• Title/Summary/Keyword: low-temperature oxide

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The Study of nc-ZnO/ZnO Field-effect Transistors Fabricated by Spray-pyrolysis Process (스프레이 공정을 이용한 nc-ZnO/ZnO 전계효과트랜지스터 제작 및 특성 분석)

  • Cho, Junhee
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.3
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    • pp.22-25
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    • 2022
  • Metal oxide semiconductor (MOS) based on spray-pyrolysis deposition technique has attracted large attention due to simple and low-cost processibility while preserving their intrinsic optical and electrical characteristics. However, their high process temperature limits practical applications. Here, we demonstrated the nc-ZnO/ZnO field-effect transistors (FETs) via spray-pyrolysis as incorporating ZnO nanocrystalline nanoparticles into typical ZnO precursor. The nc-ZnO/ZnO FETs exhibit good quality of electrical properties. Our experiments reveal that nc-ZnO in active layer enhance electrical characteristics.

Electrochemical Properties of Metal Aluminum and Its Application (금속알루미늄의 전기화학적 성질과 응용)

  • Tak, Yongsug;Kang, Jinwook;Choi, Jinsub
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.335-342
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    • 2006
  • Metal aluminum, of which has a low standard reduction potential, participates in the electrochemical oxidation reaction and results in the structural change and accompanying property variation of aluminum and its oxide film. Aluminum was electrochemically etched in acid solution and the surface area was magnified by the formation of high density etch pits. Etched aluminum was covered with a compact and dense dielectric oxide film by anodization and applied to the capacitor electrode. Anodization of aluminum in acid solution at low temperature makes a nanoporous aluminum oxide layer which can be used for the fabrication template of nanostructural materials. Electrochemical characteristics of aluminum turn the metal aluminum into functional materials and it will bring the diverse applications of metal aluminum.

Characterization of the Galvanizing Behavior Depending on Annealing Dew Point and Chemical Composition in Dual-Phase Steels

  • Shin, K.S.;Park, S.H.;Jeon, S.H.;Bae, D.C.;Choi, Y.M.
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.247-253
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    • 2010
  • The characteristics of selective oxidation prior to hot-dip galvanizing with the annealing atmosphere dew point and chemical composition in dual-phase steels and their effect on the inhibition layer formation relevant to coating adhesion have been studied using a combination of electron microscopic and surface analytical techniques. The annealed and also galvanized samples of 3 kinds of Si/Mn ratios with varied amounts of Si addition were prepared by galvanizing simulator. The dew point was controlled at soaking temperature $800^{\circ}C$ in 15%$H_2$ -85%$N_2$ atmosphere. It was shown that good adhesion factors were mainly uniformity of oxide particle distribution of low number density and low Si/Mn ratio prior to hot-dip galvanizing. Their effect was the greatly reduced coating bare spots and the formation of uniform inhibition layer leading to good adhesion of Zn overlay. The mechanism of good adhesion is suggested by two processes: the formation of inhibition layer on the oxide free surface uncovered with no $SiO_2$-containing particles in particular, and the inhibition layer bridging of oxide particles. The growth of inhibition layer was enhanced markedly by the delayed reaction of Fe and Al with the increase of Si/Mn ratio.

Characteristics of oxynitride films grown by PECVD using $N_2O$ gas ($N_2O$가스를 사용하여 PECVD로 성장된 Oxynitride막의 특성)

  • 최현식;이철인;장의구
    • Electrical & Electronic Materials
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    • v.9 no.1
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    • pp.9-17
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    • 1996
  • Plasma enhanced chemical vapor deposition (PECVD) allows low temperature processing and so it is widely used, but it causes instability of devices due to serious amount of impurities within the film. In this paper, electrical and chemical characteristics of the PECVD oxynitride film formed by different N$_{2}$O to N$_{2}$O+NH$_{3}$ gas ratio is studied. It has been found that hydrogen concentration of PECVD oxynitride film was decreased from 4.25*10$^{22}$ [cm$^{-2}$ ] to 1.18*10$^{21}$ [cm$^{-2}$ ] according to the increase of N$_{2}$O gas. It was also found that PECVD oxynitride films have low trap density in the oxide and interface in comparison with PECVD nitroxide films, and has higher refractive index and capacitance than oxide films. In particular, oxynitride film formed in gas ratio of N$_{2}$O/(N$_{2}$O+NH$_{3}$)= 0.88 shows increased capacitance and decreased leakage current due to small portion of hydrogen in oxide and the accumulation of nitrogen about 4[atm.%] at the interface.

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Direct Growth of Graphene at Low Temperature for Future Device Applications

  • Kim, Bum Jun;Nasir, Tuqeer;Choi, Jae-Young
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.203-223
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    • 2018
  • The development of two-dimensional graphene layers has recently attracted considerable attention because of its tremendous application in various research fields. Semi-metal materials have received significant attention because of their excellent biocompatibility as well as distinct physical, chemical, and mechanical properties. Taking into account the technical importance of graphene in various fields, such as complementary metal-oxide-semiconductor technology, energy-harvesting and -storage devices, biotechnology, electronics, light-emitting diodes, and wearable and flexible applications, it is considered to be a multifunctional component. In this regard, material scientists and researchers have primarily focused on two typical problems: i) direct growth and ii) low-temperature growth of graphene. In this review, we have considered only cold growth of graphene. The review is divided into five sections. Sections 1 and 2 explain the typical characteristics of graphene with a short history and the growth methods adopted, respectively. Graphene's direct growth at low temperatures on a required substrate with a well-established application is then precisely discussed in Sections 3 and 4. Finally, a summary of the review along with future challenges is described in Section 5.

Combustion and Emissions Characteristics of a Diesel Engine with the Variation of the HP/LP EGR Proportion (고압/저압 EGR 공급 비율에 따른 디젤 엔진의 연소 및 배기 특성)

  • Park, Youngsoo;Bae, Choongsik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.7
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    • pp.90-97
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    • 2014
  • The effects of high pressure and low pressure exhaust gas recirculation (HP/LP EGR) portion on diesel engine combustion and emissions characteristics were investigated in a 2.2 L passenger-car diesel engine. The po3rtion of HP/LP EGR was varied from 0 to 1 while fixing the mass flow rate of fresh air. The intake manifold temperature was lowered with the increasing of the portion of LP EGR, which led to the retardation of heat release by pilot injection. The lowered intake manifold temperature also resulted in low nitrogen oxide (NOx) emissions due to decreased in-cylinder temperature and prolonged ignition delay, however, the carbon monoxide (CO) emission showed opposite trend to NOx emissions. The brake specific fuel consumption (BSFC) was decreased as the portion of LP EGR increased due to lowered exhaust manifold pressure by wider open of turbocharger vane. Consequently, the trade-off relationship between NOx and BSFC could be improved by increasing the LP EGR portion.

The effect of sintering temperature on the electrical properties of ZnO ceramics (ZnO세라믹스의 소결온도가 전기적 특성에 미치는 영향)

  • 김용혁;이덕출
    • Electrical & Electronic Materials
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    • v.8 no.1
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    • pp.40-47
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    • 1995
  • Electrical properties of ZnO ceramics based on Bi oxide was investigated in relation to sintering temperature. In the temperature range >$1150^{\circ}C$ to >$1350^{\circ}C$ the grain size increased from 9.mu.m to 20.mu.m when the sintering temperature was raised. The leakage current in the low voltage range increased as the potential barrier decreases, which is caused by increasing the grain size at high temperature. The dielectric characteristics of the ZnO ceramics was also affected by sintering temperature. Large dielectric constant was attributed, to the grainboundary layer of polycrystalline ZnO ceramics and decreasing grainboundary width. The variation of breakdown voltage with sintering temperature was attributed to the change of the donor concentration in the ZnO grain and grain size. The results showed that breakdown voltage increased decreasing grain size and donor concentration. Nonohmic coefficient was associated with the lower breakdown voltage per grainboundary layer due to the grain growth and higher donor concentration.

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Electrothermal Analysis for Super-Junction TMOSFET with Temperature Sensor

  • Lho, Young Hwan;Yang, Yil-Suk
    • ETRI Journal
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    • v.37 no.5
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    • pp.951-960
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    • 2015
  • For a conventional power metal-oxide-semiconductor field-effect transistor (MOSFET), there is a trade-off between specific on-state resistance and breakdown voltage. To overcome this trade-off, a super-junction trench MOSFET (TMOSFET) structure is suggested; within this structure, the ability to sense the temperature distribution of the TMOSFET is very important since heat is generated in the junction area, thus affecting its reliability. Generally, there are two types of temperature-sensing structures-diode and resistive. In this paper, a diode-type temperature-sensing structure for a TMOSFET is designed for a brushless direct current motor with on-resistance of $96m{\Omega}{\cdot}mm^2$. The temperature distribution for an ultra-low on-resistance power MOSFET has been analyzed for various bonding schemes. The multi-bonding and stripe bonding cases show a maximum temperature that is lower than that for the single-bonding case. It is shown that the metal resistance at the source area is non-negligible and should therefore be considered depending on the application for current driving capability.

Syngas Production Based on Co-electrolysis of CO2 and H2O in Solid Oxide Electrolysis Cell (고체 산화물 CO2-H2O 공전해 기반 합성가스 생산 기술 )

  • NAMGI JEON;SANGHYEOK LEE;SANGKUK KIM;CHIKYU AHN;JIN SOO AHN
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.2
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    • pp.140-145
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    • 2024
  • High temperature co-electrolysis of H2O-CO2 mixtures using solid oxide cells has attracted attention as promising CO2 utilization technology for production of syngas (H2/CO), feedstock for E-fuel synthesis. For direct supply to E-fuel production such as hydrocarbon and methanol, the outlet gas ratio (H2/CO/CO2) of co-electrolysis should be controlled. In this work, current voltage characteristic test and product gas analysis were carried out under various reaction conditions which could attain proper syngas ratio.

A Study on Reverse-water Gas Shift Reaction in Solid Oxide Water Electrolysis Cell-stack for CO2 Reduction (CO2 저감을 위한 고체산화물 수전해 스택의 역수성가스 전환 반응 고찰)

  • SANGKUK KIM;NAMGI JEON;SANGHYEOK LEE;CHIKYU AHN;JIN SOO AHN
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.2
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    • pp.162-167
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    • 2024
  • Fossil fuels have been main energy source to people. However, enormous amount of CO2 was emitted over the world , resulting in global climate crisis today. Recently, solid oxide electrolyzer cell (SOEC) is getting attention as an effective way for producing H2, a clean energy resource for the future. Also, SOEC could be applicable to reverse water-gas shift reaction process due to its high-temperature operating condition. Here, SOEC system was utilized for both H2 production and CO2 reduction process, allowing product gas composition change by controlling operating conditions.