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Corrosion and Nanomechanical Behaviors of 16.3Cr-0.22N-0.43C-1.73Mo Martensitic Stainless Steel

  • Ghosh, Rahul;Krishna, S. Chenna;Venugopal, A.;Narayanan, P. Ramesh;Jha, Abhay K.;Ramkumar, P.;Venkitakrishnan, P.V.
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.281-289
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    • 2016
  • The effect of nitrogen on the electrochemical corrosion and nanomechanical behaviors of martensitic stainless steel was examined using potentiodynamic polarization and nanoindentation test methods. The results indicate that partial replacement of carbon with nitrogen effectively improved the passivation and pitting corrosion resistance of conventional high-carbon and high- chromium martensitic steels. Post-test observation of the samples after a potentiodynamic test revealed a severe pitting attacks in conventional martensitic steel compared with nitrogen- containing martensitic stainless steel. This was shown to be due to (i) microstructural refinement results in retaining a high-chromium content in the matrix, and (ii) the presence of reversed austenite formed during the tempering process. Since nitrogen addition also resulted in the formation of a $Cr_2N$ phase as a process of secondary hardening, the hardness of the nitrogen- containing steel is slightly higher than the conventional martensitic stainless steel under tempered conditions, even though the carbon content is lowered. The added nitrogen also improved the wear resistance of the steel as the critical load (Lc2) is less, along with a lower scratch friction coefficient (SFC) when compared to conventional martensitic stainless steel such as AISI 440C.

Analysis of difference in elementary-school students' recognition on CS education according to CS education with application of Education Programing Tool (교육용 프로그래밍 도구 활용의 정보과학교육을 통한 초등학생의 정보과학에 대한 인식 분석)

  • Shim, Jae-Kwoun;Kim, Ja-Mee;Lee, Won-Gyu
    • Journal of The Korean Association of Information Education
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    • v.14 no.3
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    • pp.385-393
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    • 2010
  • Elementary information education is currently provided in accordance with the 2000 ICT educational guidelines. Although the focus of education has shifted from practical use to computer science since 2005, in which way academic education should be led isn't yet clear. The purpose of this study was to examine the impacts of computer science education(CS education) by an education programming tool on school children's awareness of that education. The selected students received education about unplugged, scratch and robot programming, part of the computer science curriculum, in 12 sessions. As a result, there were significant differences between the experimental and control groups in all the variables that included attitude to computer science, interest in that, satisfaction level, self-efficacy and perception of the value of CS education. The findings of the study suggested that in CS education, the improvement of thinking faculty should take precedence over practical use of what's learned, which is expected to heighten the value of that education.

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Analysis of Effectiveness of Programming Learning for Non-science Major Preliminary Teachers' Development of Computational Thinking (비전공자 예비교사의 컴퓨팅 사고력 함양을 위한 프로그래밍 교육의 효과성 분석)

  • Han, Youngshin
    • Journal of The Korean Association of Information Education
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    • v.22 no.1
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    • pp.41-52
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    • 2018
  • In Computational thinking is emphasized as a basic learning ability to grow into a key talent in the digital society. There is much interest and discussion on computing education nationally, and the Korean government has also included education in the curriculum. As a result of these changes, the level of computer literacy that preliminary teachers need to be imporved, and the role of computational thinking as a leader in digital society is being emphasized by teachers. Therefore, it is necessary to have a curriculum that can understand computational thinking through various programming learning from preliminary teacher education curriculum. In this study, we designed and taught programming curriculum for non-majored preliminary teachers. Through the developed questionnarie, we analyzed the affect of programming education on the preliminary teacher's development of computational thinking ability.

A Study on Digital Storytelling Based Programming Education (디지털 스토리텔링기반 프로그래밍 교육에 관한 연구)

  • Park, Jung-Ho
    • Journal of the Korea Society of Computer and Information
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    • v.19 no.5
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    • pp.119-128
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    • 2014
  • This study conducted digital storytelling-based programing education targeting students at elementary school and analyzed educational significance as looking into perception on programing, making cognitive-affective assessments and having interviews. The results of the study are provided as follows. First, in terms of ex-post perception, from all the areas of fun, usefulness and ease of use, statistically significant differences were observed. It was also learned that female students have positive perception similar to male students. Second, the ex-ante and ex-post cognitive assessments came up with significant differences. Third, more affectively the class is developed, the number of students who would feel 'happiness' constantly increases. What the study has found there proves educational value of digital storytelling to programing education, and they will be used effectively as basic references for any relevant field to design measures for programing education of students at elementary school in the future.

INTERNATIONAL COLLABORATION FOR SILICON CARBIDE MIRROR POLISHING AND DEVELOPMENT

  • HAN, JEONG-YEOL;CHO, MYUNG;POCZULP, GARY;NAH, JAKYUNG;SEO, HYUN-JOO;KIM, KYUNG-HWAN;TAHK, KYUNG-MO;KIM, DONG-KYUN;KIM, JINHO;SEO, MINHO;LEE, JONGGUN;HAN, SUNG-YEOP
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.687-690
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    • 2015
  • For research and development of Silicon Carbide (SiC) mirrors, the Korea Astronomy and Space Science Institute (KASI) and National Optical Astronomy Observatory (NOAO) have agreed to cooperate and share on polishing and measuring facilities, experience and human resources for two years (2014-2015). The main goals of the SiC mirror polishing are to achieve optical surface figures of less than 20 nm rms and optical surface roughness of less than 2 nm rms. In addition, Green Optics Co., Ltd (GO) has been interested in the SiC polishing and joined the partnership with KASI. KASI will be involved in the development of the SiC polishing and the optical surface measurement using three different kinds of SiC materials and manufacturing processes (POCO$^{TM}$, CoorsTek$^{TM}$ and SSG$^{TM}$ corporations) provided by NOAO. GO will polish the SiC substrate within requirements. Additionally, the requirements of the optical surface imperfections are given as: less than 40 um scratch and 500 um dig. In this paper, we introduce the international collaboration and interim results for SiC mirror polishing and development.

Characteristics of Sapphire Wafers Polishing Depending on Ion Conductivity of Silica Sol (실리카졸의 이온전도도 변화에 따른 사파이어 웨이퍼의 연마 특성)

  • Na, Ho Seong;Cho, Gyeong Sook;Lee, Dong-Hyun;Park, Min-Gyeong;Kim, Dae Sung;Lee, Seung-Ho
    • Korean Journal of Materials Research
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    • v.25 no.1
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    • pp.21-26
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    • 2015
  • CMP(Chemical Mechanical Polishing) Processes have been used to improve the planarization of the wafers in the semiconductor manufacturing industry. Polishing performance of CMP Process is determined by the chemical reaction of the liquid sol containing abrasive, pressure of the head portion and rotational speed of the polishing pad. However, frictional heat generated during the CMP process causes agglomeration of the particles and the liquidity degradation, resulting in a non-uniform of surface roughness and surface scratch. To overcome this chronic problem, herein, we introduced NaCl salt as an additive into silica sol for elimination the generation of frictional heat. The added NaCl reduced the zata potential of silica sol and increased the contact surface of silica particles onto the sapphire wafer, resulting in increase of the removal rate up to 17 %. Additionally, it seems that the silica particles adsorbed on the polishing pad decreased the contact area between the sapphire water and polishing pad, which suppressed the generation of frictional heat.

Properties of Sputter Deposited Cr Thin Film on Polymer Substrate by Glancing Angle Deposition (폴리머 기판에 스퍼터법으로 경사 증착한 Cr박막의 특성)

  • Bae, Kwang-Jin;Choi, In-Kyun;Jeong, Eun-Wook;Kim, Dong-Yong;Lee, Tae-Yong;Cho, Young-Rae
    • Korean Journal of Materials Research
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    • v.25 no.1
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    • pp.54-59
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    • 2015
  • Glancing angle deposition (GLAD) is a powerful technique to control the morphology and microstructure of thin film prepared by physical vapor deposition. Chromium (Cr) thin films were deposited on a polymer substrate by a sputtering technique using GLAD. The change in thickness and Vickers microhardness for the samples was observed with a change in the glancing angle. The adhesion properties of the critical load (Lc) by a scratch tester for the samples were also measured with varying the glancing angle. The critical load, thickness and Vickers microhardness for the samples decreased with an increase in the glancing angle. However, the thickness of the Cr thin film prepared at a $90^{\circ}$ glancing angle showed a relatively large value of 50 % compared to that of the sample prepared at $0^{\circ}$. The results of X-ray diffraction and scanning electron microscopy demonstrated that the effect of GLAD on the microstructure of samples prepared by sputter technique was not as remarkable as the samples prepared by evaporation technique. The relatively small change in thickness and microstructure of the Cr thin film is due to the superior step-coverage properties of the sputter technique.

An Incremental Method Using Sample Split Points for Global Discretization (전역적 범주화를 위한 샘플 분할 포인트를 이용한 점진적 기법)

  • 한경식;이수원
    • Journal of KIISE:Software and Applications
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    • v.31 no.7
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    • pp.849-858
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    • 2004
  • Most of supervised teaming algorithms could be applied after that continuous variables are transformed to categorical ones at the preprocessing stage in order to avoid the difficulty of processing continuous variables. This preprocessing stage is called global discretization, uses the class distribution list called bins. But, when data are large and the range of the variable to be discretized is very large, many sorting and merging should be performed to produce a single bin because most of global discretization methods need a single bin. Also, if new data are added, they have to perform discretization from scratch to construct categories influenced by the data because the existing methods perform discretization in batch mode. This paper proposes a method that extracts sample points and performs discretization from these sample points in order to solve these problems. Because the approach in this paper does not require merging for producing a single bin, it is efficient when large data are needed to be discretized. In this study, an experiment using real and synthetic datasets was made to compare the proposed method with an existing one.

Pulsed Magnetron Sputtering Deposit ion of DLC Films Part I : Low-Voltage Bias-Assisted Deposition

  • Oskomov, Konstantin V.;Chun, Hui-Gon;You, Yong-Zoo;Lee, Jing-Hyuk;Kim, Kwang-Bok;Cho, Tong-Yul;Sochogov, Nikolay S.;Zakharov, Alexender N.
    • Journal of the Korean institute of surface engineering
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    • v.36 no.1
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    • pp.27-33
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    • 2003
  • Pulsed magnetron sputtering of graphite target was employed for deposition of diamond-like carbon (DLC) films. Time-resolved probe measurements of magnetron discharge plasma have been performed. It was shown that the pulsed magnetron discharge plasma density ($∼10^{17}$ $m^{-3}$ ) is close to that of vacuum arc cathode sputtering of graphite. Raman spectroscopy was sed to examine DLC films produced at low ( $U_{sub}$ / < 1 kV) pulsed bias voltages applied to the substrate. It has been shown that maximum content of diamond-like carbon in the coating (50-60%) is achieved at energy per deposited carbon atom of $E_{c}$ =100 eV. In spite of rather high percentage of $sp^3$-bonded carbon atoms and good scratch-resistance, the films showed poor adhesion because of absence of ion mixing between the film and the substrates. Electric breakdowns occurring during the deposition of the insulating DLC film also thought to decrease its adhesion.

Effect of Anode Voltage on Diamond-like Carbon Thin Film Using Linear Ion Source (Linear Ion Source를 이용한 Anode Voltage 변화에 따른 DLC 박막특성)

  • Kim, Wang-Ryeol;Jung, Uoo-Chang;Jo, Hyung-Ho;Park, Min-Suk;Chung, Won-Sub
    • Journal of the Korean institute of surface engineering
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    • v.42 no.4
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    • pp.179-185
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    • 2009
  • Diamond-like carbon(DLC) films were deposited by linear ion source(LIS)-physical vapor deposition method changing the anode voltages from 800 V to 1800 V, and characteristics of the films were investigated using residual stress tester, nano-indentation, micro raman spectroscopy, scratch tester and Field Emission Scanning Electron Microscope(FE-SEM). The results showed that the residual stress and hardness increased with increasing the ion energy up to anode voltage of 1400 V. It was also found that the content of $SP^3$ carbon increased with increasing the anode voltage $SP^3/SP^2$ ratio through investigation of $SP^3/SP^2$ ratio by the micro-raman analysis. From these results, it can be concluded that the physical properties of DLC films such as residual stress and hardness are increased with increasing the anode voltage. These results can be explained that 3-dimensional cross-links between carbon atoms and Dangling bond are enhanced and the internal compressive stress also increased with increasing the anode voltage. The optimal anode voltage is considered to be around 1400 V in these experimental conditions.