• Title/Summary/Keyword: reversibility

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The Time Responses of Spirometric Values in Response to Single Doses of Inhaled Salbutamol (기관지확장제 사용 후 시간에 따른 폐활량 측정치의 변화)

  • Park, Sun Hyo;Choi, Won-Il;Lee, Sang Won;Park, Hun Pyo;Seo, Yong Woo;Ku, Duk Hee;Lee, Mi Young;Lee, Choong Won;Jeon, Young June
    • Tuberculosis and Respiratory Diseases
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    • v.56 no.2
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    • pp.144-150
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    • 2004
  • Background : An assessment of the presence and the degree of reversibility of airflow obstruction is clinically important in patients with asthma or chronic obstructive pulmonary disease. However, the time responses of spirometric parameters in response to bronchodilator have not been well investigated. Methods: We studied 15 patients with asthma. Spirometric and mini-Wright peak expiratory flow measurements were performed at 15, 30, 45, and 60 minutes after using single dose($200{\mu}g$) of inhaled bronchodilator, salbutamol. Results : The mean values of forced expiratory volume in one second($FEV_1$) and forced vital capicaty(FVC) were significantly increased at 60 minutes after using bronchodilator in comparison to 15 minutes. And peak expiratory flow rate measured by either mass flow sensor or mini-Wright peak flow meter were significantly increased at 45 minutes after using bronchodilator in comparison to 15 minutes. Conclusions : To appropriate evaluation of the bronchodilator response in patients with reversible airflow limitation, it would be useful measuring either $FEV_1$ or PEF at the later time point 60 or 45 minutes in comparison to 15 minutes after using bronchodilator.

Study on the Urethane Restoration Filling Material and Adhesive for Stone Cultural Heritage (석조문화재 복원용 우레탄 메움제 및 접착제에 관한 연구)

  • Han, Won-Sik;Lee, Ho-Youn;Park, Gi-Jung;Hong, Tae-Kee;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.27 no.1
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    • pp.115-121
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    • 2011
  • A Urethane resin restoration material was made to be used in the restoration of stone cultural assets. The Urethane resin restoration material showed strong adhesive strength and tensile strength similar to epoxy recovery material, which had been mainly used for the recovery of stone cultural assets. The sealing property, anti-shrinking property and paint-ability of Urethane resin restoration material are also similar to existing epoxy system restoration materials. Especially, this Urethane resin restration material is expected to give permanence and continuous stability in the restoration of cultural assets made in stone by resolving the two big issues of existing epoxy recovery material, which are 'yellowing' and 'ir-reversibility'. This Urethane resin restration material had been directly applied as a filling material and adhesive and it was dissolved again. The Urethane resin, which had been used for the recovery, was able to be perfectly removed, which means that this Urethane resin recovery material has perfect reversibility. This Urethane resin restoration material also has enhanced convenience since user can adjust the working-life dependent on work environment. It is believed that this Urethane resin restoration material can also be used as a filling material or adhesive for other cultural assets made of ceramic or metal heritage, in addition to stone, since it has strong adhesive strength and tensile strength.

The Principles of Learning and Education involved in Xugua zhuan, the Sequence of the Hexagrams in I Ching (「서괘전」에 함의된 공부의 관점 - 태괘(泰卦)에서 이괘(離卦)까지를 중심으로 -)

  • Kim, Jeong-Nae
    • The Journal of Korean Philosophical History
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    • no.59
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    • pp.155-190
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    • 2018
  • The paper has focused on the 20 Iching-hexagrams from the eleventh t'ai[ ] to the final one of the Upper Book li[離] to examine the principles of learning and education involved in Xugua zhuan[序卦傳], the Ordinal Sequence of the Hexagrams as one among Ten Wings in I Ching. Some implications involved in this part of the Book of Change provides us with numerous teachings and educational principles. I try to concisely note the three teachings of the major argument as shown in the paper. Firstly, we should take the process of learning as the circular system of thought[環 相型], not as the linear system assuming the final destination like the Final Cause in the Aristotelian teleology. In the same token, the process of learning should be regarded as 'initiation', which has been initially adopted to justify the concept of education by R. S. Peters. As a circular system, there are two kinds of initiation. The one sense is 'crossing the threshold of illiteracy' seen as 'small initiation', which apprehends the points of argument in the previous paper, namely, on hexagrams from ch'ien[乾] to t'ai[泰]. The other sense is 'getting on the inside of the worthwhile activities', seen as 'Grand Initiation', which apprehend the present points of argument. Secondly, as shown in the paper, the Book enables us to recognize the process of learning as 'Seeing What Is There'. This requires us the Principles of Mean and Perfection, which are to be taken differently from the Western ones. For this a learner should always hold the endless self-reflection and attitude to re-examine the original intention of one's own, whilst he is involved in the task of learning. Finally, we should take the Principles of Change seriously, such as extremity-reversibility[物極必反] and the sense of conformity, in order that we can establish the proper educational principles to tackle the social domains of learning as well as the personal ones.

The Stability of Aging and Synthetic Development of Paper Mending Tape for Conservation of Archive Document (종이 기록물 보수용 테이프 점착제 합성 및 열화 안전성 연구)

  • Shin, Joung-Soon;Lee, Kwi-Bok
    • Journal of the Korean Graphic Arts Communication Society
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    • v.30 no.1
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    • pp.35-45
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    • 2012
  • Polyacrylate dispersion(emulsion) as adhesive material was superior in quality such as preservation characteristics and reversibility. The tapes for repairing archival documents manufactured with four different types of formulation resulted in pH 7~8.8, soluble solid 50~52%, and viscosity 1,300~2,500 cps. Sample 4 of those was most excellent. Probably, sample 4 included inorganic materials such as MgO, silica gel, and zeolite. For selecting carrier of tape, tracing papers, were applied for manufacturing tapes and tested for adhesive strength and peel strength. Adhesive strength of tracing papers, was 3.1~3.8(N/10mm), 2.2~2.8(N/10mm), and 1.7-2.3(N/10mm), respectively. Peel strength was similar in all samples. To determine characteristic of conservation to the selected carriers, stability of deterioration was examined at conditions of $105^{\circ}C$ and $80^{\circ}C$ 65% for 7 days.

Methyl Viologen Mediated Oxygen Reduction in Ethanol Solvent: the Electrocatalytic Reactivity of the Radical Cation

  • Lin, Qianqi;Li, Qian;Batchelor-McAuley, Christopher;Compton, Richard G.
    • Journal of Electrochemical Science and Technology
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    • v.4 no.2
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    • pp.71-80
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    • 2013
  • The study of methyl viologen ($MV^{2+}$) mediated oxygen reduction in electrolytic ethanol media possesses potential application in the electrochemical synthesis of hydrogen peroxide mainly due to the advantages of the much increased solubility of molecular oxygen ($O_2$) and high degree of reversibility of $MV^{2+/{\bullet}+}$ redox couple. The diffusion coefficients of both $MV^{2+}$ and $O_2$ were investigated via electrochemical techniques. For the first time, $MV^{2+}$ mediated $O_2$ reduction in electrolytic ethanol solution has been proved to be feasible on both boron-doped diamond and micro-carbon disc electrodes. The electrocatalytic response is demonstrated to be due to the radical cation, $MV^{{\bullet}+}$. The homogeneous electron transfer step is suggested to be the rate determining step with a rate constant of $(1{\pm}0.1){\times}10^5M^{-1}s^{-1}$. With the aid of a simulation program describing the EC' mechanism, by increasing the concentration ratio of $MV^{2+}$ to $O_2$ electrochemical catalysis can be switched from a partial to a 'total catalysis' regime.

Enhanced Electrochemical Properties of Surface Modified LiMn2O4 by Li-Fe Composites for Rechargeable Lithium Ion Batteries

  • Shi, Jin-Yi;Yi, Cheol-Woo;Liang, Lianhua;Kim, Keon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.2
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    • pp.309-314
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    • 2010
  • The surface modified $LiMn_2O_4$ materials with Li-Fe composites were prepared by a sol-gel method to improve the electrochemical performance of $LiMn_2O_4$ and were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), and transmission electron microscopy (TEM)-EDS. XRD results indicate that all the samples (modified and pristine samples) have cubic spinel structures, and XRD, XPS, and TEM-EDS data reveal the formation of $Li(Li_xFe_xMn_{2-2x})O_4$ solid solution on the surface of particles. For the electrochemical properties, the modified material demonstrated dramatically enhanced reversibility and stability even at elevated temperature. These improvements are attributed to the formation of the solid solution, and thus-formed solid solution phase on the surface of $LiMn_2O_4$ particle reduces the dissolution of Mn ion and suppresses the Jahn-Teller effect.

Physicochemical and Electrochemical Characteristics of Carbon Nanomaterials and Carbon Nanomaterial-Silicon Composites

  • Kim, Soo-Jin;Hyun, Yura;Lee, Chang-Seop
    • Journal of the Korean Chemical Society
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    • v.60 no.5
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    • pp.299-309
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    • 2016
  • In this study, the physicochemical and electrochemical properties of carbon nanomaterials and synthesized nano-carbon/Si composites were studied. The nano-carbon/Si composites were ball-milled to a nano size and coated with pyrolytic carbon using Chemical Vapor Deposition (CVD). They were then finely mixed with respective nano-carbon materials. The physicochemical properties of samples were analyzed using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDS), Raman spectroscopy, X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), and surface area analyzer. The electrochemical characteristics were investigated using the galvanostatic charge-discharge and cyclic voltammetry (CV) measurements. Three-electrode cells were fabricated using the carbon nanomaterials and nano-carbon/Si composites as anode materials and LiPF6 and LiClO4 as electrolytes of Li secondary batteries. Reversibility using LiClO4 as an electrolyte was superior to that of LiPF6 as the electrolyte. The initial discharge capacities of nano-carbon/Si composites were increased compared to the initial discharge capacities of nano-carbon materials.

Polarographic Behavior of Azo Series Organic Compounds (Ⅰ). Reduction of 4-(2-Pyridylazo)resorcinol in Acetonitrile (Azo계 유기화합물의 폴라로그래프법적 거동 (제1보). 아세토니트릴 중에서 4-(2-Pyridylazo) resorcinol의 환원)

  • Heung Lark Lee;Zun Ung Bae
    • Journal of the Korean Chemical Society
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    • v.26 no.6
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    • pp.389-395
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    • 1982
  • The polarographic behavior of 4-(2-pyridylazo)-resorcinol(PAR) in acetonitrile solution was studied. In order to investigate the type of reduction current at every reduction step, dependence of limiting current on the height of mercury head, solution temperature, and concentration of PAR have been examined. The results were shown that the reduction current was controlled by diffusion. And the effect of proton donor such as water and phenol on DC polarograms of PAR and the reversibility of every reduction wave have been evaluated. Based on the experimental results, the polarographic reduction of PAR in acetonitrile solution occurred in two one-electron steps.

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The Stable Rechargeability of Secondary Zn-Air Batteries: Is It Possible to Recharge a Zn-Air Battery?

  • Lee, Sang-Heon;Jeong, Yong-Joo;Lim, Si-Hyoun;Lee, Eun-Ah;Yi, Cheol-Woo;Kim, Keon
    • Journal of the Korean Electrochemical Society
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    • v.13 no.1
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    • pp.45-49
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    • 2010
  • The rechargeable Zn-air battery is considered as one of the potential candidates for the next generation secondary batteries due to its many advantages. However, its further applications and commercialization have been limited by the complexity of the reactions on air electrode which are oxygen reduction and evolution reactions (ORR/OER) upon discharging and charging processes, respectively. In the present study, lanthanum was impregnated into a commercial Pt/C gas diffusion electrode, and it clearly verified significantly enhanced cycling stability and reversibility. The results presented in this study show the possibility of repeated charge/discharge processes for Zn-air batteries with a La-loaded air electrode, and they demonstrate the potential as a promising next generation secondary battery.

Hydrolytic Behavior of Vinylsulfonyl Reactive Dyes - Easiness of Dimerization -

  • Kim, In Hoi
    • Textile Coloration and Finishing
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    • v.27 no.1
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    • pp.1-10
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    • 2015
  • The aim of the current study is to identify the dimerization and decomposition kinetics of the F-$D_M$ type. The regeneration of F-VS from $F_iF_j-D_M$ or the reversibility of the dimerizations were investigated. The order of real rate constants of the dimerization('$K_D{^{ij}}$) would seem to be similar to that of rate constants of a dimerization($K_D{^{ij}}$) for VS dyes at a given pH because of the constancy of the equilibrium constants($K_a{^j}$-value). The reverse reactions of the $D_M$ types are appeared to occur in two steps, the deprotonation of ${\alpha}$-carbon of the $D_M$ types and disproportionation. The ratio of the decomposition of the $D_M$ type to F-Hy and F-VS appears to be related with the ratio of $K_i/K_j$. Similarities were also found among various other reactions, including homo- and mixed dimerization. VS dyes undergoing fast hydrolysis have difficulty in forming a dimer. The higher the reactivity with cellulose or hydroxide ion, the smaller the dimerization. The easiness of the dimerization was thus found to be inversely proportional to the rate of hydrolysis.