• Clean Technology
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• v.27 no.3
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• pp.240-246
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• 2021

The waste etching solution for chip on film (COF) contained about 3.5% copper, and it was recovered through cementation using iron samples. The effect of cementation with plate, chip, and powder iron samples was investigated. The molar ratio (m/r) of iron to copper was used as a variable in order to increase the recovery rate of copper. As the molar ratio increased, the copper content in the solution rapidly decreased at the beginning of the cementation reaction. Before and after the reaction, the copper content of the solution was determined by Inductively Coupled Plasma (ICP) using copper concentration according to time. After cementation at room temperature for 1 hour, the recovery rate of copper had increased the most in the iron powder sample, having the largest specific surface area of the samples, followed by the chip and plate samples. The recovered copper powder was characterized for its crystalline phase, morphology, and elemental composition by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Energy-dispersive X-ray spectroscopy (EDS), respectively. Copper and unreacted iron were present together in the iron powder samples. The optimum condition for recovering copper was obtained using iron chips with a molar ratio of iron to copper of 4 giving a recovery rate of about 98.4%.

• Journal of the Korean Geosynthetics Society
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• v.19 no.4
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• pp.21-32
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• 2020

As the global large-scale infrastructure construction market expands, the construction of civil engineering structures in extreme environments such as cold or hot regions is being planned or constructed. Accordingly, the construction of the pile foundation is essential to secure the bearing capacity of the upper structure, but there is a concern about loss of stability and function of the pile foundation due to the possibility of ground deformation in extreme cold and hot regions. Therefore, in this study, a new type of pile foundation is developed to respond with the deformation of the ground, and the ground deformation that can occur in extreme cold and hot region is largely divided into heaving and settlement. The new type of pile foundation is a form in which a cylinder capable of shrinkage and expansion is inserted inside the steel pipe pile, and the effect of the cylinder during the heaving and settlement process was analyzed numerically. As a result of the numerical analysis, the ground heaving caused excessive tensile stress of the pile, and the expansion condition of the cylinder shared the tensile stress acting on the pile and reduced the axial stress acting on the pile. Ground settlement increased the compressive stress of the pile due to the occurrence of negative skin friction. The cylinder must be positioned below the neutral point and behave in shrinkage for optimum efficiency. However, the amount and location of shrinkage and expansion of cylinder must comply with the allowable displacement range of the upper structure. It is judged that the design needs to be considered.

• Applied Chemistry for Engineering
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• v.32 no.3
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• pp.320-325
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• 2021

In this study, an optimization for the production of water emulsion was designed by adding an extract of wheat sprout, which is known to contain a large amount of antioxidants. The central composite design of reaction surface analysis method (CCD-RSM) was used for the optimization process. The amount of emulsifier, emulsification time, and added amount of wheat sprout extract were selected as independent variables based on our preliminary experiments. The mean droplet size (MDS), viscosity, and emulsion stability index (ESI) were set as the responses to evaluate the stability of the emulsion. For each independent variable, the P-value and coefficient of determination were evaluated to verify the reliability of the experiments. From the result of CCD-RSM, optimum conditions for the emulsification were determined as 23.6 min, 7.7 wt.%, and 3.9 wt.% for the emulsification time, amount of emulsifier, and amount of sprout, respectively. From the optimized condition obtained, MDS, viscosity, and ESI after 7 days from reaction were estimated as 252.3 nm, 616.7 cP, and 88.7%, respectively. The overall satisfaction was 0.9137, which supported the validity of the experiments, and the error rate was measured at 0.5% or less by advancing the experiments. Therefore, an optimized process for producing an emulsion by adding the malt extract was designed by the CCD-RSM.

• Applied Chemistry for Engineering
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• v.32 no.3
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• pp.283-289
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• 2021

Adsorption characteristics of carbol fuchsin (CF) dye by coal-based activated carbon (CAC) were investigated using pH, initial concentration, temperature and contact time as adsorption variables. CF dissociates in water to have a cation, NH₂⁺, which is bonded to the negatively charged surface of the activated carbon in the basic region by electrostatic attraction. Under the optimum condition of pH 11, 96.6% of the initial concentration was adsorbed. Isothermal adsorption behavior was analyzed using Langmuir, Freundlich, Temkin and Dubinin-Radushkevich models. Langmuir's equation was the best fit for the experimental results. Therefore, the adsorption mechanism was expected to be adsorbed as a monolayer on the surface of activated carbon with a uniform energy distribution. From the evaluated Langmuir's dimensionless separation coefficients (R_L = 0.503~0.672), it was found that CF can be effectively treated by activated carbon. The adsorption energies determined by Temkin and Dubinin-Radushkevich models were E = 15.31~7.12 J/mol and B = 0.223~0.365 kJ/mol, respectively. Therefore, the adsorption process was physical (E < 20 J/mol, B < 8 kJ/mol). The experimental result of adsorption kinetics fit better the pseudo second order model. In the adsorption reaction of CF dye to CAC, the negative free energy change increased as the temperature increased. It was found that the spontaneity also increased with increasing temperature. The positive enthalpy change (40.09 kJ/mol) indicated an endothermic reaction.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.5
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• pp.95-102
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• 2020

For the purpose of developing a PE fiber-reinforced highly ductile cementitious composite having high tensile strain capacity more than 2% under the condition of containing aggregates with large particle size, this study investigated the tensile behavior of composites according to the particle size and distribution of aggregates in the composite. Compared with the mixture containing silica sand of which particle size is less than 0.6 mm, mixtures containing river sand and/or gravel with the maximum particle size of 2.36 mm, 4.75 mm, 5.6 mm, 6.7 mm were considered in the experimental design. The particle size distributions of aggregates were adjusted for the optimized distribution curves obtained from modified A&A model by blending different sizes of aggregates. All the mixtures presented clear strain-hardening behavior in the direct tensile tests. The mixtures with the blended aggregates to meet the optimum curves of aggregate size distributions showed higher tensile strain capacity than the mixture with silica sand. It was also found that the tensile strain capacity was improved as the maximum size of aggregate increased which resulted in wider particle size distribution. The mixtures with the maximum size of 5.6 mm and 6.7 mm presented very high tensile strain capacities of 4.83% and 5.89%, respectively. This study demonstrated that it was possible to use coarse aggregates in manufacturing highly ductile fiber-reinforced cementitous composite by adjusting the particle size distribution.

• Journal of the Korean Institute of Gas
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• v.26 no.1
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• pp.1-6
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• 2022

This paper is a purpose to study and analyze the engine starting failure examples for LPG car. The first example, the researcher verified the phenomenon that didn't supply the fuel because of filter clogging by fine alien substance in the gas valve line when he inspected the emergency cutting valve. The second example, there was no the influence of gas leakage when the solenoid operated at first. But the damage part of solenoid assemblying face wad downed a durability according to running a valve. Eventually, the researcher checked on the phenomenon of engine stopping by no gas feeding in solenoid because of leaking of gas. The third example, the researcher sought that the wiring sheaths of connector fin between EGR 10A fuse and LPG switch verified the burn-out phenomenon due to the bad contacting as tension damage produced the overheating. Therefore, the manager of a car has to do pre-inspection no producing electric failure and he must maintain his car with optimum condition.

• Journal of Practical Agriculture & Fisheries Research
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• v.23 no.2
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• pp.51-61
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• 2021

As a result of examining the germination rate between ginseng varieties, Jagyongjong varieties had the highest germination rate, and Yeonpung. had the lowest germination rate. In the ginseng seed germination rate experiment, the highest germination rate and growth condition were shown in artificial soil conditions of the ratio of Peatmoss 6.5: Pearlite 2: Masato 1.5. Good soil conditions require adequate soil moisture forces during the incubation period. The cultivation of ginseng medicinal crops requires optimal soil breathability, soil pH, and soil stabilization, which are important for root breathing. Microbial activity in the soil has a great influence on the growth of ginseng. The optimum pH of the soil for ginseng cultivation is 5.0-5.5 As a result of the experiment, the soil remained in an appropriate range after a month. In general, when the EC concentration value of the soil for ginseng cultivation is 0.2 mS/cm or more, growth deteriorates, and when the EC concentration value is 0.5 mS/cm or more, concentration obstacles such as root decay occur. As a result of the analysis, the higher the concentration value of EC, the more likely it is to interfere with ginseng growth.

• Resources Recycling
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• v.30 no.1
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• pp.60-65
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• 2021

The recycling of titanium turning scraps requires the removal of cutting oil and other contaminants remaining on the surface. In this study, an experiment was conducted in which titanium scraps were cleaned by a combination of ultrasonic immersion-steam cleaning and subsequent drying at high temperature. To determine the removal mechanism of cutting oil, the contact angle between titanium surface and cutting oil was measured. The result confirmed the optimum condition of the immersion solution of the titanium turning scraps. In the case of immersion cleaning of Na4P2O7 aqueous solution, the degree of carbon removed in the cutting oil was the highest at 50℃, and it was confirmed that the carbon content obtained from the combination of steam cleaning and ultrasonic immersion-steam cleaning was lower than that from steam cleaning after ultrasonic immersion. The oxidation and decomposition behaviors of cutting oil were investigated using Thermogravimetric analysis (TGA) and the result was applied in the high temperature drying process. From the results of the high temperature drying tests, it was concluded that 200℃ is the optimal drying temperature.

• Journal of the Korean Geotechnical Society
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• v.38 no.12
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• pp.113-123
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• 2022

The required density relationship according to the press pressure of the floating die method and the homogeneity of the density distribution in the buffer block was evaluated to analyze the manufacturing characteristics of engineering scale bentonite-sand buffer blocks. In addition, the thermal conductivity was measured and compared with that of the pure bentonite buffer block to evaluate the level of thermal conductivity performance improvement of the bentonite-sand buffer material. As a result, it was confirmed that the standard deviation of dry density decreased to 0.011 and showed a homogeneous density distribution under the condition of press pressure greater than 400 kg/cm². Furthermore, as a result of the thermal conductivity test, the thermal conductivity of the buffer with optimum moisture content conditions was 1.345 and 1.261 W/(m·K) under the press pressure of 400 and 600 kg/cm², respectively. It increased by 16.1% and 11.0% compared to the pure bentonite buffer material. Based on the results of this study, it is judged that it can be used as fundamental data for manufacturing a homogeneous bentonite-sand buffer block on an engineering scale.

• Clean Technology
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• v.28 no.3
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• pp.227-231
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• 2022

The demand for high-voltage power devices is rising in various industries, but especially in the transportation industry due to autonomous driving and electric vehicles. IGBT module parts of 3.3 kV or more are used in the power propulsion control device of electric vehicles, and the procurement of these parts for new construction and maintenance is increasing every year. In addition, research to optimize high-voltage IGBT parts is urgently required to overcome their very high technology entry barrier. For the development of high-voltage IGBT devices over 3.3 kV, the resistivity range setting of the wafer and the optimal conditions for major unit processes are important variables. Among the manufacturing processes to secure the optimal junction depth, the optimization of the diffusion process, which is one step of the unit process, was examined. In the diffusion process, the type of gas injected, the injection time, and the injection temperature are the main variables. In this study, the range of wafer resistance (Ω cm) was set for the development of high voltage IGBT devices through unit process simulation. Additionally, the well drive in (WDR) condition optimization of the diffusion process according to temperature was studied. The junction depth was 7.4 to7.5 ㎛ for a ring pattern width of 23.5 to25.87 ㎛, which can be optimized for supporting 3.3 kV high voltage power devices.