• 한국수소및신에너지학회논문집
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• 제32권6호
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• pp.497-505
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• 2021

Water management is essential to improve the performance of proton exchange membrane fuel cells. This study targets to understand the characteristics of water concentration in proton exchange membrane fuel cells at a dynamic load variable environment. The fuel cell model was developed to simulate nonlinear water transport in membrane by the MATLAB/Simulink^® (MathWorks, Natick, MA, USA) platform, and it calculates water content in membrane, ionic conductivity, and predicts fuel cell performance through one-dimensional analysis.

• 한국수소및신에너지학회논문집
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• 제24권4호
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• pp.311-319
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• 2013

A clear understanding on cell voltage-reversal behavior due to local hydrogen starvation in a stack is of paramount importance to operate the fuel cell vehicle (FCV) stably since it affects significantly the cell performance and durability. In the present study, a novel experimental method to simulate the local cell voltage-reversal behavior caused by local hydrogen starvation, which typically occurs only one or several cells out of several hundred cells in a stack of FCV, has been proposed. Contrary to the conventional method of overall fuel starvation, the present method of local hydrogen starvation caused the local cell voltage-reversal behavior in a stack very well. Degradation of both membrane electrode assembly (i.e., pin-hole formation) and gas diffusion layer due to an excessive exothermic heat under voltage-reversal condition was also observed clearly.

• 한국수소및신에너지학회논문집
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• 제24권6호
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• pp.467-471
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• 2013

In present work, optimized the manufacturing process of anode-supported tubular SOFCs cell and stack were studied. For this purpose, we first developed a high performance tubular SOFC cell, and then made electrical connection in series to get high voltage. The gas sealing was established by attaching single cells to alumina jig with ceramic bond. Through these process, we can obtain such high OVP as around 15V, which means that the electrical connection and gas sealing were optimized. Finally we developed a new tubular SOFC stack which shows a maximum power of 65W @ $800^{\circ}C$.

• 전기화학회지
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• 제6권1호
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• pp.23-27
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• 2003

본 연구는 휴대용 전원으로 사용 가능성이 높은 소형 직접메탄을 연료전지의 단위전지와 모노폴라 스택의 운전특성을 살펴본 것이다. 공기와 메탄올이 외부에서 강제로 공급되지 않는 수동형(passive)의 운전조건에서 최적 메탄을 농도는 4M이었으며, 촉매 담지량도 $8mg/cm^2$에서 가장 높은 성능을 나타내었다. 상온 상압 수동형 조건에서 얻은 최대 성능은 $55mW/cm^2$이었다. 6개의 단전지로 이루어진 모노폴라 스택에서는 셀간의 성능차이는 크게 나타나지 않았으며, 출력밀도는 $37mW/cm^2$이고, 1W의 출력을 보였다. 또한, 16셀로 구성된 2.4W급 모노폴라 스택을 제작하여 모형 자동차에 장착하고 시범 운전을 성공적으로 수행하였다.

• Bulletin of the Korean Chemical Society
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• 제25권6호
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• pp.813-818
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• 2004

A systematic study of microbial fuel cells comprised of thermophilic Bacillus licheniformis and Bacillus thermoglucosidasius has been carried out under various operating conditions. Substantial amount of electricity was generated when a redox mediator was used. Being affected by operation temperature, the maximum efficiency was obtained at 50$^{\circ}C$ with an open circuit voltage of ca. 0.7 V. While a small change around the optimum temperature did not make much effect on the cell performance, the rapid decrease in performance was observed above 70$^{\circ}C$. It was noticeable that fuel cell efficiency and discharge pattern strongly depended on the kind of carbon sources used in the initial culture medium. In the case of B. thermoglucosidasius, glucose alone was utilized constitutively as a substrate in the microbial fuel cell irrespective of used carbons sources. When B. licheniformis was cultivated with lactose as a carbon source, best charging characteristics were recorded. Trehalose, in particular, showed 41.2% coulombic efficiency when B. thermoglucosidasius was cultured in a starch-containing medium. Relatively good repetitive operation was possible with B. thermoglucosidasius cells up to 12 cycles using glucose as a carbon source, when they were cultured with lactose as an initial carbon source. This study demonstrates that highly efficient thermophilic microbial fuel cells can be constructed by a pertinent modulation of the operating conditions and by carefully selecting carbon sources used in the initial culture medium.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2005년도 수소연료전지공동심포지움 2005논문집
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• pp.75-78
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• 2005

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2001년도 연료전지심포지움 2001논문집
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• pp.9-10
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• 2001

• 한국수소및신에너지학회논문집
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• 제20권4호
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• pp.309-316
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• 2009

The effect of gas diffusion layers (GDLs) on the freeze/thaw condition durability in polymer electrolyte fuel cells (PEFCs) were investigated. For this purpose, three kinds of GDLs, such as, felt, paper and cloth types with different basic properties have been first prepared, then the changes in the properties and performance of cells was observed during the freeze/thaw cycles ranging from -30 to $70^{\circ}C$. The performance evaluations were conducted by using the single cells consisting of different GDLs. The performance degradation and the cell resistance increase could be directly correlated. The physical destruction of electrode was shown by SEM analysis. The mechanically supporting ability on the interface between the cell components can help enhancing the durability of PEFCs in the freeze/thaw condition.

• Journal of Electrochemical Science and Technology
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• 제11권2호
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• pp.132-139
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• 2020

Solid oxide fuel cells (SOFCs) are among one of the promising technologies for efficient and clean energy. SOFCs offer several advantages over other types of fuel cells under relatively high temperatures (600℃ to 800℃). However, the thermal behavior of SOFC stacks at high operating temperatures is a serious issue in SOFC development because it can be associated with detrimental thermal stresses on the life span of the stacks. The thermal behavior of SOFC stacks can be influenced by operating or material properties. Therefore, this work aims to investigate the effects of the thermal conductivity of each component (anode, cathode, and electrolyte) on the thermal behavior of samarium-doped ceria-based SOFCs at intermediate temperatures. Computational fluid dynamics is used to simulate SOFC operation at 600℃. The temperature distributions and gradients of a single cell at 0.7 V under different thermal conductivity values are analyzed and discussed to determine their relationship. Simulations reveal that the influence of thermal conductivity is more remarkable for the anode and electrolyte than for the cathode. Increasing the thermal conductivity of the anode by 50% results in a 23% drop in the maximum thermal gradients. The results for the electrolyte are subtle, with a ~67% reduction in thermal conductivity that only results in an 8% reduction in the maximum temperature gradient. The effect of thermal conductivity on temperature gradient is important because it can be used to predict thermal stress generation.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.87.2-87.2
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• 2011

Many type of fuel cell stacks have been developed to improve the efficiency of reactants usage. The cascade type fuel cell stack using dead end operation is able to attain above 99% usage of hydrogen and oxygen. It is sectionalized to several parts and the residual reactants which are used previous parts would be supplied again to next parts which have less number of cells in dead end operation stack. The oversupply of reactants which is usually 120%~150% of the theoretical amount to generate current for preventing the flooding effect could be provided to each part except the last one. The final section which is called monitoring cells is supposed to be supplied insufficient the fuel or oxidant that would have some accumulated inert gas from former parts. It makes some voltage drop in the part and the fresh reactants must be supplied to the part for recovering it by venting the residual gas. So the usage of fuel and oxidant is depend on the time and frequency of opening valves for venting of residual gas and it is important to optimize the vent logic for achieving higher usage of hydrogen and oxygen. In this research, many experiments are performed to find optimal condition by evaluating the effect of time and frequency under several power conditions using over 100kW class fuel cell module. And the characteristics of the monitoring cells are studied to know the proper cell voltage which decide the condition of opening the vent valve for stable performance of the cascade type fuel cell module.