf areas, shoot numbers were not statistically different. The fruit weight at 700 µmol·mol-1(152.5 g) was higher than those at the control(141.8 g) and 940 µmol·mol-1(147.4 g). The soluble solids were higher at 700 µmol·mol-1, 940 µmol·mol-1 compared to the control. These results suggest that a carbon dioxide elevated to 700 µmol·mol-1 in the future may give a positive effect on the yield and fruit quality of peach 'Mihong' while a carbon dioxide elevated above 940 µmol·mol-1 may affect negatively such as early senescence and loss of fruit set.