• 한국수소및신에너지학회논문집
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• 제3권2호
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• pp.45-54
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• 1992

An applicability microencapsulation, using electroless copper plating, of hydrogen storage alloy powder as an anode material for nickel-hydrogen secondary batteries was investigated. Alloys employed were $LaNi_{4.7}Al_{0.3}$ and $MmNi_{4.5}Al_{0.5}$(Mm=mischmetal) which have an appropriate equilibrium pressure and capacity. The microencapsulation of the alloy powder was found to accelerate initial activation of electrodes and to increase capacity which is about 285mAh/g for $LaNi_{4.7}Al_{0.3}$. In addition, other charge and discharge characteristics, such as polarization and flatness of charge and discharge potential, were improved due to the role of copper layer as a microcurrent collector and an oxidation barrier of the alloy powder. $MmNi_{4.5}Al_{0.5}$ alloy showed lower capacity than $LaNi_{4.7}Al_{0.3}$ because of higher equilibrium pressure. Cyclic characteristics of both alloys were somewhat poor because of mainly shedding and partial oxidation of alloy powder during the cycling. However, it was considered that the microencapsulation method is effective to improve the performances of the hydrogen storage alloy electrodes.

• 한국표면공학회지
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• 제30권4호
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• pp.262-271
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• 1997

Nickel-matal hydride(Ni-MH) batteries are receiving attention as non-pollunting. high performance rehargeable energy stoage system. The performance of Ni-Mh is significantly influenced by the hydrogen storage alloy materiels used as an anode material. Recently, having discharge capacities higher than the $AB_5$-type hydrogen storage alloys, the Zr-based $AB_2$-Type hydrogen storage alloys has remaining problems regarding cycle life and self-dischareg. These problems need to be solved by improvements in the alloy design and/or surface treatment. This work investiggates the effects the effects of surface property by fluorination on $Zr_{0.7}Ti_{0.3}V_{0.4}Mn_{0.4}Ni{1.2}$ composittion $AB_2$-Type hydrogen storage alloys. EPMA, SEM and AES techniques were used for surface analysis, and the crystal structure was characterized by constant current cycling test and potential sweep methods. Fluorination was found to be effective when La-was incorporated into the alloy, and has unique morphology, higher reactivity, and at the same time formed a protective film. Through, fluorination, the cycle life of an electrode was found to increase significantly, charge/discharge characteristics of the electrode the potential difference between the charge/discharge plateau, i.e polarization(overpotential)were improved.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제10권10호
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• pp.4703-4723
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• 2016

The verification of data integrity is an urgent topic in remote data storage environments with the wide deployment of cloud data storage services. Many traditional verification algorithms focus on the block-oriented verification to resolve the dispute of dynamic data integrity between the data owners and the storage service providers. However, these algorithms scarcely pay attention to the data verification charge and the users' verification experience. The users more concern about the availability of accessed files rather than data blocks. Moreover, the data verification charge limits the number of checked data in each verification. Therefore, we propose a mixed verification protocol to verify the data integrity, which rapidly locates the corrupted files by the file-oriented verification, and then identifies the corrupted blocks in these files by the block-oriented verification. Theoretical analysis and simulation results demonstrate that the protocol reduces the cost of the metadata computation and transmission relative to the traditional block-oriented verification at the expense of little cost of additional file-oriented metadata computation and storage at the data owner. Both the opportunity of data extracted and the scope of suspicious data are optimized to improve the verification efficiency under the same verification cost.

• Journal of Electrical Engineering and Technology
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• 제12권5호
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• pp.2043-2050
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• 2017

This paper presents two MPC (Model Predictive Control) based charging and discharging algorithms of BESS (Battery Energy Storage System) for capacity firming of wind generation. To deal with the intermittency of the output of wind generation, a single BESS is employed. The proposed algorithms not only make the output of combined systems of wind generation and BESS track the predefined reference, but also keep the SoC (State of Charge) of BESS within its physical limitation. Since the proposed algorithms are both presented in simple if-then statements which are the optimal solutions of related optimization problems, they are both easy to implement in a real-time system. Finally, simulations of the two strategies are done using a realistic wind farm library and a BESS model. The results on both simulations show that the proposed algorithms effectively achieve capacity firming while fulfilling all physical constraints.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 제39회 하계학술대회
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• pp.994-995
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• 2008

It is possible to suppress voltage drops, power loading fluctuations and regeneration power lapses for DC railway systems by applying an energy storage system. A electric double layer capacitor (EDLC) of the rapid charge/discharge type has been developed and used in wide ranges. It has a long life, high efficiency and maintenance free/low pollution features as a new energy storage element. In this paper, an efficient charge and discharge control method of a bidirectional DC-DC converter using the supercapacitor is proposed.

• Transactions on Electrical and Electronic Materials
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• 제8권2호
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• pp.97-102
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• 2007

The charging/discharging characteristics of electric double layer capacitors (EDLCs) for an electric power storage device application were investigated. The specific area of the carbonaceous electrode surface by the BET method was in the range of $1800{\sim}2000\;m^2/g$. The charge distributions during charging and discharging were measured by means of a pulsed-electro-acoustic (PEA) method, and the voltage characteristics of EDLCs connected to solar cells were evaluated. The results showed that the distributions of positive and negative charges were spatially uneven, which was due to the mobility of the positive and negative charges in the carbonaceous electrode surface of the EDLCs. The charge accumulation region concentrated on central part of the carbonaceous electrode and the required times for charging and discharging were almost same.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2008년도 하계학술대회 논문집
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• pp.97-99
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• 2008

It is possible to suppress voltage drops, power loading fluctuations and regeneration power lapses for DC railway systems by applying an energy storage system. Recently the electric double layer capacitor (EDLC) of the rapid charge/discharge type has been developed and used in wide ranges. The on board energy storage system with supercapacitor for railway vehicles presented in this paper seems to be a reliable technical solution with an enormous energy saving potential. In this paper, an efficient charge and discharge control method of a bidirectional DC-DC converter using the supercapacitor is proposed.

• Transactions on Electrical and Electronic Materials
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• 제15권2호
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• pp.73-76
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• 2014

$Pt/Al_2O_3/La_2Si_5O_x/SiO_2/Si$ charge trap memory capacitors were prepared, in which the $La_2Si_5O_x$ film was used as the charge trapping layer, and the effects of post annealing atmospheres ($NH_3$ and $N_2$) on their memory characteristics were investigated. $La_2O_3$ nanocrystallites, as the storage nodes, precipitated from the amorphous $La_2Si_5O_x$ film during rapid thermal annealing. The $NH_3$ annealed memory capacitor showed higher charge storage performances than either the capacitor without annealing or the capacitor annealed in $N_2$. The memory characteristics were enhanced because more nitrogen was incorporated at the $La_2Si_5O_x/SiO_2$ interface and interfacial reaction was suppressed after the $NH_3$ annealing treatment.

• 전기학회논문지
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• 제67권7호
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• pp.833-839
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• 2018

This paper presents an analysis and the methodology of optimal operation strategy of the ESS(Energy Storage System) for reduce electricity charges. Electricity charges consist of a basic charge based on the contract capacity and energy charge according to the power usage. In order to use electrical energy at minimal charge, these two factors are required to be reduced at the same time. QP(Quadratic Programming) is appropriate for minimization of the basic charge and LP(Linear Programmin) is adequate to minimize the energy charge. However, the integer variable have to be introduced for modelling of different charge and discharge efficiency of ESS PCS(Power Conversion System), where MILP(Mixed Integer Linear Programming) can be used. In this case, the extent to which the peak load savings is accomplished should be assumed before the energy charge is minimized. So, to minimize the electricity charge exactly, optimization is sequentially performed in this paper, so-called the Two Stage Hybird optimization, where the extent to which the peak load savings is firstly accomplished through optimization of basic charge and then the optimization of energy charge is performed with different charge and discharge efficiency of ESS PCS. Finally, the proposed method is analyzed quantitatively with other optimization methods.

• Transactions on Electrical and Electronic Materials
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• 제15권1호
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• pp.16-19
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• 2014

Charge trapping nonvolatile memory capacitors with $ZrO_2$ as charge trapping layer were fabricated, and the effects of post annealing atmosphere ($NH_3$ and $N_2$) on their memory storage characteristics were investigated. It was found that the memory windows were improved, after annealing treatment. The memory capacitor after $NH_3$ annealing treatment exhibited the best electrical characteristics, with a 6.8 V memory window, a lower charge loss ~22.3% up to ten years, even at $150^{\circ}C$, and excellent endurance (1.5% memory window degradation). The results are attributed to deep level bulk charge traps, induced by using $NH_3$ annealing.