• Biotechnology and Bioprocess Engineering:BBE
• /
• 제6권6호
• /
• pp.426-432
• /
• 2001

Perstractive fermentation is a good way to increase the productivity of bioreactors. Us-ing Propionibacteria as the model system, the feasibility of using supported emulsion liquid mem-brane(SELM) fro perstractive fermentation is assessed in this study. Five industrial solvents were considered as the solvent for perparing the SELM. The more polar a solvent, is the higher the par-tition coefficeint However, toxicity of a solvent also increases with its polarity. CO-1055(indus-trial decanol/octanol blend)has the highest partition coefficient toward propionic acid among the solvents that has no molecular toxicity toward Propionibacteria, A preliminary extraction study was conducted using tetradecane as solvent in a hydrophobic hollow fiber contactor. The results confirmed that SELM eliminates the equilibrium limitation of conventional liquid-liquid extrac-tion and allows the use of a non-toxic solvent with low partition coefficient.

• 한국세라믹학회지
• /
• 제29권2호
• /
• pp.107-118
• /
• 1992

Alumina supports for TiO2 ultrafiltration membrane coating were prepared by presintering disk-type preforms at 140$0^{\circ}C$. These supports showed uniform microstructures which had the apparent porosity of 40%, the pore size distribution in the range of 0.1~0.5${\mu}{\textrm}{m}$, and the water flux of 1400ι/$m^2$.h at the pressure difference of 10 atm. The optimum pH and concentration of the TiO2 sol for coating were 0.8 and 1.0 wt%, respectively, and sol particles were identified as rutile forms of 20 nm size. Crack-free alumina-supported rutile TiO2 membranes could be prepared through well controlled drying and heating the gel layer coated by the sol-gel dipping. The pore size of the TiO2 membranes heat-treated at 50$0^{\circ}C$ for 2 hrs was 30~80$\AA$, and their thickness varied from 1.1 to 3.8 ${\mu}{\textrm}{m}$ in accordence with the dipping time (4~40 min). The flux of water through this composite membrane at 10 atm was found to be in the range from 800 to 1100ι/$m^2$.hr depending on the dipping time (10~40 min). The membrane thickness increased linearly with the square root of the dipping time and the slope was 0.62 ${\mu}{\textrm}{m}$/{{{{ SQRT { min} }}.

• 한국공간정보시스템학회:학술대회논문집
• /
• 한국공간정보시스템학회 2004년도 춘계 학술발표회 논문집 제1권1호(통권1호)
• /
• pp.148-157
• /
• 2004

The structure systems with non-rigid member were classified by the composition type of line and surface members. As a result of the classification, there are 1-way cable structure, cable net and radial cable net structure in the line member system. And there are pneumatic structure and suspension membrane structure in surface member system. In addition, when the line and surface members are composed together, there is the hybrid membrane system which are divided into hanging type and supported type. In this paper, the Korean terms of structure systems with non-rigid member are recommended through this classification. In each the structure systems with non-rigid member, the examples were also investigated considering their historical developments. It present that the light weight structure system and the openness of space have pursued with the developments. So largely, cable net structure with membrane, membrane structure and hybrid structure have used in these days.

• Membrane and Water Treatment
• /
• 제13권1호
• /
• pp.51-62
• /
• 2022

Vacuum-assisted air gap membrane distillation (V-AGMD) has the potential to achieve higher flux and productivity than conventional air gap membrane distillation (AGMD). Nevertheless, there is not much information on technical aspects of V-AGMD operation. Accordingly, this study aims to analyze the effect of membrane deformation on flux in V-AGMD operation. Experiments were carried out using a bench-scale V-AGMD system. Statistical models were applied to understand the flux behaviors. Statistical models based on MLR, GNN, and MLFNN techniques were developed to describe the experimental data. Results showed that the flux increased by up to 4 times with the application of vacuum in V-AGMD compared with conventional AGMD. The flux in both AGMD and V-AGMD is affected by the difference between the air gap pressure and the saturation pressure of water vapor, but their dependences were different. In V-AGMD, the membranes were found to be deformed due to the vacuum pressure because they were not fully supported by the spacer. As a result, the deformation reduced the effective air gap width. Nevertheless, the rejection and LEP were not changed even if the deformation occurred. The flux behaviors in V-AGMD were successfully interpreted by the GNN and MLFNN models. According to the model calculations, the relative impact of the membrane deformation ranges from 10.3% to 16.1%.

• 한국재료학회지
• /
• 제19권12호
• /
• pp.667-673
• /
• 2009

The electrocatalytic characteristics of oxygen reduction reaction of the $PtxM_{(1-x)}$ (M = Co, Cu, Ni) supported on multi-walled carbon nanotubes (MWNTs) have been evaluated in a Polymer Electrolyte Membrane Fuel Cell (PEMFC). The $Pt_xM_{(1-x)}$/MWNTs catalysts with a Pt : M atomic ratio of about 3 : 1 were synthesized and applied to the cathode of PEMFC. The crystalline structure and morphology images of the $Pt_xM_{(1-x)}$ particles were characterized by X-ray diffraction and transmission electron microscopy, respectively. The results showed that the crystalline structure of the Pt alloy particles in Pt/MWNTs and $Pt_xM_{(1-x)}$/MWNTs catalysts are seen as FCC, and synthesized $Pt_xM_{(1-x)}$ crystals have lattice parameters smaller than the pure Pt crystal. According to the electrochemical surface area (ESA) calculated with cyclic voltammetry analysis, $Pt_{0.77}Co_{0.23}$/MWNTs catalyst has higher ESA than the other catalysts. The evaluation of a unit cell test using Pt/MWNTs or $Pt_xM_{(1-x)}$/MWNTs as the cathode catalysts demonstrated higher cell performance than did a commercial Pt/C catalyst. Among the MWNTs-supported Pt and $Pt_xM_{(1-x)}$ (M = Co, Cu, Ni) catalysts, the $Pt_{0.77}Co_{0.23}$/MWNTs shows the highest performance with the cathode catalyst of PEMFC because they had the largest ESA.

• 한국수소및신에너지학회논문집
• /
• 제26권1호
• /
• pp.45-53
• /
• 2015

The objective of this study is to develop a gas pro-treatment system for DME synthesis, wherein this system separates $CO_2$ from Flaring gas as Membrane, in order to save raw material ($CH_4$) cost of DME. In this study, hollow fiber membrane is developed, which is able to separate high-pressure gas, supported by polysulfone and coated with amorphous fluorinated polymer. Throughout the evaluation of the membrane's separation characteristics, the membrane is applied to this system. The membrane is designed by 2 stages for over 90% removal rate of $CO_2$ and over 90% recovery rate of $CH_4$. The bench scale of pro-treatment system is developed as $25Nm^3/hr$.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2007년도 추계학술대회 논문집
• /
• pp.201-204
• /
• 2007

A novel self-humidifying composite membrane for the proton exchange membrane fuel cell (PEMFC) at low humidity condition was developed. The $Pt/TiO_2 catalyst particles were synthesized via supercritical impregnation methods. Pt precursor was dissolved in supercritical carbon dioxide and impregnated onto $TiO_2$ particles. Pt precursors were platinum(II) acetylacetonate, Dimethyl(1,5-cyclooctadiene) platinum(II) and we controlled the ratio of Pt to $TiO_2$ The impregnated Pt precursor was converted to $TiO_2$ supported Pt nanoparticle under various reducing conditions. $TiO_2$ catalyst particles were dispersed uniformly into the Nafion solution, and then $Pt/TiO_2/Nafion$composite membrane was prepared using solution-cast method. The size, dispersion and content of the platinum had been characterized with Transmission Electron Micrograph (TEM), X-ray diffract ion (XRD) and Inductively Coupled Plasma - Atomic Emission Spectrometer (ICP-AES). The cell performance with the self-humidifying composite membrane was compared with a recast Nafion membrane under both humidified and dry conditions at 65 $^{\circ}C$.

• 한국공간구조학회논문집
• /
• 제21권4호
• /
• pp.49-56
• /
• 2021

This study aims to develop a form-finding algorithm for a single-layered pneumatic membrane. The initial shape of this pneumatic membrane, which is an air-supported type pneumatic membrane, is to find a state in which a given initial tension and internal pneumatic pressure are in equilibrium. The algorithm developed to satisfy these conditions is that a nonlinear optimization problem based on the force method considering the deformed shape is formulated, and, it's able to find the shape by iteratively repeating the process of obtaining a solution of the governing equations. An computational technique based on the Gauss-Newton method was used as a method for obtaining solutions of nonlinear equations. In order to verify the validity of the proposed form-finding algorithm, a single-curvature pneumatic membrane example and a double-curvature air pneumatic membrane example were adopted, respectively. In the results of these examples, it was possible to well observe the step-by-step convergence process of the shape of the pneumatic membrane, and it was also possible to confirm the change in shape according to the air pressure. In addition, the calculation results of the shape and internal force after deformation due to initial tension, air pressure, and self-weight were obtained.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 1990년도 가을 학술발표회 논문집
• /
• pp.13-18
• /
• 1990

This paper introduced truss model and one-way slab elastic Model to analyse flexure of unbonded prestressed concrete member. After cracking, we could determine concrete membrane depth, deflection and stress. In order to do that, an numerical example of simply supported one way slab which has non-external membrane support(s=0) is analysed. The analytical results using the analytical model were compared with several experimental results and were generally satisfied.

• 한국재료학회지
• /
• 제31권7호
• /
• pp.375-381
• /
• 2021

Chitosan powder is synthesized by a deasetylation process of chitin, obtained from processing of dried shrimp shell powder. Subsequently, chitosan (CS) membranes filled by montmorillonite (MMT) particles and phosphotungstic acid are prepared, and characterized by FT-IR and SEM. The morphology, obtained by SEM for the composite membrane, showed that MMT filler is successfully incorporated and relatively well dispersed in the chitosan polymer matrix. Water and methanol uptake for the CS/MMT composite membranes decrease with increasing MMT loadings, but IEC value increases. In all prepared CS/MMT composite membranes, the CS membrane filled by 5 wt% MMT particles exhibits the best proton conductivity, while that with 10 wt% MMT loading exhibits the lowest methanol permeability; these values are 2.67 mS·cm^-1 and 3.40 × 10^-7 cm²·s^-1, respectively. The best membrane selectivity is shown in the CS/MMT10 composite membrane; this shows that 10 wt% filled MMT is the optimum loading to improve the performance of the chitosan composite membrane. These characteristics make the developed chitosan composite membranes a promising electrolyte for direct methanol fuel cell (DMFC) application.