• Title/Summary/Keyword: structured electrode

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Extracting Photosynthetic Electrons from Thylakoids on Micro Pillar Electrode

  • Ryu, DongHyun;Kim, Yong Jae;Ryu, WonHyoung
    • International Journal of Precision Engineering and Manufacturing-Green Technology
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    • v.5 no.5
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    • pp.631-636
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    • 2018
  • Extraction of photosynthetic currents from thylakoids was studied using micro pillar structured electrode. Thylakoids were isolated from spinach leaves, and the size and shape of thylakoids were estimated from scanning electron microscopy images. Based on the geometry information of thylakoids, micro pillar shaped electrode was designed and fabricated using metal-assisted chemical etching of silicon wafers. Influence of photovoltaic effect on the silicon-based micro pillar electrode was confirmed to be negligible. Photosynthetic currents were measured in a three-electrode setup with an electron mediator, potassium ferricyanide. Photosynthetic currents from micro pillar electrodes were enhanced compared with the currents from flat electrodes. This indicates the significance of the enhanced contact between thylakoids and an electrode for harvesting photosynthetic electrons.

Effect of deposition method of source/drain electrode on a top gate ZnO TFT Performance

  • Kopark, Sang-Hee;Hwang, Chi-Sun;Yang, Shin-Hyuk;Yun, Young-Sun;Park, Byung-Chang
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.254-257
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    • 2008
  • We have investigated the effect of source/drain electrode deposition method on a performance of top gate structured ZnO TFT performance. TFT using S/D of ITO film, consisted of bi-layer which deposited by ion beam assisted sputtering at the initial stage then deposited by DC magnetron sputtering, showed better performance compared to that using S/D of ITO deposited by just DC magnetron sputtering. Two ITO films exhibited different grain shapes and these resulted in different etching properties. We also suspect that charge trapping on the glass substrate (back channel) during the ITO film deposition may influence the characteristics of top gate structured ZnO TFT.

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Bendable ac-PDP using Fence-Structured Electrodes on Polyethylene Terephthalate Substrate

  • Choi, Won-Yeol;Hong, Cho-Rong;Kim, Yong-Seog
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.593-596
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    • 2007
  • A possibility of manufacturing bendable ac-PDP using aluminum electrode with anodic aluminum oxide dielectric material system on PET film substrate was explored. For this structure, PET film with fence-structured aluminum electrodes was used for front plate and PET film with barrier ribs of UV curable resin for the rear plate. The results demonstrate that it is feasible to manufacture the bendable ac-PDPs using those material system and are expected to expand the applications of plasma display panels.

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Enhancement in Selectivity of Nonenzymatic Glucose Sensors Based on Mesoporous Platinum by A.C. Impedance

  • Park, Se-Jin;Boo, Han-Kil
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.147-153
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    • 2008
  • Improvement of the selectivity of nonenzymatic glucose based on mesoporous platinum ($H_1$-ePt) by using A.C. impedance is reported. The idea of the present work is based on the novel effect of the mesoporous electrode that the apparent exchange current due to glucose oxidation remarkably grows although the reaction kinetics on the surface is still sluggish. It is expected that the enlarged apparent exchange current on the mesoporous electrode can raise the sensitivity of admittance in A.C. impedance to glucose concentration. At a low frequency, A.C. impedance could become more powerful. The admittance at 0.01 Hz is even more sensitive to glucose than to ascorbic acid while amperometry exhibits the inverse order of sensitivity. This is the unique behavior that is neither observed by A.C. impedance on flat platinum electrode nor obtained by amperometry. The study shows how the combination of A.C. impedance and nano-structured surface can be applied to the detection of sluggish reaction such as electrochemical oxidation of glucose.

Electron Emission From Porous Poly-Silicon Nano-Device for Flat Panel Display (다결정 다공성 실리콘의 전계방출 특성)

  • Lee, Joo-Won;Kim, Hoon;Lee, Yun-Hi;Jang, Jin;Ju, Byeong-Kwon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.4
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    • pp.330-335
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    • 2003
  • This paper reports the optimum structure of the vacuum packaged Porous poly-silicon Nano-Structured (PNS) emitter. The PNS layer was obtained by electrochemical etching process into polycrystalline silicon layer in a process controlled to anodizing condition. Current-voltage studies were carried out to optimize process condition of electron emission properties as a function of anodizing condition and top electrode thickness. Also, we measured in advance the electron emission properties as a function of substrate temperature because the vacuum packaged process was performed under the condition of high temperature ambient (430$^{\circ}C$). Auger Electron Spectrometer (AES) studies shows that Au as a top-electrode was diffused to PNS layer during temperature experiments. Thus, we optimized the thickness of top-electrode in order to make the vacuum package PNS emitter. As a result, the vacuum Packaged PNS emitter was successfully emitted by optimizing process.

A Study on the Corona Discharge Simulation Using FEM-FCT Method (FEM-FCT 기법을 이용한 코로나 방전 시뮬레이션에 대한 연구)

  • Min, Ung-Gi;Kim, Hyeong-Seok;Lee, Seok-Hyeon;Han, Song-Yeop
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.3
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    • pp.200-208
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    • 1999
  • In this paper, the corona discharge is analyzed by Finite Element Method(FEM) combined with Flux-corrected Transport(FCT) algorithm. In the previous papers, Finite Difference Method(FDM) combined with FCT was used. Usually in the FDM, the regionof interest is discretized with structured grids. But to refine local regions with same resolution, much more grids are required for the structured grids than for unstructured grids than for unstructured grids. Therefore, we propose the FEM-FCT method to simulate the corona discharge. The proposed method has good flexibility in model shape and can reduce the computational cost by the local refinement where the physical quantities have steep gradients. Using the proposed method, we study the streamer growth of parallel plate electrodes which is initiated by the low and high perturbation density. We find that the varying the initial density of perturbation has very little effect on the streamer propagation. And the corona discharge of the rod-to-plane electrode is simulated. On the surface of the rod electrode, the high concentration of the electric field gives rise to many number of streamer seeds. The strong axial streamer propagate to the plane electrode. The weaker non-axial streamer repel each other and stop growing more. The results are very similar to those of the papers which used the FDM-FCT method on structured grids. Thus we can conclude that the proposed FEM-FCT method is more efficient than the conventional FDM-FCT method by virtue of the reduction in computational grids number.

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Enhanced Electrical Performance of SiZnSnO Thin Film Transistor with Thin Metal Layer

  • Lee, Sang Yeol
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.3
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    • pp.141-143
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    • 2017
  • Novel structured thin film transistors (TFTs) of amorphous silicon zinc tin oxide (a-SZTO) were designed and fabricated with a thin metal layer between the source and drain electrodes. A SZTO channel was annealed at $500^{\circ}C$. A Ti/Au electrode was used on the SZTO channel. Metals are deposited between the source and drain in this novel structured TFTs. The mobility of the was improved from $14.77cm^2/Vs$ to $35.59cm^2/Vs$ simply by adopting the novel structure without changing any other processing parameters, such as annealing condition, sputtering power or processing pressure. In addition, stability was improved under the positive bias thermal stress and negative bias thermal stress applied to the novel structured TFTs. Finally, this novel structured TFT was observed to be less affected by back-channel effect.

Properties of Urchin-Structured Zinc Oxide Nanorods Gas Sensor by Using Polystyrene Sphere Array (Polystyrene 입자 정렬을 이용한 성게 구조 ZnO 나노막대 가스 센서의 특성)

  • Kim, Jong-Woo;Kim, Do Hoon;Ki, Tae Hoon;Park, Jung Hyuk;Myoung, Jae-Min
    • Korean Journal of Materials Research
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    • v.27 no.12
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    • pp.658-663
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    • 2017
  • Urchin-structured zinc oxide(ZnO) nanorod(NR) gas sensors were successfully demonstrated on a polyimide(PI) substrate, using single wall carbon nanotubes(SWCNTs) as the electrode. The ZnO NRs were grown with ZnO shells arranged at regular intervals to form a network structure with maximized surface area. The high surface area and numerous junctions of the NR network structure was the key to excellent gas sensing performance. Moreover, the SWCNTs formed a junction barrier with the ZnO which further improved sensor characteristics. The fabricated urchin-structured ZnO NR gas sensors exhibited superior performance upon $NO_2$ exposure with a stable response of 110, fast rise and decay times of 38 and 24 sec, respectively. Comparative analyses revealed that the high performance of the sensors was due to a combination of high surface area, numerous active junction points, and the use of the SWCNTs electrode. Furthermore, the urchin-structured ZnO NR gas sensors showed sustainable mechanical stability. Although degradation of the devices progressed during repeated flexibility tests, the sensors were still operational even after 10000 cycles of a bending test with a radius of curvature of 5 mm.

Fabrication of Nano-Channeled Tin Oxide Film Electrode and Evaluation of Its Electrochemical Properties (나노 채널 구조를 가진 산화 주석 박막 전극 제조 및 전기화학적 특성 평가)

  • Park, Su-Jin;Shin, Heon-Cheol
    • Korean Journal of Materials Research
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    • v.22 no.1
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    • pp.1-7
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    • 2012
  • Thin film electrode consisting purely of porous anodic tin oxide with well-defined nano-channeled structure was fabricated for the first time and its electrochemical properties were investigated for application to an anode in a rechargeable lithium battery. To prepare the thin film electrode, first, a bi-layer of porous anodic tin oxides with well-defined nano-channels and discrete nano-channels with lots of lateral micro-cracks was prepared by pulsed and continuous anodization processes, respectively. Subsequent to the Cu coating on the layer, well-defined nano-channeled tin oxide was mechanically separated from the specimen, leading to an electrode comprised of porous tin oxide and a Cu current collector. The porous tin oxide nearly maintained its initial nano-structured character in spite of there being a series of fabrication steps. The resulting tin oxide film electrode reacted reversibly with lithium as an anode in a rechargeable lithium battery. Moreover, the tin oxide showed far more enhanced cycling stability than that of powders obtained from anodic tin oxides, strongly indicating that this thin film electrode is mechanically more stable against cycling-induced internal stress. In spite of the enhanced cycling stability, however, the reduction in the initial irreversible capacity and additional improvement of cycling stability are still needed to allow for practical use.

One-step Microwave Synthesis of Hierarchical Structured LiFePO4 using Citric Acid

  • Wu, Mihye;Choi, Sungho;Kang, Yongku;Jung, Ha-Kyun
    • Bulletin of the Korean Chemical Society
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    • v.35 no.10
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    • pp.2901-2905
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    • 2014
  • The hierarchical-structured $LiFePO_4$ cathode materials were synthesized by one-step microwave synthesis, and their electrochemical properties were investigated. Addition of citric acid during the reaction lead to the formation of hierarchical structured $LiFePO_4$, which has both nano- and micron-characteristics advantageous for energy density and electrode fabrication. Adjusting the molar ratio of Fe to citric acid enhanced the electrochemical properties of $LiFePO_4$.