• Title/Summary/Keyword: polymer fibers

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Investigating the performance of polymer cement resistance in football stadium construction

  • Yangguang Zhang
    • Advances in concrete construction
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    • v.15 no.3
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    • pp.203-213
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    • 2023
  • New techniques, technologies, and materials should be used to design and build sports stadiums. Since this century, much progress has been made in covering the roofs of sports stadiums, and the possibility of accurate computer calculation has been provided for stadiums, so by choosing a new structure, we can double the beauty and resistance of these stadiums. A stadium has an excellent and valuable design when its structure, shell, building, materials, and joinery follow a high architectural idea at all levels and scales. This article examines the mechanical performance of polymer cement strength in the construction of football stadiums, along with their structural knowledge in the form of the best examples in the world. Portland cement is one of the most used materials for constructing football stadiums. However, its production requires spending a lot of money, wasting energy, and damaging the environment. Considering the disadvantages in the production and consumption of concrete in different environments, it is necessary to find alternative materials. It should be used with cheaper, simpler technology, abundant primary resources, energy saving, less environmental damage, and better chemical and physical properties in concrete. High-strength concrete technology is considered a new development in the construction industry of concrete structures. In hardened concrete, strength and durability are two main factors, and as the compressive strength of concrete increases, concrete becomes more brittle. As a result, its tensile strength does not increase in proportion to the increase in compressive strength and has less strain tolerance. For this reason, the need to use is evident from the fibers in high-strength concrete. Fibers are used in concrete to increase tensile strength, prevent crack propagation, and significantly increase softness. The increase with the change of these resistances depends on the strength of concrete without fibers, the shape of fibers, and the percentage of fibers. This cement is obtained from the wastes of chemical and petrochemical industries and the wastes from coal combustion, which have the properties mentioned as substitutes for Portland cement.

Studies of Degradation Behavior of Stereochemical Poly(lactide) Blend Fibers Prepared by Electrospinning (전기방사에 의한 이성질 폴리락타이드 블렌드의 섬유제조와 분해거동에 관한 연구)

  • Jang, Ei-Sup;Lee, Won-Ki
    • Journal of Environmental Science International
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    • v.23 no.3
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    • pp.473-481
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    • 2014
  • Poly(lactide)s(PLA) is an attractive material to solve the problem of waste plastic accumulation in nature because of its biodegradability. The lactide exists in three stereoisomeric configurations: L-lactide, D-lactide, and meso-lactide. PLA stereocomplexes, formed by the mixing of two enantiomers, poly(L-lactide)(PLLA) and poly(D-lactide)(PDLA), have many favorable characteristics because the stereocomplex showed $50^{\circ}C$ higher melting point than each enantiomeric polymer and the resistance toward degradation increased. In this study, we investigated the influence of the composition and the optical purity of each component on the formation of stereocomplexes. Also, the nanofibers of stereochemical PLA and their blends were prepared by electrospinning method. The properties of the obtained fibers were analyzed by differential scanning calorimetry and scanning electron microscopy. The results showed that a degree of stereocomplex was controlled by change of optical purity of each component. The enzymatic degradation of the fibers were strongly dependent on the stereocomplex.

Regulation of precursor solution concentration for In-Zn oxide thin film transistors

  • Chen, Yanping;He, Zhongyuan;Li, Yaogang;Zhang, Qinghong;Hou, Chengyi;Wang, Hongzhi
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1300-1305
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    • 2018
  • The tunable electronic performance of the solution-processed semiconductor metal oxide is of great significance for the printing electronics. In current work, transparent thin-film transistors (TFTs) with indium-zinc oxide (IZO) were fabricated as active layer by a simple eco-friendly aqueous route. The aqueous precursor solution is composed of water without any other organic additives and the IZO films are amorphous revealed by the X-ray diffraction (XRD). With systematic studies of atomic force microscopy (AFM), X-ray photoemission spectroscopy (XPS) and the semiconductor property characterizations, it was revealed that the electrical performance of the IZO TFTs is dependent on the concentration of precursor solution. As well, the optimum preparation process was obtained. The concentrations induced the regulation of the electronic performance was clearly demonstrated with a proposed mechanism. The results are expected to be beneficial for development of solution-processed metal oxide TFTs.

Influence of Oxyfluorination on Physicochemical Characteristics of Carbon Fibers and their Reinforced Epoxy Composites

  • Seo, Min-Kang;Park, Soo-Jin
    • Macromolecular Research
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    • v.17 no.6
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    • pp.430-435
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    • 2009
  • The effect of oxyfluorination temperature on the surface properties of carbon fibers and their reinforced epoxy composites was investigated. Infrared (IR) spectroscopy results for the oxyfluorinated carbon fibers revealed carboxyl/ester (C=O) and hydroxyl (O-H) groups at 1632 and 3450 $cm^{-1}$, respectively, and that the oxyfluorinated carbon fibers had a higher O-H peak intensity than that of the fluorinated ones. X-ray photoelectron spectroscopy (XPS) results indicated that after oxyfluorination, graphitic carbon was the major carbon functional component on the carbon fiber surfaces, while other functional groups present were C-O, C=O, HO-C=O, and $C-F_x$. These components improved the impact properties of oxyfluorinated carbon fibers-reinforced epoxy composites by improving the interfacial adhesion between the carbon fibers and the epoxy matrix resins.

Thermal and Mechanical Properties of Short Fiber-Reinforced Epoxy Composites (단섬유 강화 에폭시 복합재료의 열적/기계적 특성)

  • Huang, Guang-Chun;Lee, Chung-Hee;Lee, Jong-Keun
    • Polymer(Korea)
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    • v.33 no.6
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    • pp.530-536
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    • 2009
  • A cycloaliphatic epoxy/acidic anhydride system incorporating short carbon fibers (SCF) and short glass fibers (SGF) was fabricated and thermal/mechanical properties were characterized. At low filler content both SCF- and SGF-reinforced composites showed a similar decrease in coefficient of thermal expansion (CTE), measured by a thermomechanical analyzer, with increasing loadings, above which SCF became more effective than SGF at reducing the CTE. Experimental CTE data for the SCF-reinforced composites is best described by the rule of mixtures at lower SCF contents and by the Craft-Christensen model at higher SCF contents. Storage modulus (E') at $30^{\circ}C$ and $180^{\circ}C$ was greatly enhanced for short fiber-filled composites compared to unfilled specimens, Scanning electron microscopy of the fracture surfaces indicated that the decreased CTE and the increased E' of the short fiber-reinforced composites resulted from good interfacial adhesion between the fibers and epoxy matrix.

Characterization of degree of alignment of polymer microfibers electrospun on a rotating water collector

  • Li, Shichen;Lee, Bong-Kee
    • Journal of Sensor Science and Technology
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    • v.30 no.3
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    • pp.125-130
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    • 2021
  • In this study, the degree of alignment of polymer microfibers produced by electrospinning using a rotating water collector was evaluated. Aligned micro- and nano-fibers are required in various practical applications involving anisotropic properties. The degree of fiber alignment has many significant effects; hence, and accurate quantitative analysis of fiber alignment is necessary. Therefore, this study developed a simple and efficient method based on two-dimensional fast Fourier transform, followed by ellipse fitting. As a demonstrative example, the polymer microfibers were electrospun on the rotating water collector as the alignment of microfibers can be easily controlled. The analysis shows that the flow velocity of the liquid collector significantly affects the electrospun microfiber alignment, that is, the higher the flow velocity of the liquid collector, the greater is the degree of microfiber alignment. This method can be used for analyzing the fiber alignment in various fields such as smart sensors, fibers, composites, and textile engineering.

A Study on the Basic Properties of Polymer Repair Mortar Using Waste Fishing Nets as Fibers (폐어망을 섬유로 활용한 폴리머 보수 모르타르의 기초 특성 연구)

  • Kim, Jin-Young;Park, Jong-Ho
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.83-84
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    • 2023
  • In this study, in order to utilize waste fishing net as a building materail, the possibility of replacing the fiber used in polymer repair mortar with waste fishing net fiber was confirmed. As for basic characteristics, flow, compressive strength, and flexural strength tests were performed to compare and analyze fiber performance, and the test results showed performance equal to or better than existing fibers.

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Synthesis of Hybrid Cation Exchange Fibers by E-Beam Preirradiation and Their Adsorption Properties for Metal Ions (E-Beam 전조사법을 이용한 복합양이온 교환섬유의 합성 및 금속이온 흡착특성)

  • Baek Ki-Wan;Nho Young-Chang;Hwang Taek-Sung
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.305-310
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    • 2006
  • The hybrid cation exchange fibers using graft copolymer of styrene onto PE/PP with PET trunk polymers were synthesized by electron beam preirradiation. The degree of grafting showed 123% value at 80% concentration of styrene. And also, amount of sulfonyl group in the ion exchanger was showed 3.3 mmol/g at 70% concentration of styrene and their values were constant after 70%. The tensile strength for fibers was lower than trunk fibers, and their value of ion exchange fibers were also below than copolymer. It was $0.206kgf/mm^2$ value. The breakthrough time for Ca and Mg ions of hybrid cation exchange fibers were increased with the increase in the pH and temperature. The breakthrough of Mg was slower the mixture than single Mg solution. Adsorption rate constant for Ca, Mg ions and maximum ion exchange capacity were 0.012, 0.011 L/mg.h and 47.06, 42.83 mg/g, and also, activation energies were 2169 and 1534 J/mol, respectively.

Adsorption Properties of Oxidized NO by Plasma Using Hybrid Anion-Exchange Fibers (복합음이온 교환섬유의 플라스마 산화 처리한 NO의 흡착특성)

  • Cho In-Hee;Kang Kyung-Seok;Hwang Taek-Sung
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.291-297
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    • 2006
  • In this study, adsorption properties of oxidized NO by plasma using aminated polyolefin-g-GMA hybrid anion exchange fibers were investigated. The maximum conversion of $NO_2$ by plasma was 49% at the conditions of 200 ppm NO, 10% $O_2$ and 30 L/min of flow rate. The adsorption content for N02 of hybrid anion exchange fibers increased with increasing the swelling ratio and the highest value was 1.5 g $H_2O/g$ IEF. The adsorption of $NO_2$ by hybrid anion exchange fibers were very fast until 10 min and reached its maximum value of 80% at 120 min. Ion exchange capacity of hybrid anion exchange fibers increased with increasing the swelling ratio and it showed the highest 0.6 mmol/g IEF values at L/D=5. The adsorption isotherm model for hybrid anion exchange fibers were closer to Freundlich than Langmuir adsorption isotherm model. It was shown that adsorption of the multi-molecular layer was dominant.

Preparation of Surface-Hydrolyzed Cellulose Acetate Fibers and Their Applications to LCD Rubbing Cloth (표면가수분해된 셀룰로오스 아세테이트 섬유의 제조 및 LCD 러빙포로의 응용)

  • Kim, Hyun-Sun;Kim, Young Ho
    • Polymer(Korea)
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    • v.37 no.1
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    • pp.52-60
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    • 2013
  • Partially hydrolyzed cellulose acetate (CA) fibers were prepared by treating CA fibers in aqueous $Na_2CO_3$ solutions of various concentrations. The deacetylation of CA fibers was confirmed through FTIR spectra and WAXD patterns. The hydrolysis was confined to the surface part of the CA fiber by controlling the treatment conditions. The resultant fibers had a sheath-core structure with a sheath component of regenerated cellulose and a core of non-hydrolyzed cellulose acetate. The SEM images of the surface-hydrolyzed CA fibers, the core of which was dissolved out using acetone as the solvent, showed that the sheath thickness increased with increasing alkaline concentration, indicating an increase in the hydrolyzed fiber, i.e., regenerated cellulose. Polarized FTIR analysis of the polyimide film rubbed with velvet fabrics of surface-hydrolyzed CA fibers showed that polyimide molecules were preferentially oriented to the rubbing direction.