• 제목/요약/키워드: rapid thermal annealing

검색결과 571건 처리시간 0.025초

Effect of Dry Process on Dielectric Properties of PZT Thin Films Prepared by Sol-Gel Process

  • Bae, Min-Ho;Lim, Kee-Joe;Kim, Hyun-Hoo;No, Kwang-soo
    • Transactions on Electrical and Electronic Materials
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    • 제3권1호
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    • pp.42-45
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    • 2002
  • Properties of lead zirconate titanate ferroelectric thin films prepared by rapid thermal annealing/direct insertion thermal annealing were investigated. The remnant polarization (Pr), saturation polarization (Ps), and coercive force (Ec) of typical samples annealed by rapid thermal annealing (RTA) are about 13.7 $\mu$ C/cm$^2$, 27.1 $\mu$C/cm$^2$, and 55.6 kV/cm, respectively. The dielectric constant of the sample is about 786, the dielectric loss tangent is about 2.4% at 1 kHz. Furthermore, ferroelectric, conduction, and piezoelectric properties of the thin films annealed by RTA process and the direct insertion thermal annealing (DITA) process were compared. The influence of temperature in the dry process on the above properties was also investigated.

Ion Beam Mixing과 급속열처리 방법을 이용한 Ti-SALICIDE용 $TiSi_2$ 박막 개선에 관한 연구 (Study on the Improvement of $TiSi_2$ film for Ti-SALICIDE Process Using Ion Beam Mixing and Rapid Thermal Annealing)

  • 최병선;구경완;천희곤;조동율
    • 한국진공학회지
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    • 제1권1호
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    • pp.168-175
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    • 1992
  • Ion beam mixing과 질소분위기에서 Rapid Thermal Annealing을 이용하여 형성된 TiSi2 박막의 표면과 계면의 물리적, 전기적 특성이 크게 개선되었으며, 기존 Ti-SALICIDE 의 신뢰도 측면에서 문제가 될 수 있는 Oxide Spacer 상에서의 Lateral Silicide 형성이 최 대한 억제된 수 있었다. 또한 Ti-SALICIDE 공정에서의 Ti/Si와 Ti/SiO2의 Interaction을 반응 조건별로 연구하였다.

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MgO 절연막을 갖는 자기 터널 접합구조에서의 급속 열처리 효과 (Rapid Theraml Annealing Effect on the Magnetic Tunnel Junction with MgO Tunnel Barrier)

  • 민길준;이경일;김태완;장준연
    • 한국자기학회지
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    • 제25권2호
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    • pp.47-51
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    • 2015
  • 이 연구에서는 DC스퍼터링(DC Magnetron Sputtering)방식으로 제작 된 MgO 터널 장벽층을 갖는 자기터널접합을 급속 열처리 방식(Rapid Thermal Annealing)을 이용하여 열처리 공정 중의 구조적, 조성적 변화 및 스핀 수송 특성의 변화를 연구하였다. 본 연구를 통하여 급속 열처리 방식이 기존 일반적인 열처리 방식에 비하여 높은 터널링자기저항비를 얻을 수 있다는 것을 발견하였다. 또한, 열처리 시간의 단축을 통하여 Mn, Ta, Ru 등의 내부물질의 인접한 층으로의 확산을 억제할 수 있다는 것을 알 수 있었다. 유의미한 데이터를 수집하기 위하여 다양한 열처리 온도 조건과 시간조건에서 급속 열처리를 실시 한 후 자기 터널 접합의 전, 자기적 특성을 관찰하였다. 이러한 특성 변화는 향후 보다 우수하고 안정적인 자기적 특성과 열적 안정성을 갖는 자기터널접합 제작을 위해 다양하게 응용될 수 있다고 생각된다.

ECR plasma로 전처리된 Cu seed층 위에 전해도금 된 Cu 막에 대한 Annealing의 효과 (Effects of Post-deposition Annealing on the Copper Films Electrodeposited on the ECR Plasma Cleaned Copper Seed Layer)

  • 이한승;권덕렬;박현아;이종무
    • 한국재료학회지
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    • 제13권3호
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    • pp.174-179
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    • 2003
  • Thin copper films were grown by electrodeposition on copper seed layers which were grown by sputtering of an ultra-pure copper target on tantalum nitride-coated silicon wafers and subsequently, cleaned in ECR plasma. The copper films were then subjected to ⅰ) vacuum annealing, ⅱ) rapid thermal annealing (RTA) and ⅲ) rapid thermal nitriding (RTN) at various temperatures over different periods of time. XRD, SEM, AFM and resistivity measurements were done to ascertain the optimum heat treatment condition for obtaining film with minimum resistivity, predominantly (111)-oriented and smoother surface morphology. The as-deposited film has a resistivity of ∼6.3 $\mu$$\Omega$-cm and a relatively small intensity ratio of (111) and (200) peaks. With heat treatment, the resistivity decreases and the (111) peak becomes dominant, along with improved smoothness of the copper film. The optimum condition (with a resistivity of 1.98 $\mu$$\Omega$-cm) is suggested as the rapid thermal nitriding at 400oC for 120 sec.

Effect of Rapid Thermal Annealing on the Ti doped In2O3 Films Grown by Linear Facing Target Sputtering

  • Seo, Ki-Won;Kim, Han-Ki
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.342.1-342.1
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    • 2014
  • The electrical, optical and structural properties of Ti doped $In_2O_3$ (TIO) ohmic contacts to p-type GaN were investigated using linear facing target sputtering (LFTS) system. Sheet resistance and resistivity of TIO films are decreased with increasing rapid thermal annealing (RTA) temperature. Although the $400^{\circ}C$ and $500^{\circ}C$ annealed samples showed rectifying behavior, the $600^{\circ}C$ and $700^{\circ}C$ annealed samples showed linear I-V characteristics indicative of the formation of an ohmic contact between TIO and p-GaN. The annealing of the contact at $700^{\circ}C$ resulted in the lowest specific contact resistivity of $9.5{\times}10^{-4}{\Omega}cm^2$. Based on XPS depth profiling and synchrotron X-ray scattering analysis, we suggested a possible mechanism to explain the annealing dependence of the properties of TIO layer on rapid thermal annealing temperature.

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급속 열처리 장치를 이용한 실리콘 산화막의 Annealing 효과 (Effects of Annealing on Silicon Dioxide using Rapid Thermal Process System)

  • 박현우;장현룡;황호정
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1988년도 전기.전자공학 학술대회 논문집
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    • pp.383-386
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    • 1988
  • In MOS integrated circuits, annealing after oxidation process is necessary to improve physical properties of silicon dioxide. With subsequent annealing in inert gases such as nitrogen or argon, and excess silicon bond is allowed time to complete the oxidation and surface charge density is reduced. In this paper, we will present effects of the rapid thermal annealing on silicon dioxide. In order to evaluate characteristics of silicon dioxide, we analyzed C-V curve dependent on annealing time and temperature, and presented variation of fixed oxide charge.

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급속열처리에 따른 ZTO/Ag/ZTO 박막의 전기적, 광학적 특성 개선 효과 (Effect of Post-deposition Rapid Thermal Annealing on the Electrical and Optical Properties of ZTO/Ag/ZTO Tri-layer Thin Films)

  • 송영환;엄태영;허성보;김대일
    • 열처리공학회지
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    • 제30권4호
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    • pp.151-155
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    • 2017
  • The ZTO single layer and ZTO/Ag/ZTO tri-layer films were deposited on glass substrates by using the radio frequency (RF) and direct current (DC) magnetron sputtering and then rapid thermal annealed (RTA) in a low pressure condition for 10 minutes at 150 and $300^{\circ}C$, respectively. As deposited tri-layer films show the 81.7% of visible transmittance and $4.88{\times}10^{-5}{\Omega}cm$ of electrical resistivity, while the films annealed at $300^{\circ}C$ show the increased visible transmittance of 82.8%. The electrical resistivity also decreased as low as $3.64{\times}10^{-5}{\Omega}cm$. From the observed results, it is concluded that rapid thermal annealing (RTA) is an attractive post-deposition process to optimize the opto-elecrtical properties of ZTO/Ag/ZTO tri-layer films for the various display applications.

급속 열처리 온도 변화에 따른 AZO 박막의 구조, 전기 및 광학적 특성 (Structural, Electrical, and Optical Properties of AZO Thin Films Subjected to Rapid Thermal Annealing Temperature)

  • 정재용;조신호
    • 한국전기전자재료학회논문지
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    • 제23권4호
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    • pp.280-286
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    • 2010
  • We have investigated the influence of rapid thermal annealing (RTA) temperature on properties of Al-doped zinc oxide (AZO) thin films deposited on glass substrate by using radio-frequency magnetron sputtering. The RTA is performed in a nitrogen ambient in the temperature range from 300 to $600^{\circ}C$ for 1 minute in a rapid thermal annealer after growing the AZO thin films. The crystallographic structure and the surface morphology of AZO thin film are measured by using X-ray diffraction, and atomic force microscopy and scanning electron microscopy, respectively. The optical transmittance of the deposited thin films is examined in the wavelength range of 300-1100 nm, where the average transmittance is above the 90% in the visible and near-infrared regions. The optical bandgap is calculated from the Tauc's model, and it shows a significant dependence on the RTA temperature. As for the electrical properties of the thin films, the AZO thin film annealed at $400^{\circ}C$ shows the lowest electrical resistivity of $8.6{\times}10^{-3}{\Omega}cm$ and the Hall mobility of $11.3cm^2$/V-sec. These results suggest that the RTA temperature is an important parameter to influence on the structural, electrical, and optical properties of AZO thin films.

산소플라즈마와 급속열처리에 의해 제조된 티타니아 박막의 휴믹산 제거 (Removal of Humic Acid Using Titania Film with Oxygen Plasma and Rapid Thermal Annealing)

  • 장준원;박재우
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제12권3호
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    • pp.29-35
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    • 2007
  • 본 연구에서는 산소플라즈마로 티타늄을 산화하고 급속열처리하여 티타니아 광촉매 박막을 제조하고 휴믹산 제거실험을 수행하였다. 플라즈마 화학기상증착장치에서의 산소플라즈마는 티타늄 표면을 산화시킴으로써 광촉매 피막을 생성하게 된다. 증착조건에서 RF power는 최대 500 W 이하에서 100 W, 150 W, 300 W, 처리시간은 5분, 10분에서 조절되었다. 박막의 특성은 XPS와 XRD로 측정하였다. 실험으로서 우리는 박막이 높은 성능을 나타내는 최적을 조건을 찾았다. 또한 제조된 박막의 경우 기존 Thermal spray Titania film에 비해 2배정도 우수하였고 분말만큼 광촉매 성능을 갖는다.

Fabrication of Cu2ZnSnS4 Films by Rapid Thermal Annealing of Cu/ZnSn/Cu Precursor Layer and Their Application to Solar Cells

  • Chalapathy, R.B.V.;Jung, Gwang Sun;Ko, Young Min;Ahn, Byung Tae;Kwon, HyukSang
    • Current Photovoltaic Research
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    • 제1권2호
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    • pp.82-89
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    • 2013
  • $Cu_2ZnSnS_4$ thin film have been fabricated by rapid thermal annealing of dc-sputtered metal precursor with Cu/ZnSn/Cu stack in sulfur ambient. A CZTS film with a good uniformity was formed at $560^{\circ}C$ in 6 min. $Cu_2SnS_3$ and $Cu_3SnS_4$ secondary phases were present at $540^{\circ}C$ and a trace amount of $Cu_2SnS_3$ secondary phase was present at $560^{\circ}C$. Single-phase large-grained CZTS film with rough surface was formed at $560^{\circ}C$. Solar cell with best efficiency of 4.7% ($V_{oc}=632mV$, $j_{sc}=15.8mA/cm^2$, FF = 47.13%) for an area of $0.44cm^2$ was obtained for the CZTS absorber grown at $560^{\circ}C$ for 6 min. The existence of second phase at lower-temperature annealing and rough surface at higher-temperature annealing caused the degradation of cell performance. Also poor back contact by void formation deteriorated cell performance. The fill factor was below 0.5; it should be increased by minimizing voids at the CZTS/Mo interface. Our results suggest that CZTS absorbers can be grown by rapid thermal annealing of metallic precursors in sulfur ambient for short process times ranging in minutes.